• Title/Summary/Keyword: organic combination

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Study of the Energy Level Alignment of Organic Materials' Planar Junction Prepared by Electrospray Vacuum Deposition

  • Kim, Ji-Hun;Hong, Jong-Am;Seo, Jae-Won;Gwon, Dae-Gyeon;Maeng, Min-Jae;Park, Yong-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.235-235
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    • 2012
  • We investigated the energy levels of valence region at the planar junction of poly (3-hexylthiophene) (P3HT) and C61-butyric acid methylester (PCBM) using ultraviolet photoemission spectroscopy (UPS) with ultra high vacuum. These are the most widely used materials for bulk heterojunction (BHJ) organic solar cells due to their high efficiency. In order to make the planar junction, we carried out the electrospray vacuum deposition (EVD) of PCBM onto spin-coated P3HT in high vacuum conditions (${\sim}10^{-5}-10^{-6}$). The planar junction interface exhibited 0.71 eV for the offset between P3HT HOMO and PCBM LUMO, which is different from the gap (0.85 eV) of individual values and is closer to the open circuit voltage of solar cells fabricated with the same material combination.

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A Study on the Analysis of Volatile Flavour of Kimchee (김치 휘발성 향기성분의 분석 방법에 관한 연구)

  • Hawer, Wooderck S.
    • Analytical Science and Technology
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    • v.7 no.1
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    • pp.125-132
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    • 1994
  • Flavours in kimchee are the result of unique combination of various sugars, organic acids and amino acids as well as various volatile organic compounds including sulfur-containing compounds, terpenes, alcohols, and some volatile organic acids. In the experiment for the flavour extracting methods, dynamic headspace(DHS) is more effective for collection of volatile flavour than simultaneous distillation extraction(SDE). The best polarity available at the moment is 5% phenyl methyl poly-siloxane which will separate non-polar, intermediate and polar components with good resolution.

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시멘트/슬래그/Fe(II) 시스템에 의한 NAPL TCE의 분해 특성

  • 박정현;강완협;황인성;박주양
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.218-222
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    • 2004
  • Batch slurry experiments were conducted to develop cement/slag/Fe(II) system that could treat hazardous liquid wastes containing halogenated organic solvents. Portland cement in combination with Fe(II) was reported to reductively dechlorinate chlorinated organics in a modified solidification/stabilization process. TCE (trichloroethylene) was used a model halogenated organic solvent. The objectives of this study were to assess the feasibility of using cement and steel converter slag amended with Fe(II) as a low cost abiotic reductive dechlorination and to investigate the kinetics of TCE dechlorination over a wide range of TCE concentration. From the result of screening experiments, cement/slag/Fe(II) system was identified as a potentially effective system to treat halogenated organic solvent. Kinetic studies were carried out to further investigate degradation reaction of TCE NAPL (Non Aqueous Phase Liquids) in cement/slag/Fe(II) systems by using batch slurry reactors. Degradation rate of TCE solution in this system can be explained by pseudo-first-order rate law because the prediction with the rate law is in good agreement with the observed data.

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Comparative Study of Volatile Organic Compound Concentrations in the Yochon Industrial Estate during Spring and Fall (여천 공업단지 봄, 가을 대기 중 휘발성 유기화합물 농도 비교 연구)

  • 김영성;송철한
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.2
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    • pp.153-160
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    • 1998
  • The concentrations of volatile organic compounds (VOCs) in the atmosphere were measured from the Yochon Industrial Estate and compared with those from Tongkwangyang and Seoul. The first important phenomenon observed in the air of Yochon was high concentrations of alkenes and in particular, ethylene and propene. For most dominant species, their means and standard deviations were high simultaneously. Concentrations of several major aliphatic species exhibited a similar pattern of diurnal variation, however, with different species combination on each day. Concentrations of several hazardous aromatic species also exhibited a similar pattern of diurnal variation on the same day, which was different from that observed in the diurnal variation of major aliphatic species. It was interpreted that some species were intermittently released from relevant processes. It was also understood that high concentrations and variations of VOC species in Yochon were localized and not related to high average concentrations of ozone in Yochon and Tongkwangyang areas.

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Synthesis and microphase-separated structures of rod-coil triblock polymers

  • Uchida, Satoshi;Tanimura, Kotaro;Ishizu, Koji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.326-326
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    • 2006
  • The combination of living anionic and coordination polymerization techniques enabled to synthesize the polystyrene-b-polyisoprene-b-poly (butyl isocyanate) triblock polymers. Their microphase-separated structures were zig-zag structures for high ${\phi}_{PIC}$ samples, and hockey-puck structures were also observed. The phase diagram for PSt-b-PIp-b-PIC rod-coil polymers was different from that for PS-PBd-PMMA triblock polymers, and it was found that ${\phi}_{PIC}$ was the important factor to determine the microphase-separated structures.

