• Title/Summary/Keyword: ordered structure

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A Study on the Preparation and Application of Au/TiO2 Nanofiber from AAO Template (AAO Template를 이용한 Au/TiO2 나노섬유 제조 및 응용에 관한 연구)

  • Eom, Seon-Mi;Park, Sang-Sun;Kim, Young-Deok;Kim, Yong-Rok;Shul, Yong-Gun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.1
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    • pp.47-53
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    • 2009
  • In this study, highly ordered AAO (Anodic Aluminum Oxide) with nanopores was prepared by commercial grade Al substrate containing 3.5 wt.% impurities through two step anodizing method. Nanopores of prepared AAO arrays were used as templates for preparing nanofiber. $TiO_2$ was deposited by using DP (deposition-precipitation) method into AAO pores to grow nanofiber. Au particles were loaded on this $TiO_2$ nanofiber which was grown vertically. Prepared 2 wt.% $Au/TiO_2$ nanofiber was characterized by XRD, SEM and Raman. The crystal structure was analyzed by the XRD. SEM was used to observe pore size and pore wall thickness. Photocatalytic activity of co-oxidation was compared with $TiO_2$ and $Au/TiO_2$ nanofiber on AAO arrays.

Analysis on the Vegetation Structure of the Decomposed Granite Cut-slope - In case study on forest road of Gyeongsang-do and Jeolla-do - (화강암질 풍화토 절토비탈면의 식생구조 분석 - 경상도와 전라도 임도를 중심으로 -)

  • Song, Ho-Kyung;Park, Gwan-Soo;Lee, Joon-Woo;Lee, Mi-Jeong;Kim, Hyo-Jeong;Kwon, Oh-Won
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.7 no.1
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    • pp.59-67
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    • 2004
  • This study was carried out to select proper species for early stage replantation in granite forest roads cut-slope. From one to fourteen year elapsed forest roads in eight regional areas of Gyeongsang-do and Jeolla-do, sample plots were selected, and their vegetations and environmental factors were investigated. Soil organic matter, total nitrogen, soil moisture content, and bulk density in the granite weathering soils were below 0.4%, 0.03%, 12.4%, and above 1.2g/$cm^3$, respectively. The result indicated that the soil was not good for plant growth. The environmental factors affecting distribution of species in the granite forest roads were the elapsed year, elevation, and cut-slope aspect. Invaded species with high frequency in the forest road cut-slope ordered Pinus densiflora, Lespedeza bicolor, Rubus crataegifolius, Alnus hirsuta, Youngia denticulata, Patrinia villosa, Artemisia princeps var. orientalis, Zanthoxylum schinifolium, and Dactylis glomerata. Herbs seeded in earth stage such as Dactylis glomerata, Eragrostis curvula, Festuca arundinacea, Lespedeza sp., and Amorpha fruticosa had changed into perennial herbs and shrubs such as Youngia denticulata, Patrinia villosa, Aster scaber, Patrinia scabiosaefolia, Melica onoei, Astilbe chinensis var. davidii, Chrysanthemum zawadskii var. latilobum, Pueraria thunbergiana, Stephanandra incisa, and Clematis apiifolia, and had changed into plants such as Artemisia princeps var. orientalis, Artemisia keiskeana, Miscanthus sinensis, Pinus densiflora, Rhododendron mucronulatum, Rubus crataegifolius, and Zanthoxylum schinifolium according to elapsed year of forest roads. Leguma such as Lespedeza sp., Pueraria thunbergiana, Amorpha fruticosa, etc., herbs such as Artemisia keiskeana, Artemisia princeps var. orientalis, Chrysanthemum zawadskii var. latilobum, Miscanthus sinensis, etc., and woody plants such as Pinus densiflora, Rubus crataegifolius, Rhododendron mucronulatum, etc., with foreign herbs were considered as proper species for replantation in granite forest road cut-slope.

