• 제목/요약/키워드: organic N

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Comparison of Pollutant Load Discharge Characteristics with Fertilizer Treatments from Small Scale Plot (소규모 시험포에서의 비료처리별 오염배출 농도 특성 비교)

  • Lyou, Chang-Woun;Shin, Yong-Cheol;Heo, Sung-Gu;Han, Yun-Su;Lim, Kyoung-Jae;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.997-1001
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    • 2006
  • Organic compost has been widely applied to the cropland because it has been thought as Environmentally Sound Agriculture (ESA) in Korea. In this study, two-year indoor rainfall experiments were performed. Surface runoff and groundwater volume from 10% and 20% slope plots were measured and water quality samples were collected and analyzed for BOD, COD, T-P and T-N. Flow weighted mean concentration (FWMC) values were computed to assess effects of various fertilizer treatments. FWMC BOD values for organic compost treated plots were higher than chemical fertilizer treated plots. FWMC BOD values for 20% slope plots were higher than those from those for 10% slope plots. The similar trends were found for COD and T-P. FWMC T-N values for chemical fertilizer treated plots were higher than organic compost treated plots. FWMC T-N values for 10% slope plots were higher than those for 20% slope plots. In Korea, excessive use of organic compost has caused extremely high levels of organic matter contents at the cropland. Since organic compost is very slow in releasing its nutrients to the soil, farmers usually apply excessive organic compost for immediate effects and maximum crop yields, which has been causing soil and water quality degradations. Therefore, thorough investigations for better nutrient management plans are needed to develop the ESA strategy in Korea.

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A Study on the Fabrication of Piezoelectric Organic Thin Films by using Physical Vapor Deposition Method and Sensor Characteristics (진공증착법을 이용한 압전 유기 박막의 제조와 센서 특성에 관한 연구)

  • Park, Su-Hong;Lim, Eung-Choon;Park, Jong-Chan;Lee, Duck-Chool
    • Proceedings of the KIEE Conference
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    • 2001.07e
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    • pp.35-39
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    • 2001
  • The purpose of this paper is improvement the piezoelectric of Polyvinylidene fluoride(PVDF) organic thin films is fabricated by vapor deposition method. The piezoelectric of PVDF organic thin films attributed to dipole orientation in crystalline region. Also, the piezoelectric characteristic reduced that dipole moments orientation in crystalline region interfered with impurity carriers. Therefore, PVDF organic thin films fabricated with high substrate temperature condition for crystallinity improvement. The crystallinity of PVDF organic thin films fabricated by this condition increase from 47 to 67.8%. The ion density of PVDF organic thin films fabricated by substrate temperature variation from $30^{\circ}C$ to $105^{\circ}C$ decreased from $1.62{\times}10^{16}cm^3$ to $6.75{\times}10^{11}cm^3$ when temperature and frequency were $100^{\circ}C$, 10Hz, respectively. The $d_{33}$ and piezo-voltage coefficient of PVDF organic thin films increased from 20pPC/N to 33pC/N and $162.9{\times}10^{-3}V{\cdot}m/N$ to $283.2{\times}10^{-3}V{\cdot}m/N$, respectively. For the sake of the applications of piezoelectric sensor, we analyzed the output voltage characteristic as a function of the distance between an oscillator of 28kHz and PVDF organic thin film transducer. From this, we found that the output voltage is inversely proportional to the distance. At this time, the period was about $35.798{\mu}s$ and equal the oscillator frequency.

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Modifications Induced by Organic Solvents to Aeromonas hydrophila IB Bct4 (유기용매에 의하여 유발된 Aeromonas hydrophila Bct4의 변형)

  • Lazaroaie, Mihaela Marilena
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.325-334
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    • 2009
  • Many bacteria that are capable to tolerate and degrade organic solvents have been isolated from seawater. However, their roles in the biodegradation of organic solvents in the marine environment have remained unknown. Aeromonas hydrophila IB$B_{ct4}$, isolated from Constanta seawater, was able to tolerate and degrade different organic solvents. Toluene, styrene, xylene isomers, ethylbenzene, with the logarithm of the partition coefficient in octanol-water mixture (log $P_{ow}$) between 2.64 and 3.17, were more toxic for bacterial cells, compared with propylbenzene, n-hexane, n-heptane, with log $P_{ow}$ between 3.69 and 4.39. There were revealed cellular and molecular modifications induced by organic solvents to Aeromonas hydrophila IB$B_{ct4}$. The study of cellular and molecular modifications induced by different organic solvents showed a complex response of bacterial cells to the presence of organic solvents in the culture media.

Electrical Properties of Organic Light-emitting Diodes Using TCNQ Molecules (TCNQ 분자를 이용한 유기 발광 소자의 전기적 특성)

  • Na, Su-Hwan;Kim, Tae-Wan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.11
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    • pp.896-900
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    • 2010
  • Electrical properties of organic light-emitting diodes were studied in a device with 7,7,8,8-tetracyano-quinodimethane (TCNQ) to see how the TCNQ affects on the device performance. Since the TCNQ has a high electron affinity, it is used for a charge-transport and injection layer. We have made a reference device in a structure of ITO(170 nm)/TPD(40 nm)/$Alq_3$(60 nm)/LiF(0.5 nm)/Al(100 nm). And two types of devices were manufactured. One type of device is the one made by doping 5 and 10 vol% of TCNQ to N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) layer. And the other type is the one made with TCNQ layer inserted in between the ITO anode and TPD organic layer. Organic layers were formed by thermal evaporation at a pressure of $10^{-6}$ torr. It was found that for the TCNQ doped devices, turn-on voltage of the device was reduced by about 20 % and the current efficiency was improved by about three times near 6 V. And for devices with TCNQ layer inserted in between the ITO anode and TPD layer, it was found that the current efficiency was improved by more than three times even though there was not much change in turn-on voltage.

