• 제목/요약/키워드: optical purity

검색결과 154건 처리시간 0.028초

비구면렌즈 설계를 위한 칼코게나이드 Ge-Sb-Se계 구조적, 광학적 특성 연구 (Structural and Optical Characteristics of ChalcogenideGe_Sb_Se for Basic Aspheric Lens Design)

  • 고준빈;명태식
    • 한국생산제조학회지
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    • 제23권2호
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    • pp.133-137
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    • 2014
  • The recent development of electro-optic devices and anticorrosion media has made it necessary investigate infrared optical systems with solid-solid interfaces of materials with amorphous characteristics. One of the most promising classes of materials for these purposes seems to be chalcogenide glasses, which are based on the Ge_Sb_Se system, have drawn much attention because of their use in preparing optical lenses and fibers that are transparent in the range of 3-12 um. In this study, a standard melt-quenching technique was used to prepare amorphous Ge_Sb_Sechalcogenideto be used in the design and manufacture of infrared optical products. The results of structural, optical, and surface roughness analyses of high purity Ge_Sb_Sechalcogenide glasses after various annealing processes reported.

비구면렌즈 설계를 위한 칼코게나이드 Ge-Sb-Se 광학계 및 결정화 특성 연구 (Chalcogenide Ge-Sb-Se Optical and Crystallization Characteristics for Basic a Planning Aspheric Lens)

  • 명태식;고준빈
    • 한국재료학회지
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    • 제26권11호
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    • pp.598-603
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    • 2016
  • The recent development of electro-optic devices and anticorrosion media has led to the necessity to investigate infrared optical systems with solid-solid interfaces of materials that often have the characteristic of amorphousness. One of the most promising classes of materials for those purposes seems to be the chalcogenide glasses. Chalcogenide glasses, based on the Ge-Sb-Se system, have drawn a great deal of attention because of their use in preparing optical lenses and transparent fibers in the range of 3~12 um. In this study, amorphous Ge-Sb-Se chalcogenide for application in an infrared optical product design and manufacture was prepared by a standard melt-quenching technique. The results of the structural, optical and surface roughness analysis of high purity Ge-Sb-Se chalcogenide glasses are reported after various annealing processes.

광학활성 분리능을 갖는 유기화합물의 친핵성치환반응에서 키랄성의 유지 및 반전에 미치는 용매효과 (Solvent Effect on Preservation and Inversion of the Chirality in the Processes of Nucleophilic Substitution Reaction of Organic Compound bearing Optical Activity Resolution)

  • 이용희;이영세
    • 한국산업융합학회 논문집
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    • 제7권3호
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    • pp.299-303
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    • 2004
  • A systematic investigation for the reactivity and solvent effect was studied on the reaction of optical resolving agents with the optically active assistant compounds. The reaction rate constants of the nucleophillic substitution reactions were determined by means of conductometric method The linear solvent energy relationship based on the solvent parameters and the thermodynamic parameters was discussed on the reactions of various physiological active compounds and optical resolving agents The reaction mechanism was discussed from the kinetic results compared with the optical purity.

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Cobalt를 첨가한 $Cd_4GeS_6$ 단결정에서 Energy Gap의 온도의존성 및 열역학적 함수 추정 (Temperature Dependence of Energy Gap and Thermodynamic Function Properties of Coblt-doped $Cd_4GeS_6$Single Crystals)

  • 김덕태
    • 한국전기전자재료학회논문지
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    • 제11권9호
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    • pp.693-699
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    • 1998
  • In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

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전기방사에 의한 이성질 폴리락타이드 블렌드의 섬유제조와 분해거동에 관한 연구 (Studies of Degradation Behavior of Stereochemical Poly(lactide) Blend Fibers Prepared by Electrospinning)

  • 정의습;이원기
    • 한국환경과학회지
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    • 제23권3호
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    • pp.473-481
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    • 2014
  • Poly(lactide)s(PLA) is an attractive material to solve the problem of waste plastic accumulation in nature because of its biodegradability. The lactide exists in three stereoisomeric configurations: L-lactide, D-lactide, and meso-lactide. PLA stereocomplexes, formed by the mixing of two enantiomers, poly(L-lactide)(PLLA) and poly(D-lactide)(PDLA), have many favorable characteristics because the stereocomplex showed $50^{\circ}C$ higher melting point than each enantiomeric polymer and the resistance toward degradation increased. In this study, we investigated the influence of the composition and the optical purity of each component on the formation of stereocomplexes. Also, the nanofibers of stereochemical PLA and their blends were prepared by electrospinning method. The properties of the obtained fibers were analyzed by differential scanning calorimetry and scanning electron microscopy. The results showed that a degree of stereocomplex was controlled by change of optical purity of each component. The enzymatic degradation of the fibers were strongly dependent on the stereocomplex.

