• Title/Summary/Keyword: number of cycles

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In Situ X-ray Photoemission Spectroscopy Study of Atomic Layer Deposition of $TiO_2$ on Silicon Substrate

  • Lee, Seung-Youb;Jeon, Cheol-ho;Kim, Yoo-Seok;Kim, Seok-Hwan;An, Ki-Seok;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.222-222
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    • 2011
  • Titanium dioxide (TiO2) has a number of applications in optics and electronics due to its superior properties, such as physical and chemical stability, high refractive index, good transmission in vis and NIR regions, and high dielectric constant. Atomic layer deposition (ALD), also called atomic layer epitaxy, can be regarded as a special modification of the chemical vapor deposition method. ALD is a pulsed method in which the reactant vapors are alternately supplied onto the substrate. During each pulse, the precursors chemisorb or react with the surface groups. When the process conditions are suitably chosen, the film growth proceeds by alternate saturative surface reactions and is thus self-limiting. This makes it possible to cover even complex shaped objects with a uniform film. It is also possible to control the film thickness accurately simply by controlling the number of pulsing cycles repeated. We have investigated the ALD of TiO2 at 100$^{\circ}C$ using precursors titanium tetra-isopropoxide (TTIP) and H2O on -O, -OH terminated Si surface by in situ X-ray photoemission spectroscopy. ALD reactions with TTIP were performed on the H2O-dosed Si substrate at 100$^{\circ}C$, where one cycle was completed. The number of ALD cycles was increased by repeated deposition of H2O and TTIP at 100$^{\circ}C$. After precursor exposure, the samples were transferred under vacuum from the reaction chamber to the UHV chamber at room temperature for in situ XPS analysis. The XPS instrument included a hemispherical analyzer (ALPHA 110) and a monochromatic X-ray source generated by exciting Al K${\alpha}$ radiation (h${\nu}$=1486.6 eV).

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A Study on the Fatigue Failure Behavior of Cheon-Ho Mt. Limestone Under Cyclic Loading (천호산 석회암의 반복하중에 의한 피로파괴거동에 관한 연구)

  • Lee, Jong-Uk;Rhee, Chan-Goo;Kim, Il-Jung;Kim, Yeong-Seok
    • Nuclear Engineering and Technology
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    • v.24 no.1
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    • pp.98-109
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    • 1992
  • In this study uniaxial cyclic loading tests were performed on Cheon-Ho Mt. Limestone specimens to investigate the fatigue failure behavior. The loading rate was kept constantly at 760kg/$\textrm{cm}^2$/sec under cyclic loading. In order to reveal the fatigue behavior for each rock type, the test results were mutually compared with previous studies carried out on Indiana Limes-tone and Seong-Ju Sandstone. Fatigue data is presented in the form of S-N curves, which illustrate the relationship of maximum applied stress(S) to the number of cycles(N) required to produce failure. For the purpose of comparing the S-N curves for each rock type, the test data were formulated up to 10$^4$cycles and the correlation coefficients(R) on Cheon-Ho Mt. Limestone and Seong-Ju Sandstone specimen are 0.886 and 0.983, respectively. All three rock specimens were found to have shorter fatigue life at higher applied stress levels. The fatigue life for each rock type was considered as no less than 81.5, 70 and 74.8%, for Cheon-Ho Mt. Limestone, Indiana Limestone and Seong-Ju Sandstone, respectively. The comparison in static strength for monotonic loaded specimens and specimens which did not fail even after 10$^4$cycles indicated that the increasing rate of strength was about 6.18 and 10.96% , for Cheon-Ho Mt. Limestone and Indiana Limestone, respectively. Poisson's ratio and volumetric strain for Cheon-Ho Mt. Limestone and Seong-ju Sandstone, tended in all the cases to rapidly increase at higher stress levels and with an increase in number of cycles. This increasing trend becomes rapid and obvious just before failure. Also Poisson's ratio and volumetric strain for each stress level were compared and analyzed at the first cycle and the cycle prior to failure.

