• Applied Chemistry for Engineering
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• v.28 no.5
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• pp.559-564
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• 2017

In this study, the optimization process was carried out by using the central composite model of the response surface methodology in waste cooking oil based biodiesel production process. The acid value, reaction time, reaction temperature, methanol/oil molar ratio, and catalyst amount were selected process variables. The response was evaluated by measuring the FAME content (more than 96.5%) and kinematic viscosity (1.9~5.5 cSt). Through basic experiments, the range of optimum operation variables for the central composite model, such as reaction time, reaction temperature and methanol/oil molar ratio, were set as between 45 and 60 min, between 50 and $60^{\circ}C$, and between 8 and 12, respectively. The optimum operation variables, such as biodiesel production reaction time, temperature, and methanol/oil molar ratio deduced from the central composite model were 55.2 min, $57.5^{\circ}C$, and 10, respectively. With those conditions the results deduced from modeling were as followings: the predicted FAME content of the biodiesel and the kinematic viscosity of 97.5% and 2.40 cSt, respectively. We obtained experimental results with deduced operating variables mentioned above as followings: the FAME content and kinematic viscosity of 97.7% and 2.41 cSt, respectively. Error rates for the FAME content and kinematic viscosity were 0.23 and 0.29%, respectively. Therefore, the low error rate could be obtained when the central composite model among surface reaction methods was applied to the optimized production process of waste cooking oil raw material biodiesel.

• Environmental Engineering Research
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• v.17 no.3
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• pp.157-165
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• 2012

This experimental study was performed to obtain thermal energy from the combustion of synthetic gas, produced by the pyrolysis of insulating oil containing polychlorinated biphenyls (PCBs) in a high temperature and high pressure reactor. The average synthetic gas generated was $59.67Am^3/hr$ via the steady state gasification of insulating oil waste (20 kg/hr) with average concentrations (standard deviation) of $CO_2$, CO, and $H_2$ in the synthetic gas of $38.63{\pm}3.11%$, $35.18{\pm}1.93%$, and $28.42{\pm}1.68%$, respectively. The concentrations of the PCBs in the transformer insulating oil and synthetic gas after its gasification, and the concentrations of the dioxins that could be produced from the incomplete degradation of PCBs were measured. It was revealed that the PCBs in the insulating oil were composed of the series from tetrachlorobiphenyl to octachlorobiphenyl. However, only the #49, #44, #52, and #47/75/48 congeners were detected from the synthetic gas after gasification of the insulating oil and in the flue gas from the combustor. In conclusion, the experimental conditions suggested in this study were very useful for the appropriate treatment of insulating oil containing PCBs. Also, fuel gas containing CO and $H_2$ can be obtained from the pyrolysis of insulating oil containing PCBs.

• Resources Recycling
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• v.4 no.4
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• pp.16-21
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• 1995

When waste t~re/~vastmz otor oil is pyrolyzed. most of them hecome gaseous produds. and thc remaining onc, whascwelght is ahout in% oi the waste Ore, is pyrolyced residue mnstly composcd oi ca~bnn black A rescsrcll was canicrl nut loutilize lhe pyralyred residue of waste tnelwuste lnotol 011 us retnin~cing agent of asphall concrete, bescd on iolelg~r lesearchrepurl. This shows thal the properlies ol asphall concrele ~nclud~cd~ugl ah~l~tyre, sistance to Tear. temperature-v~scusilysusceptil,ilily u e g reatly improved when lhe pellellrcd hrln aI carlmn hlack usmg petroleum o ~als a hinder Iar ihe pellels isused with asphalt. The surface of the pyralyred resirh~ei s covned by ocl film and thla lnakes good comllatibllity with asphallIn order lo ulilk pyrolyzed residue as a reinforcing agenl oi lhe itsphalt concrete, various tests such as Marshnll tcsi, wheeltracking, and revelhng test has been carried out a1 KLER, Ko~ea I-lighway Coo~poration, and TCMO. Tcst lcsults satirry KSslandard, show "npmvements an the dynam~cs tab~l~lzym, d incrcase reslslance to wear at cold telnpelatule Invrsligadon wascarlied oul to sludg the possibility of soil pallul~on when pyrolyzed residue is used as a tzmioicing agenl. E~pcrimentalresulls show the rcsidue contained in thc asphall docs not cause cnv~ranma~lparlo blems.e cnv~ranma~lparlo blems.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2000.06a
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• pp.83-91
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• 2000

This paper illustrates a new idea methods and results of WPD oil applied to marine diesel engines. in recent years, we must make an effort to develop an advanced technique for recycling of waste plastics in order to utilize scrapped plastics as fuel source for diesel engine. It is very important and necessary for us to cope with the increasing calorific value and the growing need of environment protection. The experiment fuel oil was obtained by mixing of diesel oil, WPD and water.

