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Development of Graphene Nanocomposite Membrane Using Layer-by-layer Technique for Desalination (다층박막적층법을 이용한 담수화용 그래핀 나노복합체 분리막 개발)

  • Yu, Hye-Weon;Song, Jun-Ho;Kim, Chang-Min;Yang, Euntae;Kim, In S.
    • Membrane Journal
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    • v.28 no.1
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    • pp.75-82
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    • 2018
  • Forward osmosis (FO) desalination system has been highlighted to improve the energy efficiency and drive down the carbon footprint of current reverse osmosis (RO) desalination technology. To improve the trade-off between water flux and salt rejection of thin film composite (TFC) desalination membrane, thin film nanocomposite membranes (TFN), in which nanomaterials as a filler are embeded within a polymeric matrix, are being explored to tailor the separation performance and add new functionality to membranes for water purification applications. The objective of this article is to develop a graphene nanocomposite membrane with high performance of water selective permeability (high water flux, high salt rejection, and low reverse solute diffusion) as a next-generation FO desalination membrane. For advances in fabrication of graphene oxide (GO) membranes, layer-by-layer (LBL) technique was used to control the desirable structure, alignment, and chemical functionality that can lead to ultrahigh-permeability membranes due to highly selective transport of water molecules. In this study, the GO nanocomposite membrane fabricated by LBL dip coating method showed high water flux ($J_w/{\Delta}{\pi}=2.51LMH/bar$), water selectivity ($J_w/J_s=8.3L/g$), and salt rejection (99.5%) as well as high stability in aqueous solution and under FO operation condition.

A Study on the Microstructure and Properties of Y-BA-Cu-O/Ag composite High $T_{c}$ Superconductor prepared by Sinter-forging Process (Sinter forging으로 제조한 Y-BA-Cu-O/Ag 고온 초전도 복합체의 미세조직과 특성)

  • Park, Jong-Hyeon;Kim, Byeong-Cheol;Song, Jin-Tae
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.37-43
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    • 1994
  • Y-Ra-Cu-0 oxide superconductors were fabricated by the sinter-forging method to make the critical current density improve through controlling of microstructure and crystal texture. The grain alignment of oxide superconductor was formed by the sinter-forging process and it's c-axis orientation was parallel to the press direction.The orientation factor of texture increased with sinking temperature and pressure, and also grain alignment was improved by the addition of Ag. As for the sinterforged Y-Ba-Cu-O/Ag sample, the $T_c$(on-set) was not almost varied with the sinter-forging temperature, but $T_c\;^{zero}$ decreased more or less at high sinter-forging temperatures. In addition, it was observed that added-Ag was mainly distributed along the grain boundar~es in the (123) matrix, resulting in the densification of microstructure. From these results, i t was thought that the improvement of $J_c$ over 2000A/$\textrm{cm}^2$ was attributed to the texture, densification of microstructure, and (123) grain growth due to the Ag addition.

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A Segment-based Minimum Cutset Method for Estimating the Reliability of Water Distribution Systems (상수관망의 신뢰도 산정을 위한 Segment 기반의 Minimum Cutset 방법)

  • Jun, Hwan-Don;Park, Jae-Il;Baek, Chun-Woo;Kim, Joong-Hoon
    • Journal of Korea Water Resources Association
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    • v.40 no.9
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    • pp.735-742
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    • 2007
  • In this study, a methodology which is based on segments and minimum outsets to estimate the reliability of a real water distribution system efficiently and accurately is suggested. The current reliability assessment models based on minimum cutset consider a pipe as only area impacted by a pipe failure which incurs underestimation of pipe failure impact. In contrary, the suggested methodology adopts "segment" and "unintended isolation" with the hydraulic pressure failure area to define the actual service interruption area in a water distribution system due to a pipe failure, which is different from the Previous reliability estimating methodologies. In addition, a minimum cutset is defined as a single segment incurring abnormal operating conditions and the success mode approach is used to account for the probability of multiple failure combinations of minimum outsets. The model considers numbers and locations of on-off valves when the service interruption area is defined. Once the methodology is applied to a real water distribution system, it is possible to define actual service interruption areas and using the defined areas, the reliability of the water distribution system is estimated reliably, compared with the previous reliability assessment methodologies.