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To develop the classification method of Agricultural by-productions for biogas production

  • Kim, Minjee;Kim, Sanghun
    • International Journal of Internet, Broadcasting and Communication
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    • v.7 no.2
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    • pp.155-160
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    • 2015
  • The objective of this study was to develop the classification method of various organic wastes. Specifically, the effects of proximate composition on the biogas production and degradation rates of agricultural by-production was investigated and a new standards for mixture of various organic wastes based on proximate composition combination was developed. Agricultural by-products (ABPs) with medium total carbohydrate, medium crude protein and low fat contents demonstrated the single step digestion process. ABPs with low total carbohydrate, high crude protein and high fat contents demonstrated the two step digestion process of Diauxic growth. The single ABP (Class No. 15) and the mixed ABPs (Class No. 12+18, 6+12+22, 9+12+18) after 10days showed the similar biogas yield pattern. We can use the classification method for the more ABPs and organic wastes from factory and municipal waste treatment plant for the high efficient biogas production.

Adsorption and catalytic ozonation of aquatic organic compound by acid-treated granular activated carbon (산 처리한 활성탄을 이용한 수중 유기물의 흡착 및 오존 분해)

  • Nam, Yun-Seon;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.31 no.B
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    • pp.127-132
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    • 2011
  • Humic substances is accounted for for the largest proportion in natural organic matter(NOM) and NOM is widely distributed in varying concentration in all aquatic and soil. They can affect water quality adversely in several ways by contributing undesirable color, complexing with metal and yielding metal concentrations exceeding normal solubility. Ozonation is one of the efficient treatments for degradation of humic substances which cause some problems in water treatment. Especially, the combination of ozone and granular activated carbon was applied to degradation humic acid in aquatic system. The aim of this work to test the available of acid-treated granular activated carbon as catalyst in the ozonation of humic acid.

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Equivalent-circuit Analysis of ITO/Alq3/Al Organic Light-emitting Diode

  • Chung, Dong-Hoe;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.3
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    • pp.131-134
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    • 2007
  • An $ITO/Alq_3/Al$ structure was used to study complex impedance of $Alq_3$ based organic light-emitting diodes. Equivalent circuit was analyzed in a device structure of $ITO/Alq_3/Al$ with a thickness layer of $Alq_3$ of 100 nm. The obtained impedance was able to be fitted using equivalent circuit model of parallel combination of resistance $R_p$ and capacitance $C_p$ with a small series resistance of $R_s$.

SAPS의 탄소원 공급을 위한 유기물 연구

  • 이지은;고주인;김선준;유상희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.231-234
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    • 2004
  • The experiments on some organic materials used in SAPS are carried out for the better sulfate reduction efficiency and the longer lifetime. Organic materials include spent mushroom compost, sewage sludge, oak chip compost and the combination of there. Reactors with mushroom compost, sewage sludge, the mixture of mushroom compost and sewage sludge, and the mixture of mushroom compost and oak chip compost maintained pH higher than 6.0. Reactors with mushroom compost, the mixture of mushroom compost and sewage sludge, and the mixture of mushroom compost and oak chip compost maintained reduction condition. Reactors with sewage sludge, oak chip compost and the mixture of sewage and oak chip compost produced COD less than 2,000ppm. Reactors with sewage and the mixture of mushroom compost, sewage sludge, oak chip compost showed about 60% of sulfate removal ratios.

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Routes to Improving Performance of Solution-Processed Organic Thin Film Transistors

  • Li, Flora M.;Hsieh, Gen-Wen;Nathan, Arokia;Beecher, Paul;Wu, Yiliang;Ong, Beng S.;Milne, William I.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1051-1054
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    • 2009
  • This paper investigates approaches for improving effective mobility of organic thin film transistors (OTFTs). We consider gate dielectric optimization, whereby we demonstrated >2x increase in mobility by using a silicon-rich silicon nitride ($SiN_x$) gate dielectric for polythiophene-based (PQT) OTFTs. We also engineer the dielectric-semiconductor ($SiN_x$-PQT) interface to attain a 27x increase in mobility (up to 0.22 $cm^2$/V-s) using an optimized combination of oxygen plasma and OTS SAM treatments. Augmentative material systems by combining 1-D nanomaterials (e.g., carbon nanotubes, zinc oxide nanowires) in an organic matrix for nanocomposite OTFTs provided a further boost in device performance.

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