• Title/Summary/Keyword: organic contaminants

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Pig slurry treatment by the pilot scale hybrid multi-stage unit system (HMUS) followed by sequencing batch reactor (SBR) (HMUS와 SBR 반응조를 이용한 축분처리에 관한 연구)

  • Lee, Young-Shin;Han, Gee-Bong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.2
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    • pp.63-70
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    • 2013
  • Experiments in a pilot-scale hybrid multi-stage unit system (HMUS) combination of ATAD and EGSB followed by SBR process for pig slurry treatment were conducted to demonstrate the feasibility of using autothermal thermophilic aerobic digestion (ATAD) and expended granular sludge bed (EGSB) followed by sequencing batch reactor (SBR) system. Contaminants in pig slurry with high organic matter, nitrogen (N) and phosphorus (P) content were completely removed in the combined process. The highest removal rate for CODcr among contaminants in the feed pig slurry was attained by about 43.3% in ATAD unit process. Also TS removal rate of 96.5% was attained and the highest in the next coagulation unit process. The highest removal rate of CODcr under operating parameter conditions of OLR(organic loading rate), 3-6Kg $COD/m^3{\cdot}day$ and line velocity, 1.5-4m/h was earned at 3days of HRT. The disinfection of pathogens was effective at 50,000mg/L of TS in ATAD unit process. Biogas production per organic removal was $2.3{\sim}8.5m^3/kgTS{\cdot}d$ (average $5.2m^3/kgTS{\cdot}d$) in EGSB unit process. The average removal rates of CODcr 71.7%, TS 64.1%, TN 45.9%, and TP 50.4% were earned in the intermittent aeration SBR unit process.

Estimation of Initial Concentrations of Phenanthrene and Atrazine from Soil Properties and Bioavailability During Aging

  • Chung, Namhyun
    • Journal of Applied Biological Chemistry
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    • v.44 no.4
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    • pp.194-198
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    • 2001
  • Contaminated sites are often abandoned for an extended period of time, thus organopollutants becoming sequestered. The information on the initial concentrations of the contaminants would be helpful for the economic bioremediation of the chemicals. The present study estimated the initial concentrations of atrazine and phenanthrene through multiple regression analyses using soil properties and the amount of chemicals available in situ. Percentage mineralized or extracted was best correlated with organic C or logarithm of organic C, and the $R^2$ values were 0.548 and 0.894 for atrazine and phenanthrene, respectively. Estimation of the initial concentration of the chemicals was then calculated from both the percentage mineralized or extracted and the amount of chemicals extracted or mineralized. Results showed that the estimation of the initial concentration of the chemical at the time of contamination is feasible.

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Desorption Characteristics of Volatile Organics Compounds in Soil by Microwave Heating (마이크로파 가열에 의한 토양 유기오염물질 탈착특성)

  • 문경환;김덕찬
    • Journal of environmental and Sanitary engineering
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    • v.11 no.2
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    • pp.65-73
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    • 1996
  • The objective of this study is to investigate the removal efficiency of volitile organic compounds in soil, and the mechanism of desorption by bench scale microwave heating, Silt soil used for experiment and was impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene and the microwave treatment was conducted in a modified domestic microwave oven : 2450MHz, 700W. According to the results of the research the removal efficiency was improved with increasing water contents and the soil temperature appeared to plateau period extending to 2-3minutes corresponds to the temperature a which steam distillation was expected. The value of removal rate constant (k) were calculated on dry and moisty silt soil, respectively, which showed linear with increasing microwave heating time. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants.

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Prediction of Sediment-Bound Metal Bioavailability in Benthic Organisms: Acid Volatile Sulfide (AVS) Approaches

  • Song, Ki-Hoon
    • Korean Journal of Environmental Biology
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    • v.20 no.2
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    • pp.101-108
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    • 2002
  • Benthic organisms dwell in sediment-water interface that contains significant amount of organic and inorganic contaminants. Their feeding behavior is highly related with sediment itself and pore water in the sediments, especially in ease of deposit feeder (i.e. polychaete, amphipod). The acid volatile sulfide (AVS) is one of the important binding phases of sediment-bound metals in addition to organic matter and Fe and Mn oxide fractions in sediments, particularly in anoxic sediments. The AVS model is a powerful tool to predict metal bioavailability and bioaccumulation in benthic organisms considering SEM/AVS mole ratios in surficial sediments. However, several biogeochemical factors must be considered to use AVS model in the sediment-bound metal bioavailability.

Biological Removal Characteristics by the Internal Recycle Rate in the Attached Growth Process (부착증식공정에서 내부 반송율 변화에 따른 생물학적 제거 특성)

  • 박충기;김병욱;임재명
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.110-116
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    • 1999
  • This study was conducted to investigate the contaminants removal efficiency and the optimal operating parameters by the internal recycle rate (IRR) in the combining A2/O process with fixed film. The average removal efficiency of BOD and COD was 92.5%~94.6%, 73.9%~87.0% in RUN 1 and 91.9%~94.7%, 77.7%~89.0% in RUN 2, respectively. Organic removal efficiency, at two different hydraulic retention time of 10 and 14hr, was similar. At 50% of the internal recycle rate, organic removal efficiency was somewhat higher than the other. Total nitrogen (T-N) and total phosphorus (T-P) were removed, highly, at 50% of internal recycle rate. It could be suggested by this study that the optimum internal recycle rate is 50% and hydraulic retention time is 14hr.

