• Title/Summary/Keyword: oil resistance

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리튬 이온 전지 씰링에의 응용을 위한 EPDM, NBR, FKM, VMQ 및 FVMQ 특성연구 (The Study of Characteristics on EPDM, NBR, FKM, VMQ and FVMQ for Sealing Applications to Lithium Ion Battery)

  • 서관호;조광수;윤인섭;최우혁;허병기;강동국
    • Elastomers and Composites
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    • 제45권3호
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    • pp.212-216
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    • 2010
  • 리튬 이온 전지의 가스켓 재료로 사용되기 위해서는 내전해액성, 전기절연성, 낮은 압축 영구 줄음률, 비오염성, 내열성이 요구된다. Perfluoroalkoxy (PFA)보다 압축 영구 줄음률이 우수한 고무의 적합성을 평가하기 위하여 Ethylene Propylene Diene Monomer (EPDM), Nitrile Butadiene(NBR), Fluoro Elastomers(FKM), Methyl-Vinyl Silicone Rubber (VMQ), Fluorosilicone(FVMQ)을 이용하여 최적상태의 compound를 제작하고 특성을 살펴보았다. 시험편을 $80^{\circ}C$의 propylene carbonate액에 침적하여 경도 및 체적변화를 1,000시간까지 시간별로 측정하였다. EPDM과 VMQ가 내전해액성이 우수하였으며, 전기절연성에서도 체적저항 기준 $10^{10}{\Omega}cm$이상의 결과를 얻을 수 있었다. 따라서, EPDM과 VMQ가 적절한 것으로 판단되었다.

연안선박의 선수부 개조에 의한 에너지 효율 성능 분석 (Assessment on the Energy Efficiency Performance by the Fore-body Retrofit of the Coastline)

  • 박동우;김경성
    • 해양환경안전학회지
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    • 제23권7호
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    • pp.965-971
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    • 2017
  • 본 논문의 주 목적은 기존선형과 저항을 최소화하는 최적선형에 대한 에너지효율 성능을 평가하는 것이다. 설계 흘수와 설계 선속을 고려하여 대상선박의 선수부 형상을 검토하였다. 실제 운항 상태에서 대상선박의 저항성능을 평가하였다. 상용 전산유체역학(CFD) 코드와 수조 모형시험 자료는 유효마력 평가를 위해 사용되었다. 실제 운항 상태를 고려하여 최소저항을 가지는 최적선형을 제시하였다. 기존선형과 최적선형에 대하여 3가지 선속에서 유효마력을 추정하였다. 최적선형의 저항성능은 기존선형과 비교하여 볼 때 설계속도(12노트)에서 약 6 % 향상된 결과를 보여 주었다. 준추진효율 계수(ETAD, ${\eta}_D$)는 모형시험 자료를 활용하였다. 에너지 효율 성능은 년간 운항일수, 벙커C유 가격, 1일 연료사용량 그리고 연료소비계수를 바탕으로 작성되었다. 최적선형의 에너지 효율 성능은 기존선형과 비교하였을 때 12노트에서 연간 약 3천만원 절약된 결과를 보여 주었다.

Photoelectrochemical Properties of $TiO_2$ Electrodes Prepared Using Chemical Functionalized Binders

  • 송용환;김상기;양재창;박준호;김명수;구할본;박경희
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.60.1-60.1
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    • 2010
  • Chemically functionalized plant oils such as acrylated epoxidized soybean oil (AESO) and maleinized acrylated epoxidized soybean oil (MAESO) were used as new bio-based binders for $TiO_2$ electrodes of dye-sensitized solar cells (DSSC). More porous networks and larger porosities were fabricated on the $TiO_2$ films using plant oil binders due to the larger number of functionalities, in comparison with the film using polyethylene glycol (PEG). The charge-transfer resistance in the $TiO_2$ films was considerably shrunk due to the reduced impurity states. The short circuit photocurrent (Isc) and the open circuit photovoltage (Voc) of the cell using plant oil binders increased and the conversion efficiency improved significantly.

