• Title/Summary/Keyword: optimum mixture

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Optimum Process Condition by Experimental Design Method for the Synthesis of Methylchlorosilanes(MCS) (실험계획법에 의한 메틸염화실란 합성의 최적공정조건)

  • Cho, Chul Kun;Han, Kee Do
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.394-398
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    • 1998
  • An optimum synthetic condition was studied for the MCS used as a silicone monomer. The contact mixture was made from the four component catalyst system($CuCl/ZnCl_2/Sn/Cd$) and silicon particles. The contact mass was used for a series of experiments with methyl chloride, which were designed and done to explore the optimum condition for MCS synthesis by an experimental design method. The optimum temperature and MeCl flow rate, which were obtained using 50g contact mass at 60rpm and 1 atm, were in the range of $300-305^{\circ}C$ and of 70-80ccm. Also a continuous run was performed to confirm the conditions. The results showed that the average reaction rate and selectivity were 170(g-MCS/hr.kg-Si) and 0.05 respectively at 67% conversion of MeCl and 92% silicon utilization rate. Also the parameters of overall reaction rate equation and a total pressure were estimated on the basis of the results of the continuous run.

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A Study on Optimum Mixing Ratio of Paper Wastes as Bulking Agent in Cornposting of Swine Feces (돈분의 퇴비화에 있어서 종이류 폐기물의 적정 배합량에 관한 연구)

  • 정문식;박석환;최경호;손현석;김성균;박지영
    • Journal of Environmental Health Sciences
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    • v.22 no.4
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    • pp.82-90
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    • 1996
  • This study was performed to find the optimum mixing ratio of paper waste in composting of mixture of swine feces and newspaper. Using the experimental setting of aeration rate which was found in the experiment carried out priorly, and moisture contents reported in other literature, just the initial C:N ratios were differentiated by mixing different amount of newspaper with the same amount of swine feces. This study was carried out by operating 4 experimental cornposting reactors of bench scale for 3 weeks. The followings are the conclusions that were derived from this study. 1. During composting reaction, the C:N ratio of each cornposter was decreased. Degree of decrease was in order of run 3, run 2, run 4, and run 1 of which initial C:N ratio was 30, 25, 35, and 20 respectively. All of the final composts were found to be completed composting reaction. 2. Ash contents of each reactor increased rapidly in order of run 3, run 2, run 4, and run 1. The absolute values of quadratic effect coefficients of each second order regression function was 0.059, 0.038, 0.032, and 0.030 respectively. Ash contents evolution trend had a linear correlation with the C:N ratio trend. (r=-0.96932, p<0.05) 3. The range of highest temperatures reached during composting was 47.2-53.5$\circ$C. Those were not significantly different from one another. Thermophilic temperatures were maintained in the range of 48-108 hours. 4. Contents of heavy metal detected in the final compost were lower than those of Korean and European standards. 5. Concentration range of Nitrogen in the final compost was 1.11-2.27%, and that of phosphorus was 8.40-10.70 mg/kg. 6. The optimum C:N ratio which has been proposed without the consideration of types of bulking agents should be re-examined. Biodegradabilities of each bulking agents was thought to be important factor when determining the optimum initial C:N ratio for cornposting.

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The Preparation of Fermented Milk from Milk and Fruit Juices (우유와 과즙을 이용한 발효유의 제조)

  • Ko, Young-Tae;Kang, Jung-Hwa
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1241-1247
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    • 1997
  • Gel-type fermented milk was prepared from milk or mixture of milk and apple juice/grape juice. Acid production (pH change) and growth of Lactobacillus acidophilus (KCTC 2182) were studied. The effects of juice addition on sensory property of fermented milk were also studied. The pH value of samples containing mixture of milk and apple juice/grape juice (25 mL : 25 mL to 5 mL : 45 mL) was lower than that of milk sample. However, number of viable cells of L. acidophilus at 21 hr in milk and samples containing juices was similar. During lactic fermentation for 24 hr, pH of all samples dropped significantly between 6 hr and 21 hr. pH values of mixture of milk and juices were lower than that of milk sample. Growth curve showed that lag phase continued to approximately 3 hr and log phase continued to approximately 15 hr in all samples. Number of viable cells in all samples was similar Sensory evaluation showed that overall acceptability of fermented milk prepared from apple juice/grape juice and milk (15 mL : 35 mL or 5 mL : 45 mL) was better than that of reference sample. The optimum ratio of mixture of juice and milk was 15 mL : 35 mL. The score values of sensory test of fermented milk prepared from mixture of grape juice and milk were slightly higher than those of mixture of apple juice and milk.

