• Title/Summary/Keyword: oil emulsions

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Emulsification of the Mixture of Catalytic Pyrolysis Oil Obtained under Methane and Nitrogen Environment in Diesel Using Span 80 and Atlox 4916 as Surfactants

  • Farooq, Abid;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.357-360
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    • 2021
  • Emulsions were prepared using a mixture of bio-oil obtained from the pyrolysis of sawdust in an N2 environment and Quercus mongolica in a CH4 environment for both non-catalytic and catalytic cases. Both prepared emulsions were examined by measuring the physical stability and Fourier transform infrared spectroscopy. The emulsion with HLB 5.8 (Span 80 and Atlox 4916) for the ratio of bio-oil (B-oil and C-oil): surfactant: diesel = 10% : 3% : 87% showed stability for 15 days. Combining oils produced in N2 and CH4 environments could be a potential solution for generating high-quality emulsions with a high heating value.

Effect of Glutamic Acid and Monosodium Glutamate on Oxidative Stability of Riboflavin Photosensitized Oil-in-Water Emulsion

  • Ji-Yun Bae;Mi-Ja Kim
    • The Korean Journal of Food And Nutrition
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    • v.37 no.1
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    • pp.48-56
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    • 2024
  • Effects of glutamic acid (Glu) and monosodium glutamate (MSG) on oxidative stability of oil-in-water (O/W) emulsions with different emulsifier charges during riboflavin (RF) photosensitization were evaluated by analyzing headspace oxygen content and conjugated dienes. Cetyltrimethylammonium bromide (CTAB), Tween 20, and sodium dodecyl sulfate (SDS) were used as cationic, neutral, and anionic emulsifiers, respectively. Glu acted as an antioxidant in CTAB- and Tween-20-stabilized O/W emulsions during RF sensitization, whereas Glu acted as prooxidants in SDS-stabilized O/W emulsions in the dark. However, adding MSG did not have a constant impact on the degree of oxidation in O/W emulsions irrespective of the emulsifier charge. In RF-photosensitized O/W emulsions, the emulsifier charge had a greater influence on antioxidant properties of Glu than on those of MSG.

Emulsion Viscosity with Oil Polarity and Interpretation by Organic Conceptual Diagram (오일 극성도에 따른 에멀젼의 점도와 유기개념도에 의한 해석)

  • Kim, Jung-Il;Kim, Hyun-Dong
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.623-627
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    • 2014
  • Emulsions are a class of disperse systems consisting of two immiscible liquids. Emulsions are affected by the size of oil drop, the type of continuous and disperse phase, the ratio of continuous and disperse phase, the type of emulsifies and emulsification devices. This study is to observe the viscosity of emulsions with oil polarities and interpret the results by organic conceptual diagram. The emulsions were made with hydrocarbon, ester and silicone oils and then the viscosity of emulsions was measured. As the oil polarity was increased, the viscosity of emulsion was decreased by reducing the amount of emulsifies and emulsion stabilizers arranged at interface. Organic conceptual diagram was used to compare the polarities among oils numerically. The interpretation of organic conceptual diagram and the results of experimental measurement were corresponded except emulsion made with silicone oil.

Properties of Oil-in-Water Nano-emulsions Prepared from Hydrogenated Lecithin with High Pressure Homogenizer

  • Cho, Wan-Goo;Bae, Duck-Whan
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.1-5
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    • 2011
  • In this study, We investigated the properites of nano-emulsions containing hydrogenated lecithin prepared by high pressure homogenizer. The size of droplet of emulsions prepared by homogenizer at various rpm (rotation per minute) was not measured due to the unstability of emulsions, however, the size of droplet of nano-emulsions prepared by high pressure homogenizer was around 300 nm and the appearance of emulsions was bluish. The stability of emulsions with various lecithin concentration was tested against time. POV (Peroxide value) of emulsions were plotted against time. POVs of emulsions prepared with an egg lecithin and a soy lecithin were increased with time, however, POV of emulsion with Lecinol S-$10^{(R)}$ was kept constant within 60 hours and at $60^{\circ}C$. In consumer test, the nano-emulsion showed higher affinity regardless of skin type. Both of irritation scores of emulsions were similar.

Study of complete transparent nano-emulsions which contain oils

  • Kwak, Jong-Im;Kim, Ju-Duck;J, i-Hong-Geun
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.258-267
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    • 2003
  • Recently inside nano liposome particles or nano-emulsions which contain tough-melting physiology activity materials or the coefficient of low organism utilization promote the coefficient of organism utilization, so this part has been studied a lot because they can absorb selectly cosmetics, specially physiology activity materials, into the skin. Also, in particle size, cells interstitial lipid interval are 30~50nm, so nano-emulsions that the size is similar to 30~50 nm are made to study for absorbing quickly into the skin. And transparent skin which contains oils in common skin lotion dosage form has become the center of public interest. The used nano-emulsions in this study were unsaturated lecithin/co-surfactant! ethanol/ oil / water. And polysorbate 20/ polysorbate 80/ Dicetyl phosphate/hydrogenated .caster oil/ isoceteth-20/SLS were used in co-surfactant. The used oils were cyclomethicone and caprylic/capric triglyceride. The manufacturing process was that microfluidizer was fixed in 1000bar and transit times were changed from 1 to 10 times. From transparency and particle size, the transparency sequence was SLS> polysorbate 20= polysorbate 80> isoceteth-20> dicetyl phosphate >hydrogenated caster oil and the particle size was small. Specially cyclomethicone nano-emulsions, when we made unsaturated lecithin /SLS /ethanol/water/cyclomethicone, cyclomethicone 5% was good for transparency. And 20% of this was used for making transparent skin toner in common skin dosage form.

