• 제목/요약/키워드: oil-degradation

검색결과 405건 처리시간 0.024초

벤치 규모 연속반응시스템에서 저급 열분해유 분해반응에 대한 반응온도 프로그램의 영향 (Effect of Reaction Temperature Program on Thermal Degradation of Low-quality Pyrolytic Oil for Bench-scale Continuous Reaction System)

  • 이경환;남기윤
    • 청정기술
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    • 제15권3호
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    • pp.186-193
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    • 2009
  • 본 연구에서는 상용운전 중에 있는 반연속식 로터리 킬른형 열분해반응기에 지자체에서 발생되는 필름형 혼합 폐플라스틱을 투입한 후 열분해하여 얻은 저급의 열분해유를 세 형태의 반응온도 프로그램에서 분해반응시키고, 여기에서 얻어지는 생성유의 특성을 논의하였다. 원료인 저급 열분해유의 특성은 원소분석 및 발열량 분석, SIMDIST 분석으로 확인하였고, 각 반응온도 프로그램에 따른 분해반응 결과는 각 성분의 수율분포, 액상 생성물의 누적수율과 생성비 등으로 논의하였다. 연구결과는 한 단계 반응온도 프로그램에 비해 다단계 반응온도 프로그램의 경우가 원하는 생성물인 오일수율이 높았고, 상대적으로 잔류물의 수율은 낮게 나타났다. 연속적인 열분해반응에서 반응온도 프로그램은 생성물의 수율분포 등 생성유 특성에 많은 영향을 주었다.

유류성분이 지하구조물의 방수층 침식에 미치는 영향평가 (Performance analysis of waterproofing corrosion as effecting oil)

  • 김영찬;이정윤;권시원;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2004년도 학술.기술논문발표회
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    • pp.91-95
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    • 2004
  • Utilization of underground construction if increased by the large size & skycraperlization of building recently. Therefore. waterproof dependence of underground construction is risen. However, water leakage was happened by rupture by concrete conduct, drying shrinkage. form tie. In underground environment soil class, degradation of waterproofing is showing to corrode by oil. An odious smell by oil, promotion evil of reinforcing rod corrosion, declination of durability can happen. Then, practical un degree of underground spare becomes low, Because oil or water permeates by construction by degradation to waterproof class corrode by oil, is considered to affect evil durability of construction.

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유류오염토양의 생물적용기술 적용타당성 검토 (Treatability Study on Oil-Contaminated Soils for Bioremediation Application)

  • 이연희;설미진;오영숙
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2001년도 추계학술발표대회
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    • pp.578-581
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    • 2001
  • A treatability study was conducted using a hydrocarbon-contaminated soil for the oPtimization of bioremediation strategy best fit to a given set of contamination. The applicability of nutrients, biosurfactant, and oil-degrading microorganisms were examined by monitoring $CO_2$ evolution and oil degradation The addition of inorganic nutrients in the form of slow released fertilizer accelerated the initial rate of $CO_2$ evolution by a factor of 3. The application of oil-degrading microorganisms did not significantly increased $CO_2$ evolution or biodegradation efficiency. Application of a commercial biosurfactant was most effect in terms of the total $CO_2$ evolution and the oil degradation rate. The results indicate that $CO_2$ evolution measurement was found to be a simple and reliable countermeasure of crude oil hydrocarbon mineralization for the rapid determination of the best-fit bioremediation strategy.

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고분자 폐가물의 열분해공정에서 유효자원의 회수 (Recovery of Available Resource from Waste Polymer using Thermal Degradation Process)

  • 김형진;정수경;홍인권
    • 환경위생공학
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    • 제15권4호
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    • pp.98-104
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    • 2000
  • Commercial rubber(IR, NR, BR), SBR, and tire were degraded by thermal degradation process. The oil yield of rubbers and tire ranges about 37~86%, it was increased with increase of operation temperature in pyrolysis. And the yield of pyrolytic oil was increased with increase of heating rate. The maximum oil yields of IR, NR, BR, SBR, and tire were 80, 73, 83, 86 and 55% each at $700^{\circ}C$ with a heating rate of $20^{\circ}C$/min, respectively. The pyrolytic oil components were consisted of about 50 aromatic compounds. The calorific value of purolytic oil of commercial rubber, SBR, and tire was measured by calorimeter, it was 39~40 kJ/g. The BET surface area of pyroblack was $47~63m^2/g$. The optimum condition of pyrolysis was operating temperature of $700^{\circ}C$ with heating rate of $20^{\circ}C$. Therefore, the pyrolytic oil and pyroblack are possible to alternative fuel and carbon black.

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자동차 엔진오일과 연비 (Automotive Engine Oil and Vehicle Fuel Economy)

  • 이영재;김강출;표영덕
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2000년도 제32회 추계학술대회 정기총회
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    • pp.155-161
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    • 2000
  • To improve the vehicle fuel economy, various technologies such as improvement of power train efficiency, use of light weight material, improvement of aerodynamic design, have been studied. One of the possible way to improve the vehicle fuel economy is to reduce the engine friction loss by improving the engine oil characteristics. In the present paper, it was examined the effect of the engine oil viscosity and the addition of friction modifier to engine oil on vehicle fuel economy improvements. Moreover, the effect of engine oil degradation on vehicle fuel economy was examined with two gasoline vehicles and one diesel vehicle by using the fuel economy test facility.

