• 제목/요약/키워드: organic crystal

검색결과 524건 처리시간 0.025초

유기-무기 복합소재로부터 CuO합성 (Synthesis of CuO from organic-inorganic hybrid)

  • 허영덕;권석순;국원근
    • 한국결정성장학회지
    • /
    • 제15권5호
    • /
    • pp.193-197
    • /
    • 2005
  • 층상 구조의 유기-무기 복합 소재 $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$를 전구체로 사용하여 CuO를 합성하였다. 외부의 다른 유기화합물 주형이 없이 단순한 $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$의 열분해 방법을 사용하였다 이 방법은 저렴한 가격으로 단일 결정의 CuO 입자를 양산하는 방법을 제공한다 응집된 CuO 입자의 형태는 전구체의 구조에 크게 영향을 받는다.

유기 박막의 전기적 특성 및 가스 반응 특성 (Gas Response and Electrical Properties of Organic Ultra-thin Films)

  • 박재철
    • 한국전기전자재료학회논문지
    • /
    • 제11권10호
    • /
    • pp.820-825
    • /
    • 1998
  • We deposited stearic acid LB films by using Langmuir-Blodgett (LB)method and investigated anisotropy electrical conduction characteristics by I-V measurement for horizontal direction and vertical direction. Also, we measured gad response between deposited LB films and organic gas for various temperature(0~8$0^{\circ}C$) by 9MHz At-cut quartz crystal microbalance. The LB films have electrical conduction characteristics such as semiconducting and insulating properties. The is, the conductivity of LB films for the horizontal and vertical direction is about 10\ulcornerS/cm and 10\ulcorners/cm, respectively. the frequency shift of stearic acid LB films for the organic gases depended on the mass change by the surface adsorption and the inner penetration to the sensing films. The resonant frequency shift of the quartz crystal microbalance for temperature properties of LB films is thought to the effect of the rearrangement or the damage pf LB films above the melting point and the mobility increasement of the organic gas by the temperature rising.

  • PDF

LC Orientation Characteristics Treated on Organic Hybrid Overcoat Layer with Ion Beam Irradiation

  • Lee, Sang-Keuk;Kim, Byoung-Yong;Kim, Young-Hwan;Lee, Kang-Min;Oh, Byeong-Yun;Han, Jeong-Min;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
    • /
    • 제9권5호
    • /
    • pp.202-205
    • /
    • 2008
  • We have studied the liquid crystal (LC) orientation behavior on the organic hybrid overcoat layer with ion beam irradiation. Excellent LC alignments of the nematic liquid crystal (NLC) on the ion beam irradiated organic hybrid overcoat layers were observed in various intensities above 600 eV. Pretilt angles of the NLC on the organic hybrid overcoat layers for all ion beam energy intensities were observed from 0.2 to 0.5 degrees. Also, we used the atomic force microscopy (AFM) images for measuring the roughness of the organic hybrid overcoat layers with ion beam irradiation before and after. The surface of organic hybrid overcoat layers was leveled off by the ion beam irradiation. Finally, a good LC alignment thermal stability on the organic hybrid overcoat layer with ion beam irradiation can be achieved.

A Series of 3D Lanthanide Complexes Containing (La(III), Sm(III) and Gd(III)) Metal-organic Frameworks: Synthesis, Structure, Characterization and Their Luminescent Properties

  • Zhang, Huai-Min;Yang, Hao;Wu, Lan-Zhi;Song, Shuang;Yang, Li-Rong
    • Bulletin of the Korean Chemical Society
    • /
    • 제33권11호
    • /
    • pp.3777-3787
    • /
    • 2012
  • Three kinds of 3D isomorphous and isostructural coordination polymers, namely, $\{[Ln_2(PDA)_3(H_2O)_3]{\cdot}0.25H_2O\}_{\infty}$ (Ln = La(1), Sm(2), and Gd(3)) ($PDA^{2-}$ = pyridine-2,6-dicarboxylate anion) have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectroscopy, thermal analyses and single crystal X-ray diffraction. In these MOFs, Ln(III) centers adopt eight-coordinated and nine-coordinated with the $N_1O_7$ and $N_2O_7$ donor sets to construct distorted trianglar dodecahedron geometry and tricapped trigonal prism configurations, respectively. Based on the building block of tetranuclear homometallic $Ln_4C_4O_8$ unit (16-membered ring), 1-3 are connected into highly ordered 2D sheets via O-C-O linkers and further constructed into 3D architectures through hydrogen bonds. Crystallographic parameters suggest that the lanthanide contraction effect exist in these coordination polymers. Luminescent properties of the lanthanide-based MOFs (metal-organic frameworks) have been measured at room temperature, which reveal that they presenting ionselective characters toward certain metals, such as $Mg^{2+}$, $Cd^{2+}$ and $Pb^{2+}$ ions.

