• 분석과학
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• 제5권1호
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• pp.1-5
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• 1992

Amberlite XAD 고분자수지 및 고분자수지 대체흡착제인 rice bran, rice straw 그리고 sawdust에 대한 petroleum oil의 흡착량을 최저 흡착조건에서 뱃치법으로 측정하여 조사하였다. Rice bran과 rice straw에 대한 petroleum oil의 흡착량은 XAD계열수지의 흡착량의 약 50% 정도로 흡착성이 우수하였다. 또한 이들 대체흡착제의 흡착능을 증대시키기 위한 탄화시간은 $200^{\circ}C$, 30분이 최적 조건이었다. Sawdust의 경우에는 30% MeOH 매질에서는 흡착성이 매우 약한 반면 0.5M NaCl 매질에서는 XAD수지 흡착능이 약 1/2에 도달하였다. Rice bran과 rice straw는 외관상의 구조차이와는 관계없이 비슷한 흡착능력을 보였다. 따라서 rice bran과 rice straw들은 XAD계열 수지에 대한 대체흡착제로 충분한 흡착능력을 가지고 있는 것으로 보인다.

• Carbon letters
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• 제14권3호
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• pp.193-195
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• 2013

Expanded graphite (EG) was prepared using a drying process for application as an oil-adsorbent: the morphology, expansion volume, and oil absorption capacity of the EG were investigated. The expanded volume of the EG increased with an increasing reaction time and heat treatment temperature. The oil adsorption capacity of the EG was 45 g of n-dodecane per 1 g of EG. It is noted that the drying process of EG is a useful technique for a new oil-adsorbent.

• 한국환경과학회지
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• 제21권5호
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• pp.573-578
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• 2012

In this study, adsorption of polychlorinated biphenyls(PCBs) in transformer oil on powder activated carbon (PAC) and synthetic zeolite was evaluated. Adsorption characteristics of PCBs on the PAC and zeolite has been investigated in a batch system with respect to adsorbents amount and contact time. BET results showed 908 m2/g for PAC and 483 m2/g for zeolite. The adsorption capacity of PCBs increased with an increasing input amount of absorbent. The adsorption experimental results showed that PAC removed 90% of input PCBs in transformer oil while zeolite removed only 64%. Adsorption of PCBs to PAC and zeolite fit the Freundlich model well. The Freundlich parameter, Kf, for PAC and zeolite was 193.1 and 43.0 respectively, indicating that PAC is effect adsorbent for PCBs adsorption in transformer oil.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.416-424
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• 2018

Oil spill and oily wastewater have now become a serious threat to the freshwater and marine environments. Porous materials with super-hydrophobicity and super-oleophilicity are good candidates for the oil adsorption and oil/water separation. Here, flexible hybrid nanofibrous membrane (FHNM) containing $SiO_2$/polyvinylidene fluoride (PVDF) microspheres was prepared by simultaneous electrospinning and electrospraying. The obtained FHNM combined the flexibility of the nanofiber mat and super-hydrophobicity of the microspheres, which could not be achieved by either only electrospinning or only electrospraying. It was found that when the weight ratio between the $SiO_2$ and PVDF reached a critical value, the $SiO_2$ nanoparticles were present on the PVDF microsphere surface, significantly improving the surface roughness and hence the contact angle of the FHNM. Compared with the pure electrospun PVDF nanofiber mat, most of the FHNMs have a higher oil adsorption capacity. The FHNM could separate the oil with water quickly under the gravity and displayed a high efficiency and good reusability for the oil/water separation. More importantly, the FHNM could not only separate the oil with the pure water but also the corrosive solution including the salt, acid and alkali solution.

• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.777-782
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• 2013

In order to further reduce the sulfur content in liquid hydrocarbon fuels, a desulfurization process by adsorption for removing dimethyl sulfide (DMS) and propylmercaptan (PM) was investigated. Bentonite adsorbents modified by $CuCl_2$ for the desulfurization of model oil was investigated. The results indicated that the modified bentonite adsorbents were effective for adsorption of DMS and PM. The bentonite adsorbents were characterized by X-ray diffraction (XRD) and thermal analysis (TGA). The acidity was measured by FT-IR spectroscopy. Several factors that influence the desulfurization capability, including loading and calcination temperature, were studied. The maximum sulfur adsorption capacity was obtained at a Cu(II) loading of 15 wt %, and the optimum calcination temperature was $150^{\circ}C$. Spectral shifts of the ${\nu}$(C-S) and ${\nu}$(Cu-S) vibrations of the complex compound obtained by the reaction of $CuCl_2$ and DMS were measured with the Raman spectrum. On the basis of complex adsorption reaction and hybrid orbital theory, the adsorption on modified bentonite occurred via multilayer intermolecular forces and S-M (${\sigma}$) bonds.

