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Experimental Study on Reduction of Nitrogen-Containing Compounds Contained in Crude Methylnaphthalene Oil by Solvent Extraction (II) (용매 추출에 의한 조제 메틸나프탈렌유에 함유된 함질소화합물의 저감에 관한 실험적 연구(II))

  • Kang, Ho-Cheol;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.477-481
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    • 2022
  • As a part of improving the quality of crude methylnaphthalene (CMNO), this study was experimentally examined the reduction of nitrogen-containing compounds (NC) present in the CMNO by solvent extraction. The CMNO was composed of three kinds of NC [quinolone (QU), iso-quinoline (IQU), indole (IN)], three kinds of bicyclic aromatic compound [BAC; naphthalene (NA), 1-methylnaphthalene (1MNA), 2-methylnaphthalene (2MNA)] and biphenyl (BP) etc., in addition to an aqueous formamide solution, which were used as raw materials and a solvent, respectively. The increase in the volume fraction of water to the solvent in the initial state (yw,0) caused a sharp decrease in the distribution coefficient and the yield of NC, but conversely raised the increased selectivity of NC based on 2MNA. The compositions of QU, IQU and IN in the raffinate oil recovered through the equilibrium extraction of batch co-current 5-stage under constant conditions [yw,0 = 0.1, volume fraction of solvent to feed (CMNO) at the initial state = 1, operating temperature = 303 K, liquid-liquid contacting time = 72 h] were reduced by about 51.5%, 55.2%, and 71.8%, respectively, when compared to those of CMNO. From the excellent reduction rate of NC, the formamide extraction method suggested in this study can be expected to be a useful reduction method for NC contained in the CMNO.

Machine Classification in Ship Engine Rooms Using Transfer Learning (전이 학습을 이용한 선박 기관실 기기의 분류에 관한 연구)

  • Park, Kyung-Min
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.2
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    • pp.363-368
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    • 2021
  • Ship engine rooms have improved automation systems owing to the advancement of technology. However, there are many variables at sea, such as wind, waves, vibration, and equipment aging, which cause loosening, cutting, and leakage, which are not measured by automated systems. There are cases in which only one engineer is available for patrolling. This entails many risk factors in the engine room, where rotating equipment is operating at high temperature and high pressure. When the engineer patrols, he uses his five senses, with particular high dependence on vision. We hereby present a preliminary study to implement an engine-room patrol robot that detects and informs the machine room while a robot patrols the engine room. Images of ship engine-room equipment were classified using a convolutional neural network (CNN). After constructing the image dataset of the ship engine room, the network was trained with a pre-trained CNN model. Classification performance of the trained model showed high reproducibility. Images were visualized with a class activation map. Although it cannot be generalized because the amount of data was limited, it is thought that if the data of each ship were learned through transfer learning, a model suitable for the characteristics of each ship could be constructed with little time and cost expenditure.

Implementation of Responsive Web-based Vessel Auxiliary Equipment and Pipe Condition Diagnosis Monitoring System (반응형 웹 기반 선박 보조기기 및 배관 상태 진단 모니터링 시스템 구현)

  • Sun-Ho, Park;Woo-Geun, Choi;Kyung-Yeol, Choi;Sang-Hyuk, Kwon
    • Journal of Navigation and Port Research
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    • v.46 no.6
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    • pp.562-569
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    • 2022
  • The alarm monitoring technology applied to existing operating ships manages data items such as temperature and pressure with AMS (Alarm Monitoring System) and provides an alarm to the crew should these sensing data exceed the normal level range. In addition, the maintenance of existing ships follows the Planned Maintenance System (PMS). whereby the sensing data measured from the equipment is monitored and if it surpasses the set range, maintenance is performed through an alarm, or the corresponding part is replaced in advance after being used for a certain period of time regardless of whether the target device has a malfunction or not. To secure the reliability and operational safety of ship engine operation, it is necessary to enable advanced diagnosis and prediction based on real-time condition monitoring data. To do so, comprehensive measurement of actual ship data, creation of a database, and implementation of a condition diagnosis monitoring system for condition-based predictive maintenance of auxiliary equipment and piping must take place. Furthermore, the system should enable management of auxiliary equipment and piping status information based on a responsive web, and be optimized for screen and resolution so that it can be accessed and used by various mobile devices such as smartphones as well as for viewing on a PC on board. This update cost is low, and the management method is easy. In this paper, we propose CBM (Condition Based Management) technology, for autonomous ships. This core technology is used to identify abnormal phenomena through state diagnosis and monitoring of pumps and purifiers among ship auxiliary equipment, and seawater and steam pipes among pipes. It is intended to provide performance diagnosis and failure prediction of ship auxiliary equipment and piping for convergence analysis, and to support preventive maintenance decision-making.