Liquid Crystal Aligning Capabilities Treated on Organic Overcoat Thin Films by Ion Beam Irradiation Method

  • Han, Jeong-Min;Kim, Byoung-Yong;Kim, Jong-Yeon;Kim, Young-Hwan;Han, Jin-Woo;Hwang, Jeoung-Yeon;Lee, Sang-Keuk;Kang, Dong-Hun;Ok, Chul-Ho;Seo, Dae-Shik
    • 한국전기전자재료학회논문지
    • /
    • 제20권3호
    • /
    • pp.245-249
    • /
    • 2007
  • The liquid crystal display (LCD) applications treated on the organic overcoat thin film surfaces by ion beam irradiation was successfully studied. The good LC aligning capabilities treated on the organic overcoat thin film surfaces with ion beam exposure of $60^{\circ}$ for 2 min above ion beam energy of 1200 eV can be achieved. But, the alignment of defect of NLC on the organic overcoat surface at low energy of 600 eV was measured. The pretilt angle of NLC on the organic overcoat thin film surface with ion beam exposure of $60^{\circ}$ for 2 min at energy of 1800 eV was measured about 1 degree. Finally, the good thermal stability of LC alignment on the organic overcoat thin film surface with ion beam exposure of $60^{\circ}$ for 2 min until annealing temperature of $200^{\circ}C$ can be measured.

Light Emitting Devices Based on Organic Single Crystals

  • Nakanotani, Hajime;Saito, Masatoshi;Nakamura, Hiroaki;Adachi, Chihaya
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
    • /
    • pp.342-345
    • /
    • 2009
  • Bright light-emitting single crystal organic field-effect transistors (FETs) based on highly luminescent oligo(p-phenylenevinylene) (OPV) derivatives are demonstrated. Although OPV single crystal FETs show both p - and n - type FET operation, we found that an increase in the conjugation length of the OPV derivatives from three phenylene rings to five phenylene rings results in an improvement in the electron mobility by an order of magnitude, while retaining the high hole mobility with intense electroluminescence.

  • PDF

수정진동자에 의한 감응성막의 유기가스 응답특성 분석 (Analysis of Response Characteristics for Organic Gas of Polymeric Sensitive Films by Using Q. C. M.)

  • 김경철;김정명;장상목;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
    • /
    • pp.409-412
    • /
    • 1996
  • In this paper, the response characteristics of organic gases were investigated by using quartz crystal microbalance(Q.C.M) with different polymeric sensitive materials. The new linear parameter was discussed in order to develope gas sensing system using neural network and pattern recognition. We analyzed the response characteristics by the area of resonant frequency shift of quartz crystal, which mean affinities of organic gases for polymeric sensitive firm. The experimental results shows that the parameter made by the area of frequency shift which was linear with injection amount of organic gases has possibility to be used for pattern recognition and neural network. And they have different normalized pattern.

  • PDF

지프라시돈의 결정형 (Crystal Forms of Ziprasidone)

  • 윤미희;방효춘;손영택
    • Journal of Pharmaceutical Investigation
    • /
    • 제39권2호
    • /
    • pp.117-120
    • /
    • 2009
  • Two crystal forms of ziprasidone have been isolated by recrystallization from different organic solvents and characterized by differential scanning calorimetry, powder X-ray diffractometry and thermogravimetric analysis. It was confirmed that Form 2 has the same crystal structure as Form 1.

세푸록심 악세틸의 결정형 (Crystal Form of Cefuroxime axetil)

  • 김보연;손영택
    • Journal of Pharmaceutical Investigation
    • /
    • 제37권1호
    • /
    • pp.23-26
    • /
    • 2007
  • Two crystal forms of cefuroxime axetil were obtained by the recrystallization from different organic solvents and characterized by differential scanning calorimetry (DSC), X-ray powder diffraction (XRD). It was confirmed that two crystal forms are identical. The dissolution patterns of these two forms were also checked in 0.07 N HCl at $37{\pm}0.5^{\circ}C$, 100 rpm for 180 minutes. The transformation during storage was also studied.