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해양에서 분리된 Klebsiella sp. KCL-1에 의한 원유분해 특성의 규명 (Characterization of Crude Oil Degradation by Klebsiella sp. KCL-1 Isolated from Sea Water)

  • 차재영;정선용;조용수;최용락;김범규;이영춘
    • 한국미생물·생명공학회지
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    • 제27권6호
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    • pp.452-457
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    • 1999
  • Several bacterial strains utilizing crude oil as their sole carbon and energy sources were isolated from marine. One of the strains named KCL-1 showed the highest degradative activity for crude oil and the best growth rate. This strain was identified as a Klebsiella sp. based on the morphological, biochemical, and physiological characteristics. The optimum cultural conditions were as follows; $32^{\circ}C$~$37^{\circ}C$ for temperature and 7.0 for initial pH. Additionally, the optimal concentration of sodium chloride was 3.0%, indicating that this strain was derived from seawater. KCL-1 could use several kinds of n-alkane hydrocarbons from octadecane to hexacosane as a sole carbon source. The degradation of crude oil by KCL-1 was stimulated by addition of octadecane in the culture. The emulsifying activity by KCL-1 was highest after 3 days of cultivation under the condition of 3.0% sodium chloride, pH 7.0 and $37^{\circ}C$.

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가스량, Tan $\delta$, 수분량, 전산가에 의한 유침 전력 변압기의 열화현상에 관한 연구 (The degradation of insulation oil in power transformers by the evolution of gases, Tan $\delta$, moisture and total acid number)

  • 최종갑;한민구;권태원;윤용범
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1989년도 추계학술대회 논문집 학회본부
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    • pp.159-163
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    • 1989
  • The various degradation phenomena, such as the evolution of gases, tan $\delta$, moisture content and total acid number in power transformer insulation oil, have been measured and analyzed. Mineral oil has been degraded at laboratory by the forced thermal stress of $60^{\circ}C$ and $90^{\circ}C$ respectively. Thermal aging oil has been degraded about 17, 34, 72 days. Also, we extracted insulation oil from working transformers. We measured gases dissolved in samples, tan $\delta$, moisture content, total acid number. Activation energy and resistivity is calculated from them. It is found that gases and tan $\delta$ increases as partial discharge and total acid number increases and that conductivity of the sample increases as activation energy increases.

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엔진오일 상태점검을 위한 프로브 시스템 구현 (Implementation of the Probe System with Respect to the Engine Oil States Inspection)

  • 김영주
    • 한국해양환경ㆍ에너지학회지
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    • 제15권1호
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    • pp.25-29
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    • 2012
  • 본 논문은 프로브의 반사계수를 이용하여 엔진오일의 열화정도를 측정하기 위해 반사 계수를 측정하는 회로를 설계한다. 프로브에 펄스를 인가하고 반사 신호를 측정할 수 있는 회로를 구현 하였다. 엔진오일의 상태가 열화 될 수록 반사 신호는 증가하는 것을 알 수 있었고, 엔진오일의 온도가 상승함에 따라 열화된 엔진오일의 유전율이 감소하는 현상을 측정하였다. 결론적으로, 프로브의 반사 계수를 이론치와 측정치를 비교 분석하였다.

필름형 혼합폐플라스틱의 열분해로부터 얻은 왁스오일의 고급화연구 - 촉매 양과 반응온도의 영향 - (A Study of Upgrading Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste with Film Type - The Influence of Catalyst Amount and Reaction Temperature)

  • 이경환;송광섭;남기윤
    • 신재생에너지
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    • 제5권4호
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    • pp.52-58
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    • 2009
  • Upgrading of pyrolysis wax oil using HZSM-5 catalyst has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation was studied with a function of catalyst amount and reaction temperature. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The catalytic degradation using HZSM-5 catalyst shows the high conversion of pyrolysis wax oil to light hydrocarbons. The liquid product obtained shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Here, the experimental variable such as catalyst amount and reaction temperature was influenced on the product distribution.

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금강밀과 dark northern spring밀의 기울과 배아에서 추출한 기름의 광산화 과정 중 천연산화방지성분의 변화 (Changes in Natural Antioxidants in Oils Extracted from the Bran and Germ of Keumkang and Dark Northern Spring Wheats During Photo-oxidation)

  • 최현기;최은옥
    • 한국식품과학회지
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    • 제42권1호
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    • pp.14-20
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    • 2010
  • 금강밀과 Dark Northern Spring(DNS)밀의 제분 중 발생하는 기울과 배아로부터 추출한 기름(WBG oil)을 $5^{\circ}C$, 1700 Lux로 12일 동안 광산화시킬때 토코페롤, 카로티노이드, 인지질 함량 변화를 측정하고 이들과 WBG oil의 광산화 관련성을 평가하였다. 토코페롤, 카로티노이드, 인지질은 WBG oil의 광산화 중 분해되었으며 DNS밀 WBG oil이 금강밀 WBG oil에서보다 토코페롤의 분해가 빨랐으나, 카로티노이드와 인지질 분해 속도는 느렸다. WBG oil의 광산화 정도와 산화방지성분의 상관관계는 매우 높았으며 인지질이 WBG oil의 광산화에 가장 큰 영향을 나타내었다. 금강밀 WBG oil에 비해 리놀레산 함량이 낮고 올레산 함량이 높았던 DNS밀 WBG oil은 지방산 조성은 물론 인지질의 높은 함량과 낮은 분해 속도에 기인하여 높은 광산화안정성을 나타내었다. 본 결과는 빛의 존재하에서 DNS밀 WBG oil보다는 금강밀 WBG oil이 토코페롤 source로 사용될 수 있는 가능성을 보여주었다.