• 제목/요약/키워드: oil-absorption

검색결과 327건 처리시간 0.025초

생분해성 유류고형화제의 제조와 효소에 의한 생분해 특성 (Preparation of Biodegradable Oil Gelling Agent and Biodegradation Characteristics by Enzyme)

  • 김정두;유수용;이민규
    • 한국환경과학회지
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    • 제14권10호
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    • pp.973-978
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    • 2005
  • Biodegradable oil gelling agent was prepared, and their oil absorption capacities using light oil, lubricant oil and corn oil were investigated. The result showed that the oil absorption capacity was depended on the amount of surfactant and starch added, and was increased in the order of light oil, lubricant oil and corn oil. Also, the oil-absorption capacity was saturated within 30 min at $18^{\circ}C$. The biodegradability of the prepared biodegradable oil gelling agent was also studied by determination of reduced sugar produced after enzymatic hydrolysis. Their surface morphologies and thermal properties of the prepared biodegradable oil gelling agent were observed by scanning electron microscopy (SEM) and thermogravimetric analysis (TGA), respectively.

오일유막의 연료 흡수 및 방출에 관한 연구 (Modeling of Absorption/Desorption of Fuel in Oil film on the Cylinder Liner in SI Engines)

  • 유상석;민경덕
    • 한국자동차공학회논문집
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    • 제7권9호
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    • pp.165-171
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    • 1999
  • An oil layer fuel absorption /desorption modeling was developed. Multi-component fuel model has showed more reasonable condition than single component model. Henry's constant which is related to solubility is the most important variable in the oil layer absorption/desorption mechanism. The oil segments close to the top of the cylinder liner have more significant contribution to the fuel absorption and desorption process than other oil segments. At the warmed-up condition, the effect of the engine speed on the precent fuel absorbed/desorbed is minimal. But at low il film temperature, percent of fuel abosrbed/desorbed is decreased with increasing the engine speed because of low value of molecular diffusion coefficient of fuel. The amount of fuel trapped in the piston crevice is from 2 to 2.3 times larger than that of fuel in the oil fim. However, fuel form oil film slowly desorbs into the combustion chamber compared with fuel from the piston crevices when the engines is cold.

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흡유제인 생분해석 Poly(2-ethylhexylacrylate)의 제조 (Preparation of Biodegradable Poly(2-ethylhexylacrylate) as Oil Sorbers)

  • 유수용;이동환;감상규;이민규
    • 한국환경과학회지
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    • 제19권1호
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    • pp.97-103
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    • 2010
  • The biodegradable oil absorption resin was prepared by the suspension polymerization of the modified starch and 2-ethylhexyl acrylate (2-EHA). The highest oil-absorption capacity of B-PEHA prepared showed at the condition of the modified starch content of 10 g and ethyleneglycol dimethacrylate (EGDMA) of 0.133 wt%. Its maximum oil absorption capacity per g of oil absorber was chloroform 30.88 g, toluene 19.75 g, xylene 18.78 g, tetrahydofuran (THF) 15.96 g, octane 11.43 g, hexane 9.5 g diesel oil 12.80 g, and kerosene 13.79 g, respectively. The biodegradation of poly-2-ethylhexylacrylate (B-PEHA) determined by enzymatic hydrolysis showed approximately 17~20%. The results showed that the preparation of the biodegradable oil absorption resin is available using the modified starch.

유기 다공성 소재의 흡유 효과 (Oil Absorption Effects of Organic Porous Materials)

  • 강영구;한상범
    • 한국안전학회지
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    • 제21권1호
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    • pp.86-91
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    • 2006
  • Oil spills caused by the accidents have been occurred from house and factory waste, grounded tanker, the rupture of storage tank and oil pipelines, the deterioration of various industrial facilities, etc. Many oil spills result in contamination of shorelines and workplace. Fire and explosion may happen from these spills. There are several technologies used for clean-up application, which include use of oil dispersing agents, absorbents, solidifiers, booms and skimmers by physical, chemical, and biological methods. Methods for oil spill clean-up operation are classified into the absorption type, gel type and self-swelling type. Porous materials with oil absorptive properties are classified into micropore, mesopore, and macropore depending on their pore sizes. Recently, new porous materials with smaller size have been developed, but the selective oil absorption in water-in-oil interface demonstrates the macro pore size. In this study oil absorption effects were evaluated using the organic porous materials with a complex function of gel type and swelling type. Samples were subjected to analysis by FT-IR spectroscopy and were characterized in terms of gel formation and morphologies. Oil sorption capacity, pressure retention force and gel strength were also measured. From these results, the physicochemical reactivity before and after gelation was verified and the industrial applications of clean-up operation were suggested.

