• Title/Summary/Keyword: nylon 4

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Anionic Graft Copolymerization Using Copolymer of Acryloyllactam Type Monomer (Acryloyllactam형 단량체의 공중합 및 그 공중합체를 이용한 음이온 그라프트 중합)

  • Hee G. Woo;Sam K. Choi
    • Journal of the Korean Chemical Society
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    • v.26 no.3
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    • pp.179-187
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    • 1982
  • The copolymerization of N-acryloylpyrrolidone and acrylonitrile was performed in N,N'-dimethylformamide at 50$^{\circ}$C and monomer reactivity ratio was obtained by using IR working curve and Fineman and Ross equation. ($r_1$ = 0.43, $r_2$ = 1.56) It is found that resulting copolymer is good polymeric initiator for anionic graft copolymerization of 2-pyrrolidone. Graft copolymers with polybutylamide (nylon-4) grafts onto poly(NAP-Co-AN) backbone were synthesized and the various effects on the graft copolymerization of 2-pyrrolidone were examined. The rate constants ($K_p$) of graft anionic polymerization at 40 and 50$^{\circ}$C were 2.82${\times}$10 and 2.93${\times}$10(l/mole, min), respectively.

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Determination of Ethanol in Alcoholic Beverages by Alcohol Oxidase Sensor (Alcohol oxidase 효소센서를 이용한 알코올 음료 중의 에탄올 정량)

  • Lee, Ok-Kyung;Kim, Tai-Jin;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.27 no.2
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    • pp.266-269
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    • 1995
  • In order to measure alcohol contents with speed and accuracy, alcohol sensor was prepared. Alcohol sensor was made by connecting with oxygen electrode after immobilized alcohol oxidase on nylon net with glutaraldehyde. Alcohol was determined by changing the rate of dissolved oxygen consumption using D.O. analyzer. Alcohol contents in alcoholic beverages were determined under the optimum conditions. The results were 0.71% in low-alcohol beverage, $4{\sim}5%$ in beers, 10.06% in wine, 16.12% in chungju, 25.71% in soju, and 6.18% in takju, respectively. The values by alcohol sensor showed an excellent correlation(r=0.999) with GC method.

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An Experimental Study on the Thermal Insulation of the Linin Fabrics (의복 안감의 보온성에 관한 실험적 연구)

  • Jeong Young Ok;Choi Jeong Wha
    • Journal of the Korean Society of Clothing and Textiles
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    • v.8 no.1
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    • pp.1-11
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    • 1984
  • An attempt was made to determine individual thermal resistances of 2-lining fabrics ad 4-outer fabrics for Korean-styled clothes, and 4-lining fabrics ad 5-outer fabrics for Western-styled clothes at $19^{\circ}C$ and $24^{\circ}C$. The thermal insulation effects for different lining fabrics in Korean and Western-styled clothes were deduced in determining heart rate, rectal temperature, mean skin temperature and microclimates of subjects. The subjects were dressed experimental clothing which were made of lining and outer fabrics in question, and seated in an environmental chamber during the experiment. 1. Thermal resistances of lining fabrics : For Korean-styled clothes. nylon sheer is larger than unzosa. For Western-styled clothes, rayon, acetate, nylon(taffeta) and kalkali in that order. 2. Thermal resistances of lining fabrics combined : with outer fabrics: For Korean-styled clothes. the measured value is larger than the one of simple aggregate value. But in the case of Western-styled clothes, the measured value is smaller than simple aggregate value. 3. The effects of lining on the thermal insulation of the whole clothing: In case when subjects wore unlimited number of underwear, no matter what lining fabrics were used in Korean and Western-styled clothes less thermal insulation effects were indicated. For the case, however, if subjects wore only limited underwear, there are significant differences of thermal insulation between experimental clothings.

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Tissue reactions to suture materials in the oral mucosa of beagle dogs

  • Kim, Jae-Seok;Shin, Seung-Il;Herr, Yeek;Park, Joon-Bong;Kwon, Young-Hyuk;Chung, Jong-Hyuk
    • Journal of Periodontal and Implant Science
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    • v.41 no.4
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    • pp.185-191
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    • 2011
  • Purpose: The objective of this study was to compare and evaluate the inflammatory responses of three widely used suture materials in the keratinized gingiva and buccal mucosa of beagle dogs. Methods: Silk, polyglycolic acid, and nylon sutures were placed within the mandibular keratinized gingiva and maxillary buccal mucosa of four male beagle dogs. Biopsies were taken 3, 7, and 14 days after suturing. Specimens were prepared with hematoxylineosin stain for evaluation under a light microscope. Results: The suture materials placed in the oral mucosa elicited more inflammatory reactions than did those placed in the keratinized gingiva. The multifilament suture materials caused more inflammatory tissue reactions than did the monofilament suture materials in the oral mucosa. Conclusions: If oral hygiene is well maintained and suture materials are placed in the keratinized gingiva, silk, nylon, and polyglycolic acid are considered to be proper suture materials for oral surgery. However, it is advisable to use monofilament suture materials if the suture site is within the oral mucosa.

