• 제목/요약/키워드: nucleation

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Vapor Bubble Nucleation : A Microscopic Phenomenon

  • Kwak, Ho-Young
    • Journal of Mechanical Science and Technology
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    • 제18권8호
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    • pp.1271-1287
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    • 2004
  • In this article, vapor bubble nucleation in liquid and the evaporation process of a liquid droplet at its superheat limit were discussed from the viewpoint of molecular clustering (molecular cluster model for bubble nucleation). For the vapor bubble formation, the energy barrier against bubble nucleation was estimated by the molecular interaction due to the London dispersion force. Bubble nucleation by quantum tunneling in liquid helium under negative pressure near the absolute zero temperature and bubble nucleation on cavity free micro heaters were also presented as the homogenous nucleation processes.

Investigation on HT-AlN Nucleation Layers and AlGaN Epifilms Inserting LT-AlN Nucleation Layer on C-Plane Sapphire Substrate

  • Wang, Dang-Hui;Xu, Tian-Han
    • Journal of the Optical Society of Korea
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    • 제20권1호
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    • pp.125-129
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    • 2016
  • In this study, we have investigated a high-temperature AlN nucleation layer and AlGaN epilayers on c-plane sapphire substrate by low-pressure metal-organic chemical vapor deposition (LP-MOCVD). High resolution X-ray diffraction (HRXRD), atomic force microscopy (AFM), scanning electron microscope (SEM) and Raman scattering measurements have been exploited to study the crystal quality, surface morphology, and residual strain of the HT-AlN nucleation layer. These analyses reveal that the insertion of an LT-AlN nucleation layer can improve the crystal quality, smooth the surface morphology of the HT-AlN nucleation layer and further reduce the threading dislocation density of AlGaN epifilms. The mechanism of inserting an LT-AlN nucleation layer to enhance the optical properties of HT-AlN nucleation layer and AlGaN epifilm are discussed from the viewpoint of driving force of reaction in this paper.

고분자 포움의 초음파 가공 (Ultrasonic Processing of Polymer Foam)

  • 변성광;윤재륜
    • 대한기계학회논문집
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    • 제13권4호
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    • pp.618-624
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    • 1989
  • 본 연구의 목적은 낮은 포화 압력하에서의 초음파에 의한 미세포 포움 구조 획득의 가능성을 평가하기 위한 것으로, 이 초음파 가공을 고분자 포움의 연속적인 압출 가공에 적용하기 위한 기초 연구를 이론적 및 실험적으로 수행함에 있다.따라서 미세포구조의 획득이 본 연구의 목적은 아니며 초음파를 이용한 열가소성 수지내의 핵생성 거동에 대한 고찰을 하고자 한다.

Nucleation of CVD Diamond on Various Substrate Materials

  • Fukunaga, O.;Qiao, Xin;Ma, Yuefei;Shinoda, N.;Yui, K.;Hirai, H.;Tsurumi, T.;Ohashi, N.
    • The Korean Journal of Ceramics
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    • 제2권4호
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    • pp.184-187
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    • 1996
  • Diamod nucleation by mw assisted CVD was examined various conditions namely, (1) diamond nucleation on variour substrate materials, such as Si, cubic BN, pyrolytic BN and AIN, (2) AST(Activated species transport) method which promote nucleation of diamond on single crystal and polycrystalline alumina substrate was developed. (3) Effect of bias enhancement of nucleation on single crystalline Si was examined, and finally (4) DST (Double step treatment) method was developed to enhance diamond nucleation on Ni. In this method, we separated carbon diffusing process into Ni, carbon precipitating process from the inside of Ni and diamond precipitation process.

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사각 마이크로 히터위에서의 기포의 형성 및 거동 (Bubble Nucleation and Behavior on Square Micro Heaters)

  • 정정열;곽호영
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1464-1469
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    • 2004
  • In this study, micro square heaters having dimensions of $65{\times}65{\mu}m^2$and $100{\times}100{\mu}m^2$ were fabricated and bubble nucleation experiments on the heaters were performed. Bubble nucleation temperature was also measured using a bridge circuit and the photographs of bubble nucleation and subsequent growth were taken by a camera with a flash unit. Measured bubble nucleation temperatures were found to be closer to the superheat limit of working fluid (FC-72). Also quasi-1D analyses for the square heaters were performed. The quasi-1D analysis yielded proper temperature distribution of the square heater at steady state, however failed to predict the temperature rise up to the steady state. Similar time dependent temperature can be obtained with proper value of thermal diffusivity. For the $100{\times}100{\mu}m^2$ square heater, nucleation of several bubbles was observed while only one bubble was observed to be nucleated on $65{\times}65{\mu}m^2$ heater.

