• 제목/요약/키워드: optical and thermal changes

검색결과 87건 처리시간 0.027초

비정질 SeGe 박막의 PL 특성과 광흑화 효과에 관한 연구 (The Photoluminescence(PL) Spectroscopy and the Photo-Darkening(PD) Effect of the Amorphous SeGe Thin Films)

  • 김진우;이현용;정홍배
    • 한국전기전자재료학회논문지
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    • 제15권5호
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    • pp.435-440
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    • 2002
  • In this study, we have investigated photo-induced changes of optical energy gap( $E_{OP)}$ and photoluminescence (PL) in amorphous ($\alpha$-) S $e_{100-x}$G $e_{x}$ (x=5, 25 and 33) thin films prepared by conventional thermal evaporation method. In the $\alpha$-S $e_{100-x}$G $e_{x}$ thin film, the $E_{OP}$ is obtained by a linear extrapolation of the ($\alpha$hν)$^{\frac{1}{2}}$ versus hν plot to the energy axis using the optical absorption coefficient ($\alpha$) calculated from the extinction coefficient k measured in the wavelength range of 290~900nm. Although the values of $\Delta$ $E_{OP}$ are very different, all films exhibit photo-induced photo-darkening (PD) effect that is a red shift of $E_{OP}$ . In particular, $\Delta$ $E_{OP}$ in $\alpha$-S $e_{75}$ G $e_{25}$ thin film exhibits the largest value (i, e., $\Delta$ $E^{OP}$ ~40meV for $\alpha$-S $e_{95}$ G $e_{5}$ , $\Delta$ $E_{OP}$ ~200meV for $\alpha$-S $e_{75}$ G $e_{25}$ , $\Delta$ $E_{OP}$ ~130meV for $\alpha$-S $e_{67}$ G $e_{33}$ ). PL spectra in $\alpha$-SeGe by hν$_{HeCd}$ have no-Stokes shift (SS) and show a tendency dependent on both composition and illumination time. We explain the energy-induced phenomena such as the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..the PD and thermal bleaching, the native charged-defect generation and the no-SS PL, etc..tc..

다채널 체적식 태양열 흡수기에서 열전달 수치해석 (Numerical Analysis of Heat Transfer in Multichannel Volumetric Solar Receivers)

  • 이현진;김종규;이상남;강용혁
    • 대한기계학회논문집B
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    • 제35권12호
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    • pp.1383-1389
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    • 2011
  • 본 연구는 태양열 발전에 사용하는 공기식 다채널 체적식 흡수기의 일관성 있는 열전달 해석에 초점을 두고 있다. 이를 위해 흡수 소재 물성과 채널 형상 변화의 영향을 몬테카를로 광선추적법에 기반한 광학 모델과 전도, 대류, 복사를 고려한 1 차원 열전달 모델에 동시에 반영하였다. 광학 모델 결과는 채널 반경 대비 길이의 형상비가 매우 커서 대부분의 태양 에너지는 15 mm 이내의 짧은 길이에서 흡수됨을 증명하고 있다. 복사 열손실 분류를 통해 채널의 낮은 흡수율에서는 방사 손실은 줄지만 반사손실이 증가하여 흡수기 효율이 감소하는 것을 보였다. 큰 채널 반경이나 작은 질량 유량으로 인해 흡수기 평균 온도가 상승할 때, 방사 손실과 반사 손실 모두 증가하지만 방사 손실의 영향이 더 큰 것으로 나타났다.

Optimal Design of a Coudé Mirror Assembly for a 1-m Class Ground Telescope

  • Jaehyun Lee;Hyug-Gyo Rhee;Eui Seung Son;Jeon Geon Kang;Ji-Young Jeong;Pilseong Kang
    • Current Optics and Photonics
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    • 제7권4호
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    • pp.435-442
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    • 2023
  • These days, the size of a reflective telescope has been increasing for astronomical observation. An additional optical system usually assists a large ground telescope for image analysis or the compensation of air turbulence. To guide collimated light to the external optical system through a designated path, a coudé mirror is usually adopted. Including a collimator, a coudé mirror of a ground telescope is affected by gravity, depending on the telescope's pointing direction. The mirror surface is deformed by the weight of the mirror itself and its mount, which deteriorates the optical performance. In this research, we propose an optimization method for the coudé mirror assembly for a 1-m class ground telescope that minimizes the gravitational surface error (SFE). Here the mirror support positions and the sizes of the mount structure are optimized using finite element analysis and the response surface optimization method in both the horizontal and vertical directions, considering the telescope's altitude angle. Throughout the whole design process, the coefficients of the Zernike polynomials are calculated and their amplitude changes are monitored to determine the optimal design parameters. At the same time, the design budgets for the thermal SFE and the mass and size of the mount are reflected in the study.