Effects of Neon Plasma Emission on Optical Properties of Phosphor Layers in Surface-Type Alternate Current Plasma Display Panel

  • Jang, Sang-Hun;Cho, Ki-Duck;Tae, Heung-Sik;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.171-174
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    • 2000
  • This study uses neon and xenon gas mixture discharges to determine the effects of the neon plasma emission on the characteristics of visible emission from the stimulation of the red, green, blue(RGB) phosphor layers in a surface-type alternate current plasma display panel(AC PDP). With a mixture of less than 2% xenon to neon, it is found that the luminance changes in the visible emission of the phosphor layers are similar to those of the neon plasma emission. In the range of xenon mix ratio from 2 to 5%, the luminance of the red, green, blue(RGB) phosphor layers decreases with a decrease in the neon plasma emission intensity. However, with a mixture of above 5% xenon to neon, the luminance of the red, green, blue(RGB) phosphor layers increases regardless of a decrease in the neon plasma emission intensity. Furthermore, the color purity of the red, green, blue(RGB) phosphor layers improve as the neon plasma emission intensity decreases. Accordingly, it is concluded that the optical properties of the phosphor layers, including color purity and luminance, depend on the neon plasma discharge emission as well as the visible emission from the stimulation of the phosphor layers.

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Determination of the optical isomers of ethambutol (myambutol) and 2-amino-1-butanol by gas-liquid chromatography

  • Kim, Ye-Sook;Youm, Jeong-Rok;Park, Man-Ki;Paik, Nam-Ho
    • Archives of Pharmacal Research
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    • 제4권1호
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    • pp.1-8
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    • 1981
  • Our need for a convenient method of analytical estimation of the precise optical purity of d-2 aminobutanol (d-2AB) and d-ethambutol has prompted us to examine in detail the preparation and G. L. C. separation of the N-TFA-L-prolyl derivatives of their optical isomers (d-and l-2AB, d-, meso-and l-ethambutol). Silicon OV-1 columns were used for the G. L. C. separation.

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Chiral Purity Test of Bevantolol by Capillaryelectrophoresis and High Performance Liquid Chromatography

  • Long, Pham Hai;Trung, Tran Quoc;Oh, Joung-Won;Kim, Kyeong-Ho
    • Archives of Pharmacal Research
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    • 제29권9호
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    • pp.808-813
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    • 2006
  • Two methods for the chiral purity determination of bevantolol were developed, namely capillary electrophoresis (CE) using carboxymethyl-${\beta}$-cyclodextrin (CM-${\beta}$-CD) as a chiral selector and high-perfomance liquid chromatography (HPLC) using a chiral stationary phase. In the HPLC method, the separation of bevantolol enantiomers was performed on a Chiralpak AD-H column by isocratic elution with n-hexane-ethanol-diethylamine (10:90:0.1, v/v/v) as mobile phase. In the CE method, bevantolol enantiomers were separated on an uncoated fused silica capillary with 50 mM amonium phosphate dibasic adjusted to a pH 6.5 with phosphoric acid containing 15 mM CM-${\beta}$-CD as running buffer. Validation data such as linearity, recovery, detection limit, and precision of the two methods are presented. The detection limits of S-(-)-bevantolol were 0.1% and 0.05% for CE and HPLC method, respectively and R-(+)-bevantolol were 0.15% and 0.05% for CE and HPLC method, respectively. There was generally good agreement between the HPLC and CE results.

고휘도 LED R/G/B/A/W의 광특성 (The Optical Characteristics of High-Brightness LEDs for R/G/B/A/W Properties)

  • 황명근;송정용;허창수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마연구회
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    • pp.100-103
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    • 2003
  • 고휘도 LED(light emitting diode) 빨강(R), 녹색(G), 파랑(B), 호박색(A), 백색(W) 등의 중요한 광학특성인 광속(luminous flux), 효율(luminous efficacy), 피크 파장(peak wavelength), 가중치 평균 파장(weighted average wavelength), 반치폭 (full width at ha1f maximum), 색도좌표(chromaticity coordinate), 주 파장(dominant wavelength), 자극순도 (excitation purity) 와 휘도순도(colorimetric purity)에 대해서 비교검토하였다. 시험결과로 제시된 LED의 기본적인 특성 데이터는 추후, 새로운 조명용 LED 램프나 등기구(luminaire)를 개발 및 특성연구에 많은 도움을 줄 것으로 사료된다.

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