• 한국산업보건학회지
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• 제23권2호
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• pp.75-83
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• 2013

Objectives: This study was conducted to estimate quartz concentrations in the airborne respirable dust from concrete manufacturing industries and to compare performance of two analytical methods, direct on filter(DOF) and the transfer methods in the Fourier Transform Infrared Spectroscopy(FTIR). Methods: Total 36 area samples were collected from 8 concrete manufacturing industries. Each respirable dust sample was collected by a 25 mm cassette attached to a 10 mm Dorr-Oliver nylon cyclone. The quartz content was estimated using the intensity of the absorption peak of quartz at $799cm^{-1}$ by FTIR. Results: By the comparison of quartz content in respirable dust between the two methods, the results of using DOF method were higher than that of transfer method. And the result of quartz concentrations in respirable dust estimated by DOF method were mostly higher than those by transfer method. Statistically significant difference of quartz concentrations in respirable dust were not found in shakeout, input, loading and transporting processes by two methods. But quartz concentrations in the molding process had the statistically significant difference between DOF and transfer method. Conclusions: The results of the study is suggested that, it be needed to correct the influence of the interferences in order to establish the DOF method when interfering minerals have an effect on quantitative analysis of quartz in respirable dust by the direct on filter method with FTIR.

• 분석과학
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• 제19권3호
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• pp.255-262
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• 2006

본 연구에서는 VOC가 옷감이나 물질소재와 접촉하여 흡착손실하는 경향을 평가하고자 하였다. 이를 위하여 필터홀더에 필터의 형식으로 비교대상 소재를 장착하고 이들에 VOC 가스를 흘려주는 방식으로 화합물의 흡착손실반응을 평가할 수 있는 기법의 적용 가능성을 다각도로 평가하였다. 테플론 소재의 필터는 양호한 안정성이나 재현성을 보여 주었다. 이러한 시스템에 각각의 소재(글래스 파이버, 면, 나일론)를 장착한 상태로 벤젠, 톨루엔, 자일렌이 혼합된 가스를 흘려 주면서 각각의 검량선을 작성하였다. 본 연구의 결과에 의하면, 각각의 소재 및 VOC 성분별로 뚜렷한 흡착특성을 확인할 수 있었다. 소재들 중에서는 글래스 파이버 < 면 < 나일론의 순서로 그리고 성분별로는 벤젠 < 톨루엔 <자일렌의 순서로 흡착손실이 증가하는 양상이 뚜렷하게 나타났다. 그 결과, 재질이나 화학물질의 특성과 같은 변수가 동시에 흡착손실의 경향성을 결정짓는다는 결론에 도달하였다.

• 한국대기환경학회지
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• 제13권2호
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• pp.147-159
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• 1997

산성 건성침적은 산성비침적만큼 생태계에 중요한 영향을 미친다고 사료된다. 여러 실측소로부터 필터팩 데이터를 비교하는 과정에서 발생되는 가장 중요한 문제들 가운데 하나는 서로 다른 샘플채취 유량의 사용에 있다고 본다. 본 연구에서는 다양한 시료채취 조건이 비교되었는 바, 시료채취 유량의 변화(1.5 $\sim$ 10sLpm)가 건성침적물의 농도측정에 어떠한 영향을 주는 지를 평가하기 위해 밀도 있는 연구가 이루어졌다. 샘플링과 분석의 재현성을 결정하기 위해 한 쌍의 필터팩시료가 동시에 채취되었다. 대기중 시료들은 또한 다양한 유량변화 조건하에서 일주일동안 동시에 채취되었는 데, 그 시료 물질들은 아황산 가스, 질산 가스, 질산염 및 황산염 분진물질들이었다. 동시 측정된 한 쌍의 필퍼팩 시료는 재현성이 있는 것으로 나타났고 언제나 거의 유사한 대기농도 값을 나타내어 주었다. 결론적으로 대기중 산성 건성침적물들의 채취를 위한 유량변화는 그 물질들의 농도측정에 거의 영향을 주지 않는 것으로 나타났다. 그러나, 상대적으로 낮은 유량 (<5 sLpm)과 높은 유량만 (>5 sLpm)을 비교하였을 때에는, 높은 유량의 경우에 오차의 도입소지가 높다는 것을 알 수 있었다. 또한, 필터물질 자체만을 고려해 볼 때, 시료 유입량의 증가에 따라 나일론 필터에 흡착된 아황산가스의 양은 상당히 감소되는 것으로 나타났다.

