• 제목/요약/키워드: oil resistance

검색결과 483건 처리시간 0.026초

Cu-7Al-2.5Si 합금의 기계적 및 내식특성에 미치는 열처리 효과 (Effect of the Heat Treatment on the Mechanical Property and Corrosion Resistance of CU - 7Al - 2.5Si Alloy)

  • 이성열;원종필;박동현;문경만;이명훈;정진아;백태실
    • Corrosion Science and Technology
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    • 제13권1호
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    • pp.28-35
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    • 2014
  • Recently, the fuel oil of diesel engines of marine ships has been increasingly changed to heavy oil of low quality as the oil price is getting higher and higher. Therefore, the spiral gear attached at the motor of the oil purifier which plays an important role to purify the heavy oil is also easy to expose at severe environmental condition due to the purification of the heavy oil in higher temperature. Thus, the material of the spiral gear requires a better mechanical strength, wear and corrosion resistance. In this study, the heat treatment(tempering) with various holding time at temperature of $500^{\circ}C$ was carried out to the alloy of Cu-7Al-2.5Si as centrifugal casting, and the properties of both hardness and corrosion resistance with and without heat treatment were investigated with observation of the microstructure and with electrochemical methods, such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram, and a.c. impedance. in natural seawater solution. The ${\alpha}$, ${\beta}^{\prime}$ and ${\gamma}_2$ phases were observed in the material in spite of no heat treatment due to quenching effect of a spin mold. However, their phases, that is, ${\beta}^{\prime}$ and ${\gamma}_2$ phases decreased gradually with increasing the holding time at a constant temperature of $500^{\circ}C$. The hardness more or less decreased with heat treatment, however its corrosion resistance was improved with the heat treatment. Furthermore, the longer holding time, the better corrosion resistance. In addition, when the holding time was 48hrs, its corrosion current density showed the lowest value. The pattern of corroded surface was nearly similar to that of the pitting corrosion, and this morphology was greatly observed in the case of no heat treatment. It is considered that ${\gamma}_2$ phase at the grain boundary was corroded preferentially as an anode. However, the pattern of general corrosion exhibited increasingly due to decreasing the ${\gamma}_2$ phase with heat treatment. Consequently, it is suggested that the corrosion resistance of Cu-7Al-2.5Si alloy can be improved with the heat treatment as a holding time for 48 hrs at $500^{\circ}C$.

유변성(油變性) 알키드 수지(樹脂)와 규사(硅砂)를 사용(使用)한 밀입도(密粒度) 투수(透水)콘크리트의 강도(强度) 및 내구특성(耐久特性) (Durability and Strength of Dense Grate Permeable Concrete Using Silica sand and Flexible Alkyd Resin)

  • 김인중;홍창우
    • 자원리싸이클링
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    • 제19권6호
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    • pp.36-42
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    • 2010
  • 건설 분야의 자원재활용 연구는 폐콘크리트의 순환골재화, 아스팔트의 재활용 등에 광범위하게 진행되어온 반면에, 폐식용유를 원료로 한 도로용 포장공법에 관한 연구는 전무한 설정이다. 한국에서는 년간 20만톤의 폐식용유가 배출되며 이중 약 10만톤이 회수 가능한 것으로 추산된다. 폐식용유를 재활용한다면, 폐기비용을 절감할 수 있음은 물론, 하천의 수질오염도 방지할 수 있을 것으로 기대된다. 따라서 본 연구에서는 폐식용유를 회수하여 알키드 수지를 만들기 위해 에스테르반응을 시켜 제조된 유변성 알키드 수지에 규사를 혼입한 밀입도 투수콘크리트가 비차도용 도로 포장에 적용가능한지에 대한 역학적 특성(강도, 내수성, 화학저항성, 마모저항성, 동결융해저항성, 투수계수)을 평가하였다 실험결과 휨강도는 도로설계기준 4.5MPa에 1.6배의 결과를 보였으며, 내수성 및 화학저항성, 동결융해저항성은 재령 초기에 강도저하현상이 나타났으나, 재령이 증가함에 따라 큰 변화는 보이지 않았다. 그리고 양생온도는 수지의 유리전이온도 특성에 의해 고온에 비해 저온에서 강도증진현상을 보이는 것으로 나타났다. 따라서 도로포장용으로 적용시에는 작업성, 강도 및 내구성 측면을 고려해서 유변성 알키드 수지의 혼입률이 규사 중량대비 10~12%가 적정한 것으로 나타났다

대두유 에스테르계 절연유의 합성과 분석 (Synthesis and Characterization of Soybean-based Ester Insulation Oils)