Microwave Absorption Study of Carbon Nano Materials Synthesized from Natural Oils

  • Kshirsagar, Dattatray E.;Puri, Vijaya;Sharon, Maheshwar;Sharon, Madhuri
    • Carbon letters
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    • 제7권4호
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    • pp.245-248
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    • 2006
  • Thin films of carbon-nano materials (CNMs) of different morphology have been successfully deposited on ceramic substrate by CVD at temperatures $800^{\circ}C$, $850^{\circ}C$ and $900^{\circ}C$ using plant based oils in the presence of transition metal catalysts (Ni, Co and Ni/Co alloys). Based on the return and insertion loss, microwave absorption properties of thin film of nanocarbon material are measured using passive micro-Strip line components. The result indicates that amongst CNMs synthesized from oil of natural precursors (mustered oil - Brassica napus, Karanja oil - Pongamia glabra, Cotton oil - Gossipium hirsuta and Neem oil - Azadirachta indica) carbon nano fibers obtained from neem's seed oil showed better microwave absorption (~20dB) in the range of 8.0 GHz to 17.90 GHz.

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자외선 흡수특성을 이용한 참기름의 이종기름 혼입판별에 관하여 (Determination of Sesame oil Adulterated with other Vegetable oils by Spectrophotometric Method)

  • 이영근
    • 한국식품위생안전성학회지
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    • 제8권3호
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    • pp.151-155
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    • 1993
  • 참기름에 이종의 식용유를 혼합하였을 때 이를 판별할 수 있는 방법을 연구하기 위하여, 순수한 참기름을 비롯한 일반적인 식용유 5종의 UV흡수양상을 조사하여 각 식용유의 UV흡수특성을 이용하여 순수한 참기름과 혼합 기름을 구별할 수 있는 근거를 마련하였다. 순수한 참기름의 spectrum은 215, 230 및 290 nm에서 흡수피크를 형성한 반면, 옥수수유, 들기름 및 대두유는 모두 215, 230 및 280 nm에서, 그리고 미강유는 215, 290 및 320 nm에서 흡수피크를 형성하였다. 참기름의 290 nm에서의 흡수피크는 참기름 제조과정인 참깨의 볶는 온도와 시간이 증가할수록 그 흡광도가 증가하는 경향이 있었으며, 일반적인 조건으로 추정되는 $200^{\circ}C$, 60분간 볶은 후 제조한 참기름은 대략 0.7 정도의 흡광도를 나타내었다. 참기름에 미강유를 혼합한 기름에서는 320 nm에서 미강유의 존재를 확인할 수 있는 흡수피크가 나타나고, 참기름에 옥수수유, 들기름 또는 대두유를 각각 혼합한 기름들은 290 nm에서의 흡광도가 순수한 참기름의 흡광도에 비하여 적었으며, 이종기름의 혼합율이 높을수록 비례적인 감소를 나타내었다.

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멜트블로운 부직포의 흡유도와 흡유거동에 관한 연구 (A Study on Oil Absorption Rate and Oil Absorbency of Melt-blown Nonwoven)

  • 신현세;유주환;김로
    • 한국염색가공학회지
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    • 제22권3호
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    • pp.257-263
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    • 2010
  • Oil-absorbable nonwovens were produced by meltblown processing of polypropylene chips. In this study, experimental array and variance analysis of the design of experiment were used to increase the field repeatability and universality. Oil absorbency was decreased, as oil absorbable nonwovens of packing density and gearpump speed were increased. Oil absorption rate was increased, as packing density was increased. Also the oil absorption rate increased with increasing gear-pump speed.

