• Title/Summary/Keyword: optimum dosage

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Isotherm, kinetic and thermodynamic studies of dye removal from wastewater solution using leach waste materials

  • DEN, Muhammed Kamil O;ONGAR, Sezen KUC UKC
    • Advances in environmental research
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    • v.8 no.1
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    • pp.23-38
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    • 2019
  • In this study, Malachite Green (MG) dye removal from synthetic wastewaters by adsorption process using raw boron enrichment waste (BEW) and it's modifications (with acid and ultrasound) were aimed. 81% MG removal was obtained by BEW at optimum equilibrium conditions (time: 40 min., dosage: 500 mg/dm3, pH: 5-6, speed: 200 rpm, 298 K). MG removal from wastewaters using acid modified boron enrichment waste (HBEW) was determined as 82% at optimum conditions (time: 20 min., dosage: 200 mg/dm3, pH: 10, speed: 200 rpm, 298 K). For ultrasound modified BEW (UBEW), the highest MG removal percent was achieved as 84% at optimum conditions (time: 30 min, dosage: 375 mg/ dm3, pH: 8, speed: 200 rpm, 298 K). The equilibrium data of Malachite Green was evaluated for BEW, HBEW and UBEW adsorbents by using sorption isotherms such as Langmuir, Freundlich and Temkin models, out of which Langmuir model (R2 = 0.971, 0.987 and 0.984) gave better correlation and maximum adsorption capacity was found to be 147.05, 434.78 and 192.30 mg/g, respectively. The adsorption kinetics followed the pseudo-second-order kinetic equation for sorption of MG onto wastes. A look at thermodynamic data reveals that natural sorption is spontaneous and endothermic because of free negative energy exchange and positive change in enthalpy, respectively. The results indicated that boron enrichment waste, and HCl and ultrasound-modified boron enrichment waste served as good alternative adsorbents in dye removal from wastewater.

Effect of Operating Parameters on Electrochemical Degradation of Rhodamine B by Three-dimensional Electrode (3차원 전극을 사용한 Rhodamine B의 전기분해에 미치는 운전인자의 영향)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.35 no.4
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    • pp.295-303
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    • 2009
  • A simulated wastewater containing the dye Rhodamine B (RhB) was electrolytically treated using a three-dimensional electrode reactor equipped with granular activated carbon (GAC) as particle electrode. The effect of type of packing material (GAC, ACF, Nonwoven fabric fiber coated with activated carbon), amounts of GAC packing (25-100 g), current (0.5-3 A) and electrolyte concentration (0.5-3 g/l) was evaluated. Experimental results showed that performance for RhB decolorization of the 3 three-dimensional electrodes lie in: GAC > Nonwoven fabric fiber > ACF. When considered RhB decolorization, oxidants concentration and electric power, optimum GAC dosage was 50 g. Generated concentration of 3 oxidants ($ClO_2$, free Cl, $H_2O_2$) was increased with increase of applied current, however optimum current for RhB degradation was 2.5 A. The oxidants concentration was increased with increase of NaCl concentration and optimum NaCl dosage for RhB degradation was 1.5 g/l.

Estimation of Optimum PP Fiber Content for the Spalling Control of High Strength Reinforced Concrete Columns (고강도 철근콘크리트 기둥의 폭열제어를 위한 최적의 PP섬유함유량 산정)

  • Kim, In Ki;Yoo, Suk Hyeong;Shin, Sung Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.2
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    • pp.155-163
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    • 2007
  • High Strength Concrete (HSC) has weakness that in a fire, it is spalled and brittles. The phenomenon of spalling is made by water vapor's (resulting from evaporation in the material at over $100{^{\circ}C}$)' being confined in watertight concrete. As the concrete strength increases, the degree of damage caused by the spalling becomes more serious because of the permeability. It is reported that the polypropylene(PP) fiber has an important role in protecting concrete from spalling and the optimum dosage of PP fiber is 0.2%. This study was conducted on the nonreinforced concrete specimens. The high-temperature behavior of high-strength reinforced concrete columns with various concrete strength and various dosage of PP fibers was investigated in this study. The results show that the ratio of unstressed residual strength of columns increases as the concrete strength increases and the ratio of unstressed residual strength of columns increases as the dosage of PP fiber increases from 0% to 0.2%, however, the effect of fiber dosage on residual strength of column barely changes above 0.2%.