  • 한동희;조한구;한세원;오대희
    • 한국전기전자재료학회논문지
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    • 제19권1호
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    • pp.40-45
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    • 2006
  • Electrical insulation is one of the most important parts in a high voltage apparatus. Traditionally mineral oils and synthetic esters have been widely used as dielectric coolants for power transformers. Recently, researchers are interested in the environmentally friendly vegetable oil from the environmental viewpoint. This paper reports on the synthesis and characterization of soybean based ester oils. Two different types of soybean based transformer oils, named as methyl ester and isopropyl ester were synthesized. The synthesis of these esters was achieved by transesterification reactions between soybean oil and alcohol in the presence of catalyst. The GC and NMR spectroscopic analysis of the esters have been performed. It was observed that isopropyl ester has better thermal resistance than methyl ester by TGA. Also, two esters have a good breakdown voltage and electrical resistance.

마이크로버블이 유화처리 정제유지류(ERCO)혼입 고로슬래그 다량 치환 콘크리트의 특성에 미치는 영향 (Effect of Micro Bubble on the High-Voiume Slag Concrete Mixed with Emulsified Refined Cooking Oil)

  • 김민영;박용준;백두환;백병훈;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 춘계 학술논문 발표대회
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    • pp.44-45
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    • 2015
  • Although the carbonation problem of high-volume slag concrete has been solved by the mixed use of emulsified refine cooling oil as the pilot study, there was an instance of securing air quantity and frost resistance followed by the use of Expancel due to the problem of having vulnerability in frost resistance in result as the air quantity has not been secured. But due to the problem of Expancel not being economical, air quantity and frost resistance of high-volume slag concrete mixed with ERCO are attempted to be secured using micro bubble that can remain in the water for a long time as a relatively economical and very microscopic bubble.

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Evaluation of the Quality of Canned Seafood with Added Spice-oil Extract

  • Yoon, Ho Dong;Shulgin, Yu.P.;Lazhentseva, L. Yu;Shulgina, L.V.;Xie, Chengliang;Mok, Jong Soo;Kim, Jeong Gyun
    • Fisheries and Aquatic Sciences
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    • 제18권1호
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    • pp.7-11
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    • 2015
  • The influence of spice (cinnamon, allspice, black pepper)-oil extract on canned seafood quality was studied. During the processing of canned seafood, the substitution of spice-oil extract for vegetable oil (refined sunflower, corn, soybean and olive oil) resulted in a decrease in the heat resistance of spore microorganisms, making it possible to reduce the duration of sterilization for canned food to 5-10 min at $115^{\circ}C$. This reduction in the sterilization duration of canned seafood with spice-oil extract inhibited residual microflora in the product, thus reducing the deleterious effect of heating on the main food compounds while preserving protein digestibility.

배추 무름병에 대한 저항성 품종 검정 (Screening of Disease Resistance of Chinese Cabbage Cultivars and Lines to Bacterial Soft Rot)

  • 정은경;장현철;최보라;이은주;용영록;김병섭
    • 식물병연구
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    • 제9권1호
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    • pp.39-41
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    • 2003
  • Erwinia carotovora subsp. carotovora에 의한 배추 무름병은 배추에서 가장 큰 문제가 되고 있는 병중 하나이다. 본 연구는 배추 품종별 무름병 저항성을 조기에 검정하고자 실시하였다. 선발된 균주를 이용하여 세균현탁액과 mineral oil을 4:1로 혼합하여 배추의 중앙 기부에 10m1 관주 접종하는 mineral oil 접종법으로 접종하였다. 국내의 3개 종묘회사와 대학으로부터 분양 받은 43개의 배추품종 및 계통의 저항성 정도를 조사하였다. 그 결과 C3-26, C3-28, C3-29, C29-51-51-52는 저항성, 강타배추, 금촌얼갈이, 미니배추, 금빛, DB50, 지부, 평층, 산촌배추는 감수성인 것으로 나타났으며, 나머지는 중간정도의 저항성을 나타냈다.

펄프몰드용 새로운 고기능 코팅제 제조기술개발(제4보) - 고기능 생분해성 코팅제 제조 - (Development of High Functional Coating Agents for Pulp Mold (IV) - Manufacture of higher functional and biodegradable coating agents -)

  • 강진하;임현아;박성철
    • 펄프종이기술
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    • 제38권1호통권113호
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    • pp.45-53
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    • 2006
  • This study was carried out to produce high functional and biodegradable coating agents for pulp mold by evaluating various kinds of biodegradable polymers. Five kinds of biodegradable polymers were used. In addition, the mixture of the carboxymethylated starch and biodegradable polymers(${\kappa}$-carrageenan, chitosan) were used for mixed coating agents. Physical properties of coated paperboards were evaluated. Conclusions obtained were as follows. 4% ${\kappa}$-carrageenan and 5% chitosan showed higher water and oil resistance. 10% sodium alginate, 4% corn zein and 15% polycaprolactone showed high water resistance while no improvement was found on oil resistance. The optimum mixture ratios for the mixed coating agents were 90:10(carboxymethylated starch : ${\kappa}$-carrageenan) and 50:50(carboxymethylated starch : chitosan). Since these mixed coating agents have excellent biodegradability with higher water and oil resistance, these can be used for the environmental-friendly coating agents.