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Development of Optimized State Assignment Technique for Testing and Low Power (테스팅 및 저전력을 고려한 최적화된 상태할당 기술 개발)

  • Cho Sangwook;Yi Hyunbean;Park Sungju
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.1
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    • pp.81-90
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    • 2004
  • The state assignment for a finite state machine greatly affects the delay, area, power dissipation, and testabilities of the sequential circuits. In order to improve the testabilities and power consumption, a new state assignment technique . based on m-block partition is introduced in this paper. By the m-block partition algorithm, the dependencies among groups of state variables are minimized and switching activity is further reduced by assigning the codes of the states in the same group considering the state transition probability among the states. In the sequel the length and number of feedback cycles are reduced with minimal switching activity on state variables. It is inherently contradictory problem to optimize the testability and power consumption simultaneously, however our new state assignment technique is able to achieve high fault coverage with less number of scan nfp flops by reducing the number of feedback cycles while the power consumption is kept low upon the low switching activities among state variables. Experiment shows drastic improvement in testabilities and power dissipation for benchmark circuits.

A Design of Interger division instruction of Low Power ARM7 TDMI Microprocessor (저전력 ARM7 TDMI의 정수 나눗셈 명령어 설계)

  • 오민석;김재우;김영훈;남기훈;이광엽
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.41 no.4
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    • pp.31-39
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    • 2004
  • The ARM7 TDMI microprocessor employ a software routine iteration method in order to handle integer division operation, but this method has long execution time and many execution instruction. In this paper, we proposed ARM7 TDMI microprocessor with integer division instruction. To make this, we additionally defined UDIV instruction for unsigned integer division operation and SDIV instruction for signed integer division operation, and proposed ARM7 TDMI microprocessor data Path to apply division algorithm. Applied division algorithm is nonrestoring division algorithm and additive hardware is reduced using existent ARM data path. To verify the proposed method, we designed proposed method on RTL level using HDL, and conducted logic simulation. we estimated the number of execution cycles and the number of execution instructions as compared proposed method with a software routine iteration method, and compared with other published integer divider from the number of execution cycles and hardware size.

Effect of fuel octane number on knock characteristics in a spark-ignition engine (연료의 옥탄가 변화에 따른 스파크 점화기관의 노킹특성의 변화)

  • 이홍철;전광민
    • Journal of the korean Society of Automotive Engineers
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    • v.14 no.5
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    • pp.61-68
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    • 1992
  • Knock phenomenon is an abnormal combustion originated from autoignition of unburned gas in the end-gas region during the later stage of combustion process and it accompanys a high pitched metallic noise. Engine Knock is accompanied with a vibration of engine cylinder and when it is severe, it can cause major engine demage. Engine Knock is characterized in terms of knock crank angle, knock pressure, pressure jump and knock intensity. In this study, a 4-cylinder spark ignition engine was used for experiment and eighty consecutive cycles were analyzed statistically. The purpose of this study is to characterize spark ignition engine knock as a function of ignition timing and fuel research octane number. The result of this study can be summerized as follows. Knock occurrence angle approached TDC as ignition timing is advanced. Pressure and knock intensity gradually increased as spark timing is advanced. Mean knock occurence angle gradually approached TDC as fuel research octane number is decreased for identical spark timing. Knock intensity increased linearly as RON is decreased.

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Experimental study on rock-concrete joints under cyclically diametrical compression

  • Chang, Xu;Guo, Tengfei;Lu, Jianyou;Wang, Hui
    • Geomechanics and Engineering
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    • v.17 no.6
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    • pp.553-564
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    • 2019
  • This paper presents experimental results of rock-concrete bi-material discs under cyclically diametrical compression. It was found that both specimens under cyclical and static loading failed in three typical modes: shear crack, tensile crack and a combined mode of shear and wing crack. The failure modes transited gradually from the shear crack to the tensile one by increasing the interface angle between the interface and the loading direction. The cycle number and peak load increased by increasing the interface angle. The number of cycles and peak load increased with the interface groove depth and groove width, however, decreased with increase in interface groove spacing. The concrete strength can contribute more to the cycle number and peak load for specimens with a higher interface angle. Compared with the discs under static loading, the cyclically loaded discs had a lower peak load but a larger deformation. Finally, the effects of interface angle, interface asperity and concrete strength on the fatigue strength were also discussed.