Development and Application of Ultra Small Micro-Cone Penetrometer (초소형 마이크로콘 관입시험기의 개발 및 적용)

  • Lee, Jong-Sub;Shin, Dong-Hyun;Yoon, Hyung-Koo;Lee, Woo-Jin
    • Journal of the Korean Geotechnical Society
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    • v.24 no.2
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    • pp.77-86
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    • 2008
  • The disturbance zone and measured values are affected by the size of the penetrometer. The local value may be measured by the smaller penetrometer. An ultra small Micro-Cone penetrometer (5mm in outer diameter) is designed and manufactured to characterize soil properties with minimum disturbance during penetration tests. The tip resistance is measured by using stain gauges attached near the Micro-Cone. In addition, the friction sleeve is adopted to effectively remove the skin friction from the tip resistance. Design concern includes the installation of stain gauges, circuits, penetration systems, penetration rate, sampling rate, operating temperature, and calibration. Application tests show that the clay interface, and the soil layers consisting of clay and sand are clearly detected by the Micro-Cone. Furthermore, the cone tip resistances measured by the Micro-Cone and the miniature cone (16mm in outer diameter) are similar. Note the resolution is much higher in the Micro-Cone. This study shows that the Micro-Cone may effectively detect the soil interface with high resolution, and with minimum disturbance.

A Study on the Power Converter Control of Utility Interactive Photovoltaic Generation System (계통 연계형 태양광 발전시스템의 전력변환기 제어에 관한 연구)

  • Na, Seung-Kwon;Ku, Gi-Jun;Kim, Gye-Kuk
    • Journal of the Korea Society of Computer and Information
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    • v.14 no.2
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    • pp.157-168
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    • 2009
  • In this paper, a photovoltaic system is designed with a step up chopper and single phase PWM(Pulse Width Modulation) voltage source inverter. Where proposed Synchronous signal and control signal was processed by one-chip microprocessor for stable modulation. The step up chopper operates in continuous mode by adjusting the duty ratio so that the photovoltaic system tracks the maximum power point of solar cell without any influence on the variation of insolation and temperature because solar cell has typical voltage and current dropping character. The single phase PWM voltage source the inverter using inverter consists of complex type of electric power converter to compensate for the defect, that is, solar cell cannot be developed continuously by connecting with the source of electric power for ordinary use. It can cause the effect of saving electric power. from 10 to 20[%]. The single phase PWM voltage source inverter operates in situation that its output voltage is in same phase with the utility voltage. In order to enhance the efficiency of photovoltaic cells, photovoltaic positioning system using sensor and microprocessor was design so that the fixed type of photovoltaic cells and photovoltaic positioning system were compared. In result, photovoltaic positioning system can improved 5% than fixed type of photovoltaic cells. In addition, I connected extra power to the system through operating the system voltage and inverter power in a synchronized way by extracting the system voltage so that the phase of the system and the phase of single-phase inverter of PWM voltage type can be synchronized. And, It controlled in order to provide stable pier to the load and the system through maintaining high lurer factor and low output power of harmonics.

Regenerating Condition Optimization of NGCC Combined Carbon Capture Process Simultaneously Considering Absorption and Regeneration Rates (흡수율과 재생율을 동시 고려한 천연가스복합발전 공정 연계 이산화탄소 포집 공정의 재생 조건 최적화)

  • Jeong Hun Choi;Young-Hwan Chu
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.368-377
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    • 2023
  • Natural Gas Combined Cycle(NGCC) recently receives lots of attention as an attractive form of power plants by virtue of its low carbon emission compared with coal-fired power plant. Nevertheless, it also needs carbon capture process since it is difficult to completely suppress carbon emission even for the NGCC. A simulation study has been performed to optimize operating condition of a carbon capture process using MEA considering low partial pressure of carbon dioxide in NGCC emission gas. For accurate optimization, overall process model including both NGCC and the carbon capture process has been built with a simulation software. Then, optimization in which various performance indices such as carbon dioxide absorption rate, solvent regeneration rate and power loss in the NGCC are simultaneously reflected has been done. Especially, it is noticeable that this study focuses on not only the amount of energy consumption but also the absorption and regeneration performance of carbon capture process. The best result considering all the performance indices has been achieved when the reboiler temperature is 120 ℃ and the reason has been analyzed.

A study on the crop switching of farmers in Jeju Islands related to the climate changes - focused on the citrus farms of the graduates of the KNCAF - (제주지역의 기후변화에 따른 농가의 작목전환 실태 -한농대 졸업생 감귤 농가를 중심으로-)

  • Kim, J.S.;Kang, S.K.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.17 no.1
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    • pp.163-179
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    • 2015
  • The aim of this study is to investigate to which degree farmers did the crop switching and cultivar renewal as a confrontational strategy to climate change, and which problems they had in that process, and then to provide the supporting plans for them. We conducted a questionnaire survey of 15 citrus farmers of the KNCAP graduates in Jeju Island. Most of the survey respondents agreed to the climate change of Jeju Island and the subtropical climate of its coastal area. The farmers have experienced irregular weather such as abnormal high temperature, frequent rain, and droughts, resulting in the harmful insects and new weeds attack. As the climate change strategies, they are adopting a greenhouse culture system, improving a soil drainage using reorganization of planting space, making a new pest management program, and trying to switch a crop to subtropical fruits. It is expected that 50% of the survey respondents have changed their crops or will do; and 73 % of them have changed cultivar or have a plan to do. Only a few farmers directly pointed to a reason for their efforts to change the crops or to renew the cultivars as the anti-climate change strategy, however, most farmers answered the reason was to increase profitability by meeting their consumers' tastes. Presently, it is not the anti-climate change strategy but increase of profitability by meeting the consumers' needs the reason why most of the survey respondents have changed their crops or renewed the cultivars, while a few of them switched their crops to a subtropical fruit trees due to climate change. On the crop switching, they had some difficulties such as a labor shortage, availability of land, operating costs and instable income. On the cultivar renewal, also, they encountered the lack of cultivating techniques for new cultivars and the dim future for the new market. In long-term perspective, Jeju's farmers need new information and educational programs about the effect of climate change on agriculture of Jeju, and cultivation techniques for new crops and new cultivars.