• Journal of Pharmaceutical Investigation
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• 제30권1호
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• pp.51-54
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• 2000

A column-switching high performance liquid chromatographic method has been developed for the determination of a fluconazole in human plasma. Each plasma sample was centrifuged for 10 min at 5000 g. After an aliqout of the supernatant was taken to nylon microcentrifuge filter, these samples were centrifuged for 10 min at 5000 g. An aliqout of the supernatant was injected directly onto the HPLC column. Deionized water was run for 2 min at a flow rate of 1.0 ml/min to retain fluconazole in an extration column, while proteins and endogenous interferences were eluted to the waste. The analyte was then back-flushed onto an analytical column, $C_{18}$ reversed-phase column. The mobile phase for analytical column, 0.01 M sodium acetate (pH 5.0)-methanol (65:35, v/v), was run at a flow rate of 1.0 ml/min. The column effluent was monitored by ultraviolet detection at 261 nm. The retention time for fluconazole was 11.76 min in human plasma. The detection limit for fluconazole in human plasma was $0.2\;{\mu}g/ml$. No interference from endogenous substances was observed.

• 대한본초학회지
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• 제23권2호
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• pp.9-17
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• 2008

Objectives : The purpose of this report was to provide the information packaging of herbal medicines by analyzing papers. We investigated the packaging materials, packaging methods and expiration date of herbal medicines by analyzing papers of the Korea, Japan and China. Methods : We survey herbal medicine-related law and crude drug monograph of compendium in each three country, we purchased herbal medicine of the Korea, Japan and China in the market and verify the expressed-item in packing paper. In case of Japan, we examine packaging materials, packaging methods, and expiration date of herbal medicine in pharmaceutical company. Results : The pharmaceutical company in japan used the methods of nitrogen gas pouring, vacuum packing for the herbal medicine packaging. The expiration date of the herbal products in Japan is generally 3 to 5 year after packaging. And packaging materials were aluminium and polyethylene. In Korea, pharmaceutical company used airtight packing for the herbal medicine packaging and expiration date of the herbal product were generally 3 year after packaging. Packaging materials were polyethylene, nylon or polyethylene-nylon mixed materials. In China, pharmaceutical company also used airtight packing for the herbal medicine packaging, and the expiration date were generally 5 year after packaging. Packaging materials were polyethylene, wrapping paper-used parcel or tea leaves filter paper. Conclusion : This results can present the basic data for expiration date and preservation methods of the herbal roots in Korea.

• 한국농공학회지
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• 제10권2호
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• pp.1454-1459
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• 1968

본(本) 실험(實驗) 실시(實施)함에 있어서 포장(圃場) 10a를 시공구(施工區) 5a, 대비구(對比區) 5a로 나누고 시공구(施工區)는 인력(人力)으로 터파기를 하는데 깊이 1m, 거리 5m 경사(傾斜) 200분지(分之)1로 하고 관경(管徑) 4.5cm의 plastic 제(製) 흡수관(吸水管) (Glass nylon filter 권(卷))을 시공구(施工區) 5a에 pipe 전소요량(全所要量)이 100m (2.5m, 40개)이며 배수조절용수갑(排水調節龍鬚閘)은 2개소(個所) 설치(設置)하여 관개기(灌漑期)에는 매일(每日) 오후(午後) 5시(時)에 개방(開放)하고 오전(午前) 6시(時)에 닫어 지온(地溫)을 측정(測定)한 결과(結果), 평균(平均) $1.2^{\circ}C$ 상승(上昇)하고 비관개기(非灌漑期)는 맥류(麥類) 및 서류재배(薯類栽培)를 위(爲)해서 수갑(水閘)을 종일(終日)열어 배수(排水)의 목적(目的)을 달성(達成)시켜 서류(薯類) 및 맥류재배(麥類栽培)가 전연불가능(全然不可能)한 저온지(低溫地)가 재배가능(栽培可能)하였으나 배수(排水)와 지외(地外), 생육(生育), 수량(收量), 토양(土壤), 관개수질조사(灌漑水質調査)는 제이차(第二次) 시험(試驗)에서 취급(取扱)하기로 하겠다.

• 한국산업보건학회지
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• 제24권4호
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• pp.462-470
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• 2014

Objectives: The purpose of this study was to evaluate quartz concentrations in airborne respirable dust and particle size-related quartz concentrations. Methods: Respirable dust samples were collected using a 10 mm Dorr-Oliver nylon cyclone equipped with a 37 mm, $5{\mu}m$ pore size PVC filter. Dust samples were collected with a Marple's personal cascade impactor from stone grinding operations in five stone-related business located in the Gyeongsangbuk-do area. Results: The geometric mean of quartz concentration in the respirable dust was $0.170mg/m^3$, and the rate of exceeding the Korean Occupational Exposure Limit(KOEL) was 93.3%. The quartz concentration by particle size shows that it was the highest($0.115mg/m^3$) in stage 5($3.50-6.00{\mu}m$), which corresponds with the size of respirable particle. The smaller the particle sizes were, the higher quartz the content became. The mass fractions of inhalable, thoracic, and respirable dust were 72.1%, 36.0%, and 14.4%. Conclusions: The rate of the quartz concentration in respirable dust from stone grinding operations exceeding the American Conference of Governmental Industrial Hygienists Threshold Limit Values was 100%, which means proper work environmental management is required through regular working environmental measurements. Given that the stone grinding operations had a higher small size dust concentrations, there is a need to reduce respirable dust, such as through wet operation and local exhaust ventilation.