Improvement of Pregnancy Rates by Coculture of Human Embryos with Cumulus Cells in Glucose and Phosphate Free M-TALP Media (Glucose와 Phosphate가 제거된 M-TALP 배지에서의 난구세포 공배양에 의한 임신율 향상에 관한 연구)

  • Chung, B.S.;Chang, W.H.;Lee, M.H.;Kim, J.Y.;Bang, J.H.;Kim, K.H.;Suh, T.K.
    • Clinical and Experimental Reproductive Medicine
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    • v.26 no.1
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    • pp.75-81
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    • 1999
  • The beneficial effect of glucose and phosphate ions in culture medium on the development of human embryos in vitro has not been fully elucidated. The purpose of this study was to evaluate the influence of fertilization and culture of embryos in glucose/phosphate-free m-TALP medium on pregnancy rates in IVF-ET program. The patients in 244 IVF-ET cycles received GnRH agonist + HMG regimens. A does of 10,000 IU HCG was administered when two or more dominent follicles reached 18mm in diameter. Thirty-six hours after HCG, oocytes were recovered transvaginally using ultrasound guidance. Aspirated oocytes were matured for 4 to 6 h in TCM-199 supplemented with 10% follicular fluid (FF). Insemination was carried out with 50,000 motile spermatozoa in TCM-199 + 10% FF or m-TALP + 5% FF + 5% fetal cord serum (FCS) according to experimental design. After 6 h, oocytes were washed 3 to 4 times and cultured in each fresh medium. After 20 h, oocytes were freed from cumulus/corona cells and examined for the presence of pronuclei. Fertilized oocytes were transferred into each co-culture drops and cultured for further incubation. On day 3, embryo transfer was performed with grade 1 and 2 embryos. Monolayers for co-culture of embryos were prepared by plating $1{\times}10^5$ cumulus cells/ml in 10ul drop of TCM-199 + 10% FF or m-TALP + 5% FF + 5% FCS media 24 h prior to the onset of co-culture. Development to 4 to 16 cell stage was observed at 70x magnification following two days of incubation. Pregnancy was confirmed by detecting increasing serum ${\beta}$-hCG concentrations for 11 days following embryo transfer. Data were analyzed by ${\chi}^2$-test. Oocytes from 244 IVF-ET cycles were randomized. The number of cycles and mean age of patients were 97 and 147, 31.3 yrs and 31.2 yrs for TCM-199 (control) and m-TALP groups, respectively. The mean number of retrieved oocytes/cycle, fertilization rates, number of embryos transferred/ET and pregnancy rates were 11.1 and 10.3, 65.1% and 67.3%, 4.1 and 4.7, 28.9% and 43.8% for TCM-199 and m-TALP groups, respectively. Differences in the pregnancy rates were found between control and m-TALP groups (p<0.05). The pregnancy rate of patients divided according to maternal age groups of ${\leq}30$, 31-35, $36{\leq}$ were 44.4% and 49.0%, 26.1% and 41.3%, 29.2% and 41.2% for control and m-TALP groups, respectively. These data indicate that culture of human embryos in glucose/phosphate-free m-TALP medium improves pregnancy rates.