Effect of fibre loading and treatment on porosity and water absorption correlated with tensile behaviour of oil palm empty fruit bunch fibre reinforced composites

  • Anyakora, Anthony N.;Abubakre, Oladiran K.;Mudiare, Edeki;Suleiman, MAT
    • Advances in materials Research
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    • 제6권4호
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    • pp.329-341
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    • 2017
  • The challenge of replacing conventional plastics with biodegradable composite materials has attracted much attention in product design, particularly in the tensile-related areas of application. In this study, fibres extracted from oil palm empty fruit bunch (EFB) were treated and utilized in reinforcing polyester matrix by hand lay-up technique. The effect of fibre loading and combined influence of alkali and silane treatments on porosity and water absorption parameters, and its correlation with the tensile behaviour of composites was analyzed. The results showed that tensile strength decreased whilst modulus of elasticity, water absorption and porosity parameters increased with increasing fibre loading. The composites of treated oil palm EFB fibre exhibited improved values of 2.47 MPa to 3.78 MPa for tensile strength; 1.75 MPa to 2.04 MPa for modulus of elasticity; 3.43% to 1.68% for porosity and 3.51% to 3.12% for water absorption at respective 10 wt.% fibre loadings. A correlation between porosity and water absorption with tensile behavior of composites of oil palm EFB fibre and positive effect of fibre treatment was established, which clearly demonstrate a connection between processing and physical properties with tensile behavior of fibre composites. Accordingly, a further exploitation of economic significance of oil palm EFB fibres composites in areas of low-to-medium tensile strength application is inferred.

파우더 베이스 메이크업 제품의 지속성 평가 방법 연구 (A Study of Cosmetic Sustainability Evaluation of Powder Base Make-up Products)

  • 이상길;김기중;김영호;표형배;이동규
    • 대한화장품학회지
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    • 제41권3호
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    • pp.209-218
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    • 2015
  • 파우더 베이스 메이크업 제품은 피부에 도포되어 8 ~ 12시간 동안 부착되며 피부에서 분비되는 땀이나 피지 등의 분비물에 의해 화장막이 변화된다. 따라서 메이크업 화장의 지속성은 중요한 품질 요소 중 하나이며 평가도 중요하다. 본 연구는 파우더 제품에서 지속성 평가를 위해 여러 가지 방법으로 파우더 반제품의 흡수, 흡유, 발수, 발유 등의 특성을 측정해보고 객관적인 평가 방법과 비교하여 연관성을 확인하여 지속성 평가 시 중요한 파우더의 특성을 살펴보았다. 또한 평가조건(땀과 피지 분비량 차이, 기온 및 습도 등)에 크게 영향을 받지 않으면서 지속성을 예측할 수 있는 간단한 방법을 검토해보았다. 타정 흡유도와 모세관법 및 침지법 등으로 반제품의 흡수, 흡유, 발수, 발유 특성을 측정해본 후 색차계와 ROBO skin analyzer 데이터와 비교하였다. 그 결과 흡수, 발유 특성보다는 흡유와 발수 특성이 지속성과의 연관성이 크다는 것을 확인할 수 있었고 흡유, 발수 특성을 확인하는 것으로 빠르고 손쉽게 지속성에 대한 예측이 가능하리라 생각되었다. 그 중 흡유 특성은 타정 흡유도와 모세관법이, 발수 특성은 침지법이 지속성에 대한 상대평가 방법으로 유용할 것이라고 판단되었다.

추출-증류-결정의 조합에 의한 콜타르 흡수유 중에 함유된 인돌의 고순도 정제 (High-Purity Purification of Indole Contained in Coal Tar Absorption Oil by Extraction-Distillation-Crystallization Combination)

  • 김수진
    • 공업화학
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    • 제25권3호
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    • pp.330-336
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    • 2014
  • 추출-증류-결정의 조합에 의해 모델 콜타르 흡수유 중에 함유된 인돌의 정제를 검토했다. 흡수유는 4종류의 질소고리 화합물(9.2% 퀴놀린, 2.4% 이소퀴놀린, 4.7% 인돌, 2.4% 퀴날딘), 3종류의 2환 방향족 화합물(14.2% 1-메틸나프탈렌, 31.8% 2-메틸나프탈렌, 23.5% 디메틸나프탈렌), 5.5% 비페닐과 3.3% 페닐에테르의 9종류의 화합물로 구성되어 있다. 포름아미드 추출-증류-노말헥산을 사용한 용액 결정화의 조합의 채택에 의해 99.5% 인돌을 회수할 수 있었다. 본 연구를 통해 얻어진 실험적 결과를 이용하여 콜타르 흡수유 중에 함유된 인돌의 회수공정을 검토했다.