Optimization of In-line Coagulation/MF Process Using On-line Streaming Potential Measurement (On-line streaming potential 측정에 의한 in-line 약품응집/정밀여과 공정의 최적화)

  • Oh, Jeong-Ik;Lee, Seockheon
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.522-528
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    • 2004
  • Microfiltration with in-line rapid coagulation for drinking water production was examined. The in-line rapid coagulation was conducted using newly developed mixing device instantaneous flash mixer. The flux decline during membrane filtration was monitored with coagulant dosage varied. Flux decline was minimized at 1.1mg/L of coagulant dosage, where streaming potential of coagulated water was near zero. The optimum dosage for the process control was explained by dimensionless distance (${\kappa}{\times}a$) of particle pairs, obtained from electrophoresis parameter describing electrostatic repulsion relative to Van der Waals energy between particle pairs in the pre-coagulated water.

The study of chemical treatment of pulp mill bleaching waste liquor using sea water (해수를 이용한 펄프공장 폐액의 화학적 처리에 관한 연구)

  • 정병곤;이헌모;윤종호
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.39-48
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    • 1997
  • The study was conducted to know the possibility that the removal efficiency of organic and suspended solids(SS) could be increased by suppling of sea water and the optimum amount of sea water to be supplied treat bleaching waste water by lime coagulation settlement at pulp mill process. When the lime dosage was increased, the removal efficiency of COD and SS in the waste water was increased based on the removal efficiency of COD and SS. The lime dosage and removal efficiency was increased proportionally with the lime concentration of 4,000 mg/l, but the increase of removal efficiency was presented slightly above the 4,000mg/l. It was evaluated that the removal efficiencies of COD and SS could be increased and the requirement of lime dosage could be decreased by the sea water supplement. The removal efficiency of SS was most increased when the sea water supplement was 10% or more in the waste water. The removal efficiencies of COD was the best at 4% sea water excepting the dilution efficiency by sea water supplement.

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Dosage Adjustment of Zinc (아연의 투여용량설정)

  • Jung, So Young;Shin, Wan Gyoon;Kim, Ho Soon;Cho, Nam Choon
    • Korean Journal of Clinical Pharmacy
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    • v.7 no.2
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    • pp.64-66
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    • 1997
  • Zinc is employed in body cell growth and immune function. Zinc deficiency causes growth retardation, night blindness, delay of wound healing, skin disorders, alopecia, et al. Pharmacokinetic study of zinc in Korean has not yet been proceeded to apply to patient. In this study, we investigated to adjust zinc dosage for maintaining constant zinc optimum serum level. Five NPO inpatients (3 males, 2 females) in Seoul National University of Hospital were evaluated, retrospectively. Zinc was mixed with parenteral nutrition solution and administrated intravenously in 24 hour-continuous infusion, and zinc dosage range was 0.17-0.45 mg/kg/day. AUC to zinc dose (AUC/Dose) was $2.421\pm1.007\;kg{\cdot}min/ml.$ 0.5 mg/kg/day zinc administration may achieve the plasma zinc concentration of $120\;{\mu}g/dl.$(Kor. J. Clin. Pharm. 1997; 7: 64-66)

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Formulation and Pharmaceutical Properties of Mucoadhesive Film Containing Dipotassium Glycyrrhizate (구내염증 치료용 구강점막 필름제의 제제설계와 약제학적 성질)

  • Rhee, Gye-Ju;Lee, Duk-Keun;Sin, Kwang-Hyun;Park, Chong-Bum
    • Journal of Pharmaceutical Investigation
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    • v.29 no.2
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    • pp.127-136
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    • 1999
  • In order to eliminate demerits of conventional dosage forms, dipotassium glycyrrhizate was formulated as a slim mucoadhesive film type dosage form. The mucoadhesive drug layer gel containing dipotassium glycyrrhizate was prepared using $Noveon^{\circledR}$ AA-1, hydroxypropylcellulose-M, ethylcellulose N 100 and citric acid, and the protective layer gel by using ethylcellulose N 100, $Eudragit^{\circledR}$ RS and castor oil. The viscosity of drug layer gel of mucoadhesive film was enhanced as the increased amount of $Noveon^{\circledR}$ AA-1 or hydroxypropyl cellulose-M. The drug content was unifonnly $1160{\pm}14.6\;{\mu}g$, and was varied within 3.5%. The optimum film dosage form showed a good fluidity and malleability of drug layer, with 179 g of thickness, pH 5.7, 411 min of in vitro adhesion time and 172 g in gravity adhesive strength. The release time of drug from the mucoadhesive film was significantly shorter but was delayed when polymers such as ethylcellulose was added. From these results, the new mucoadhesive film may be effective for the treatment of aphthous stomatitis.

