• Title/Summary/Keyword: oil-degradation

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Effect of Reaction Temperature Program on Thermal Degradation of Low-quality Pyrolytic Oil for Bench-scale Continuous Reaction System (벤치 규모 연속반응시스템에서 저급 열분해유 분해반응에 대한 반응온도 프로그램의 영향)

  • Lee, Kyong-Hwan;Nam, Ki-Yun
    • Clean Technology
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    • v.15 no.3
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    • pp.186-193
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    • 2009
  • The characteristics of product materials obtained from thermal degradation of low-qualify pyrolytic oil were investigated in this study. The reactants were produced by pyrolysis of mixed plastic waste with film type in a commercial rotary kiln reaction system. The properties of reactants were measured by elemental analysis, calorimetry analysis and SIMDIST analyst. The result of degradation experiments with different reaction temperature programs was discussed through product yields, cumulative yields and production rates of oil products. The multi-step reaction temperature program resulted in higher yields of product oils and lower yields of residues than one-step reaction temperature program. The product characteristics such as production yield and the rate of oil products etc. were influenced by reaction temperature program in the continuous thermal degradation.

Performance analysis of waterproofing corrosion as effecting oil (유류성분이 지하구조물의 방수층 침식에 미치는 영향평가)

  • 김영찬;이정윤;권시원;오상근
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2004.05a
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    • pp.91-95
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    • 2004
  • Utilization of underground construction if increased by the large size & skycraperlization of building recently. Therefore. waterproof dependence of underground construction is risen. However, water leakage was happened by rupture by concrete conduct, drying shrinkage. form tie. In underground environment soil class, degradation of waterproofing is showing to corrode by oil. An odious smell by oil, promotion evil of reinforcing rod corrosion, declination of durability can happen. Then, practical un degree of underground spare becomes low, Because oil or water permeates by construction by degradation to waterproof class corrode by oil, is considered to affect evil durability of construction.

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Treatability Study on Oil-Contaminated Soils for Bioremediation Application (유류오염토양의 생물적용기술 적용타당성 검토)

  • Lee, Yeon-Hui;Seol, Mi-Jin;O, Yeong-Suk
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.578-581
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    • 2001
  • A treatability study was conducted using a hydrocarbon-contaminated soil for the oPtimization of bioremediation strategy best fit to a given set of contamination. The applicability of nutrients, biosurfactant, and oil-degrading microorganisms were examined by monitoring $CO_2$ evolution and oil degradation The addition of inorganic nutrients in the form of slow released fertilizer accelerated the initial rate of $CO_2$ evolution by a factor of 3. The application of oil-degrading microorganisms did not significantly increased $CO_2$ evolution or biodegradation efficiency. Application of a commercial biosurfactant was most effect in terms of the total $CO_2$ evolution and the oil degradation rate. The results indicate that $CO_2$ evolution measurement was found to be a simple and reliable countermeasure of crude oil hydrocarbon mineralization for the rapid determination of the best-fit bioremediation strategy.

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Recovery of Available Resource from Waste Polymer using Thermal Degradation Process (고분자 폐가물의 열분해공정에서 유효자원의 회수)

  • 김형진;정수경;홍인권
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.98-104
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    • 2000
  • Commercial rubber(IR, NR, BR), SBR, and tire were degraded by thermal degradation process. The oil yield of rubbers and tire ranges about 37~86%, it was increased with increase of operation temperature in pyrolysis. And the yield of pyrolytic oil was increased with increase of heating rate. The maximum oil yields of IR, NR, BR, SBR, and tire were 80, 73, 83, 86 and 55% each at $700^{\circ}C$ with a heating rate of $20^{\circ}C$/min, respectively. The pyrolytic oil components were consisted of about 50 aromatic compounds. The calorific value of purolytic oil of commercial rubber, SBR, and tire was measured by calorimeter, it was 39~40 kJ/g. The BET surface area of pyroblack was $47~63m^2/g$. The optimum condition of pyrolysis was operating temperature of $700^{\circ}C$ with heating rate of $20^{\circ}C$. Therefore, the pyrolytic oil and pyroblack are possible to alternative fuel and carbon black.

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Automotive Engine Oil and Vehicle Fuel Economy (자동차 엔진오일과 연비)

  • 이영재;김강출;표영덕
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2000.11a
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    • pp.155-161
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    • 2000
  • To improve the vehicle fuel economy, various technologies such as improvement of power train efficiency, use of light weight material, improvement of aerodynamic design, have been studied. One of the possible way to improve the vehicle fuel economy is to reduce the engine friction loss by improving the engine oil characteristics. In the present paper, it was examined the effect of the engine oil viscosity and the addition of friction modifier to engine oil on vehicle fuel economy improvements. Moreover, the effect of engine oil degradation on vehicle fuel economy was examined with two gasoline vehicles and one diesel vehicle by using the fuel economy test facility.

