• Natural Product Sciences
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• v.22 no.1
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• pp.30-34
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• 2016

A simple and rapid method based on proton nuclear magnetic resonance spectroscopy was developed for determination of trans-anethole content in fennel essential oil. Spectra of pure trans-anethole, of the pure essential oil of fennel, and of the pure oil of fennel with thymol internal standard were recorded. The signal of $H-1^/$ was used for quantification of trans-anethole. This proton signal is well separated in the proton magnetic resonance spectrum of the compound. No reference compound is needed and cheap internal standard was used. The results obtained from spectroscopic analysis were compared with those obtained by gas chromatography. Additionally, the developed method was used for determination of the type of vegetable oil used as a carrier in commercial products, which cannot be quantified as such by gas chromatography. This study demonstrates the application of proton nuclear magnetic resonance spectroscopy as a quality control method for estimation of essential oil components.

• Tribology and Lubricants
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• v.22 no.3
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• pp.155-163
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• 2006

Ring, groove and cylinder bore wear may not be a problem in most current automotive engines. However, a small change in ring face, groove geometry and cylinder bore diameter can significantly affect the lubrication characteristics and ring axial motion. This in turn can cause to change inter-ring pressure, blowby and oil consumption in an engine. Therefore, by predicting the wear of piston ring face, ring groove and cylinder bore altogether, the changed ring end gap and the changed volume of gas reservoir can be calculated. Then the excessive oil consumption can be predicted. Being based on the calculation of gas flow amount by the theory of piston ring dynamics and gas flow, and the calculation of oil film thickness and friction force by the analysis of piston ring lubrication, the calculation theory of oil amount through top ring gap into combustion chamber will be set. This is estimated as engine oil consumption. Furthermore, the wear theories of ring, groove and cylinder bore are included. Then the each amount of wear is to be obtained. The changed oil consumption caused by the new end gap and the new volume of oil reservoir around second land, can be calculated at some engine running interval. Meanwhile, the wear amount and oil consumption occurred during engine durability cycle are compared with the calculated values. Next, the calculated amount of oil consumption and wear are compared with the guideline of each part's wear and oil consumption. So, the timing of part repair and engine life cycle can be predicted in advance without performing engine durability test. The wear data of rings, grooves and cylinder bore are obtained from three engines before and after engine durability test. The calculated wear data of each part are turn out to be around the band of averaged test values or a little below.

• Structural Engineering and Mechanics
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• v.84 no.6
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• pp.733-741
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• 2022

The amount of natural gas that is used on a worldwide scale is continuously going up. Natural gas and acidic components, such as hydrogen sulfide and carbon dioxide, cause significant corrosion damage to transmission lines and equipment in various quantities. One of the fundamental processes in natural gas processing is the separation of acid gases, among which the safety and environmental needs due to the high toxicity of hydrogen sulfide and also to prevent wear and corrosion of pipelines and gas transmission and distribution equipment, the necessity of sulfide separation Hydrogen is more essential than carbon dioxide and other compounds. Given this problem's significance, this endeavor aims to extend the lifespan of the transmission lines' pipes for gas and oil. Zinc oxide nanoparticles made from the environmentally friendly source of Allium scabriscapum have been employed to accomplish this crucial purpose. This is a simple, safe and cheap synthesis method compared to other methods, especially chemical methods. The formation of zinc oxide nanoparticles was shown by forming an absorption peak at a wavelength of about 355 nm using a spectrophotometric device and an X-ray diffraction pattern. The size and morphology of synthesized nanoparticles were determined by scanning and transmission electron microscope, and the range of size changes of nanoparticles was determined by dynamic light scattering device.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.222-222
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• 2011

Plastic product is increasing by the growth of its demand and most of refused plastics are incinerated or reclaimed. However, the refused plastic is not easily decomposed and has the environmental problem with its various toxic gas in case of incineration. Therefore, many countries such as USA, Japan, Germany and other developed industrial countries as well as Korea are interested in studying the recyclable resource of refused plastic. The macromolecular waste pyrolysis has the advantage of collecting of raw materials in high price and can at least get fuel gas or oil with high heat capacity. It also discharges low waste gas and low toxic gas including SOx, NOx and HCl heavy metals. However, pyrolyzed oil includes enough excess unsaturated hydrocarbons to form tar, which can cause the nozzle of engines to plug when pyrolyzed oil is used as fuel. Activated carbon was proven to have prominent adsorption capability among the other adsorbents that were mainly composed of carbon. This study examined the possibility of application in activated charcoal of its solid formation by analysing the feature of pyrolysis which is one of the chemical recycling methods and getting chemical analysis of the product and activated energy. Analyze the element of the oil produced by pyrolysis using GC-MS. The experiment of tar adsorption using fly-ash showed that fly-ash improved the optical intensity of pyrolyzed oil and decreased oxygen compounds in the pyrolyzed oil.

