• Title/Summary/Keyword: oil additives

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Effect of Additives on Solubilization of Sulfur Compounds in the Crude Oil by Tergitol Series Nonionic Surfactants (Tergitol 계열 비이온 계면활성제 시스템에서 첨가제가 원유의 황화합물 가용화에 미치는 영향에 관한 연구)

  • Han, Ji-Won;Lim, JongChoo
    • Korean Chemical Engineering Research
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    • v.45 no.3
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    • pp.226-233
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    • 2007
  • In this study, the effects of additives such as ionic surfactant and cosurfactant were studied on the solubilization of sulfur compounds contained in the crude oil by Tergitol series nonionic surfactants. It was found that the addition of an ionic surfactant such as sodium oleate, potassium oleate, CTAB and DTAB did not enhance solubilization capacity of Tergitol series nonionic surfactant. On the other hand, the addition of a long-chain alcohol as a cosurfactant increased the solubilization of sulfur compounds in the crude oil. The effect of alcohol was found to become reduced with an increase in the amount of crude oil used mainly due to partitioning phenomena of an nonionic surfactant. The enhancement of solubilizing capacity of Tergitol series nonionic surfactant with addition of a cosurfactant was associated with a decrease in interfacial tension between crude oil and surfactant solution. The pH of Tergitol nonionic surfactant solution did not affect the solubilization of sulfur compounds. Finally, it was found that the growth of sulfur reducing microoganisms was not greatly affected by both addition of nonionic surfactant and cosurfactant.

Evaluation of Oxidation Stability for Diesel Engine Oil by Hot-Tube Oxidation Test (Hot-Tube Oxidation Test에 의한 디젤엔진오일의 산화안정성 평가)

  • 정근우;조원오;김영운;서인옥;임수진
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.175-180
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    • 1998
  • This paper describes evaluation of oxidation stability for diesel engine oils by Hot-tube oxidation tester at high temperature. Evaluation was rated by visual inspection of lacquer in capillary glass tube and TAN determination of used oil. Air, NO$_2$-air and SO$_2$-air mixed gases were used as oxidizing gas. One oil which has low oxidation stability is selected and reformulated by addition of some additives such as antioxidant, detergent and disperant to improve oxidation stability. As a results of reformulation, antioxidant and detergent was effective for improvement of high temperture oxidation stability on diesel engine oil.

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Preparation and Properties of Printing Rubber Roller : (I) Oil Resistance and Mechanical Properties of Butabiene Rubber/Nitrile Rubber Compounds (인쇄용 고무roller의 제조와 물성: (I) 부타디엔고무와 니트릴고무 혼련물의 내유성 및 기계적 성질)

  • 박찬영
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.2
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    • pp.83-101
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    • 2000
  • In this experiment butadiene rubber(BR)/acrylonitrile butadiene rubber(NBR) blends was prepared and then the applicability of BR/NBR blends as printing rubber roller was examined. With the aid of open 2-roll mill, BR, NBR and another chemical additives were compounded. Then rubber vulcanizates were manufactured by hot press and maximum torque, Mooney viscosity, mechanical properties and oil resistance of the test specimens were measured. With prolonged oil aged treating time, BR/NBR blends became soft and so the hardness of blends decreased. It could be explained by the swelling of rubber matrix with oil penetration in to rubber molecules. The undesirable low value of oil resistance of BR was significantly improved by blending BR with NBR.

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An Experimental Study on the Measurement of Water Content in an Lubricating Oil by Implementing a Dew-point Condensation Sensor (이슬점 응축 현상을 이용한 오일 내 수분함량 측정에 관한 실험적 연구)

  • Kong Hosung;Yoon Eui-Sung;Han Hung-Gu;Kim Hak Yeul
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.130-136
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    • 2004
  • Presence of water in the lubricating oils could be one of the first indicators of potentially expensive and possibly catastrophic failure of the machine as it may cause displace the oil films to prevent the lubrication function of the oil or chemically react with many oil additives resulting in the oil degradation. In order to detect water content quantitatively in lubricating oils many methods and sensors has been developed. Among these, capacitive sensors including sensitive layer, whose dielectric factor changes according to the water content absorbed in the layer, are proposed mainly in the market. But these sensors are not sensitive to a high water content. Besides, the absorbing layer soils in time. In this work, an evaporation of water moisture from oil into air volume above lubricant surface and condensation of water vapor at a cooling surface was used to measure water content quantitatively in an lubricating oil. Laboratory test results of a prototype sensor were presented. Test results showed that the proposed method could be avaliable to measure a low levels of oil moisture.

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Sensory and Instrumental Characteristics of Corn and Mung bean Starch Gels with Additives (첨가물질에 따른 옥수수와 녹두전분겔의 관능적 기계적 특성)

  • 이상금;신말식
    • Korean journal of food and cookery science
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    • v.12 no.2
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    • pp.193-199
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    • 1996
  • Effects of addition of various additives, sucrose fatty acid ester 1170 (SE), carboxymethyl cellulose (CMC) and soy bean oil (SO) on textural characteristics for untreated and defatted corn and mung bean starch gels stored at room temperature for 24 hrs and 72 hrs were studied. In sensory and instrumental characteristics of starch gels with additives (0.5% for starch basis), the acceptability was highly correlated with cohesiveness and bend property of starch gels stored 24 hrs and springiness, cohesiveness, color, smoothness, bend property, hardness and clarity of starch gels stored 72 hrs. Regardless of adding additives, textural characteristics of defatted corn starch gels showed somewhat higher values than that of com starch gels. The acceptability of starch gels with additives was somewhat lowered in all the cases, which showed highly correlated in cohesiveness for 24 hrs and springiness for 72 hrs. Instrumental characteristics were similar to those of sensory evaluation, which showed no significant difference with additives.

