• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.204-204
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• 2012

Peierls instability and spin ordering of zigzag graphene nanoribbons (GNR) created on a fully hydrogenated graphene (graphane) are investigated as a function of their width using first-principles density-functional calculations within the generalized-gradient approximation. For the width containing a single zigzag C chain (N=1), we find the presence of a Peierls instability with a bond alternated structure. However, for width greater than N=1, the Peierls distortion is weakened or disappears because of the incommensurate feature of Fermi surface nesting due to the interaction of C chains. Instead, there exists the antiferromagnetic (AFM) spin ordering in which the edge states are ferromagnetically ordered but the two ferromagnetic (FM) edges are antiferromagnetically coupled with each other, showing that electron-lattice coupling and spin ordering in GNR are delicately competing at an extremely thin width of N=2. It is found that, as the width of GNR increases, the energy gain arising from spin ordering is enhanced, but the energy difference between the AFM and FM (where two edge states are ferromagnetically coupled with each other) orderings decreases.

• Applied Microscopy
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• 제27권3호
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• pp.235-241
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• 1997

(001) GaAs 기판 위에 성장된 (ZnSe/FeSe) 초격자의 구성층 사이에 상호확산으로 형성된 $Zn_{1-x}Fe_xSe$ 의 미세구조가 고분해능 투과전자현미경과 컴퓨터 이미지 시뮬레이션에 의해 연구되었다. 컴퓨터 이미지 시뮬레이션은 multislice 방법으로 여러 시편 두께와 초점 거리에서 실시되었다. 컴퓨터 시뮬레이션에 의해 얻은 이미지는 실험에 의해 얻은 이미지와 비교되었다. 또한, CuAu-I 형태 규칙화가 $Zn_{1-x}Fe_xSe$ 상호화산층에서 일어났다. 이 CuAu-I 형태 규칙격자는 <100>과 <110> 방향에 따라서 ZnSe와 FeSe 층이 교대로 구성되어 있다.

• 센서학회지
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• 제4권1호
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• pp.9-14
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• 1995

자기저항 효과를 이용한 저자장 자기센서를 제작하기 위하여 슬라이드 유리 기판위에 Ni-Co(0.7Ni-0.3Co) 합금을 $600\;{\AA}$ 두께로 진공증착 하였다. 증착된 박막을 bridge 구조의 격자무늬로 식각하는 과정에서 4개의 bridge arm을 주축과 $45^{\circ}$로 배열하고 그 면적율을 67%로 증대시켰다. 제작된 센서는 자장범위 ${\pm}0.5mT$에서 직선성이 양호하였으며 백색잡음은 0.2nV 이었고 전압감도는 7.6 $nV/{\mu}T$ 이었다.

• Macromolecular Research
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• 제17권6호
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• pp.365-377
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• 2009

In this feature article, we briefly review the new methods we have utilized recently in the investigation of morphology and phase behavior of block copolymers. We first describe the chromatographic fractionation method to purify block copolymers from their side products of mainly homopolymers or block copolymer precursors inadvertently terminated upon addition of the next monomer in the sequential anionic polymerization. The chromatographic method is extended to the fractionation of the individual block of diblock copolymers which can yield the diblock copolymer fractions of different composition and molecular weight, which also have narrower distributions in both molecular weight and composition. A more detailed phase diagram could be constructed from the set of block copolymer fractions without the need of acquiring many block copolymers each prepared by anionic polymerization. The fractions with narrow distribution in both molecular weight and composition exhibit better long-range ordering and sharper phase transition. Next, epitaxial relationships between two ordered structures in block copolymer thin film is discussed. We employed the direct visualization method, transmission electron microtomography(TEMT) to scrutinize the grain boundary structure.

• Preventive Nutrition and Food Science
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• 제8권4호
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• pp.343-348
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• 2003

To elucidate the effect of gamma-irradiation on the physicochemical properties of zein films, the molecular and mechanical properties of the films were examined after irradiation at various irradiation doses. Gamma-irradiation of zein solutions caused the disruption of the ordered structure of the zein molecules, as well as degradation, cross-linking, and aggregation of the polypeptide chains based on an SDS-PAGE study. Gamma-irradiation increased the solubility of zein and decreased the viscosity due to cleavage of the polypeptide chains. Protein solubility of the zein films in urea/2-mercaptoethanol also increased with increasing irradiation doses. Alterations of the zein molecules by irradiation decreased water vapor per-meability by 12% and increased the elongation of zein films. However, mean tensile strength of the zein films was decreased by gamma-irradiation treatment. Measurement of Hunter color values indicated that irradiation caused a destructive effect on yellow pigments, resulting in a significant decrease in Hunter b values. The microstructure as observed by scanning electron microscopy showed that irradiated zein film had a smoother and glossier surface than the non-irradiated films.

