• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.289-294
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• 2022

Oil contained in domestic and industrial wastewater or marine spilled oil gives rise to severe environmental pollution issues such as water pollution and ecosystem destruction. The membrane filtration method as one of representative oil/water separation strategies has technological challenges such as membrane fouling and low separation rate. In this work, we devise a 3D-printed microhydrocyclone for oil/water separation by utilizing a digital lighting processing-based 3D printer. We demonstrate that the 3D-printed microhydrocyclone can effectively separate oil and water phases from oil-in-water emulsion.

• The KSFM Journal of Fluid Machinery
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• v.19 no.4
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• pp.48-53
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• 2016

The centrifugal separator which uses gravity separation method for oil-water separation, rotating at high-speed, is one of the most commonly used device for controlling the amount of the oil in waste water collected in bilge. The IMO (International Maritime Organization) has set regulations, also known as MARPOL 73/78, for the prevention of marine pollution. In addition, DET NORSKE VERITAS (DNV) has set standards regarding the assignment of Environmental Class Notation, CLEAN or CLEAN DESIGN, of ships. One of the requirements for classification is that in addition to conforming to MARPOL 73/78, more stringent measures must be taken as well. One of these measures is to limit the oil concentration in bilge water to less than 5ppm. So in this study, an Oil-Water Separator (OWS) is used together with multiple separating plates as a filtration system to be used as an oil-water separation device. The OWS operates using centrifugal separation in which the mixture is separated by centrifugal forces. The main purpose of this paper is to present the OWS separation efficiency according to the rotation speed, mass-flow rate, the angle and the number of stacked layers of the laminated plate using Computational Fluid Dynamics (CFD). Improvements to the device will be investigated from these results.

• Journal of the Korean Society for Marine Environment & Energy
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• v.4 no.2
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• pp.52-60
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• 2001

The need to control the oil content in oily bilge water discharges to meet the increasing stringent seawater pollution standards has led to the development of gravity type separators. Among the several gravitational methods, a plate type oily water separator can be used as an assistant equipment for the oil filtering system to meet the present IMO standard of 15 ppm, because it is believed to be an efficient method dealing with a large amount of rich oil with high specific gravity. The purpose of this paper is to examine the efficiency of oil/water separation with the characteristics of separating plate arrangement. An experimental study was carried out to analyse an efficient treatment oil-water mixture with variation of operating parameters, including flow rates, inlet oil concentrations and the height between the plates. The experimental results show that the height between the plates has a significant effect on the separation efficiency. The best efficiency was acquired when the ration of the height between the plates the plates to distance(H/Ci) was 2 with lower inlet oil concentration and lower flow rate.

• Membrane and Water Treatment
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• v.5 no.2
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• pp.147-170
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• 2014

This paper focuses on the study of the most recent ultra-filtration techniques, based on porous polymer membranes, used for the treatment of wastewater from oil, mine and hydrometallurgical industries. The performance of porous membranes used in separation and recovery of oil and heavy metals from wastewater, was evaluated by the polymer composition and by the membrane characteristics, as it follows: hydrophobicity or hydrophilicity, porosity, carrier (composition and concentration), selectivity, fouling, durability, separation efficiency and operating conditions. The oil/water efficient separation was observed on ultra-filtration (UF) techniques, with porous membranes, whereas heavy metals recovery from wastewater was observed using porous membranes with carrier. It can be concluded, that in the ultra-filtration wastewater treatments, a hybrid system, with porous polymer membranes with or without carrier, can be used for these two applications: oil/water separation and heavy metals recovery.

• Journal of Environmental Science International
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• v.10 no.6
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• pp.401-405
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• 2001

For the purpose of developing a new process f3r the elimination of oil components from oily waste water, experimental researches using oil gelling agent were performed. The process is composed of three units, that is, decantator, gelling column and adsorption column. 10g of gelling agent in the gelling column could effectively absorb 15.65g of oil from ship washing waste water and 16.93g of oil from steel industry waste water. COD in waste waters dramatically diminished not in the gelling column but in the adsorption column. The .gelling is hindered by other organic components in waste water, and the optimum space time f3r the gelling column Is 20min. 1g of gelling agent absorbed 3.7-4.0g of oil from waste waters with 25 min in the batch operation.

