• Title/Summary/Keyword: organic light emitting diode

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Synthesis of 5,6-Dihydro[1,10]phenanthroline Derivatives and Their Properties as Hole-Blocking Layer Materials for Phosphorescent Organic Light-Emitting Diodes

  • Lee, Hyo-Won;An, Jung-Gi;Yoon, Hee-Kyoon;Jang, Hyo-Sook;Kim, Nam-Gwang;Do, Young-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1569-1574
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    • 2005
  • To develop new hole-blocking materials for phosphorescent organic light-emitting diodes (PhOLEDs), 5,6-dihydro-2,9-diisopropyl-4,7-diphenyl[1,10]phenanthroline (1) and 5,6-dihydro-2,9-diisopropyl-4-(4-methoxyphenyl)-7-phenyl[1,10]phenanthroline (2) were synthesized. While the absorption spectrum of 1 is very similar to that of 2, the photoluminescence spectrum of 1 has the feature of the narrower and blue-shifted blueviolet emission at the peak of 356 nm compared to that of 2. The HOMO and LUMO energy levels of 1 and 2 were estimated from the measurement of cyclic voltammetry, and 1 has the appropriate levels for a holeblocking layer (HBL). The use of 1 as a HBL in a green PhOLED led to good efficiency of 23.6 cd/A at 4.4 mA/$cm^2$.

Characteristic Effects of Buffer Layers on Organic Light Emitting Devices

  • Park, Jae-Hoon;Lee, Yong-Soo;Kwak, Yun-Hee;Choi, Jong-Sun
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.43-48
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    • 2001
  • The stability and efficiency of organic light emitting devices are the most critical problems to be solved. The devices based on tris-8-(hydroxyquinoline) aluminum ($Alq_3$) and N,N-diphenyl-N,N-bis(3-methylphenyl)-1, 1-biphenyl-4,4-diamine (TPD) were used to study the effects of buffer layers on their characteristics. We have investigated the characteristic effects of CuPc (copper phthalocyanine) and pentacene buffer layers on the device characteristics, the (5${\sim}$20 nm thick) CuPc layers and the (10${\sim}$20 nm thick) pentacene layers were deposited. Efficiency was slightly improved and the turn-on voltages of the devices with the buffer layers were observed to have lower values than those of the devices without the buffer layers. It is believed that this result is attributed to the improvement of hole injection capability through the buffer layers into hole transport layer (HTL). We have also studied the atomic force microscopic images of the TPD layers deposited on the buffer layer and the bare ITO.

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Realization of Static Image on OLEO using Photoluminescence Degradation (PL Degradation을 활용한 OLED 소자의 사진 이미지 구현)

  • Suh, Won-Gyu;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.9
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    • pp.859-862
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    • 2008
  • We have realized static image on organic light emitting diodes (OLEDs) using photoluminescence degradation. Ultraviolet (UV) was irradiated to the glass side of device. UV power was 350 Wand the wavelength was 365 nm. The UV irradiation gives rise to the degradation of photoluminescence. Due to the degradation, the current density-voltage curve was shifted to the higher voltage side and the luminescence was also degraded by the current and photoluminescence drop. The negative imaged films were prepared to control the transmittance of UV. The UV light was passed through the film. By this method, the film image was transferred to the device with reversed image and the static image was realized on the OLED.

Conversion of Organic Carbon in Food Processing Wastewater to Photosynthetic Biomass in Photo-bioreactors Using Different Light Sources

  • Suwan, Duangkamon;Chitapornpan, Sukhuma;Honda, Ryo;Chiemchaisri, Wilai;Chiemchaisri, Chart
    • Environmental Engineering Research
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    • v.19 no.3
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    • pp.293-298
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    • 2014
  • An anaerobic photosynthetic treatment process utilizing purple non-sulfur photosynthetic bacteria (PNSB) was applied to the recovery of organic carbon from food processing wastewater. PNSB cells, by-product from the treatment, have high nutrition such as proteins and vitamins which are a good alternative for fish feed. Effects of light source on performance of anaerobic photosynthetic process were investigated in this study. Two bench-scale photo-bioreactors were lighted with infrared light emitting diodes (LEDs) and tungsten lamps covered with infrared transmitting filter, respectively, aiming to supply infrared light for photosynthetic bacteria growth. The photo-bioreactors were operated to treat noodle-processing wastewater for 323 days. Hydraulic retention time (HRT) was set as 6 days. Organic removals in the photo-bioreactor lighted with infrared LEDs (91%-95%) was found higher than those in photo-bioreactor with tungsten lamps with filter (79%-83%). Biomass production in a 150 L bench-scale photo-bioreactor was comparable to a 8 L small-scale photo-bioreactor in previous study, due to improvement of light supply efficiency. Application of infrared LEDs could achieve higher treatment performance with advantages in energy efficiency and wavelength specifity.

