• Journal of Environmental Health Sciences
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• v.36 no.5
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• pp.351-359
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• 2010

The objectives of this study were to understand the characteristics of residents in industrial areas and factors affecting exposure to the Volatile Organic Compounds(VOCs : Benzene, Toluene, Xylene) as well as to assess exposure levels according to house-type, and whether residents were indoors or outdoors. This research was designed to assess the differences in exposure levels to indoor, outdoor and personal VOCs in a case group and a control group across all areas, as well as in each different area, from May to October 2007, in. 110 residents of the G, Y and H industrial areas of the Jun-nam province. The geometric mea-levels of airborne benzene for the case group 1.31part per billion(ppb) indoor, 1.29 ppb outdoor, and 1.32 ppb for personal exposure were significantly higher than for the control group 0.99, 0.87 and 0.57 ppb, respectively. The geometric mean level for toluene personal exposure across the G, Y and H areas was 5.70 ppb for the case group and 6.31 ppb for the control group. While the outdoor level was 4.27 ppb for the case group and 5.06 ppb for the control group, The indoor level for the case group was 4.78 ppb, similar to that of the control group 4.69 ppb. The geometric mean levels for airborne xylene across the G, Y and H areas were 0.16 ppb(outdoor), 0.12 ppb(personal exposure) and 0.10 ppb(indoor) for the case group, and for the control group were 0.17(personal exposure) and 0.09 ppb(indoor and outdoor). The indoor/outdoor(I/O) ratio for case group is 1.19, while that of the control group is 1.15, indicating that the indoor level was higher than the outdoor level. The interrelationship differences among the three different types of levels in the air in the G, Y and H areas are statistically significant, except for the difference between the indoor and outdoor figures for xylene. In terms of the different types of houses and energy type uesd, the geometric mean level for airborne benzene, toluene and xylene for houses were 1.61, 5.39 and 0.12 ppb, respectively. while the figures for flats were 0.67, 3.32 and 0.05 ppb, respectively. Outdoors, the levels of benzene and toluene in flats were 0.71 and 2.62 ppb, respectively. and 1.58 and 5.35 ppb in houses. For personal exposure, the house levels of benzene, toluene and xylene were all higher than for flats. Houses using oil for heating have significantly higher levels than flats, which use gas for heating.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.4
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• pp.289-303
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• 2009

The chemical and meteorological effects on the concentration variations of ozone ($O_3$) were evaluated based on the intensive air quality measurement (5 pollutants and aromatic volatile organic compounds (AVOCs)) in and out-side an urban valley during spring and summer of 2006. The 5 pollutants measured in the study area include $O_3$, $NO_2$, NO, $PM_{10}$, and CO; the AVOCs include benzene (BEN), toluene (TOL), ethylbenzene (EB), m,p-xylene (MPX), and o-xylene (OX). For the purpose of this study, study areas were classified into two categories: valley area (VA) with a semi-closed topography covering a number of industrial complex, public building, and mountains and non-valley area (NVA) surrounding the suburban and residential areas. In general, the mean concentration levels of most pollutants (except for $PM_{10}$) in the VA were higher than those in the NVA. It was found that the average $O_3$ increase in the VA during spring might result from the combined effects such as the photochemical production from diverse anthropogenic sources and the $O_3$ accumulation due to geographical features (e.g., the semi-closed topography) and wind conditions (e.g., a low wind speed). In addition, the nocturnal $O_3$ increase in the VA during spring was primarily caused by local wind conditions (e.g., mountain and valley winds) with the low wind speed (approximately $1{\sim}2\;m\;s^{-1}$). On the other hand, the $O_3$ difference between the two areas during summer might be because of the photo-chemical production with the $O_3$ precursors (especially the AVOCs) rather than the contribution of wind conditions.