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Characterization of Crude Oil Degradation by Klebsiella sp. KCL-1 Isolated from Sea Water (해양에서 분리된 Klebsiella sp. KCL-1에 의한 원유분해 특성의 규명)

  • 차재영;정선용;조용수;최용락;김범규;이영춘
    • Microbiology and Biotechnology Letters
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    • v.27 no.6
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    • pp.452-457
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    • 1999
  • Several bacterial strains utilizing crude oil as their sole carbon and energy sources were isolated from marine. One of the strains named KCL-1 showed the highest degradative activity for crude oil and the best growth rate. This strain was identified as a Klebsiella sp. based on the morphological, biochemical, and physiological characteristics. The optimum cultural conditions were as follows; $32^{\circ}C$~$37^{\circ}C$ for temperature and 7.0 for initial pH. Additionally, the optimal concentration of sodium chloride was 3.0%, indicating that this strain was derived from seawater. KCL-1 could use several kinds of n-alkane hydrocarbons from octadecane to hexacosane as a sole carbon source. The degradation of crude oil by KCL-1 was stimulated by addition of octadecane in the culture. The emulsifying activity by KCL-1 was highest after 3 days of cultivation under the condition of 3.0% sodium chloride, pH 7.0 and $37^{\circ}C$.

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The degradation of insulation oil in power transformers by the evolution of gases, Tan $\delta$, moisture and total acid number (가스량, Tan $\delta$, 수분량, 전산가에 의한 유침 전력 변압기의 열화현상에 관한 연구)

  • Choi, Jong-Kab;Han, Min-Koo;Kwon, Tae-Won;Yun, Yong-Bum
    • Proceedings of the KIEE Conference
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    • 1989.11a
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    • pp.159-163
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    • 1989
  • The various degradation phenomena, such as the evolution of gases, tan $\delta$, moisture content and total acid number in power transformer insulation oil, have been measured and analyzed. Mineral oil has been degraded at laboratory by the forced thermal stress of $60^{\circ}C$ and $90^{\circ}C$ respectively. Thermal aging oil has been degraded about 17, 34, 72 days. Also, we extracted insulation oil from working transformers. We measured gases dissolved in samples, tan $\delta$, moisture content, total acid number. Activation energy and resistivity is calculated from them. It is found that gases and tan $\delta$ increases as partial discharge and total acid number increases and that conductivity of the sample increases as activation energy increases.

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Implementation of the Probe System with Respect to the Engine Oil States Inspection (엔진오일 상태점검을 위한 프로브 시스템 구현)

  • Kim, Young-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.1
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    • pp.25-29
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    • 2012
  • In this paper, in order to measure the degree of degradation using the reflection coefficient of the probe, the measuring circuit is designed. we put pulse signal into the probe and measure the reflected signal in the circuit. As the condition of engine oil degradation, we can see that the reflected signal was increased and as the engine oil temperature increases, a phenomenon shows that the degradated dielectric constant is decreased. Finally, the theoretical values and measured values of the reflection coefficients of the probe are analyzed.

A Study of Upgrading Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste with Film Type - The Influence of Catalyst Amount and Reaction Temperature (필름형 혼합폐플라스틱의 열분해로부터 얻은 왁스오일의 고급화연구 - 촉매 양과 반응온도의 영향 -)

  • Lee, Kyong-Hwan;Song, Kwang-Sup;Nam, Ki-Yun
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.52-58
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    • 2009
  • Upgrading of pyrolysis wax oil using HZSM-5 catalyst has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation was studied with a function of catalyst amount and reaction temperature. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The catalytic degradation using HZSM-5 catalyst shows the high conversion of pyrolysis wax oil to light hydrocarbons. The liquid product obtained shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Here, the experimental variable such as catalyst amount and reaction temperature was influenced on the product distribution.

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Changes in Natural Antioxidants in Oils Extracted from the Bran and Germ of Keumkang and Dark Northern Spring Wheats During Photo-oxidation (금강밀과 dark northern spring밀의 기울과 배아에서 추출한 기름의 광산화 과정 중 천연산화방지성분의 변화)

  • Choi, Hyun-Ki;Choe, Eun-Ok
    • Korean Journal of Food Science and Technology
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    • v.42 no.1
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    • pp.14-20
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    • 2010
  • Naturally present antioxidants, tocopherols, carotenoids, and phospholipids in the bran and germ oils from Keumkang (K-WBG oil) and Dark Northern Spring wheats (DNS-WBG oil) were determined during storage under 1700 lux light at $5^{\circ}C$ by HPLC. Oil oxidation was monitored by peroxide values (POV) and conjugated dienoic acid content. The results showed that antioxidants were degraded during storage of the WBG oils under light, with higher degradation rates for carotenoids and phospholipids in the K-WBG oil compared to the DNS-WBG oil. Light increased oil oxidation and the rate of oxidation was higher in K-WBG oil than in the DNS-WBG oil. There was a high correlation between POV and residual amounts of antioxidants during photo-oxidation, with phospholipids showing the greatest effects on POV. This study suggests that a higher amount and lower degradation rate of phospholipids in the DNS-WBG oil contributed to its higher photo-oxidative stability compared to the K-WBG oil.