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표면 젖음성을 이용한 물/오일 분리막 제작 (Fabrication of Stable Water/Oil Separation Filter Using Effect of Surface Wettability)

  • 김도형;안태창
    • 센서학회지
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    • 제25권3호
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    • pp.213-217
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    • 2016
  • The superhydrophobic and superoleophobic meshes surfaces have been used in various applications such as self-cleaning, anti-icing, gas exchange, oil-water separation, sound-wave penetrable anti-wetting structures, etc. In particular, there are many studies for oil-water separation with environmental issues. Because of high pressure and dynamic environment, oil-water separation filters must have stable surface properties as super-hydrophobicity and superoleophobicity. The oleophobicity of surface depends on the surface chemistry and roughness of the surface. The roughness of oleophobic surface enhances its static contact angle and stability. The multi-scale hierarchical structure provides a stable superhydrophobic state by maintaining a Cassie state. In this research, we fabricated a superoleophobic mesh with a multi-scale hierarchical structure to increase the pressure resistance and adjusted a size of the mesh hole.

Oil Filled 케이블용 절연유의 유전특성 (Dielectric characteristics of insulating oil for oil filled cables)

  • 서정필;김왕곤;신성권;조경순;홍징웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 추계학술대회 논문집
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    • pp.147-151
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    • 1994
  • In order to investigate the dielectric characteristic insulating oil is chosen insulating oil for electric cable, and experiment is performed in the temperature range of 30∼120[$^{\circ}C$] and frequency range of 30∼1${\times}$10$\^$6/[㎐]. As a result, the observed linear decrease in tan $\delta$ value at the low frequency range is due to the influence of frequency, whereas the increase in tan $\delta$ value at high frequency range is contributed by the electrode's resistance and dielectric loss. The dipole moment and activation energy of specimen are obtained 1.22(debye) and 12.75∼18.66[㎉/㏖e] of high temperature region, 15.68 ∼ 20.6[㎉/㏖e] of low temperature region respectively.

A strategy to prepare internally plasticized PVC using a castor oil based derivative

  • Chu, Hongying;Ma, Jinju
    • Korean Journal of Chemical Engineering
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    • 제35권11호
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    • pp.2296-2302
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    • 2018
  • Internally plasticized PVC was prepared via chemical reaction of azide PVC and alkynyl group containing castor oil methyl ester. The chemical structure of alkynyl group containing castor oil methyl ester and internally plasticized PVC was characterized with FT-IR and $^1H$ NMR. Properties of internally plasticized PVC, including thermal stability, tensile tests and resistance to extraction in different solvents, was investigated. The results showed that alkynyl group containing castor oil methyl ester, as internal plasticizer of PVC, not only decreased the $T_g$ of PVC from $84.6^{\circ}C$ to $41.6^{\circ}C$ efficiently, but also presented no plasticizer loss in five different solvents. The tensile tests showed that elongation at break and tensile strength of internally plasticized PVC was 353.8% and 18.1 MPa. The internally plasticized PVC has potential application in replacing the traditional PVC material in PVC products with high durability.

Manufacture of Water-borne Biopolyurethane Film Based on Caster Oil and Tri Methylol Propane for Leather Coationg

  • Lee Joo-Youb
    • 한국응용과학기술학회지
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    • 제39권6호
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    • pp.924-931
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    • 2022
  • Undenatured castor oil and trimethylolpropane (TMP) were used to obtain bio-based water-based polyurethane. Isophorone diisocyanate (IPDI) was incorporated into the formulation to obtain a transparent film, and ethylenediamine (EDA) was used for chain extension. In order to measure the change in physical properties according to the contents of castor oil and TMP, each tensile strength, elongation, and abrasion resistance test was conducted. As the contents of castor oil and TMP increased, the tensile strength increased, the elongation decreased, and the surface hardened strongly as the respective contents increased.