• Journal of Soil and Groundwater Environment
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• v.21 no.3
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• pp.88-94
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• 2016

The simultaneous biodegradation between MTBE (Gasoline additives) and BTEX (Benzene, Toluene, Ethyl-benzene, o-Xylene, m-Xylene, p-Xylene) was achieved within a competitive inter-relationship, with not only electron accepters such as nitrate, sulfate, and iron(III) without oxygen, but also with electron donors such as MTBE and BTEX. Preexisting indigenous microorganisms from a domestic sample of gasoline contaminated soil was used for a lab-scale batch test. The result of the test showed that the biodegradation rate of MTBE decreased when there was co-existing MTBE and BTEX, compared to having just MTBE present. The growth of indigenous microorganisms was not affected in the case of the MTBE treatment, whereas the growth of the microorganisms was decreased in combined MTBE and BTEX sample. This may indicate that an inhibitor related to biodegradation when BTEX and MTBE are mixed will be found. This inhibitor may be found to retard the anaerobic conditions needed for efficient breakdown of these complex carbon chain molecules in-situ. Moreover, it is also possible that an unknown competitive reaction is being imposed on the interactions between MTBE and BTEX dependent on conditions, ratios of mixture, etc.

• Applied Chemistry for Engineering
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• v.2 no.1
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• pp.77-85
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• 1991

A series of samples having different $SiO_2/Al_2O_3$ ratio were prepared by treating hydrogen mordenites with boiling hydrochloric acid and with hydrofluoric acid. The acidities of these samples were measured by TPD of $NH_3$ and by pyridine adsorption using IR, and the catalytic activities and selectivities of isomerization were measured for the reaction of ortho-xylene. For the samples treated by boiling hydrochloric acid, the acidities decreased with the increasing $SiO_2/Al_2O_3$ ratio caused by the extraction of framework aluminum. The sample having the $SiO_2/Al_2O_3$ ratio or 22 showed better activity than the others. For the samples treated by hydrofluoric acid, the content of chemically binding fluorine increased with the increasing contact time of hydrofluoric acid solution. The catalytic activities decreased with the hydrofluoric acid treatment due to the decreased acid sites resulted from the extraction of aluminum and silicon as well as the hydroxyl group replacement by the fluoride ion. The slightly increasing catalytic activities, however, came from the newly created acid sites, due to the removal of surface silicon, having enhanced by the inductive effect of binding fluorin with further acid treatment.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.207-208
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• 2000

Since trichloroethylene (TCE), dichloroethylene (DCE), and vinyl chloride (VC) arise from anaerobic degradation of tetrachloroethylene (PCE) and TCE, there is interest in creating aerobic remediation systems that avoid the highly toxic VC and cis-DCE which predonominate in anaerobic degradation. However, it seemed TCE could not be degraded aerobically without an inducing compound (which also competitively inhibits TCE degradation). It has been shown that TCE induces expression of both the toluene dioxygenase of p. putida F1 as well as toluene-p-monooxygenase of P.mendocina KRI. We investigated here the ability of PCE, TCE, and chlorinated phenols to induce toluene-o-xylene monooxygenase (ToMO) from P.stutzeri OX1. ToMO has a relaxed regio-specificity since it hydroxylates toluene in the ortho, meta, and para positions; it also has a broad substrate range as it oxidizes o-xylene, m-xylene, p-xylene, toluene, benzene, ethylbenzene, styrene, and naphthalene; chlorinated compounds including TCE, 1, 1-DCE, cis-DCE, trans-DCE, VC, and chloroform : as well as mixtures of chlorinated aliphatics (Pseudomonas 1999 Maui Meeting). ToMO is a multicomponent enzyme with greatest similarity to the aromatic monooxygenases of Burkholderia pickettii PKO1 and P.mendocina KR1. Using P.sturzeri OX1, it was found that PCE induces P.mendocina KR1 Using P.situtzeri OX1, it was found that PCE induces ToMO activity measured as naphthalene oxygenase activity 2.5-fold, TCE induces 2.3-fold, and toluene induces 3.0 fold. With the mutant P.stutzeri M1 which does not express ToMO, it was also found there was no naphthalene oxygenate activity induced by PCE and TCE; hence, PCE and TCE induce the tow path. Using P.putida PaW340(pPP4062, pFP3028) which has the tow promoter fused to the reporter catechol-2, 3-dioxygenase and the regulator gene touR, it was determined that the tow promoter was induced 5.7-, 7.1-, and 5.2-fold for 2-, 3-, 4-chlorophenol, respectively (cf. 8.9-fold induction with o-cresol) : however, TCE and PCE did not directly induce the tou path. Gas chromatography and chloride ion analysis also showed that TCE induced ToMO expression in P.stutzeri OX1 and was degraded and mineralized. This is the first report of significant PCE induction of any enzyme as well as the first report of chlorinated compound induction of the tou operon. The results indicate TCE and chlorinated phenols can be degraded by P.stutzeri OX1 without a separate inducer of the tou pathway and without competitive inhibition.