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Activities of Essential Oils from Perilla frutescens var. acuta against Antibiotic-Susceptible and -Resistant Vibrio and Salmonella Species

  • Lim, Hye-Rim;Shin, Seung-Won
    • Natural Product Sciences
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    • v.17 no.4
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    • pp.296-302
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    • 2011
  • We determined the inhibitory activity of the essential oil fraction obtained by steam distillation from the fresh and dried leaves of Perilla frutescens var. acuta against some pathogenic Salmonella and Vibrio spp. The activities of compounds isolated from the essential oils, apiol and myristicin, were also tested and the results were compared with those of the essential oil fraction. The Perilla essential oil fraction and its main components showed significant inhibition against antibiotic-susceptive and antibiotic-resistant strains of the tested Salmonella and Vibrio strains. Synergistic or additive effects were identified by combing the oils with ampicillin by checkerboard-titer tests. We conclude that essential oils from P. frutescens can be useful in the treatment of Salmonella and Vibrio infections and as safe additives to food materials for the prevention of contamination of food by these bacteria. This is especially important because of the rapid increase in antibiotic-resistant strains, which could cause severe symptoms in humans.

Wear and Friction Characteristics with $MoS_2$ Adding in Automotive Gear Oil (자동차 기어오일의 $MoS_2$ 첨가에 따른 마찰마모 특성)

  • Oh, Seong-Mo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.2
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    • pp.167-172
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    • 2007
  • In the case of gear oil which is used under severe running condition in automotive, the various additives is used fur increasing the ability of enduring against seizure. In this paper, the wear and friction characteristics observed using the Falex friction and wear test machine in adding the $MoS_2$ to auto gear oil. As the result of experimentation, the friction and wear characteristics is the most excellent in adding concentration range of the $MoS_2\;2.5{\sim}5wt.%$.

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A study on Biodegradability of Vegetable Oil based EP Grease (식물유계 EP그리스의 생분해도 평가에 관한 연구)

  • Nam Kyung-Im;Kim Young-wun;Chung Keunwo;Cho Wonoh;Jeon In-sik;Chung Yong-Mi
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2003.11a
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    • pp.139-148
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    • 2003
  • In this study, biodegradable base Li-greases were prepared by using Li-soap thickener and vegetable oils such as soybean oil, rapeseed oil, castor oil and synthetic ester. Also, EP-greases were formulated by blending base Li-greases, anti-wear additives, EP additives, anti-oxidants and corrosion inhibitor etc. And EP-greases were characterized by analysing physical properties such as worked penetration, dropping point, 4-ball wear, extreme pressure, thermal properties etc. Biodegradability of base Li-greases and EP-greases were evaluated by CEC-L-33-A-93 method using several inoculums of domestic sewage treatment plant. As the results, biodegradability of vegetable oils were shown at the range of 97.1 to $98.4\%$. And biodegradability of base Li-greases and EP-greases were $86.2\%\;\~\;89.3\%\;and\;83.4\%\;\~\;90.0\%$ which were lower value than those o( vegetable oils due to effect of Li-soap thickener, respectively. Therefore, the EP-greases prepared in this study were easily biodegraded by microorgnism.

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Experimental Study on the DPF Engine Oil Characteristics Depending on a Mileage of Diesel Automotive (디젤차량의 주행거리에 따른 DPF 윤활유의 특성분석에 관한 실험적 연구)

  • Kim, Chung-Kyun
    • Tribology and Lubricants
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    • v.25 no.5
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    • pp.318-323
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    • 2009
  • The oil characteristics and wear particles of Diesel engines with a DPF have been investigated as a function of a driving distance. The engine oil of SAE 5W30 with ACEA C3 is used for an oil film lubrication of the engine, which is equipped with Diesel particulate filter. Depending on the oil test results, the kinematic viscosity of used engine oils at 40 is degraded up to 5.1% compared with that of unused engine oils, SAE 5W30. And the kinematic viscosity of used engine oils at 100 is more degraded up to 8.1% compared with that of unused engine oils. The oil characteristic as a function of a mileage is not changed depending on the driving distance because of high quality of engine oils. But the aluminum and copper compounds, which are used as base materials of the engine bearing and a pin bush, are much worn and contaminated for the increased mileage of the car. The oil properties of used engine oils are relatively good except phosphorus and calcium additives, which are heavily engaged in the performance of the oils.

Study on Lubrication Characteristics of Vegetable Oil Based on Blending Condition (식물성 오일의 혼합조건에 따른 윤활 특성 연구)

  • Jung, Hee-Young;Kim, Hyun-Joon
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.342-349
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    • 2020
  • The rapidly increasing threats to the environmental has increased the demand for biodegradable lubricants. Vegetable oils, such as olive, coconut, and sunflower oils, are readily obtainable and are not harmful, unlike synthetic and mineral oils. The tribological characteristics of these oils should be adequately examined for industrial applications. In this study, the lubrication characteristics of olive oil is investigated using a pin-on-disk-type tribometer under 500 gf of normal force, and the examination results are compared and analyzed with those of commercial synthetic lubricants for friction and wear. In addition, stearic acid, which is a type of saturated fatty acid, is mixed with olive oil as an additive to improve its lubrication characteristics. Olive oil with stearic acid additive is thus observed to exhibit the lowest friction coefficient for rotational speeds of 200 to 800 rpm. According to the wear analysis, a minimal amount of wear is observed when no additive is used. Hence, olive oil is able to effectively reduce friction and wear at relatively low speeds. These low friction and wear characteristics of olive oil are attributed to its compatibility with the substrate.