A Study on the Dyeing of Chitosan treated Cotton and Nylon Fabrics - Caesalpinia sappan, Cochineal, Gardenia jasminoides - (키토산처리(處理) 면포(綿布)와 나일론포(布)의 염색성(染色性)에 관(觀)한 연구(硏究) - 소목(蘇木), 코치닐, 치자(梔子)를 중심(中心)으로 -)

  • Jeon, Dong-Won;Kim, Jong-Jun;Lee, Jung-Min;Shin, Hye-Sun
    • Journal of Fashion Business
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    • v.7 no.2
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    • pp.156-164
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    • 2003
  • It has been known that the natural colorants exhibit good dye-uptake toward cotton, silk, and wool fibers, while they do poorly toward synthetic fibers. This study utilizes the chitosan treatment in order to improve the dye-uptake for the natural fibers and to enable the synthetic fibers, whose dye-uptake levels are low, show better affinity toward the natural colorants. Since chitosan has $-NH_2$ group and -OH group in the structure, the dyeability of the fabric will be improved when the fabric is treated with the chitosan. Cotton fabric as one of the natural fiber fabrics and nylon fabric as one of the synthetic fiber fabrics were selected for this study. 1. In case of cotton fabric, the chiosan treatment takes effect for the Caesalpinia sappan and cochineal, resulting in remarkable ${\Delta}E$ increase after dyeing. Chitosan helps in developing dark shade by increasing the uptake of the Caesalpinia sappan and cochineal. It does not, however, participate in the developing of the specific color as does a metallic mordant. 2. In case of dyeing cotton fabric with Gardenia jasminoides, the effect of the treatment with mordant and chitosan is not very pronounced. It is thought that the Gardenia jasminoides uptake is accomplished in a direct manner in the cellulose chains without the aid of mordant. 3. Air-permeability is decreased when the non-mordanted and non-chitosan treated cotton fabric is dyed with Caesalpinia sappan, cochineal, and Gardenia jasminoides. 4. In case of nylon fabric, premordanting and chitosan treatments are not highly effective in promoting the dye-uptake.

Study on the Charateristics of Nylon/Clay Nanocomposite Prepared by Monomer Casting Method (단량체 주형 기법에 의하여 제조한 나일론/클레이 나노복합체의 특성에 관한 연구)

  • Chung, Dae-won;Kim, Pil Young
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.502-506
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    • 2005
  • In the presence of various clays, nylon/clay nanocomposites were synthesized by anionic polymerization of ${\varepsilon}$-caprolactam (CL) via monomer casting method. The effect of each clay on polymerization reaction was investigated and the change in gallery structure of clays during polymerization was analyzed by X-ray diffraction. When the three kinds of organo-clays were used in the amount of 2 wt% of CL, polymerizations were not successful due to an increase in viscosity during polymerization. Significant changes were not observed in the mechanical and thermal properties of the composites containing organo-clays with 1 wt%. On the other hand, composites containing natural clay up to 5 wt% were successfully prepared, and the composite with 5 wt% showed a decrease in tensile strength and elongation, and remarkable improvement in thermal properties.

Enhancement of Nucleate Pool Boiling of a Wire-Wrapped Tube (와이어붙이관의 핵비등 열전달촉진)

  • 김내현;김정식;남기일
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.5
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    • pp.1235-1244
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    • 1994
  • In this study, experimental results of the nucleate boling of wire-wrapped tubes are provided. Both water and R-113 were boiled. Solid stainless steel wires, stranded copper wires and stranded nylon wires were tested. Solid stainless wire is effective to enhance the boiling of water. The performance is approximately the same(or slightly better at certain conditions) as that of GEWA-T tubes. For the test range of wire diameter 0.6 $mm{\le}d{\le}2.6 mm$, the optimum gap width increases as the wire diameter increases. The maximum heat transfer coefficient was obtained for the 1.0 mm diameter wire, and it is 1.6 times larger than that of the GEWA-T at the heat flux of 20 $kW/m^{2}.$ Solid stainless wire is also effective to enhance the boling of R-113 at low heat fluxes. The performance of the wire-wrapped tube approaches that of GEWA-T. At high heat fluxes, however, the enhancement decreases. The reason may be attributed to the cavity shape and the high wettability of the refrigerants. Stranded copper or nylon wire is effective to enhance the boiling of R-113. The performance is approximately the same(or slightly better) as that of GEWA-T tubes. Maximum heat transfer was obtained for the stranded nylon wire, and it is approximately 1.4 times larger than that for the GEWA-T at the heat flux of 20 $kW/m^{2}.$ The reason may be atrributed to the favorable thermal environment in the restricted regions formed by twisted wires.

Investigation of Surface Morphology for Nylon 4,6 Thin Film by Molecular Layer Deposition

  • Gwon, Deok-Hyeon;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.419-419
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    • 2012
  • We fabricated the Polyamide 4,6 (PA46) thin film using Adipoyl chloride and 1,4-butadiamine. PA46 film was grown at $70^{\circ}C$ by Molecular Layer Deposition (MLD) method. MLD is sequential and self-terminating fabrication method for organic thin film. The growth rate of PA46 is $3.5{\acute{\AA}}$ cycle. The thickness of PA46 film was measured by Ellipsometer. Surface morphology of this film was investigated by Atomic Force Microscopy (AFM) and roughness is directly proportional to number of growing cycles.