SUPPLY-DEMAND, COMMERCIAL DISTRIBUTION AND TRANSACTION OF THE CULTURED TUNA IN JAPAN - EMPHASIZING ON THE GLOBAL EXPANSION OF THE TUNA-FARMING BUSINESS -

  • Yamamoto, Naotoshi;Kameda, Kazuhiko;Nishida, Akari;Kitano, Shinichi
    • The Journal of Fisheries Business Administration
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    • v.39 no.1
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    • pp.87-114
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    • 2008
  • The cultured tuna production which has suddenly expanded at the short time and the demand for it attract attention. Farming mode, distribution transactions, change of the market (domestic and international) and the price trend are reviewed from the Japan's position which is the biggest consuming country. This paper tries to describe the current status of the food system related to the cultured tuna. Japanese government began the development of the tuna culture technology in 1970. It was by the Fisheries Agency's project. Kinki University which is the large scale private university in Japan participated in the project. After that, 32 years have passed. Kinki University established the full farming of the bluefin tuna in August, 2002. On the other hand, in 1974, one Japanese private enterprise began its tuna farming business in Canada. Kinki University gave this company technical cooperation. Also, in the early stages of the 90s, as for the policy of the overseas fishery cooperation foundation, it supported the tuna farming business in Australia. It is very clear to understand that the long-term technological-development has supported the take-off scene of the tuna culture business not only in foreign countries but also in Japan. The total shipment scale of the cultured tuna expanded very much within about 10 recent years. However, the decrease of the wild tuna catch, the reinforcement of the fisheries regulation and the tuna body to dwarf are remarkable now. Under the condition as the mentioned above, Japan's tuna consumption, especially, in the market at the fatty meat of tuna of the cultured tuna is building up firm status. At present, the Mediterranean Sea coastal countries, Australia, Mexico and Japan have the tuna farming sites. Australia farms the southern bluefin tuna. The others do the bluefin tuna. About for 3 years, Japan farms the juvenile of the tuna. The global production areas are as follows. 8 coastal countries of the Mediterranean Sea; 18,000 tons (61 % of the cultured tuna quantity in foreign countries), Mexico; 4,500 ton (15%), Australia; 7,000 tons (24%). In 2003, Japan has 32 managements and 39 offices for tuna farming. In Japan, Kyushu and Okinawa district, the share shows itself as 80 % of the domestic production quantity. Especially, the share of Amami-oshima Island in Kagoshima Prefecture exceeds 60 %. Therefore, this island has the maximum production scale of Japan. The amount of supply of BT and SBT was 56,000 tons in 2004. In Abroad, the tuna farming business forms a fixed connection between the importer and the wholesaler which have their office in Japan. In the field of the capital composition, the payment in advance, transaction and the way of settlement, each maintains their fixed relation. The market conditions of the cultured tuna are supported by "the decline of price level" and "the expansion of the general public consumption segment". These lead a team merchandising, and it is supported by the fixed business connection of each. This makes the profit of each business which are on the cultured tuna distribution. However, they have competition on the power balance among them.

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A Study on the Effects of the Characteristics of Internet Shopping mall on Shopping Values and Customer Retantiong (인터넷 쇼핑몰 특성에 의한 쇼핑가치와 고객유지에 관한 연구)

  • Kim, Young-Man;Kim, Dong-Hyeon
    • Journal of Global Scholars of Marketing Science
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    • v.8
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    • pp.61-87
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    • 2001
  • Internet, which has been developed as a new exchange revolution, forms a huge virtual exchange market, and the innovative electronic commerce has completely broken off the way of existing goods distribution. This study begins with an awareness of the importance of customer retention to keep winning over the competition in internet shopping mall. In order to explain of the customer retention between individual and internet shopping mall, the study introduces first a satisfaction on shopping followed by an awareness of the importance of customer retention, and looks into a formation process of trust, satisfaction, and relationship orientation occurred by the offer of valuable convenience to customers. The study also explores the influence on shopping value by the characteristics with which internet shopping mall can bear, unfold by a cause and effect relationship the degree of shopping satisfaction, trust, and relationship orientation, and inquires a question to find out how to fuse the characteristics for internet retention. Therefore, this study has the following purposes: After examining prior research for the characteristics of internet shopping mall, it presents a possibility to connect shopping value with customer retention in light of theoretical system on characteristic elements derived from emotional and utilitarian perspectives. In order to achieve the purposes, the characteristics of internet retailing shop included site design, virtual reality, web awareness, customer concern, merchandise search, information supply, product value, and transaction system. Hypotheses were set up for the relationship with these characteristics and substantially analyzed. To prove this research, we analyzed collected data in which customers had experienced in shopping at internet shopping mall and discussed strategic current issues about its analytic results.