The Effects of Organic Contamination and Surface Roughness on Cylindrical Capacitors of DRAM during Wet Cleaning Process

  • Ahn, Young-Ki;Ahn, Duk-Min;Yang, Ji-Chul;Kulkarni, Atul;Choi, Hoo-Mi;Kim, Tae-Sung
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.3
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    • pp.15-19
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    • 2011
  • The performance of the DRAM is strongly dependent on the purity and surface roughness of the TIT (TiN/Insulator/ TiN) capacitor electrodes. Hence, in the present study, we evaluate the effects of organic contamination and change of surface roughness on the cylindrical TIT capacitor electrodes during the wet cleaning process by various analytical techniques such as TDMS, AFM, XRD and V-SEM. Once the sacrificial oxide and PR (Photo Resist) are removed by HF, the organic contamination and surface oxide films on the bottom Ti/TiN electrode become visible. With prolonged HF process, the surface roughness of the electrode is increased, whereas the amount of oxidized Ti/TiN is reduced due to the HF chemicals. In the 80nm DRAM device fabrication, the organic contamination of the cylindrical TIT capacitor may cause defects like SBD (Storage node Bridge Defect). The SBD fail bit portion is increased as the surface roughness is increased by HF chemicals reactions.

A Study on the Effects of Micro Cavity on the HTL Thicknesses on the Top Emission Organic Light Emitting Diode (유기발광 다이오드의 정공수송층 두께에 따른 미소 공진 효과의 영향에 관한 연구)

  • Lee, DongWoon;Cho, Eou Sik;Seong, Jin-Wook;Kwon, Sang Jik
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.1
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    • pp.91-94
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    • 2022
  • Top emission organic light-emitting diode is commonly used because of high efficiency and good color purity than bottom - emission organic light-emitting device. Unlike BEOLED, TEOLED contain semi-transparent metal cathode. Because of semi-transparent cathode, micro cavity effect occurs in TEOLED. We optimized this effect by changing the thickness of hole injection layer. Device consists of is indium-tin-oxide / N,N'-Di-[(1-naphthyl)-N,N'-diphenyl]-1,1'-biphenyl-4,4'-diamine (x nm) / tris-(8-hydroxyquinoline) aluminum (50nm) / LiF(0.5nm) / Mg:Ag (1:9), and we changed NPB thickness which is used as HTL in our device in order to study how micro cavity effects are changed by optical path. As the results, NPB thickness at 35nm showed the current efficiency of 8.55Cd/A.

Comparison of Soil Chemical Properties and Heavy Metal Contents in Organic and Conventional Paddy of Yongin and Anseong (용인과 안성 지역의 유기논 및 관행논에서 토양 화학 특성 및 중금속 함량 비교)

  • Gu, Bon-Wun;Lee, Tae-Gu;Kang, Ku;Hong, Seong-Gu;Hong, Seung-Gil;Jang, Tae-Il;Kim, Jin-Ho;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.59 no.3
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    • pp.1-10
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    • 2017
  • The aim of this study is to investigate the chemical properties and heavy metal concentration of soils in conventional and organic paddy. We sampled and analyzed topsoil (0~15 cm) and subsoil (15~30 cm) of conventional and organic paddy fields in Yongin and Anseong, South Korea. The statistical significance between groups was determined by Duncan's multiple range test and correlation between soil properties was also analyzed. The results show that organic matter (OM) and T-N of conventional paddy soil were higher than those of organic paddy soil. However, higher T-P concentration was observed in organic paddy soil than conventional paddy soil. As, Pb, and Zn concentration in organic paddy soil were statistically lower than those in conventional paddy soil. The couple of water content (WC) & As, OM & T-N, T-P & $P_2O_5$, T-P & Zn, $P_2O_5$ & Zn, and Cr & Ni had a good positive correlation but the couple of WC & T-P, WC & Zn, T-P & As, and As & Zn had a strong negative correlation. It can be concluded that organic farming is beneficial to soil environment by reducing the amounts of organic matter, T-N, As, Pb, and Zn concentration in paddy soil when compared to conventional farming.

Electroluminescence characteristics of organic light-emitting diodes with TPD doped PVK as the hole transport layer

  • Shin, Y.C.;Song, J.H.;Lee, C.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1404-1407
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    • 2005
  • We have fabricated organic light-emitting diodes using poly(N-vinylcarbazole)(PVK) doped with N,N'- diphenyl-N,N'-bis(3-methylphenyl)-[l,l'-biphenyl]- 4,4/-diamine (TPD) as the hole transport layer. TPD molecules act as the trapping sites in PVK and reduce the hole mobility, which can enhance the electronhole balance in the emitting layer, resulting in the enhanced device performance. We have found the optimum ratio of TPD to PVK for the EL efficiency.

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