• 한국농공학회지
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• 제15권2호
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• pp.3002-3006
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• 1973

암거배수 연구는 오래전부터 해왔다. 우리나라에서는 PVC흡수관으로 제4차 시험을 했다. 제일 먼저 3배수구와 3무배수구를 설정하고 배수 방법, 토양온도, 작물의 생육, 수량등을 비교 시험하였다. 시험 방법과 결과는 다음과 같다. 1. 방법 (1) 관 길이=1m (2) 거리 = 6.5m (3) 경사 = 1/200 (4) 지수벽 깊이 : 2.5m (5) 공시품종 : 밀성 (6) PVC흡수관리 filter는 Glass nylon으로 감는다. 2. 결과 (1)지온: 전관개 기간을 통하여 배수구에서는 평균 $1.5^{\circ}C$상승하고 10일간에 최고 $2.6^{\circ}C$ 상승할 때도 있었다. (2) 수량에서는 3개 시험구를 평균한즉 20%의 증수를 얻었다. (3) 경제적 면으로 볼 때 1ha당 증수액(95,622원) 시공비(13,005원)=82,900원의 증수익이 있었다. (4) 우리나라에서 암거배수를 필요로 하는 습담의 면적은 약 20만ha이다.

• 한국임상수의학회지
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• 제24권3호
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• pp.400-405
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• 2007

This study was performed to investigate the therapeutic effects of Hovenia dulcis Thunberg (HDT) and HDTmix extracts on the biochemical analysis, histopathology and histomorphometry of liver and kidney in carbon tetrachloride $(CCl_4)$ administrated rats. Extract was prepared by autoclave ($121^{\circ}C$, 15 psi, 3 hours) and filtered with nylon cloth and filter paper then freezing dried. In blood chemistry analysis, HDTmix group, aspartate aminotransferase and alanine aminotransferase were significantly (p<0.01) decreased compared to the $CCl_4$ group, on 3rd day, respectively. In histologic and histomorphometry analysis, the $CCl_4-related$ hepatopathies and nephropathies were dramatically decreased (3rd, 5th day), and well corresponded to the histopathological changes significantly (p<0.01) decreases of degenerative regions, degenerative cells and glomeruli were detected in liver and kidney with significantly decreases of $CCl_4$ group. HDTmix group, quite similar effects on the liver and kidney were observed compared to that of HDT extracts group but more favorable efficacies were detected especially HDTmix also inhibit the hepatopathies (1 day), in which HDT extract does not showed any inhibit effects.

• 한국환경농학회지
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• 제38권4호
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• pp.321-331
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• 2019

BACKGROUND: Pinoxaden is the phenylpyrazoline herbicide developed by Syngenta Crop Protection, Inc. and marketed on 2006. The maximum residue levels for wheat and barley were set by import tolerance. Thus, Ministry of Food and Drug Safety (MFDS) official analytical method determining Pinoxaden residue was necessary in various food matrixes. Satisfaction of international guideline of CODEX (Codex Alimentarius Commission CAC/GL 40) and National Institute of Food and Drug Safety Evaluation-MFDS (2017) are additional pre-requirements for analytical method. In this study, liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was investigated to analyze residue of Pinoxaden (M4), which is defined as pesticide residue in Korea, in foods. METHODS AND RESULTS: Pinoxaden (M4) was extracted followed by acid digestion (2hr reflux with 1N HCl) and pH adjusting (pH 4-5 with 3% ammonium solution). To remove oil, additional clean-up step with hexane saturated with acetonitrile was required to high oil contained sample before purification. HLB cartridge and nylon syringe filter were used for purification. Then, samples were analyzed by LC-MS/MS using reserve phase column C₁₈. Five agricultural group representative commodities (mandarin, potato, soybean, hulled rice, and red pepper) were used to verify the method in this study. The liner matrix-matched calibration curves were confirmed with coefficient of determination (r²) > 0.99 at calibration range 0.002-0.2 mg/kg. The limits of detection and quantitation were 0.004 and 0.01 mg/kg, respectively, which were suitable to apply Positive List System (PLS). Mean average accuracies of pinoxaden (M4) were shown to be 74.0-105.7%. The precision of pinoxaden and its metabolites were also shown less than 14.5% for all five samples. CONCLUSION: The method investigated in this study was suitable to CODEX (CAC/GL 40) and National Institute of Food and Drug Safety Evaluation-MFDS (2017) guideline for residue analysis. Thus, this method can be useful for determining the residue in various food matrixes in routine analysis.