A Historical, Mathematical, Psychological Analysis on Ratio Concept (비 개념에 대한 역사적, 수학적, 심리적 분석)

  • 정은실
    • School Mathematics
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    • v.5 no.4
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    • pp.421-440
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    • 2003
  • It is difficult for the learner to understand completely the ratio concept which forms a basis of proportional reasoning. And proportional reasoning is, on the one hand, the capstone of children's elementary school arithmetic and, the other hand, it is the cornerstone of all that is to follow. But school mathematics has centered on the teachings of algorithm without dealing with its essence and meaning. The purpose of this study is to analyze the essence of ratio concept from multidimensional viewpoint. In addition, this study will show the direction for improvement of ratio concept. For this purpose, I tried to analyze the historical development of ratio concept. Most mathematicians today consider ratio as fraction and, in effect, identify ratios with what mathematicians called the denominations of ratios. But Euclid did not. In line with Euclid's theory, ratio should not have been represented in the same way as fraction, and proportion should not have been represented as equation, but in line with the other's theory they might be. The two theories of ratios were running alongside each other, but the differences between them were not always clearly stated. Ratio can be interpreted as a function of an ordered pair of numbers or magnitude values. A ratio is a numerical expression of how much there is of one quantity in relation to another quantity. So ratio can be interpreted as a binary vector which differentiates between the absolute aspect of a vector -its size- and the comparative aspect-its slope. Analysis on ratio concept shows that its basic structure implies 'proportionality' and it is formalized through transmission from the understanding of the invariance of internal ratio to the understanding of constancy of external ratio. In the study, a fittingness(or comparison) and a covariation were examined as the intuitive origins of proportion and proportional reasoning. These form the basis of the protoquantitative knowledge. The development of sequences of proportional reasoning was examined. The first attempts at quantifying the relationships are usually additive reasoning. Additive reasoning appears as a precursor to proportional reasoning. Preproportions are followed by logical proportions which refer to the understanding of the logical relationships between the four terms of a proportion. Even though developmental psychologists often speak of proportional reasoning as though it were a global ability, other psychologists insist that the evolution of proportional reasoning is characterized by a gradual increase in local competence.

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Effects of Surface Microstructure on Microwave Dielectric Properties of ZrO2-NiO added Ba(Zn1/3Ta2/3)O3 Ceramics (ZrO2와 NiO가 첨가된 Ba(Zn1/3Ta2/3)O3에서 표면 미세조직이 고주파 유전특성에 미치는 영향)

  • Kang, Sung-Woo;Kim, Tae-Heui;Moon, Joo-Ho;Kim, Sung-Youl;Park, Jun-Young;Choi, Sun-Hee;Kim, Joo-Sun
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.701-706
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    • 2008
  • High frequency dielectric ceramics have potential for applications in mobile and satellite communications systems at frequencies higher than 10GHz. The Ba$(Zn_{1/3}Ta_{2/3})O_3$ ceramics are known to have a high quality factor, a small temperature coefficient of the resonance frequency and a high dielectric constant. On the other hands, sintering at high temperature for extended time is required to obtain the ordered structure for high quality factor. In this study, the microwave dielectric properties of $ZrO_2$ and NiO-added Ba$(Zn_{1/3}Ta_{2/3})O_3$ ceramics prepared by solid-state reaction have been investigated. Adding $ZrO_2$ and NiO could effectively promote the densification even the case of decreasing the sintering time. At the surface of samples, secondary phase of Ba-Ta compounds was formed possibly due to the evaporation of ZnO, however, the interior of the samples remained as pure Ba$(Zn_{1/3}Ta_{2/3})O_3$. The samples sintered at $1600^{\circ}C$ for 2h exhibited 1:2 ordering of Zn and Ta cations. Excellent microwave dielectric properties of $Q{\cdot}f$(>96,000 GHz) and ${\varepsilon}_r$=30 has been obtained.

Synthesis, Spectral and Thermal Studies of Lanthanide(III) Complexes of Phenylbutazone (Phenylbutazone의 란탄(III) 착물에 대한 합성, 스펙트럼 및 열적 연구)

  • Anoop, M.R.;Binil, P.S.;Jisha, K.R.;Suma, S.;Sudarsanakumar, M.R.
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.612-619
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    • 2011
  • Lanthanide(III) complexes of 1,2-diphenyl-4-butyl-3,5-pyrazolidinedione(phenylbutazone, PB) have been synthesized and characterized by elemental analyses, molar conductance measurements, IR, UV-Vis. and NMR spectra. The spectral data reveal that the PB acts as a bidentate and mono-ionic ligand coordinating through both the carbonyl oxygens of the pyrazolidinedione ring. The molar conductance data suggest that the complexes are non-electrolytes. The thermal behaviour of the complexes was studied by TG and DTG in air atmosphere and the results provide information about dehydration, thermal stability and thermal decomposition. The final products are found to be the corresponding metal oxides. The thermodynamic parameters and kinetic parameters were evaluated for the dehydration and decomposition stages. The negative entropy values of the decomposition stages indicate that the activated complexes have a more ordered structure than the reactants and that the reactions are slower than normal. Based on these studies, the complexes have been formulated as $[Ln(PB)_3]{\cdot}5H_2O$(Ln=La and Ce) and $[Ln(PB)_3(H_2O)_2]{\cdot}2H_2O$(Ln=Pr, Nd and Sm).