• Clean Technology
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• v.15 no.1
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• pp.54-59
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• 2009

In this study, the separation of water/bitumen emulsion was investigated by chemical demulsification method. Motor oils (GS Caltex Deluxe Gold V 7.5W/30, Hyundai gear oil 85W/140) and asphalt (AP-5, KS M 2201, Dongnam Petrochemical MFG. Co.) were used as model oils in the preliminary experiments to effectively remove water from water/bitumen emulsion. The bitumen extracted from Canadian oilsands was used in this study. The water/oil emulsion was not separated without demulsifiers, and Hyundai motor oil showed higher efficiency of water separation at a low concentration of demulsifier compared with that for GS Caltex motor oil. However, as the concentration increased, the efficiency did not rapidly increase compared with that of GS Caltex motor oil. It was highly speculated that the water phase of Hyundai motor oil was not dispersed well compared with that of GS Caltex motor oil because the viscosity of Hyundai motor oil was much higher than that of GS Caltex motor oil. The demulsifier of higher HLB (hydrophilic - lipophilic balance) value had high separation efficiencies in water/oil emulsion. The TWEEN 20 (polyoxyethylene sorbitan monolaurate solution) showed better separation efficiency than other demulsifiers.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.823-828
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• 2011

Characteristics of water separation in a FWKO(Free Water Knok Out) vessel was investigated to remove water from oil-water mixture. Decane, toluene, and asphalt were used as model oils. Preliminary experiments were carried out for decane in a prototype FWKO vessel. Based on the results of preliminary experiments, the prototype vessel was modified and its performance was evaluated by using toluene. The effects of experimental variables on the separation of oil-water mixture were evaluated in terms of separation efficiency. The experimental variables include water cut(water ratio), number of baffles, residence times, and operation temperatures. The optimum conditions of water separation were found to be 0.8 water cut, 3 baffles, 1,200 sec, and $45^{\circ}C$.

• Clean Technology
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• v.19 no.2
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• pp.140-147
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• 2013

In this study, chemical demulsification and electrical treatment methods were investigated for improving the efficiency of water separation from a water/bitumen emulsion. Two types of motor oils (GS Caltex, Deluxe Gold V 7.5 W/30 and, Hyundai gear oil 85 W/140) were used as model oils in basic experiments to investigate the effects of a demulsifier on water/oil emulsion separation. Chemical demulsifiers showing good water separation performance were then used in asphalt emulsion and bitumen emulsion separation trials. Maleic anhydride and e-caprolactam were shown to be good oil soluble demulsifiers and 2-ethylhexyl acrylate and acrylic acid were effective as water soluble demulsifiers. Based on the results obtained in basic experiments, these four demulsifiers were used in further asphalt emulsion experiments. The oil soluble demulsifiers showed higher water separation efficiencies than the water soluble demulsifiers. To investigate the water separation efficiency using a combined chemical and electrical treatment method, the water/bitumen emulsion was separated with the electrical oil treatment apparatus after a chemical demulsifier had been added to it.

• Journal of the Korean Society of Safety
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• v.12 no.2
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• pp.22-26
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• 1997

A small scale centrifugal oil separator consisted of two concentric tubes was fabricated for spilt oil recovery. With speed control of the inner tube, its performance of oil separation was investigated. Oil-water mixture is separated by forced vortex motion with the rotating inner tube. Velocity and pressure distributions in the tubes were calculated. Control of rotating speed, which is the most influencing parameter, showed an optimum value 946rpm corresponding to the acceleration of 20g at the inner tube surface. Separation performance was suddenly deteriorated at rotating speed higher than 1200rpm.

• Membrane Journal
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• v.31 no.6
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• pp.426-433
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• 2021

In this study, a novel material polyketone (PK) was chosen and PK micro/nano fiber membranes were fabricated via electrospinning method under various conditions. After that, the potential application in oil-water separation was thoroughly investigated. The surface of microfiber membrane formed under high humidity especially became much rougher than that formed under low humidity. When salt was added to the spinning solution, the diameter of fibers was reduced up to 90% and the nanofiber membranes could be formed. The oil/water emulsions were prepared and separated under gravity condition using the manufactured rPK-LNC and PK-H membranes. The separation characteristics was evaluated by measuring total organic carbon (TOC) and turbidity. Meanwhile, the changes in the physical properties of fiber membranes under various conditions and with or without salt, as well as the changes in oil water separation characteristics were also studied.