Study on the Oil Resistance, Morphological and Dynamic Mechanical Properties, Flame Retardance of Ethylene Vinyl Acetate Copolymer and Ethylene Propylene Rubber Compounds

  • Sung, Il Kyung;Lee, Won Ki;Park, Chan Young
    • Elastomers and Composites
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    • 제52권1호
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    • pp.27-34
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    • 2017
  • In this experiment, blends of ethylene vinyl acetate rubber (EVM) with a vinyl acetate (VA) content greater than 40 wt% and ethylene propylene rubber (EPM) were prepared by mechanical mixing; a number of parameters of the blends, including oil resistance, morphological and dynamic mechanical properties and flame retardancy, were subsequently measured. In the $100^{\circ}C$ oil resistance test, both the ammonium polyphosphate/dipentaerythritol/expandable graphite (APP/DPER/EG) and aluminum hydroxide (ATH) flame retardant systems showed an increase in volume change with increasing EPM content. For the ATH system, the dispersion shape was coarse and aggregation was observed. The results of a dynamic mechanical test showed slightly higher E' and E'' for the APP/DPER/EG flame retardant system when compared to the single ATH system. For both the APP/DPER/EG and ATH systems, the limited oxygen index (LOI) tests performed at increasing content of EPM showed a LOI value higher than 30, indicating excellent flame resistance.

Effects of Silicone Mixed Fluorochemical Finishes on Fabric Performance Characteristics of a Microfiber Polyester/Cotton Blend Fabric

  • Ahn, Young-Moo;Li, Bin;Kim, Charles J.
    • 한국의류산업학회지
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    • 제3권5호
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    • pp.486-491
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    • 2001
  • The purpose of this study was to examine the effects of chemical finishes on performance characteristics of microfiber blend fabrics. A 60% polyester microfiber/40% cotton blend woven fabric was finished by ten chemicals: three silicone softeners, one fluorochemical, and their mixtures. Performance characteristics examined were abrasion resistance, and oil/water repellency. Chemical finishes containing dimethylpolysiloxane silicone performed better in fabric abrasion resistance than other chemicals. The correlation between abrasion wear and instrumental measures of fabric hand indicated that the breaking strength loss by abrasion related negatively to the coefficient of friction. This implied that the finished fabrics with lower surface frictional coefficient (slipperier) had higher breaking strength loss by abrasion. The microfiber structure of polyester did not appear to help in oil/water repellency due to the larger surface areas of the microfibers. The fluorochemical finished fabric had the most significant improvement on oil/water repellency. The silicone-only finishes, however, did not improve oil/water repellency. When mixed with the fluorochemical, silicone finishes showed improved oil/water repellency.

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Combined Effects of the Essential Oil from Pelargonium graveolens with Antibiotics against Streptococcus pneumoniae

  • Choi, Sung-Hee;Lim, Sook;Shin, Seung-Won
    • Natural Product Sciences
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    • 제13권4호
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    • pp.342-346
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    • 2007
  • The antimicrobial activity of the essential oil from Pelargonium graveolens and its effects when it was combined with current antibiotics against antibiotic-resistant strains of Streptococcus pneumoniae were evaluated. The minimal inhibitory concentrations (MICs) of the essential oil fraction and the main components of this plant were determined for two antibiotic-susceptible and two antibiotic-resistant strains of S. pneumoniae using broth microdilution tests. The combined effects of the oil with erythromycin, norfloxacin, or oxacillin were evaluated using a checkerboard microtitre assay. The combination of the oil fraction of P. graveolens, or its main component, together with the antibiotics tested significantly lowered the MICs of the antibiotics against all of the tested strains with fraction inhibiting concentration indices (FICs) ranging from 0.16 to 1.50. In particular, the activity of norfloxacin against all of the tested strains of S. pneumoniae was enhanced significantly by combination with citronellol. In conclusion, the combination of P. graveolens oil with antibiotics could be used to reduce the effective dose of antibiotic and to modulate the resistance of S. pneumoniae strains.