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HDTMA-Bentonite로부터 페놀류 화합물의 경쟁탈착

  • 신원식;김영규;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.15-18
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    • 2001
  • Sorption/desorption studies were conducted to determine sorption/desorption characteristics of phenolic compounds (phenol and 4-chlorophenol) in organically modified natural bentonite. The cationic exchange capacity (CEC) of bentonite was exchanged with a cationic surfactant, hexadecyltrimethylammonium (HDTMA), to enhance the removal capacity of organic phenol contaminants dissolved in aqueous solution. This modification produces a change of the surface property of bentonite from hydrophilic to organophilic. The single-solute and bi-solute competitive adsorptions were performed In batch mode to investigate the removal of two toxic organic Phenols, chlorophenol and 4-chlorophenol on the HDTMA-bentonite. The adsorption affinity of the 4-chlorophenol was higher than phenol due to higher octanol:water partition coefficient (Kow). The single-solute and bi-solute competitive desorptions were also performed investigate the competitive desorption of the phenolic compounds from HDTMA-bentonite. Freundlich model was used to analyze the single-solute adsorption/desorption results, while the IAST model predicted the hi-solute adsorption/desorption equilibria. The IAST model well predicted hi-solute competitive adsorption/desorption behaviors.

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Effects of Capping with Recycled Aggregates and Natural Zeolite on Inhibition of Contaminants Release from Marine Sediment (순환골재와 천연제올라이트 피복에 의한 연안퇴적물 오염물질 용출 차단 효과)

  • Kim, Young-Kee;Shin, Woo-Seok
    • Journal of Korean Society on Water Environment
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    • v.32 no.6
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    • pp.546-551
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    • 2016
  • In this study, capping with recycled aggregate and natural zeolite in marine sediment was performed to investigate its inhibitory effect on pollutants released from sediment to seawater. An experiment was performed by capping with amendments for 60 days, and concentrations of organic matter (COD), nitrate, phosphate and metallic elements (Ni, Zn, Cu, Pb, Cd, As, and Cr) were measured. Two capping materials effectively suppressed pollutant release. Recycled aggregate showed better effectiveness for organic pollutant, nitrate and phosphate release. Meanwhile, natural zeolite was effective for metallic elements. As a result, recycled aggregate and natural zeolite can be considered as cost-effective/inexpensive capping material candidates. Also, the capping material can be selected according to the target pollutant.

Individual service application for consumers's food safety

  • Lau, Shuai
    • Korean Journal of Artificial Intelligence
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    • v.3 no.1
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    • pp.1-4
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    • 2015
  • These days, men live better lives owing to economic growth. They are interested in basic desire such as clothing, food and dwelling. This study investigated food and/or eating. Men like to take better quality food to be healthy. They can hear food problems easily by news to satisfy desire. On October 13, 2014, Dongsuh Food Company was prohibited to distribute a serial product named 'Post Almond Flake' (Statistics Korea). Dongsuh Food was found to produce finished product by mixing contaminants without inspection of colon bacillus, and Crown Confectionery was found to produce 'Organic farming wafer' and 'Organic farming choco wafer' from March 2009 to early August, 2016 cognizing rejection at inspection not to inform Ministry of Health and to sell product amounting to 3.1 billion KRW .

Pesticide Analysis in Drinking Water by SPE Method (SPE법에 의한 음료수중 농약성분)

  • 김형석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.2
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    • pp.59-66
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    • 1995
  • According to the population increase and industrialization, the drinking water source, Han River and other sources, are contaminated by industrial wastewater, domestic sewage, and agricultural discharges. Among the contaminants, and toxic substances, pesticides is most interesting items (or human health Our drinking water has some problems of THMs, Fe, odor, etc., $o many people use groundwater or bottled water. But sometimes there are many reports about groundwater contamination owing to the agricultural chemicals, waste disposal, industrial wastewater. In America, there are about 45,000 groundwave supply company and in korea about 20% of total population are using groundwave as drinking water source. In America, studies about SEE is increasing Instead of liquid- liquid extraction method, because of many advantages of SEE methods. Author tried to investigate SPE methods in the spiked water samples to compare with liquid- liquid extraction method and got the following results. The amount of organic solvents which are used In SPE method is less than 1/10 compared with liquid- liquid method, the analytical duration time is shortened, and the ethyl acetate was good fluent among several organic solvents.

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토양-휴민의 물리화학적 특성 및 PAHs의 결합 특성 연구

  • Im Dong-Min;Sin Hyeon-Sang
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.16-19
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    • 2006
  • Humin is the insoluble fraction of humic materials and play an important roles in the irreversible sorption of hydrophobic organic contaminants onto soil particles. However, there have been limited knowledge about the sorption and chemical properties of humin due to the difficulties in its separation from the inorganic matrix(mainly clays and oxides). In this study, do-ashed humin was isolated from a soil sample after removing free lipid and alkali-soluble humic fractions followed by dissolution of mineral matrix with 2% HF, and characterized by elemental analysis, C-13 NMR spectroscopic method. Sorption behavior of 1-naphthol with humin was also investigated from aqueous solution. C-13 NMR spectra indicate that humin molecules are mainly made up of aliphatic carbon including carbohydrate, methylene chain etc.. Sorption intensity for 1-naphthol was increased as organic carbon content of humin increased and log Koc values for the 1-naphthol sorption were determined to be ${\sim}3.12$

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