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Relationship between Muscle Sizes from Ultrasound Images and Endurance Time with/without Experience of Low Back Pain : Pattern of Recruiting Trunk Muscles (요통경험 유무에 따른 초음파 영상에서 측정된 근육크기와 근지구력 시간과의 관계: 유지 시간에 따라 동원된 체간근육 특성)

  • Kim, Hye-Yeon;Kim, So-Yeon;Lee, Hae-Jung
    • The Journal of the Korea Contents Association
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    • v.11 no.4
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    • pp.235-243
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    • 2011
  • The purpose of the study was to examine the thickness of the trunk muscles ie. external obliques (EO), transversus abdominis (TrA), and multifidus and the trunk endurance strength in order to determine any relationship between the presence or absence of low back pain (LBP) and the size of trunk muscles. Data were obtained from 50 subjects, aged between 19-29 years. Participants had no experience of spinal problems that had resulted in a restriction of normal activity or time-off work and no current spinal symptoms. Measurements of muscle thickness of the trunk muscles were collected at rest, contraction and 15 seconds of post contraction during endurance strength tests. Background information was obtained followed all physical measures. Subjects were divided into two groups based on their experience of LBP. In draw-in maneuver, increasing the thickness of TrA was observed in all participants while EO was decreased at contraction in group 1 and increase in group 2. Only subjects in the group 2 had TrA increased during the flexion endurance test. In the side-bridge endurance test, the thickness of the right TrA was also observed differently between groups. Therefore, the results of the study may suggest that a function of specific muscle should be addressed for training persons with LBP.

Modern Sedimentary Environments Within the Gogunsan Archipelago (고군산군도 내측해역의 현생퇴적환경)

  • Lee, Hee-Jun;Kim, Min-Ji;Kim, Tae-Kyung
    • Ocean and Polar Research
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    • v.30 no.4
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    • pp.519-536
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    • 2008
  • The relatively tranquil area within the Gogunsan Archipelago was for the first time investigated preliminarily with respect to modern sedimentological processes in association with the emplacement of the Saemangeum Dyke. Basic sedimentological observations, bathymetry and surface sediments were performed twice during 2006-2008 to compare the results and elaborate changes during that period of time. In addition, sediment dynamical observations were carried out with latest measuring equipment along two transects crossing the entrances of the archipelago, including 12-hour onboard measurements of current, suspended sediments, temperature, and salinity. This dataset was used to reveal hydrodynamic characteristics for spring season April-May and to estimate the direction and relative magnitude of the net flux of suspended sediments. There occurred three depositional areas (A to C) within the archipelago, where sediment texture was also changed. In area A, around Yami Island and the dyke, and area B, in the center of the archipelago, surface sediments became coarsened over the two-year period; sand content increased 5% at the expense of silt content in the former, whereas silt content increased 3% at the expense of clay content in the latter. By comparison, area C in the western entrance of the archipelago shows a textural trend of fining with more silt and clay (combined increase of 5%) at the expense of sand content. The accumulation of sediments in areas A and B is attributable to the sand and silt resuspended from the seabed sediments off sector 4 of the dyke during the winter. The origin of the fine materials depositing on area C is uncertain at present, although suspended sediments moving offshore around the archipelago may be one of the most likely candidates for the source. The temperature of seawater increased rapidly from $9-10^{\circ}C$ in April to $14-16^{\circ}C$ in May, whereas salinity remained more or less constant at 31-32%o during the two months. Both of these parameters showed little variations with depth through a tidal cycle, suggesting good mixing of seawater without any help of significant waves. The consistency of salinity during a tidal cycle also indicates no insignificant effects of freshwater from the rivers Mangyung and Donjin emitting through the opening gap near Sinsi Island. The suspended sediment concentrations were higher at the entrance between Sunyu and Sinsi islands than at the entrance between Hoenggyong and Sinsi islands, ranging from 20 and 30 mg/l and from 5 and 15 mg/l, respectively at the sea surface. Although tidal currents were variable across a transect between Sunyu and Sinsi islands, the currents across the entrance between Hoenggyong and Sinsi islands flowed consistently in the same direction all over the transect during a tidal cycle. The estimation of net flux of suspended sediments indicates that suspended sediments are transferred to the Gogunsan Archipelago mainly through a relatively deep trough adjacent to Sinsi Island toward the shallow area around Yami Island and the dyke.