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Lateral Behavior of Driven Piles Subjected to Cyclic Lateral Loads in Sand (모래지반에서 반복수평하중을 받는 항타 말뚝의 수평거동)

  • Paik, Kyu-Ho
    • Journal of the Korean Geotechnical Society
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    • v.26 no.12
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    • pp.41-50
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    • 2010
  • The behavior of laterally cyclic loaded piles is different from that of piles under monotonic loading and depends on soil and load characteristics. In this study, model pile load tests were performed using a calibration chamber to investigate the effects of load characteristics on the behavior of laterally cyclic loaded piles in sand. Results of the model tests show that the ultimate lateral load capacity of laterally cyclic loaded piles decreases linearly with increasing the number of cycles and increases slightly with increasing the magnitude of cyclic lateral loads. When the piles reach the ultimate state, the maximum bending moment developed in the piles decreases linearly with increasing the number of cycles and it occurs at a depth of 0.36 times pile embedded length for all the number of cycles. However, both the magnitude and depth of the maximum bending moment of piles in the ultimate state increase slightly as the magnitude of cyclic lateral loads increases. It is also observed that the cyclic lateral loading generates a decrease in the ultimate lateral load capacity and maximum bending moment for piles in the ultimate state. In addition, based on the model test results, a new empirical equation for the ultimate lateral load capacity of laterally cyclic loaded piles in dense sand is also proposed. A comparison between predicted and measured load capacities shows that the proposed equation reflects satisfactorily the model test results.

Effects of Multiple-Cycle Operation and SO2 Concentration on CO2 Capture Capacity of Three Limestones in a Fluidized Bed Reactor (유동층 반응기에서 세 가지 석회석의 CO2 흡수능력에 미치는 반복횟수와 SO2 농도의 영향)

  • Ryu, Ho-Jung
    • Applied Chemistry for Engineering
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    • v.17 no.1
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    • pp.44-51
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    • 2006
  • Effects of multiple-cycle operation and $SO_2$ concentration on $CO_2$ capture characteristics of three limestones were investigated in a fluidized bed reactor. For each of these sorbents, the measured $CO_2$ capture capacity decreased as the number of cycles increased and as the $SO_2$ concentration increased. On the other hand, the $SO_2$ capture increased with the increased number of cycles and the $SO_2$ concentration. The total calcium utilization decreased as the number of cycles increased, but the effect of $SO_2$ concentrations on the total calcium utilization depended on the type of limestone. For Strassburg limestone, the total calcium utillization decreased with increasing $SO_2$ concentration. However, for Luscar and Danyang limestones, the total calcium utilization was almost independent of $SO_2$ concentration for the range investigated. The results showed that $SO_2$ in flue gas reduced the $CO_2$ capture capacity of limestone and that the sulfation pattern affected the $CO_2$ capture capacity.

Fabrication of LiMn2O4 Thin-Film Rechargeable Batteries by Sol-Gel Method and Their Electrochemical Properties (졸-겔 방법을 이용한 LiMn2O4 박막 이차 전지 제작 및 전기화학적 특성 조사)

  • Lee, J.H.;Kim, K.J.
    • Journal of the Korean Vacuum Society
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    • v.20 no.3
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    • pp.205-210
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    • 2011
  • Structural and electrochemical properties of spinel oxide $LiMn_2O_4$ thin films prepared by using a sol-gel method on Pt/Ti/$SiO_2$/Si substrates were investigated. When Li/Mn molar ratio of the film was smaller than 0.5, $Mn_2O_3$hase was found to coexist with $LiMn_2O_4$. Half-cell batteries fabricated using the $LiMn_2O_4$ films as the cathode were put into chargedischarge (C-D) cycles and the change in structural properties of the cathode after the cycles was examined by X-ray diffraction and Raman spectroscopy. As the C-D cycle number increases, the discharge capacity of pure $LiMn_2O_4$ battery gradually decreases, being reduced to 72% of the initial capacity at 300 cycles. Such capacity fading is attributable to the decrease in the number of $Li^+$ ions that return to the tetrahedral sites of the spinel structure during the discharge step and the resultant increase in $Mn^{4+}$ density in the film. Also, $Mn_2O_3$ phase gradually appeared in the film as the cycle number increases.