Efficient White Organic Light-emitting Device by utilizing a Blue-emitter Doped with a Red Fluorescent Dopant

  • Lim, Jong-Tae;Ahn, Young-Joo;Kang, Gi-Wook;Lee, Nam-Heon;Lee, Mun-Jae;Kang, Hee-Young;Lee, Chang-Hee;Ko, Young-Wook;Lee, Jin-Ho
    • Journal of Information Display
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    • v.4 no.2
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    • pp.13-18
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    • 2003
  • We synthesized bis (2-methyl-8-quinolinolato)(triphenylsiloxy) aluminum (III) (SAlq), a blue-emitting material having a high luminous efficiency, through a homogeneous-phase reaction. The photoluminescence (PL) and electroluminescence (EL) spectra of SAlq show two peaks at 454 nm and 477 nm. Efficient white light-emitting devices are fabricated by doping SAlq with a red fluorescent dye of 4-dicyanomethylene-2-methyl-6-{2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-8yl) vinyl}-4H-pyran (DCM2). The incomplete energy transfer from blue-emitting SAlq to red-emitting DCM2 results in light-emission of both blue and orange colors. Devices with the structure of ITO/TPD (50 nm)/SAlq:DCM2 (30 nm, 0.5 %)/$Alq_3$ (20 nm)/LiF (0.5 nmj/Al show EL peaks at 456 nm and 482 nm originating from SAlq and at 570 nm from DCM2, resulting in the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.32, 0.37). The device exhibits an external quantum efficiency of about 2.3 % and a luminous efficiency of about 2.41m/W at 100 $cd/m^2$. A maximum luminance of about 23,800 $cd/m^2$ is obtained at the bias voltage of 15 V.

A New Pixel Structure for Active-Matrix Organic Light Emitting Diode

  • Choi, Sang-Moo;Kwon, Oh-Kyong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.881-884
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    • 2003
  • We propose a new pixel structure for Active Matrix OLED (AMOLED). The proposed pixel structure can display full color images by compensating threshold voltage (Vth) variation of driving TFTs. And we obtain an improved contrast ratio(C/R) of higher than 600:1

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LED Backlight: LED's potential on the rise and the limitation on the decline

  • Anandan, Munisamy
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.2-6
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    • 2009
  • This presentation reviews the current progress in the technology of Light Emitting Diode (LED) as it relates to the LED backlight for Liquid Crystal Display (LCD). A vivid description is given about the performance of LED that is still on the rise and certain limitations of LED that is on the decline.

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Effects of 630-nm Organic Light-emitting Diodes on Antioxidant Regulation and Aging-related Gene Expression Compared to Light-emitting Diodes of the Same Wavelength

  • Mo, SangJoon;Kim, Eun Young;Ahn, Jin Chul
    • Current Optics and Photonics
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    • v.6 no.3
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    • pp.227-235
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    • 2022
  • To investigate the aging-related physiological functions of organic light-emitting diodes (OLEDs), we examined mRNA expression changes in aging-related genes due to oxidative stress inhibition by 630-nm red light OLEDs. As a result of irradiating 630-nm OLED with an intensity of 5 mW/cm2 for 15 min, the viability of dermal fibroblasts significantly increased by 1.3-fold. In addition, reactive oxygen species generated by H2O2 were significantly reduced about 4.9-fold by irradiation with 630-nm OLED. Quantitative reverse-transcription polymerase chain reaction results showed that 630-nm OLEDs altered aging-related gene mRNA expression levels through antioxidant activity. The mRNA expression levels of matrix metalloproteinase1 (MMP1) and MMP9 decreased significantly, by about 2.2- and 2.5-fold, compared to the control group, whereas those of collagen, type I, and alpha 1 increased significantly, by 4.9-fold. The mRNA expression levels of cancer suppression genes p16 and p53 in dermal fibroblasts were also significantly reduced by 630-nm OLED irradiation, by about 1.4- and three-fold, respectively, compared to the control. Overall, it was confirmed that 630-nm OLED irradiation lowered the level of ROS formation induced by H2O2 in dermal fibroblasts, and that this antioxidant effect could regulate the mRNA expression levels of aging- and tumor suppression-related genes. This study shows a link between 630-nm OLED irradiation and anti-aging physiological functions such as antioxidant function, and suggests the potential of OLEDs as a useful light source for skin care.