Synthesis and Characterization of Hybrid Nanocomposites of Pd Nanoparticles Containing POSS(Pd-POSS) and Poly(acrylic acid) via Ionic Interactions (실세스키옥세인을 포함한 팔라듐 나노입자와 폴리아크릴산과의 이온결합에 의한 나노복합체 제조 및 특성평가)

  • Jeon, Jong-Hwan;Lim, Jung-Hyurk;Chujo, Yoshiki;Kim, Kyung-Min
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.615-619
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    • 2009
  • Pd-POSS nanoparticles were produced from the reaction of palladium (II) acetate and octa(3-aminopropyl)octasilsesquioxane octahydrochloride (POSS-${NH_3}^+$) in methanol at room temperature. Pd-POSS nanoparticles with a mean diameter of 60-80 nm were the highly ordered spherical aggregates. In contrast, Pd nanoparticles with a size of 4.0 nm were obtained when POSS-${NH_3}^+$ was not introduced. Pd-POSS/PAA nanocomposites of Pd-POSS nanoparticles and poly(acrylic acid) (PAA) were fabricated by utilizing ionic interactions between positively charged Pd-POSS nanoparticles and negatively charged carboxylate groups of PAA. PAA was used as a cross-linker for the preparation of hybrid nanocomposites with the controlled organized structures of Pd-POSS nanoparticles. That is, the self-organization of Pd-POSS nanoparticles was formed into the shape of continuous lines by using PAA as a cross-linker. The composition, structure, surface morphology, and thermal stability of the Pd-POSS/PAA nanocomposites were studied by FE-SEM, AFM, TEM, FT-IR, and TGA.

Hilbert Cube for Spatio-Temporal Data Warehouses (시공간 데이타웨어하우스를 위한 힐버트큐브)

  • 최원익;이석호
    • Journal of KIISE:Databases
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    • v.30 no.5
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    • pp.451-463
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    • 2003
  • Recently, there have been various research efforts to develop strategies for accelerating OLAP operations on huge amounts of spatio-temporal data. Most of the work is based on multi-tree structures which consist of a single R-tree variant for spatial dimension and numerous B-trees for temporal dimension. The multi~tree based frameworks, however, are hardly applicable to spatio-temporal OLAP in practice, due mainly to high management cost and low query efficiency. To overcome the limitations of such multi-tree based frameworks, we propose a new approach called Hilbert Cube(H-Cube), which employs fractals in order to impose a total-order on cells. In addition, the H-Cube takes advantage of the traditional Prefix-sum approach to improve Query efficiency significantly. The H-Cube partitions an embedding space into a set of cells which are clustered on disk by Hilbert ordering, and then composes a cube by arranging the grid cells in a chronological order. The H-Cube refines cells adaptively to handle regional data skew, which may change its locations over time. The H-Cube is an adaptive, total-ordered and prefix-summed cube for spatio-temporal data warehouses. Our approach focuses on indexing dynamic point objects in static spatial dimensions. Through the extensive performance studies, we observed that The H-Cube consumed at most 20% of the space required by multi-tree based frameworks, and achieved higher query performance compared with multi-tree structures.

Construction of the Terminology Dictionary for National R&D Information Utilization (국가R&D정보활용을 위한 전문용어사전 구축)

  • Kim, Tae-Hyun;Yang, Myung-Seok;Choi, Kwang-Nam
    • The Journal of the Korea Contents Association
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    • v.19 no.10
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    • pp.217-225
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    • 2019
  • National research and development(R&D) information is information generated in the process of performing R&D based on programs and projects issued by national government departments, and includes information from various research fields as ordered by various departments. Therefore, for efficient R&D information retrieval, it is necessary to build a national R&D terminology dictionary that can reflect the characteristics of such national R&D information. In this study, we propose a method for constructing a national R&D terminology dictionary by applying the classification of science and technology standards used to specify the research field in national R&D information. We will discuss the structural characteristics of national R&D project information and the usefulness of the project keyword, and explain the status of national R&D information by the National Standard Science and Technology Classification(NSSTC) Codes and the characteristics of the national R&D terminologies. Based on this, a method for building a national R&D terminology dictionary is defined in terms of the type and structure of the terminology dictionary, preliminary construction procedures, and refining rules. The national R&D terminology dictionary built on the basis of this study can be used in various ways such as expansion of search terms using Korean-English equivalent words and synonyms when searching national R&D information, clarifying the scope of search using NSSTC, and providing user convenience functions using term explanation information.