Implementation & Test Results analysis Of a DTV Distributed Translator(DTxR) Network (DTV 분산중계망의 구축 및 실험방송 결과분석)

  • Mok, Ha-Kyun;Wang, Soo-Hyun;Sung, Young-Mo;Lee, Yong-Tae;Lee, Yong-Hoon;Kim, Heung-Mook
    • Journal of Broadcast Engineering
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    • v.14 no.4
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    • pp.518-536
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    • 2009
  • To verify the performance of a Distributed Translator Network(DTxR) system in the real world conditions, 5 legacy DTV broadcasting repeater sites were implemented with 5 DTxR systems and field-tested by the DTV field test truck. The 4 DTV broadcasting repeater sites are selected in congested areas where their service areas are overlapped and the 5th site is deviated from the other sites to examine the effect of long-delayed multipath signals. First of all, we checked the receiving signal of the main station that used as a transmitting signal in 5 DTxR systems on the pre-selected 60 test points and tested every case of a DTxR system's on & off except 1 repeater site due to the already built-in DTV repeater system. The test items are received signal electric field strength, noise margin, ease of reception and subjective evaluation of the picture quality for received signals. We used 3rd, 5th, and 6th generation DTV receivers to examine the differences of the receivability by each generation of DTV receivers. Reviewing the test results, we conclude that the DTxR system can be adopted in the current DTV Repeater sites and it could improve the quality and receivability of the main signals by extending the service areas and enhancing the signal levels in the shadow areas without using the extra broadcasting channels.

Observations on the Coastal Ocean Response to Typhoon Maemi at the East Sea Real-time Ocean Buoy (동해 실시간 해양관측 부이로부터 관측한 태풍 매미에 대한 연안해양의 반응 고찰)

  • Nam, Sung-Hyun;Yun, Jae-Yul;Kim, Kuh
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.9 no.3
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    • pp.111-118
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    • 2004
  • An ocean buoy was deployed 10 km off Donghae city, Korea at a depth of 130 m to measure meteorological (air pressure, air temperature, wind speed, wind gust, wind direction, relative humidity) and oceanographic data (water properties and currents in the whole column) in real-time. The buoy recorded a maximum wind gust of 25 m/s (10 minutes' average speed of 20 m/s) and a minimum air pressure of 980 hPa when the eye of typhoon Maemi passed by near the Uljin city, Korea at 03:00 on 13 September 2003. The wave height reached maximum of 9 m with the significant wave height of 4 m at 04:00 (1 hour after the passage of Maemi). The currents measured near the surface reached up to about 100 cm/s at 13:00 (10 hours after the passage of Maemi). The mixed layer (high temperature and low salinity) thickness, which was accompanied by strong southward current, gradually increased from 20 m to 40 m during the 10 hours. A simple two layer model for the response to an impulsive alongshore wind over an uniformly sloping bottom developed by Csanady (1984) showed reasonable estimates of alongshore and offshore currents and interface displacement for the condition of typhoon Maemi at the buoy position (x=8.15 km) during the 10 hours.

Recognition of Occupational Accidents related Multiple Sclerosis and Its Implications (다발성 경화증의 업무상 재해 인정과 그 시사점 : 대법원 2017. 8. 29. 선고 2015두3867 판결을 중심으로)

  • Jeon, Byeong-Joo
    • The Journal of the Korea Contents Association
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    • v.17 no.10
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    • pp.559-566
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    • 2017
  • Despite the government operating various preventive programs to ward off accidents and diseases on business sites, diseases rates are not decreasing, unlike accident rates. In many cases, diseases caused by work have a latent period before symptoms appear or progress over a longer term, making it difficult for workers to prove the causal relation between their work and the diseases. Moreover, data related to the business site are mostly owned by the employer. Even if the employee has access to parts of such data, his lack of medical expertise limits his ability to identify the characteristics of the diseases and how it appears. In August, 2017 the Supreme Court did an about-face with its ruling on the case involving diseases caused by exposure to harmful substances in work environments, by easing the burden of proof on the employees. As such, this study focuses on the case to analyze cases involving diseases that have occurred in work environments and present their implications. In doing so, the study seeks to provide a basic set of data that can help secure the employees' labor rights and rights to health by complementing the current law in relation to recognizing industrial incidents caused by rare diseases and making work environments safer for employees.