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A Study on the Mechanical and Physical Properties of Sawdustboard combined with Plastic Chip (플라스틱칩 결체(結締) 톱밥보드의 기계적(機械的) 및 물리적(物理的) 성질(性質)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Suh, Jin-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.3
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    • pp.44-55
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    • 1987
  • In order to study the effect of sawdustboard combined with plastic chips, 0.5mm($T_1$), 1mm($T_2$), 1.4mm($T_3$) thick nylon fiber. polypropylene rope fiber(RP), and 0.23mm thick moth-proof polypropylene net fiber(NP) were cut into 0.5, 1, 2cm long plastic chips. Thereafter, sawdustboard combined with plastic chips prepared as the above and plastic non-combined sawdustboard(control) were manufactured into 3 types of one-, two-, and three layer with 5 or 10% combination level. By the discussions and results at this study, the significant conclusions of mechanical and physical properties were summarized as follows: 1. The MORs were shown in the order of 3 layer> 2 layer> 1 layer among plastic non-combined boards, and $T_3$ < $T_2$ < $T_1$ < RP (NP(5%) < NP(l0%) among plastic combined boards. In 2cm long plastic chip in 1 layer board, the highest strength through all the composition was recognized. 1 layer board showing the lower strength with 0.5cm plastic chip rendered to the bending strength improvement by 2 or 3 layer board composition. On the other hand, 2 or 3 layer combined with 1, 2cm long polypropylene net fiber chips incurred MOR's conspicuous decrease requiring optimum plastic chip combined level and consideration to combined type. 2. MOE in plastic non-combined 3 layer board exhibited sandwich construction effect by higher resin content application to surface layer in the order of 3layer>1layer>2layer with the highest stiffness of the board combined with polypropylene chip, while nylon chip-combined board had little difference from plastic non-combined board. In relevant to length and layer effect, 3 layer board combined with the 0.5cm long polypropylene net fiber chip in 5% and 10% combined level presented 34-43% and 44-76% stiffness increase against plastic non-combined board(control), respectively. Moreover, in 1 layer board, 30% stiffness increase with 10% against 5% combined level in the 1 and 2cm long polypropylene net fiber chip was obtained. 3. Stress at proportional limit(Spl) showing the fiber relationship (r: 0.81-0.97) between MOR presented in the order of 1 layer<2 layer<3 layer in plastic non-combined board. Correspondingly, combined effect by layer and plastic chip length was similar to MOR's. 4. Differently from previous properties(MOR, MOE, Spl). work to maximum load(Wml) of 2 layer board approached to that of 3 layer board. Conforming the above phenomenon. 2 layer combined with 0.5cm long polypropylene net fiber chip kept the greater work than 1 layer. The polypropylene combined board superior to nylon -and plastic non - combined board seemed to have greater anti - failing capacity. 5. Internal bond strength(IB), in contrast to MOR's tendency. showed in the order of T1

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Studies on Electrostatic Propensity of Fabrics (직물대전성에 관한 연구)

  • 최병희;배도규
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.54-63
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    • 1985
  • This studies has been carried out how to effect on electrostafic propensity of synthetic fabrics by coating with 0.5% acrylic polymer solution which was previously developed by the author to improve anticrease nature of silk. The work conditions are: (A) Applied synthetic polymer was acrylic polymer 525, developed by the author. (B) Electrostatic voltage for various fabrics were carried out by Korea standard abrasion partner with Korea standard (KS K 0905) cotton, nylon, polyester and the self sample fabric. (C) Applied fabrics for the investigations were carried out by using abrasion partner with Korea standard (KS K 0905) cotton, nylon, polyester and the self sample fabric. (D) Electrostatic propensity investigations were carried out by use of sample as silk, nylon, polyester and acrylic fabrics, seperating before finish or after finish. (E) Washing after the finish or the original fabric was carried out by Korea standard method, KS K 0465. Through the investigations, he happened to find many interesting matters and the obtained results are as followings. 1. Electrostatic voltage for the finished fabrics increased more than their original silk, nylon, acrylic fabrics except polyester fabric. (See Table 5) 2. Electrostatic voltage for the finished polyester against K.S. polyester decreased remarkably than the original fabric test. 3. In spite of no problem on electrostatic propensity of silk, it showed high electrostatic voltage between the same nature fabric abrasion, because silk is very weak against abrasion and because the test method had been developed to be useful for only synthetic fabrics. 4. Electrostatic voltage increased more in case of abrasion between different nature of fabrics than the same nature of fabrics. 5. Electrostatic voltage of each fabric increased by repeat of wash. 6. Many investigation data were followed with Contact Electrification Series Principle, another word, the farther each other located fabric on the series abrasion was, the higher electrostatic voltage. (See Fig. 6) 7. Such investigation gives warning of use on the mix fiber spinning service as far as concern with electrification. 8. It may also call attention for such increase of electrification in case any finishing of silk textile.

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