Utilizing Abandoned Mines in Regional Development: Feasibility of Underground Data Centers and Public Sports Facilities (폐광지역발전을 위한 폐광산 활용방안 연구: 지하 데이터센터 및 공공체육시설로의 운용성 평가)

  • Hyeong-Geol Kim;Ganghui Kim;Sanghyun Bin;Won-Sik Woo;Jongmun Cha;Chang-Uk Hyun
    • The Journal of Engineering Geology
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    • v.33 no.4
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    • pp.737-753
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    • 2023
  • Abandoned mines represent unused space resulting from resource use and changes in industrial environments. Efforts are underway to repurpose such underground spaces, leveraging their unique attributes of temperature stability, shading, and security. This study aimed to assess the feasibility of operating high-demand data centers and public sports facilities as potential recycling options for abandoned mine spaces. The status of data centers located in abandoned mines abroad was examined, including their operational technology capitalizing on the advantages of underground spaces. Considering the varying sizes of underground spaces in different types of abandoned mine in South Korea, the suitability of installing facilities for 12 different sports was evaluated for potential contributions to the health and welfare of local residents. The utilization of abandoned mine spaces as data centers and public sports facilities is expected to not only recycle industrial heritage but also to allow new development opportunities for local communities.

Effect of Experimental Factors on Reduction of Nitrogen Compounds Contained in Crude Methylnaphthalene Oil by Formamide Extraction (포름아미드 추출에 의한 조제 메틸나프탈렌유에 함유된 질소화합물의 저감에 관한 실험인자의 영향)

  • Su Jin Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.665-669
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    • 2023
  • The crude methylnaphthalene oil (CMNO) contains nitrogen compounds (NCs) such as quinoline (QU), isoquinoline (IQU), and indole (IN). These NCs in the CMNO are treated as impurities contained in the CMNO due to contamination of the atmospheric environment and unpleasant odors. In order to improve the quality of CMNO, this study examined the effect of extraction experimental factors on the reduction of NCs contained in CMNO using CMNO as a raw material and an aqueous formamide solution as a solvent, respectively. The increase in the volume ratio of solvent to feed in initial (S/F)0 in initial increased the distribution coefficient of NCs and the selectivity of NCs in reference to 2-methylnaphthalene (2MNA). Additionally, an increase in operating temperature (T) increased the distribution coefficient of NCs but conversely decreased selectivity. The compositions of QU, IQU, and IN in the raffinate oil recovered through equilibrium extraction under a constant condition (volume fraction of water to solvent in initial (yw,0) = 0.1, (S/F)0 = 9, T = 303 K, liquid-liquid contacting time = 72 h) were reduced by about 58.5 wt%, 61.9 wt%, and 73.4 wt%, respectively, compared to those of CMNO. The formamide extraction method in this study was expected to be an effective reduction method for NCs contained in CMNO.

Effect of Intermittent Plasma Discharge on the Hydrocarbon Selective Catalytic Reduction of Nitrogen Oxides (간헐적 플라즈마 방전이 질소산화물의 탄화수소 선택적 촉매환원에 미치는 영향)

  • Kyeong-Hwan Yoon;Y. S. Mok
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.507-514
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    • 2023
  • The selective catalytic reduction (SCR) of nitrogen oxides (NOx) was investigated in a catalyst (Ag/γ-Al2O3) packed dielectric barrier discharge plasma reactor. The intermittent generation of plasma in the catalyst bed partially oxidized the hydrocarbon reductant for NOx removal to several aldehydes. Compared to using the catalyst alone, higher NOx conversion was observed with the intermittent generation of plasma due to the formation of highly reductive aldehydes. Under the same operating conditions (temperature: 250 ℃; C/N: 8), the NOx reduction efficiencies were 47.5%, 92%, and 96% for n-heptane, propionaldehyde, and butyraldehyde, respectively, demonstrating the high NOx reduction capability of aldehydes. To determine the optimal condition for intermittent plasma generation, the high voltage on/off cycle was adjusted from 0.5 to 3 min. The NOx reduction performance was compared between continuous and intermittent plasma generation on the same energy density basis. The highest NOx reduction efficiency was achieved at 2-min high voltage on/off intervals. The reason that the intermittent plasma discharge exhibited higher NOx reduction efficiency even at the same energy density, compared to the continuous plasma generation case, is that the intermediate products, such as aldehydes generated from hydrocarbon, were more efficiently utilized for the reduction of nitrogen oxides.