Comparison study of heatable window film using ITO and ATO

  • Park, Eun Mi;Lee, Dong Hoon;Suh, Moon Suhk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.300.2-300.2
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    • 2016
  • Increasing of the demand for energy savings for buildings, thermal barrier films have more attracted. In particular, as heat loss through the windows have been pointed out to major problems in the construction and automobile industries, the research is consistently conducted for improving the thermal blocking performance for windows. The main theory of the technology is reflect the infrared rays to help the cut off the inflow of the solar energy in summer and outflow of the heat from indoors in winter to save the energy on cooling and heating. Furthermore, this is well known for prevent glare, reduces fading caused by harmful ultraviolet radiation and easy to apply on constructed buildings if it made as a film. In addition to these advantages, apply the transparent electrode to eliminate condensation by heating. Generally ITO is used as a transparent electrode, but is has a low stability in environmental factors. In this study, ITO and its alternative, ATO, is deposited by sputtering system and then the characteristic is evaluated each material based thermal barrier thin film. The optical property was measured on wide range of wavelength (200 nm 2500 nm) to know the transparency in visible wavelength and reflectivity in IR wavelength range. The electrical property was judged by sheet resistivity. Finally the changes of the temperature and current of the deposited film was observed while applying a DC power.

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IrMn 교환결합층을 갖는 스핀밸브막에서의 열적안정성과 자구구조 관찰 (Thermal Stability and Domain Structure in Spin Valve Films with IrMn Exchange Biased Layers)

  • 이병선;정정규;이찬규;구본흔;야스노리 하야시
    • 한국재료학회지
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    • 제14권2호
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    • pp.94-100
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    • 2004
  • We have investigated the magnetic domain structure and the thermal stability of magnetotransport properties of IrMn biased spin-valves containing Co, CoFe and NiFe. The magnetic domain structures were imaged using a magneto-optical indicator film(MOIF) technique. To investigate the thermal stability, magnetoresistance(MR) was measured at annealing temperature(TANN) and room temperature($T_{RT}$) followed by the annealing. Domain imaging reveal that the increase of annealing temperature led to changes in the exchange coupling between the two ferromagnet(FM) layers through nonmagnetic layer rather than between FM and antiferromagnet. unlike the NiFe biased IrMn spin valve with large domains, MOIF pictures of Co and CoFe biased IrMn spin valve structures show the formation of many small microdomains. The magnetic structure, as revealed by the domain images, appeared unchanged while the MR dropped dramatically. From the combined giant magnetoresistance(GMR) and MOIF results, it was apparent that the decrease of MR ratio was not related to the spin valve magnetic structure up to about $350^{\circ}C$($T_{RT}$ ).

Characterization on the Thermal Oxidation of Raw Natural Rubber Thin Film using Image and FT-IR Analysis

  • Kim, Ik-Sik;Cho, Hwanjeong;Sohn, Kyung-Suk;Choi, Hwa-Soon;Kim, Sung-Uk;Kim, Sinkon
    • Elastomers and Composites
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    • 제55권1호
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    • pp.51-58
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    • 2020
  • In this study, the thermal oxidation of raw natural rubber (NR) was investigated under controlled conditions by optical image and fourier transform infrared (FT-IR) analysis. The thermal oxidation was performed on a transparent thin film of raw NR coated on a KBr window in a dark chamber at 80℃ under low humidity conditions to completely exclude moisture and restrict light oxidation. Images of the thin film of raw NR were obtained before and after thermal oxidation. FT-IR absorption spectra were measured in the transmission mode at different thermal exposure times. The thermal oxidation of NR was examined by the changes in the absorption peaks at 3449, 1736, 1447, 1377, 1242, 1072, and 833 cm-1, which corresponded to a hydroxyl group (-OH), a carbonyl group (-C=O) from an aldehyde and a ketone, a methylene group (-CH2-), a methyl group (-CH3), a carbon-oxygen single bond (-C-O) from an epoxide, a carbon-oxygen bond (-C-O) from an ether, an alcohol, a peroxide, or a cyclic peroxide, and a cis-methine group (cis-CCH3=CH-), respectively. In the initial stage of thermal oxidation, two different types of free radicals were produced quickly and randomly by the homolytic cleavage of a double bond and allylic hydrogen abstraction. Aldehydes and ketones were formed from chain scissions of the double bonds and alcohols were produced from allylic hydrogen abstraction at the methylene or methyl groups. Two reactions seemed to proceed competitively with each other. At a later stage, oxidative crosslinks seemed to dominate through the combination of free radicals such as an allyl radical (CH=CHCH2·), alkoxy radical (RO·), and peroxy radical (ROO·) and the reaction of a hydroperoxide (-ROOH) with a double bond. The image obtained after thermal oxidation showed hardening without cracks. Based on these observations, a plausible two-step mechanism was suggested for chain hardening caused by the thermal oxidation.