• Journal of Environmental Science International
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• v.17 no.7
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• pp.767-774
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• 2008

This study was carried out to evaluate the characteristics of atmospheric concentrations of volatile organic compounds(VOCs) and aldehydes for near a large shipyard. Most of the painting work in marine coating is performed indoor and outdoor. Most of the VOCs are emitted to the atmosphere as the paint is applied and cures. The massive scale of a ship makes it difficult to capture the emissions from outdoor painting. The VOCs are an important health and contributors to photochemical smog. The VOCs and aldehydes samples were collected using adsorbent tube and 2,4-DNPH cartridge, and were determined by an automatic thermal desorption coupled with GC/MS and HPLC-UV analysis, respectively. A total of 16 aromatic VOCs and 12 aldehydes of environmental concern were determined. At indoor coating facilities, the most abundant compound among 16 target VOCs appeared to be m,p-xylene, being followed by o-xylene. But most of the aldehydes were extremely lower concentrations. The atmospheric concentration of VOCs, m,p-xylene concentrations were the highest and the mean value were outdoor workshop 11.323 ppb, residental area 5.134 ppb, and green area 2.137 ppb, respectively. However, the most aldehydes were extremely lower concentrations such as formaldehyde, acetaldehyde and non-detection such as iso-valeraldehyde, n-valeraldehyde and o-tolualdehyde.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.5
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• pp.375-384
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• 2001

Optical remote sensing techniques are particularly advantageous over the conventional fixed point methods because with these methods large-area monitoring can be possible and sample preparation difficulties are avoidable. Instruments based on the differential optical absorption spectroscopy (DOAS) technique are widely used for monitoring air pollutants in urban areas in recent years. In this study, $O_3$, SO$_2$, NO$_2$, and VOCs (benzene, toluene, xylene, and styrene) are measured continuously at Sihwa industrial area using a DOAS from February to November. 1999. Intercomparison between the DOAS method and the conventional methods (filed point samplers for $O_3$, NO$_2$, and SO$_2$, and adsorbent sampling methods and gas chromatography for VOCs) are performed simultaneously at the same site. The time series of the DOAS data and that of fixed point method show good match at the view point of the tendency, but the absolute concentration values of these two methods differ quite a lot from each other; correlation coefficients shows 0.78 for $O_3$and 0.97 for SO$_2$. However, the results of VOCs measurements are not quite satisfactory ; the spectral interference with $O_2$and $O_3$appears to be the major cause of the errors for VOCs .

• Journal of ILASS-Korea
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• v.20 no.1
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• pp.28-34
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• 2015

Recently, some researchers have been carried out risk assessment of vehicles exhaust on human health. Especially, some of VOCs which is non-controlled, was classified to hazardous pollutant, such as 1,3-Butadiene and BTEX(Benzene, Toluene, Ethylbenzene and Xylene). Therefore, the profile on non-controlled pollutant may be needed in the future, because it would be critical data or information to control them. Additionally, with increasing amount of motorcycle, the source profiling is essential for estimating emission factor and amount on motorcycle exhaust. For these, in this study, imported motorcycles (8 vehicles) were selected as a test model while considering the increasing ratio on sales volume between 2013 and 2014; it was also compared with domestic motorcycles on those. The experiment was conducted by driving mode, UDC and ECE+EUDC that made from EURO III. In addition, it was performed at cold start driving mode without effect by displacement, for evaluating only correlation of BTEX with HC. In order to apply the ratio (m,p-Xylene/o-Xylene) as a marker, the ratio was compared with those of tunnel, road side and residential area. As a result, it showed best correlation ($R^2=0.98$) among those. In the future, it has to be considered as a marker for effect evaluation to atmospheric environment by exhaust emission.

• Proceedings of the Microbiological Society of Korea Conference
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• 2005.05a
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• pp.201.1-201
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• 2005

• Proceedings of the Zoological Society Korea Conference
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• 1999.10b
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• pp.99.1-99
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• 1999

No Abstract, See Full Text