• 한국재료학회지
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• 제17권5호
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• pp.273-277
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• 2007

Vertically aligned Zinc Oxide rod arrays were grown by the self-assembly hydrothermal process on the GaN epitaxial layer which has a same lattice structure with ZnO. Zinc nitrate and DETA solutions are used in the hydrothermal process. The $(HfO_2)$ thin film was deposited on GaN and the patterning was made by the photolithography technique. The selective growth of ZnO rod was achieved with the patterned GaN substrate. The fabricated ZnO rods are single crystal, and have grown along hexagonal c-axis direction of (002) which is the same growth orientation of GaN epitaxial layer. The density and the size of ZnO rod can be controlled by the pattern. The optical property of ordered array of vertical ZnO rods will be discussed in the present work.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권5호
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• pp.379-384
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• 1999

Langmuir-Blodgett(LB) films which have high ordered orientation and ordering structure are fabricated by LB method which deposit the ultra-thin films of organic materials at a molecular level. The electrical characteristics of stearic acid LB ultra-thin films for the horizontal direction were investigated to develop the gas sensor using LB ultra-thin films. The optimal deposition condition to deposit the LB ultra-thin films was obtained from $\pi-A$ isotherms and the deposition status of stearic acid LB ultra-thin films was verified by the measurement of deposition ratio, UV-absorbance, and electrical properties for LB ultra-thin films. The conductivity of stearic acid LB ultra-thin films for horizontal direction was about $10_{-8}[S/cm]$. The activation energy for LB ultra-thin films with respect to variation of temperature was about 1.0[eV], which was correspond to semiconductor material. The response characteristics for organic gas were confirmed by measuring the response time, recovery time, and reproducibility of the LB ultra-thin to each organic gas. Also, the penetration and adsorption behavior of gas molecule were confirmed through the organic gas response characteristics of LB ultra-thin films with respect to temperature.

• 정보처리학회논문지D
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• 제15D권1호
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• pp.23-30
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• 2008

유비쿼터스 환경에서 상황정보 인식 분야를 연구하면서 가장 밑바탕에서 기초가 될 수 있는 것은 인터넷 기술과 XML(Extensible Markup Language)이다. 인터넷을 통한 통신에서 XML 데이터의 사용이 일반화되고 있으며 데이터의 형태는 연속적이다. 그리고 XML 스트림 데이터에 대한 질의를 처리하기 위한 방안들이 제시되고 있다. 이 논문에서는 스트림 데이터에 대한 질의처리를 효율적으로 수행하기 위한 기반연구로써 XML을 레이블의 순서화된 트리로 모델링하여 온라인 환경에서 빈발한 구조를 추출하는 마이닝 방법을 제안한다. 즉, 지속적으로 입력되는 XML 데이터의 구조를 트리로 모델링하고 각각의 트리를 하나의 트리 집합의 구조로 표현하여 현재 윈도우 시점에서 빈발한 구조를 정확하고 빠르게 추출하는 방법을 제시한다. 제시하는 방법은 XML의 질의 처리 및 색인 구성의 기초 자료로 활용될 수 있다.

• 전기학회논문지
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• 제56권8호
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• pp.1484-1490
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• 2007

The Cross Reference Point(CRP) is a robust method for finding salient points in watermarking systems because it is based on the geometrical structure of a normalized image in order to avoid pointing error caused by digital attacks. After normalization of an image, the 100 CRPs are calculated. Next, the 100 blocks centered by CRPS are formed. These 100 blocks are arranged using a secrete key. Each boundary of 50 out of 100 blocks is surrounded by 8 blocks which are selected by the ordered number of a preceding block. This number is a seed of random number generator for selecting 8 out of 50 blocks. The search area of a center block is formed by a secrete key. The pixels of a center block are quantized to 10 levels by predefined thresholds. The watermarks are generated by the 50 quantized center blocks. These watermarks are embedded directly in the remaining 50 blocks. In other words, 50 out of 100 blocks are utilized to generate watermarks and the remaining 50 blocks are used to watermark embedding. Because the watermarks are generated in the given images, we can successfully detect watermarks after several digital attacks. The reason is that the blocks for the generation and detection of watermarks are equally affected by digital attacks except for the case of local distortion such as cropping.

• Macromolecular Research
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• 제11권1호
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• pp.2-8
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• 2003

The self-assembly of polymers can lead to supramolecular systems and is related to the their functions of material and life sciences. In this article, self-assembly of Langmuir-Blodgett (LB) films, polymer micelles, and polymeric nanoparticles, and their biomedical applications are described. LB surfaces with a well-ordered and layered structure adhered more cells including platelet, hepatocyte, and fibroblast than the cast surfaces with microphase-separated domains. Extensive morphologic changes were observed in LB surface-adhered cells compared to the cast films. Amphiphilic block copolymers, consisting of poly(${\gamma}$-benzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) [or poly(N-isopropylacrylamide) (PNIPAAm)] as the hydrophilic one, can self-assemble in water to form nanoparticles presumed to be composed of the hydrophilic shell and hydrophobic core. The release characteristics of hydrophobic drugs from these polymeric nanoparticles were dependent on the drug loading contents and chain length of the hydrophobic part of the copolymers. Achiral hydrophobic merocyanine dyes (MDs) were self-assembled in copolymeric nanoparticles, which provided a chiral microenvironment as red-shifted aggregates, and the circular dichroism (CD) of MD was induced in the self-assembled copolymeric nanoparticles.