Analysis of Characteristics of DLC Coating Thin Film in Tungsten Carbide for Production of Medical Thermal-Infrared Lenses

  • Park, Yong-Pil;Kim, Tae-Gon;Cheon, Min-Woo
    • Transactions on Electrical and Electronic Materials
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    • 제15권6호
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    • pp.344-347
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    • 2014
  • This study was carried out on DLC thin film deposition technology used in infrared optical system production as a method of reducing the shape changes of the molding core and the consequent loss of life. Experiments on the deposition on silicon wafer and tungsten carbide used as a substrate for molding core were conducted at each processing condition using a filtered arc system, and it was found that the surface and mechanical properties were of the greatest quality when the substrate bias voltage of -150 V was used. In addition, it was confirmed that the PV and Ra characteristics were improved by the deposition of the DLC thin film.

Spin-coating에 의한 $Ge_{20}As_{20}Se_{60}$ 비정질 chalcogenide 박막의 제조 및 광특성 분석 (Preparation and Characterization of $Ge_{20}As_{20}Se_{60}$ Amorphous Chalcogenide Thin Film by Spin Coating)

  • 이강구;최세영
    • 한국세라믹학회지
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    • 제37권3호
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    • pp.219-226
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    • 2000
  • Amorphous Ge20As20Se60 chalcogenide thin films were prepared by spin coating technique from mixed solutions of As40Se60 and Ge40Se60 dissolved in ethylenediamine. Films were prepared at a roating speed of 3500 rpm and spinning time was 10 second and heat-treateed at 27$0^{\circ}C$ for 1 hour. The resulting film thickness and RMS roughness were approximately 340 nm and 15$\AA$. Photostructure changes were investigated with 514.5nm Ar+ laser irradiation and heat-treatment. After Ar+ laser irradiation, transmittance and transmission efficiency decreased respectively up to 24.9% at 2.43 eV and 67.5% at 3.27 eV, and absorption edge shifted toward long wavelength. Optical bandgap changed from 2.03 to 1.83 eV, and absoprtion coefficient and absorption efficiency increased up to 0.33$\times$105cm-1 at 3.37eV and 88.3% at 1.31 eV, respectively. These photodarkening state were recovered reversibly by heat-treatment at 27$0^{\circ}C$ for 1 hour. Photodarkening and thermal bleaching effects by laser irradiation and heat-treatment revealed reversible amorphous-to-amorphous transition varying only coordination number.

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THERMOMECHANICAL STUDY OF LASER TREATED NiTi DENTAL ARCH WIRE

  • Kim, Young-Kon;Park, Joon-B.;Lakes, R.S.;Andreasen, G.F.
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1989년도 춘계학술대회
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    • pp.9-12
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    • 1989
  • A preliminary study has been conducted to demonstrate the effect of laser heat treatment on Ni Ti alloy dental arch wires ($0.016"\;{\times}\;0.022"$ and $0.018"\;{\times}\;0.026"$, rectangular shape). Changes in mechanical and thermal properties and surface morphologies are investigated by using optical and scanning electron microscope (SEM), energy dispersive x-ray microprobe analysis(EDX), differential scanning calorimeter (DSC), and micro hardness tester. The results indicate that the laser can affect the thermal equilibrium state of the localized surface. Titanium rich surface film is formed by the laser treatment. The surface film and rapidly resolidified underlying structures show better chemical resistance than the matrix material. Phase transition temperatures which are related to shape recovery temperatures are changed after laser treatment. Hardness of resolidified area and heat affected zone are lower than before treatment.

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선형 프레넬 반사판 시스템의 집광 특성에 대한 수치해석 연구 (Numerical Study of Concentration Characteristics of Linear Fresnel Reflector System)

  • 이현진;김종규;이상남
    • 대한기계학회논문집B
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    • 제39권12호
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    • pp.927-934
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    • 2015
  • 고일사 지역인 사우디아라비아에서 태양열로 구동하는 흡수식 냉동 시스템 개발을 염두에 두고, 본 논문에서는 태양을 추적하는 선형 프레넬 반사판 시스템의 집광 특성을 수치해석 하였다. 몬테카를로 광선추적법을 기반으로 하는 광학 프로그램을 통해 집광 열유속, 집광 효율, 집광 에너지를 일년을 대표하는 춘분, 하지, 추분, 동지 날짜에 계산하였다. 동지를 제외하면, 9 시에서 15 시까지는 집광 성능이 일정한 가운데, 집광 효율도 70% 이상으로 높게 나타났다. 이 시간대에서 흡수기 중심 20% 영역에 모이는 최대 열유속은 하지 때 약 $13.0{\sim}14.6kW/m^2$ 범위에서 변했다. 집광 시스템의 설계 인자 중에서 흡수기 설치 높이, 반사판의 폭, 반사판 사이의 거리가 집광 효율을 조사해 보면, 흡수기 설치 높이는 반사판의 폭에 관계없이 5 m 에서 최적의 성능을 나타냈다. 반사판의 폭이 작을수록 집광 효율이 좋지만, 반사판의 폭은 집광 되는 에너지에 직접적으로 비례하기 때문에 냉동 시스템의 용량에 맞추어 설계가 필요하다. 본 연구는 흡수기의 열전달 해석의 중요한 선행조건이므로 향후에 광학-열전달 연계된 해석을 통해 전체 시스템의 성능을 예측하고 설계하는데 활용할 수 있을 것이다.