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Preparation of Emulsion from Biodegradable Polymer (I) - Preparation of PLA and PBS Emulsions - (생분해성 고분자를 이용한 발수 에멀션의 제조 (I) - PLA 및 PBS 에멀션의 제조 -)

  • Lee, Min-Hyung;Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.6
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    • pp.28-35
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    • 2012
  • Water-in-oil emulsion (W/O) and oil-in-water emulsion (O/W) types biodegradable polymer emulsions prepared to PLA and PBS. The optimal mixing ratio of polymer : solvent : OA : TEA : water was found be 10 : 40 : 4 : 6 : 30(g) when preparing emulsions. Biodegradability was most retained after preparation of polymer emulsions. Particle size of PLA and PBS emulsions were 2-3 ${\mu}m$ and 3-4 ${\mu}m$, respectively. Molecular weight of PLA and PBS emulsions were 108,000 and 92,000, respectively. And molecular weight of PLA and PBS emulsions became slightly lower than those of pellets.

A Study on the Lubricational Characteristics of the Oil-in-Water Emulsions (O/W Emulsion의 潤滑特性에 관한 연구)

  • Rhee, Bong-Goo;Ji, Chang-Heon;So, Byung-Un;Yu, Ki-Uk
    • Tribology and Lubricants
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    • v.5 no.1
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    • pp.51-56
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    • 1989
  • The Lubricational characteristics of O/W Emulsions of beef tallow and mineral oil based lubricants are studied in a roller on disk apparatus. It is revealed that the coefficients of friction with both emulsion lubricants exhibit essentially similar behavior; that is, they rapidly decrease to 0.1% concentration and after they constants with increasing oil concentration, and that, with oil in water emulsions of a concentrations as low as 5wt% practically forms a elastohydrodynamic film. One hand, surface temperature effect on lubricants has virtually no severe, and that, the minimum EHL film chickness estimated that it begins to increase at a concentration of several percent; the effect of particle diameter becomes maked there after.

Stability of the Oil-in-water Type Triacylglycerol Emulsions

  • Hesson Chung;Kim, Tase-Woo;Kwon, Ich-Chan;Jeong, Seo-Young
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.4
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    • pp.284-288
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    • 2001
  • Lipid emulsions with saturated triacylglycerols (TAGs) with 4 to 10 carbons in each acyl chain were prepared to study how the oil component alters the stability of the lipid emul-sions when phosphatidylcholines were used as emulsifiers. The average droplet size of the emul-sions became smaller as the chain length of the TAG increased. For a given oil emulsion with smaller droplets was formed with an emulsifier having higher HLB value. The influence of HLB values on the droplet size was biggest for the tributyrin (C4) emulsion. For the tricaprylin(C8) emulsions, droplet size was identical at given emulsifier concentrations regardless of HLB values. The HLB value and the concentration of the emulsifiers also affect the droplet size of the emul-sions. The emulsions with smaller average droplet size were more stable than with bigger size for 20 days. The oil and water (o/w) interfacial tension in inversely proportional to the initial droplet size of the emulsion.

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Antioxidative Effects of Mushroom Flammulina velutipes Extract on Polyunsaturated Oils in Oil-in-water Emulsion

  • Jang, Mi-Soon;Park, Hee-Yeon;Ushio, Hideki;Ohshima, Toshiaki
    • Food Science and Biotechnology
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    • v.18 no.3
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    • pp.604-609
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    • 2009
  • The antioxidative activities of the water solution of crude extract from edible mushroom enokitake Flammulina velutipes were compared with those of ascorbic acid and ascorbic acid 6-palmitate in oil-in-water (O/W) emulsions of cod liver oil. Oxidation of the emulsions was carried out at 40 and $50^{\circ}C$ in the dark. The antioxidant activities were measured by in vitro assay against oxygen uptake, 2-thiobarbituric acid value, hydroperoxide formation of the oils. Also, residual docosahexaenoic acid content was measured as indices of lipid oxidation. The cod liver oil in O/W emulsions with added enokitake crude extract (ECE) was significantly more stable against lipid oxidation than the control emulsions without the extract in terms of any oxidation indices used. Moreover, ECE provided remarkable antioxidative properties to eicosapentaenoic acid ethyl ester in emulsion system. These observations demonstrate that F. velutipes can be used as a natural antioxidant, which effectively prevents oxidation of polyunsaturated oils in emulsion system.

Stability of W/O and O/W Type Emulsions by Various Solid Particles (다양한 분체를 이용한 W/O와 O/W 형 에멀젼의 안정화)

  • Lee, Sang-Gil;Kim, Young-Ho;Pyo, Hyeong-Bae;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.353-360
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    • 2010
  • This study was carried out to investigate the possibility of solid particles as a stabilizing agent instead of surfactant for preparing emulsions in the cosmetics. The type of emulsions stabilized by solid particles was dependent on wettability of the particles for water and oil. The optimal conditions of emulsions stabilized by solid particles were determined with ratio of water and oil phase, polarity of oils and amount of stabilizers. In the foundation appling the optimal condition of emulsions stabilized by solid particles without surfactant, the stable emulsion type foundation was successfully prepared. As a result, this work indicates that emulsions stabilized by solid particles can be applied to make-up cosmetics.