• Journal of the Korean Institute of Gas
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• v.19 no.1
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• pp.12-17
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• 2015

The core of the CNG fueling station is the compressor and most of CNG compressors in Korea require lubrication. Lubrication oil of CNG compressor that can be transferred into the pressure regulators and the engines of fueling system can cause a negative effect on NGV(Nature Gas Vehicle) performance during refueling due to oil Carry-over. In order to avoid the problem, it is necessary to enhance the quality of the compressed natural gas by measuring quantitatively the amount of the transferred oil. In this research, a sampling device and sampling tube were developed, which can be used with a gravimetric method of detection to measure CNG oil Carry-over. In addition, CNG samples were taken at 6 pre-selected CNG fueling stations and analysed for their trace oil Carry-over. The measured total oil Carry-over ranged from 2.569 to 6.509 ppm. This test measurements were compared with those of previous studies to verify the results.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.7
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• pp.885-893
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• 2012

DME (Dimethyl ether) is regarded as one of the candidates of alternative fuels for diesel engine, because of its higher cetane number suitable for a compression ignition engine. Also, DME is a simple chemical structure, colorless gas that is easily liquefied and transported. On the other hand, Bunker oil (JIS C heavy oil) has long been used as a basic fuel in marine diesel engines and is the lowest grade fuel oil. In this study, the combustion and emission characteristics were measured experimentally in the direct injection type diesel engine operated with DME and Bunker oil mixed fuel. From our experimental results, it is induced that DME and Bunker oil blended fuel would be an effective fuel which can reduces the concentration of harmful matter in exhaust gases.

• Journal of the Korean Institute of Gas
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• v.22 no.6
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• pp.90-103
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• 2018

This paper presents the development of two ANN models which can predict an optimum production rate by controlling choke size in oil well, and gas injection rate in gas-lift well. The input data was solution gas-oil ratio, water cut, reservoir pressure, and choke size or gas injection rate. The output data was wellhead pressure and production rate. Firstly, a range of each parameters was decided by conducting sensitive analysis of input data for onshore oil well. In addition, 1,715 sets training data for choke size decision model and 1,225 sets for gas injection rate decision model were generated by nodal analysis. From the results of comparing between the nodal analysis and the ANN on the same reservoir system showed that the correlation factors were very high(>0.99). Mean absolute error of wellhead pressure and oil production rate was 0.55%, 1.05% with the choke size model, respectively. And the gas injection rate model showed the errors of 1.23%, 2.67%. It was found that the developed models had been highly accurate.

• Journal of the Korean Society for Precision Engineering
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• v.26 no.3
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• pp.73-80
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• 2009

In accordance with the trend for high-speed multi-axes, and the increasing technical sophistication of machine tools, thermal deformation has become an important factor in the accuracy of machine tools. It was analyzed that thermal deformation error accounts for about 70% of all errors made with machine tools. For precise temperature control, both cooling and heating should be implemented. A hot gas bypass type cooling cycle method has a simplified structure and temperature control accuracy to with in ${\pm}0.1^{\circ}C$. In this study, the performances of oil cooler system, including temperature controllability according to hot gas floe and preset temperature sustainability according to temperature load, were tested. It is expected that this study will contribute to the development and performances of oil cooler system, which could minimize thermal errors and improve the quality of precision machine tools.

• Mass Spectrometry Letters
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• v.14 no.4
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• pp.160-165
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• 2023

Citronella oil, an essential oil extracted through steam distillation from the leaves and stems of Cymbopogon, is a natural complex substance (NCS) regulated by the Korean government for its use in insect repellents. The component ratios of NCSs like citronella oil vary due to differences in manufacturing processes and origins, presenting a challenge in identifying and quantifying these substances in consumer chemical products. This study analysed ten commercially available products of the most commonly used types of citronella oil, specifically Java and Ceylon types, using gas chromatography (GC)-mass spectrometry (MS) and GC with flame ionization detection (FID). Through chromatographic data, we aimed to determine the components that can qualitatively identify citronella oil and the indicator ingredients that can be used for content analysis.

• Geomechanics and Engineering
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• v.9 no.5
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• pp.645-667
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• 2015

Single treatment and staged treatments in vertical wells are widely applied in sandstone and mudstone thin interbedded (SMTI) reservoir to stimulate the reservoir. The keys and difficulties of stimulating this category of formations are to avoid hydraulic fracture propagating through the interface between shale and sand as well as control the fracture height. In this paper, the cohesive zone method was utilized to build the 3-dimensional fracture dynamic propagation model in shale and sand interbedded formation based on the cohesive damage element. Staged treatments and single treatment were simulated by single fracture propagation model and double fractures propagation model respectively. Study on the changes of fracture vicinity stress field during propagation is to compare and analyze the parameters which influence the interfacial induced stresses between two different fracturing methods. As a result, we can prejudge how difficult it is that the fracture propagates along its height direction. The induced stress increases as the pumping rate increasing and it changes as a parabolic function of the fluid viscosity. The optimized pump rate is $4.8m^3/min$ and fluid viscosity is $0.1Pa{\cdot}s$ to avoid the over extending of hydraulic fracture in height direction. The simulation outcomes were applied in the field to optimize the treatment parameters and the staged treatments was suggested to get a better production than single treatment.