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Output Enhancement of Coaxial Flashlamp Pumped Rhodamine 6G Dye Laser by Energy Transfer (에너지 전환에 의한 동축 섬광관 펌핑 Rhodamine 6G 색소 레이저의 출력 증가)

  • 장우권
    • Korean Journal of Optics and Photonics
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    • v.4 no.2
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    • pp.195-199
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    • 1993
  • The output energy of Rh-6G dye laser was enhanced by the energy transfer in the mixture of Rh-6G and C-545. The laser was pumped by coaxial flashlamp filled argon gas. The optimum concentration of Rh-6G was $10_-4mol/l$ without mixing. The output energy was enhanced about 70 % at 0.4 % C-545 mixture with respect to the concentration of Rh-6G. The peak output power and the output energy were 27 kW and 50 mJ at the pumping energy of 346 J.

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Synthesis of Aluminum Nitride Powder from Aluminum Hydroxide by Carbothermal Reduction-Nitridation (알루미나 수화물로부터 탄소환원질화법에 의한 질화알루미늄 분말의 합성)

  • 황진명;정원중;최상욱
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.893-901
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    • 1994
  • In this study, AlN powder of fine particle size and of high purity was synthesized by the carbothermal reduction-nitridation of monodisperse, spherical Al(OH)3 which had been prepared by sol-gel method using Al(O-sec-C4H9)3 as the starting material. Depending on the mixing order and kinds of reducing agents, the optimum condition for the preparation of AlN was determined as follows. AlN single-phase was produced by the carbothermal reduction-nitridation of (1) Benzene-washed Al(OH)3 and the reducing agent, carbon, which was mixed in a ball mill: for 5 hours at 140$0^{\circ}C$ under NH3 atmosphere; (2) The mixture prepared by hydrolysis of alkoxide solution into which carbon had been dispersed beforehand: for 5 hours at 135$0^{\circ}C$ ; (3) Al(OH)3 Poly(furfuryl alcohol) composite powder: for 2.5 hours at 135$0^{\circ}C$; (4) The mixture of Al(OH)3 and polyacrylonitrile: for 5 hours at 140$0^{\circ}C$. Addition of CaF2 increased the nitridation rate when carbon or polyacrylonitrile was used as the reducing agent; but it had no effect on the nitridation rate when furfuryl alcohol was used as the reducing agent.

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The Investigation of Reaction Parameters on the Reactivity in the Preparation of SiC by SHS (자전연소합성법에 의한 SiC 분말 제조시 반응변수의 영향)

  • Shin, Chang-Yun;Won, Hyung-Il;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.427-432
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    • 2006
  • The preparation of SiC powder by SHS in the system of $SiO_2-Mg-C$ was investigated in this study. The effects of various processing parameters such as the initial pressure of inert gas in reactor, the content of Mg and C in mixture and the size of $SiO_2$ particles on the synthesis of SiC by SHS methode were investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 5 atm, and as the pressure increased, and the concentration of unreacted Mg decreased. At 50 atm of the initial inert gas pressure in reactor, the optimum composition for the preparation of pure SiC was $SiO_2+2.5Mg+1.2C$. SiC powder synthesized in this condition had a mixture of ${\alpha}-SiC\;and\;{\beta}-SiC$ with an irregular shape and the particle size of $0.5{\sim}0.8{\mu}m$.

Studies on the Compressive Strength in Lime-Soil Mixtures -Influence of Lime-Content and Curing on Compressive Strength- (석회혼합토의 압축강도에 관한 연구 (제1보) -석회함량 및 갱생이 강도에 미치는 영향-)