• 대한화학회지
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• 제25권5호
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• pp.300-305
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• 1981

콩깻묵과 들깻묵을 각각 인산화 및 술폰화하여 이온교환체를 만들었다. 이렇게 만든 40-60 매쉬의 이온교환체를 사용하여 여러농도의 염산과 알코올 혼합용매에서 이온교환용량, 몇가지 금속 이온에 대한 흡착능 및 분포계수를 알아보았다. 깻묵 이온교환체의 이온교환용량은 4 meq/g 이상이었으며, 깻묵 이온교환체에 대한 금속이온은 일반적으로 pH가 증가함에 따라 증가하였다. 특히 술폰화된 콩깻묵 이온교환체에서는 Co(II)가 높은 흡착을 나타내었다. 또한 분포계수는 여러 금속에 있어서 알코올 용매분자의 탄소수가 증가하거나 히드록시기의 수가 증가함에 따라 감소한다. 이는 알킬기의 입체이성 현상이나, 리간드의 인력이 크게 작용했기 때문인 것으로 보인다. 만들어진 콩깻묵 이온교환체는 시판되는 이온교환체와 거의 비슷한 이온교환능을 가지고 있음을 알 수 있었다.

• Composites Research
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• 제36권3호
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• pp.217-223
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• 2023

본 연구에서는 폴리아크릴로니트릴계 탄소나노섬유 스펀지의 제조 및 오일 흡착 거동을 조사하였다. 제조된 탄소나노섬유 스펀지는 물과 기름의 혼합용액에서 우수한 선택적 오일 흡착 능력을 보였으며, 탄소나노섬유 스펀지의 재사용시 흡착 능력도 확인하였다. 또한, 흡착제 내부구조에 정렬된 채널을 형성함으로써, 모세관 현상에 의하여 빠른 오일 흡착 거동을 보이는 탄소나노섬유 스펀지를 제조할 수 있었다. 이후 사용 폐기된 탄소나노섬유 스펀지는 질소 분위기에서 800℃로 열처리하여, 4-아미노페놀의 전기화학적 검출을 위한 센서로의 가능성을 검토하였다.

• Journal of the Korean Wood Science and Technology
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• 제48권4호
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• pp.503-512
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• 2020

Using Na₂CO₃ versus NaCl as chemical activator, we compared the quality of activated carbon produced from oil palm fronds as raw material. These activators were selected for comparison because both are readily available and are environmentally friendly. In the manufacturing, we used Indonesian National Standard (SNI 06-3730-1995) parameters. For the quality comparison, we determined activated-carbon yield, moisture, ash, volatiles, and fixed-carbon contents; and adsorption capacity of iodine. The best characteristics, assessed by morphological surface analysis and Fourier transform infrared (FTIR) spectral analysis, were observed in the carbon activated by Na₂CO₃ at an activator concentration of 10% and carbonization temperature of 400 ℃. The results were as follows: activated-carbon yield, 84%; water content, 8.80%; ash content, 2.20%; volatiles content, 14.80%; fixed-carbon content, 68.60%; and adsorption capacity of iodine, 888.51 mg/g. Identification using the FTIR spectrophotometer showed the presence of the functional groups O-H, C=O, C=C, C-C, and C-H in the Na₂CO₃-activated carbon.

• 공업화학
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• 제24권3호
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• pp.231-238
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• 2013

본 연구에서 제조한 나노구형체 $TiO_2$는 자외선 차단 효과가 우수하면서도 노폐물 흡착을 하는 기능을 부여하기 위해 Sol-gel 방법으로 합성하였다. 다공성의 특성으로 높은 표면적에 의한 우수한 자외선 차단효과 및 흡착능력을 얻기 위해 pH를 조절하였다. 염기 처리한 $TiO_2$의 경우 가장 우수한 특성을 나타내었다. TGA로 글리세린을 흡착한 결과 1.16 mg의 높은 흡착 결과를 얻을 수 있었다. 또한 UV-A 영역에서 높은 반사율을 가지는 것을 확인하였다. 무기분체의 최적의 분산제를 찾기 위해 ester oil과 silicon oil를 사용하여 입도크기를 측정하였으며 180 nm정도의 입자로 약 6개월간 유지되었다. 이 결과를 통해, UV-A영역에서 우수한 능력을 가진 자외선 차단제로서 노폐물 흡착능력을 가진 $TiO_2$를 제조했으며 이로 인한 다양한 응용이 가능할 것으로 기대된다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.307-312
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• 2001

Adsorption capacities of toxic heavy metal ions using as-received carbon(AC), single and double surface-modified activated carbon(OAC and DSMC) in wide pH ranges are extensively evaluated. Physical and chemical properties of surface-modified activated carbons are evaluated through BET analysis, surface acidity and oxides measurements. Based oil tile adsorption isotherms of Pb, Cd and Cr ions by AC, OAC and DSMC, the adsorption amount on DSMC was obviously higher than that on the other carbons. Breakthrough behaviors of ternary metal ions in a column packed with three kinds of carbon were also characterized with respect to the variations of the influent pH and concentration. The adsorption capacity of DSMC in a fixed bed stood a favorable comparison with that of as-received carbon.