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A Study on the Coagulation of Aquatic Humic Acid and Reducing Residual Aluminum (수중 Humic Acid의 효율적 응집처리와 잔류알루미늄 감소방안에 관한 연구)

  • 김수연;정문호;두옥주
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.38-46
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    • 1998
  • The purpose of this study is to evaluate and compare the effective coagulation of commercial humic acid which is well known as major precursor of trihalomethane, with LAS and PAC and to quantify the residual aluminum in the treated water. Then the optimum pH, the dosage of coagulant were determined. 1. Humic acid concentrati6n, UV absorbance and color were well correlated and UV absorbance(254 nm) and color seem to be used in quntificative analysis of humic acid of same kind. 2. Optimal dosage of LAS and PAC increase as humic acid concentration increases. And optimal pH range for coagulation using LAS is pH 5.5-7.0 and pH 3.5-6.5 for PAC. Within these ranges the removal efficiency is 90-99%. 3. The results of quantification of residual aluminum in treated water shows that minimal aluminum remains on the optimal coagulation condition. But the residual aluminum increses as the dosage of coagulant is beyond the optimal range. Thus the dosage of coagulant should be chosen with the condition on which humic acid removal is maximum and the residual aluminum concentration is minimum. 4. In the water treatment process the raw water pH range is 6.5-8.0, and it seems to be possible to remove humic acid by charge neutralization not by sweep floc. But it should be considered that different commercial humic acids have different physical and chemical characteristics.

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Geotechnical behaviour of nano-silica stabilized organic soil

  • Kannan, Govindarajan;Sujatha, Evangelin Ramani
    • Geomechanics and Engineering
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    • v.28 no.3
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    • pp.239-253
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    • 2022
  • Suitable techniques to stabilize organic soil and improve its engineering behaviour are in demand. Despite various alternatives, nano-additives proved to be an effective stabilizer owing to their strength enhancing properties. The study focuses on using nano-silica as a potential stabilizer to improve organic silt. Soil was treated with four dosages of nano-silica namely 0.2%, 0.4%, 0.6% and 0.8% of dry weight of the soil. Nano-silica treated soil showed a strength increase of nearly 25% at a dosage of 0.4% after curing for two hours. Strength of the treated soil improved with age. Strength improved by nearly 62.9% after 28 days of curing and 221.4% after 180 days of curing due to formation of Calcium - Silicate - Hydrate (CSH) gel in the soil matrix. Dosage of 0.6% nano-silica is observed to be the optimum dosage. Coefficient of permeability and compression index showed an increase by 13.32 and 5.5 times respectively owing to aggregation of particles and creation of void spaces as visualized from the scanning electron micrographs. Further model foundation study and numerical parametric studies using PLAXIS 2D indicate that optimized and economic results can be obtained by varying the additive dosage with depth.

Study on the noodle-making properties of rice added with hydroxypropyl methylcellulose (I) (히드록시프로필 메틸셀룰로오스 첨가에 의한 쌀국수 제면성 연구 (I))

  • Yoo, Young-Jin;Kang, Mi-Young;Um, In-Chul
    • Current Research on Agriculture and Life Sciences
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    • v.30 no.2
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    • pp.61-67
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    • 2012
  • In this study, hydroxypropyl methylcelluloses (HPMCs) were added to prepare the rice noodle and the effects of water dosage, HPMC content, and viscosity level of HPMC on the noodle-making properties of rice dough were examined. As the water dosage was increased, the rice dough after roller pass became more flat and homogeneous. However, when the water dosage was over a certain range, the rice noodle became more waved. In the test result of various HPMC contents, 3% HPMC addition was turned out to be an optimum condition for the best noodle-making properties of rice dough. As the viscosity level of HPMC decreased, the rice dough after roller pass became inhomogeneous. However, the lowest viscosity level HPMC (PMC 40H) did not show any waved rice noodle at even high water dosage indicating the improved noodle-making properties of rice dough. On the whole, it seems that 56~58% water dosage, 3% HPMC content, and high viscosity HPMC (PMC60U) were the optimum condition for preparation of good rice noodle.

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