  • 김성완
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.14 no.4
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    • pp.2761-2769
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    • 1972
  • The following results were obtained by the compression test of 3, 7, 14 and 28 days cured lime soil mixtures. The soil used in this test was clayey soil(sand : 20% silt : 45%, clay : 35%) and the rates of hydrated lime mixture for the dry weight of soil were 4, 8, 12, 19 and 20 percents. 1. The optimum moisture content increases and the maximum dry density decreases with the increase of the lime content. 2. The compacted moisture for the maximum strength in lime soil mixture increases with the increase of the lime content and the increase of curing periods. 3. The compressive strength increase of curing periods and its increasing ratio is largest at the 8 percent lime content. 4. The line content for the maximum strength decreases with increase of curing period and the largest strength shows at the 8 percent lime content when the curing period is over two weeks. 5. It seems to depend on the temperature effect that the compressive strength of lime soil mixtures cured in soil shows the lowest value. Accordingly, the effect of curing moisture does not influence to the strength of lime soil mixtures as much as the variation of curing temperature.

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Triboelectrostatic Separation System for Separation of PVC and PS Materials Using Fluidized Bed Tribocharger

  • Lee, Jae-Keun;Shin, Jin-Hyouk;Hwang, Yoo-Jin
    • Journal of Mechanical Science and Technology
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    • v.16 no.10
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    • pp.1336-1345
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    • 2002
  • A triboelectrostatic separation system using a fluidized bed tribocharger for the removal of PVC material in the mixture of PVC/PS plastics is designed and evaluated as a function of electric field strength, air flow rate, and the mixing ratio of two-component mixed plastics. It consists of a fluidized-bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PS particles can be imparted negative and positive surface charges, respectively, due to the difference in the work function values of plastics suspended in the fluidized-bed tribocharger, and can be separated by passing them through an external electric field. Experimental results show that separation efficiency is strongly dependent on the electric Deld strength and particle mixing ratio. In the optimum conditions of 150 Ipm air flow rate and 2.6 kV/cm electric field strength a highly concentrated PVC (99.1%) can be recovered with a yield of more than 99.2% from the mixture of PVC and PS materials for a single stage of processing.

Study on physical characteristic of Graphite-added grout for backfilling cloed-loop groud heat exchanger (흑연(Graphite) 첨가를 통한 수직 밀폐형 지중열교환기 뒤채움재의 열전도 특성 향상 연구)

  • Lee, Kang-Ja;Gil, Hu-Jeong;Lee, Chul-Ho;Choi, Hang-Seok;Choi, Hyo-Pum
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.579-582
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    • 2009
  • The thermal conductivity and viscosity(or workability) of graphite-added bentonite grouts and cementitious grouts have been evaluated and compared to determine the suitability of these materials for backfilling vertical boreholes of ground heat exchangers. Seven bentonite grouts from different product sources and a portland cement grout with various mixture ratios were considered in this paper. As a new additive for grout, we choose graphite which has high thermal conductivity. The bentonite grouts indicate that the thermal conductivity and viscosity increase with the content of bentonite or with an addition of Graphite compared with that of silica sand. In case of cementitious grout also increase the thermal conductivity and decrease the workability dramatically though an addition of Graphite. Therefore, we cautiously select the amount of graphite and mixture ratio of bentonite and cement considering not only thermal conductivity but also viscosity for the optimum condition of backfilling material.

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Development of High Functional Coating Agents for Pulp Mold (IV) - Manufacture of higher functional and biodegradable coating agents - (펄프몰드용 새로운 고기능 코팅제 제조기술개발(제4보) - 고기능 생분해성 코팅제 제조 -)

  • Kang Jin-Ha;Lim Hyun-A;Park Seong-Cheol
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.1 s.113
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    • pp.45-53
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    • 2006
  • This study was carried out to produce high functional and biodegradable coating agents for pulp mold by evaluating various kinds of biodegradable polymers. Five kinds of biodegradable polymers were used. In addition, the mixture of the carboxymethylated starch and biodegradable polymers(${\kappa}$-carrageenan, chitosan) were used for mixed coating agents. Physical properties of coated paperboards were evaluated. Conclusions obtained were as follows. 4% ${\kappa}$-carrageenan and 5% chitosan showed higher water and oil resistance. 10% sodium alginate, 4% corn zein and 15% polycaprolactone showed high water resistance while no improvement was found on oil resistance. The optimum mixture ratios for the mixed coating agents were 90:10(carboxymethylated starch : ${\kappa}$-carrageenan) and 50:50(carboxymethylated starch : chitosan). Since these mixed coating agents have excellent biodegradability with higher water and oil resistance, these can be used for the environmental-friendly coating agents.