Development of Agenda for Pharmaceutical Care Service Research and Development using the Analytical Hierarchy Process (약료서비스 R&D 고도화를 위한 우선순위 기반 전략과제 설정)

  • Han, Nayoung;Jeong, Chae-Reen;Song, Yun-Kyoung;Yoon, Jeong-Hyun;Jang, Sunmee;Lee, Eui-Kyung;Shin, Hyun Taek;Lee, Young Sook;Sohn, Hyun Soon;Ji, Eunhee;Suh, Dong Chul;Kim, Daekyung;Oh, Jung Mi
    • Korean Journal of Clinical Pharmacy
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    • v.29 no.1
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    • pp.45-55
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    • 2019
  • Background: Although the importance of pharmaceutical care service has been growing to meet the needs of customers with the improvement of clinical and humanistic outcomes, there was not a systematic strategy to promote research in Korea. The aim of this study was to suggest the core agendas for pharmaceutical care services research and development (R&D) considering priorities. Methods: Based on desk researches, we developed R&D agendas for the needs of improving pharmaceutical care services in the area of institution, community, and public health. To determine the priority of agendas in developing pharmaceutical care service, analytic hierarchy process (AHP) analysis was performed by the 14 experts. Criteria and subcriteria were assessed for significance by pairwise comparisons. Then, agendas were evaluated for importance according to each subcriteria, and rank ordered considering the weight calculated by multiplying the importance scores of the criteria and the subcriteria. Results: We derived 25 agendas including 13 for institutional pharmaceutical care service, 8 for community pharmaceutical care service, and 4 for public-health related pharmaceutical care service. AHP model was constructed based on 4 criteria and 8 subcriteria by a hierarchical structure. From the AHP survey, the 'Development of pharmaceutical care service for metabolic and chronic disease' agenda accounted for the highest priority. Conclusion: We have developed the R&D agendas of the pharmaceutical care service which should be promoted. The results should be utilized by the government to nationally support the development of the standards and relevant regulations related to pharmaceutical care services in Korea.

Experimental study on ultra-high strength concrete(130 MPa) (초고강도 콘크리트(130MPa)에 대한 실험적 연구)

  • Cho Choonhwan;Yang Dong-il
    • Journal of the Korea Institute of Construction Safety
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    • v.6 no.1
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    • pp.12-18
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    • 2024
  • High-rise, large-scale, and diversification of buildings are possible, and the reduction of concrete cross-sections reduces the weight of the structure, thereby increasing or decreasing the height of the floor, securing a large number of floors at the same height, securing a large effective space, and reducing the amount of materials, rebar, and concrete used for designating the foundation floor. In terms of site construction and quality, a low water binder ratio can reduce the occurrence of dry shrinkage and minimize bleeding on the concrete surface. It has the advantage of securing self-fulfilling properties by improving fluidity by using high-performance sensitizers, making it easier to construct the site, and shortening the mold removal period by expressing early strength of concrete. In particular, with the rapid development of concrete-related construction technology in recent years, the application of ultra-high-strength concrete with a design standard strength of 100 MPa or higher is expanding in high-rise buildings. However, although high-rise buildings with more than 120 stories have recently been ordered or scheduled in Korea, the research results of developing ultra-high-strength concrete with more than 130 MPa class considering field applicability and testing and evaluating the actual applicability in the field are insufficient. In this study, in order to confirm the applicability of ultra-high-strength concrete in the field, a preliminary experiment for the member of a reduced simulation was conducted to find the optimal mixing ratio studied through various indoor basic experiments. After that, 130 MPa-class ultra-high-strength concrete was produced in a ready-mixed concrete factory in a mock member similar to the life size, and the flow characteristics, strength characteristics, and hydration heat of concrete were experimentally studied through on-site pump pressing.