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Nucleation Theory

  • 곽호영
    • 기계저널
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    • 제22권1호
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    • pp.34-39
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    • 1982
  • 본 해설에서는 nucleation현상의 한 예로 과포화상태에 있는 증기 (vapor)의 응축과 정(condensation)을 중심으로 설명하고자 한다. 제 2절에서는 nucleation 현상의 예와 그 응용에 대해서 설명하기로 하고 제 3절에서는 열역학적인 면에서 제 4절은 운동론적인 면에서 제 5절은 nucleation theory의 문제점에 관해 고찰해 보려 한다.

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고분자 용액에서의 기포 형성 (Bubble Nucleation in Polymer Solutions)

  • 강성린;김기영;곽호영
    • 폴리머
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    • 제28권1호
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    • pp.51-58
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    • 2004
  • 탄성체 (가교된 고분자) 가스가 용해된 고분자 또는 유기 용매에 용해된 고분자 용액에서 기포 생성을 예측하기 위하여 균일한 기포 생성은 고전적인 이론에서의 임계 기포의 생성이 아닌 임계 뭉치의 생성을 통하여 이루어진다는 분자 뭉치 이론을 적용하였다. 또한 탄성체나 고분자 내에서 기포가 생성하는 경우 임계 기포가 극복해야 할 탄성 에너지를 고려하였다. 대략 $10^{8}$$10^{12}$개에 달하는 분자 뭉치 이론에 의해 계산된 단위 부피당 생성된 기포 수는 실험치와 잘 일치하였다.

폴리머 용액에서의 기포 형성 (Bubble Nucleation in Polymer Solutions)

  • 강성린;김기영;곽호영
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1228-1233
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    • 2003
  • The molecular cluster model for the homogeneous bubble nucleation was extended to predict the bubble nucleation events in elastomers, polymers and polymer solutions. For the bubble nucleation in elastomers and polymers, the strain energy overcome by a critical bubble was also considered. The calculation results for the number of bubbles nucleated are in good agreement with observed ones.

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Nucleation Layer의 표면 거칠기가 GaAs 기판 위에 성장된 InP 에피층의 품질에 미치는 영향 (Effects of Nucleation Layer's Surface Roughness on the Quality of InP Epitaxial Layer Grown on GaAs Substrates)

  • 유충현
    • 한국전기전자재료학회논문지
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    • 제25권8호
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    • pp.575-579
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    • 2012
  • Heteroepitaxial InP films have been grown on GaAs substrates to study the effects of the nucleation layer's surface roughness on the epitaxial layer's quality. For this, InP nucleation layers were grown at $400^{\circ}C$ with various ethyldimethylindium (EDMIn) flow rates and durations of growth, annealed at $6200^{\circ}C$ for 10 minutes and then InP epitaxial layers were grown at $550^{\circ}C$. It has been found that the nucleation layer's surface roughness is a critical factor on the epitaxial layer's quality. When a nucleation layer is grown with an EDMIn flow rate of 2.3 ${\mu}mole/min$ for 12 minutes, the surface roughness of the nucleation layer is minimum and the successively grown epitaxial layer's qualities are comparable to those of the homoepitaxial InP layers reported. The minimum full width at half maximum of InP (200) x-ray diffraction peak and that of near-band-edge peak from a 4.4 K photoluminescence are 60 arcmin and 6.33 meV, respectively.

Immiscibility, nucleation and mechanical properties in the lithia-baria-silica system

  • Ertug, Burcu
    • Journal of Ceramic Processing Research
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    • 제19권5호
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    • pp.394-400
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    • 2018
  • The current work investigates the effects of nucleation heat treatments, on the microstructure and mechanical properties of a novel silicate glass in $Li_2O-BaO-SiO_2$ system with 1 mol% $P_2O_5$ as nucleating agent. As-cast glass was exposed to nucleation heat treatments at $490-550^{\circ}C$ for 1-3 h. The microstructural examination was performed by SEM/EDS. The highest Vickers microhardness was determined to be 650 Hv for the sample heat treated at $550^{\circ}C$ for 1 h. The increase in the nucleation time also affected Vickers microhardness and the highest one was determined to be 600 Hv after nucleation for 3 h. The fracture toughness, $K_{IC}$ reached $2.51MPa.m^{1/2}$ after nucleation at $550^{\circ}C$ for 1 h. The nucleation temperatures had a more pronounced effect on the fracture toughnesses in comparison to nucleation times. The indentation toughness data was used to determine Weibull parameters from Ln ln [1/(1-P)]-$lnK_{IC}$ plots. Weibull modulus, m of the samples nucleated at 500, 510, 530, $550^{\circ}C$ for 1h. and $540^{\circ}C$ for 2 h. were determined similarly to be 3.8, 3.5, 4.7 and 3.9, respectively. The rest of the samples indicated higher Weibull moduli, which may be attributed to the formations of microcracks due to the mismatch in between newly formed crystals and remaining glassy matrix.