인산 에스테르게 난연제 BDPDH를 첨가한 CPE 고무재료의 난연성 및 내열성 (Flame Retardance and Thermal Resistance of CPE Rubber Compound Containing a Phosphoric Ester Flame Retardant BDPDH)

  • 박현호;이창섭
    • Elastomers and Composites
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    • 제38권1호
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    • pp.72-80
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    • 2003
  • 자동차 Oil cooler용 호스를 구성하는 고무재료의 내열 및 난연성을 향상시키기 위하여 인산 에스테르계 화합물을 내열 및 난연제로 하여 제조한 염소화 폴리에틸렌(CPE) 배합고무의 가황 특성, 물리적 성질, 내열성, 난연성 및 변량효과를 조사하였다. 호스용 고무재료는 기존의 ethyleneacrylate rubber(EAR)보다 화학적 내식성과 내한성이 우수하면서도 가격이 저렴한 CPE 고무재료를 사용하였으며, 난연제는 비할로겐 축합 인산 에스테르계인 N,N'-bis-(diphenylphosphoro) diaminohexane(BDPDH)를 합성하여 CPE 고무재료와 $0{\sim}30 phr$ 범위에서 혼련하였다. 배합고무시편의 경도, 인장강도, 신율, 인장응력 및 열적 특성을 측정한 결과, CPE 배합고무의 유동성, 난연성, 내열성이 향상되었음을 확인하였으며, 고무재료 규격을 초과하지 않는 범위 내에서 최대의 내열 및 난연 효과를 주는 BDPDH의 배합량은 20 phr로 나타났다.

Susceptibility of Oral Bacteria to Essential Oil of Artemisia capillaris Thunb.

  • Kim Kyong-Heon;Kim Baek-Cheol;Shin Chol-Gyun;Jeong Seung-Il;Kim Hong-Jun;Ju Young-Sung
    • 대한한의학회지
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    • 제25권4호
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    • pp.121-128
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    • 2004
  • Objective : The aim of this work is to investigate the antibacterial activity of the essential oil obtained from Artemisia capillaris (A. capillaris), as the development of microbial resistance to antibiotics make it necessary to constantly look for new and active compounds effective against pathogenic bacteria. Methods : The crushed materials of A. capillaris (1 kg) were subjected to steam distillation for 3 h, using a modified Clevenger type apparatus in order to obtain essential oil. Diethyl ether was the extracting solvent kept at 25°.... The essential oil was analyzed by gas chromatography (GC) and gas chromatography/mass spectrometry (GC/MS). The essential oil and the composition were tested for antimicrobial activities against 15 different genera of oral bacteria. Results and Conclusion : The components of the essential oil identified were: β-pinene (9.36%), camphor (3.32%), 1,8­cineole (4.38%), artemisia alcohol (3.32%), β-caryophyllene (11.08%), γ-cadinene (4.23%), and capillene (32.74%). The essential oil of A. capillaris exhibited considerable inhibitory effects against all oral bacteria tested, while their major components demonstrated various degrees of growth inhibition.

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항생제 내성 및 감수성 Salmonella typhimurium 균주에 대한 개똥쑥 지상부 정유와 Kanamycin의 병용효과 (In vitro Effects of Essential Oils from the Aerial Parts of Artemisia annua L. Against Antibiotic-Susceptible and -Resistant Strains of Salmenella typhimurium)

  • 신승원
    • 약학회지
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    • 제51권5호
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    • pp.355-360
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    • 2007
  • The essential oil fraction from the aerial parts of A. annua was analyzed by GC-MS. As the results, caryophyllene oxide (11.7%), caryophyllene (7.54%), camphor (7.32%), 1,8-cineol (4.98%), and borneol (3.99%) were confirmed as the main components of the oil fraction. The effects of this oil and its main components on antibiotic-susceptible and -resistant strains of Salmonella enteritidis and S. typhimurium were assessed. A. annua oil fraction significantly inhibited all strains of the two Salmonella species examined, with minimum inhibiting concentrations (MICs) ranging from 2.0 mg/ml to 8.0 mg/ml. Among the main components of the oil, borneol and camphor showed relatively strong inhibiting activity with MICs between 1.0 mg/ml and 4.0 mg/ml. The MICs of caryophyllene and caryophyllene oxide were higher than 16 mg/ml. The combination effects of the oils with kanamycin were evaluated using a checkerboard microtiter assay. Against S. typhimurium KCCM11862 and CCARM8009 strains, the oil fraction of A. annua, camphor, and 1,8-cineol exhibited significant synergistic with kanamycin with fractional inhibitory concentration (FIC) indices in the range of 0.085 to 0.375. In conclusion, a combination of kanamycin and A. annua oil or its main component, camphor, and cineol, may be useful for reducing the minimum effective dose of antibiotic required for the treatment of resistant S. typhimurium infections.