• Journal of Environmental Science International
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• v.12 no.1
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• pp.41-45
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• 2003

Magnetite powder for kerosene-based ferrofluid was synthesized by air oxidation of waste acid containing $Fe^{2+}$ and $Fe^{3+}$ ions in the pH=11 at $60^{\circ}C$. Stable kerosen-based ferrofluid was prepared by addition of polyoxyethylene nonylphenyl ether(POENPE) to the magnetite containing water. Dispersion mechanism of an addition POENPE to the magnetite was examined by means of the fraction of solid dispersed FT-IR spectrum. And magnetic properties of kerosen-based ferrofluid were examined by method of Vibrating Sample Magnetometer. In order to remove oil on the water surface by an addition of kerosen-based ferrofluid, the optimum conditions were examined.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.471-474
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• 2008

The pyrolytic behavior of waste tire under microwave heating was investigated. Experiments were conducted using a lab- and bench-scale system to delineate the effects of microwave output power on the response. As the results of experiments, it was found that as the microwave output power was increased between 0.84 and 3.04 kW/kg, the oil yield and required time rapidly increased and decreased, respectively. With further increase of the microwave output power, the oil yield and required time did not change significantly.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.161-162
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• 2014

The subject of this study, Eco-friendly Polyurethane Waterproofing Membrane Coating of Exposed Type is manufactured by replacing environmental hazardous substance such as Toluene, Dioctyl Phthalate with Dimethyl Carbonate, waste-soybean oil. As part of existing filler is also replaced with waste-rubber chip and waste-soybean oil. As a result of environment friendly tests, in test of detection of VOCs case was contented with the Ministry of Environment standards at 5% below. Testing methods for heavy metal extracted was contented with standards for official wastes test method. So it is judged that environment friendly is secured.

• Journal of the Korean Wood Science and Technology
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• v.39 no.4
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• pp.359-369
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• 2011

The study was carried out to investigate the quality characteristics of pellets manufactured with adding soybean oil, waste soybean oil, ozonized soybean oil and ozonized waste soybean oil to Larix kaemferi Carr sawdust. The characteristics of pellet included moisture contents, heating value, ash contents, apparent densities, durabilities, absorption ratio and elementary analysis. Moisture contents were shown 7.66~9.48% which satisfied the first grade (less than 10%) of quality standard of wood pellets announced by Korea Forest Research Institute. The heating value of the manufactured wood pellets in this study exceeded the first grade of quality standard (more than 4,300 kcal/kg) and it appeared that the pellets manufactured with adding oils and ozonized oils had more heating value than the control pellets. Ash contents 0.34~0.42% also passed the first grade (less than 0.7%) of quality standard and apparent densities were adequate for the first grade (640 kg/$m^3$) on the quality standard. Durabilities of the pellets manufactured with adding soybean oil and ozonized waste soybean oil were shown over the first grade (97.5 kg/$m^3$) of quality standard. In the general results of durabilities, the pellets manufactured with additives had better values than the control pellets. After 24 hours absorption ratio experiment, absorption ratio of pellets manufactured with additives also appeared much lower moisture absorption than the control pellets and they still had the same results after 5days absorption ratio experiment. Elementary analysis of the sulfur content was satisfied the first grade (less than 0.05%) of quality standard of wood pellets and the nitrogen content was also adequate for the first grade (less than 0.3%) of quality standard of wood pellets.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.222-222
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• 2011

Plastic product is increasing by the growth of its demand and most of refused plastics are incinerated or reclaimed. However, the refused plastic is not easily decomposed and has the environmental problem with its various toxic gas in case of incineration. Therefore, many countries such as USA, Japan, Germany and other developed industrial countries as well as Korea are interested in studying the recyclable resource of refused plastic. The macromolecular waste pyrolysis has the advantage of collecting of raw materials in high price and can at least get fuel gas or oil with high heat capacity. It also discharges low waste gas and low toxic gas including SOx, NOx and HCl heavy metals. However, pyrolyzed oil includes enough excess unsaturated hydrocarbons to form tar, which can cause the nozzle of engines to plug when pyrolyzed oil is used as fuel. Activated carbon was proven to have prominent adsorption capability among the other adsorbents that were mainly composed of carbon. This study examined the possibility of application in activated charcoal of its solid formation by analysing the feature of pyrolysis which is one of the chemical recycling methods and getting chemical analysis of the product and activated energy. Analyze the element of the oil produced by pyrolysis using GC-MS. The experiment of tar adsorption using fly-ash showed that fly-ash improved the optical intensity of pyrolyzed oil and decreased oxygen compounds in the pyrolyzed oil.

• Journal of Korea Soil Environment Society
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• v.5 no.1
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• pp.97-108
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• 2000

A Gram-type negative bacteria that can utilize crude oil as the sole source of carbon and energy was isolated from an activated sludge of a local sewage treatment plant and identified tentatively as belonging to the genus Acinetobacter. The isolate could degrade n-alkanes and unidentified hydrocarbons in crude oil and utilize n-alkanes, hydrophobic substrates, as sole carbon and energy sources. n-Alkanes from tridecane (Cl3) to triacontane (C30) in crude oil were degraded simultaneously with no difference in degradation characteristics between the two close odd and even numbered alkanes in carbon numbers. The linear growth of the isolate and the degradation characteristics of Pr-alkanes suggested that the transport of substrates from the oil phase to the site where the substrates undergo the initial oxidation in microorganism might be the rate limiting in the biodegradation process of crude oil constituents. The remainder fraction of substrates after cultivation was considered to reflect the hydrocarbon inclusions in the cell mass, characteristics in Acinetobacter species, and to control the transport of substrates from crude oil phase. On the basis of the results, the isolate was considered to play an important role in the degradation study of hydrophobic environmental pollutants.