• Nano
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• v.13 no.12
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• pp.1850145.1-1850145.8
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• 2018

In this study, a double-solvent radiation method is proposed to prepare silver nanoparticles in the pores of metal-organic framework MIL-101(Cr). The results reveal that well-dispersed silver nanoparticles with a diameter of about 2 nm were successfully fabricated in the cages of monodisperse octahedral MIL-101(Cr) with a particle size of about 400 nm. The structure of MIL-101(Cr) was not destroyed during the chemical treatment and irradiation. The resulting Ag/MIL-101 exhibits excellent catalytic performance for the reduction of 4-nitrophenol. This method can be extended to prepare other single or bimetallic components inside porous materials.

• 한국초전도학회:학술대회논문집
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• v.12
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• pp.72-72
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• 2002

• 한국초전도학회:학술대회논문집
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• v.12
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• pp.84-84
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• 2002

• Proceedings of the Korean Magnestics Society Conference
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• 2007.05a
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• pp.22.1-22.1
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• 2007

• 한국초전도학회:학술대회논문집
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• v.13
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• pp.90-90
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• 2003

• 한국초전도학회:학술대회논문집
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• v.14
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• pp.72-72
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• 2004

• Proceedings of the Korean Nuclear Society Conference
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• 2005.10a
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• pp.967-968
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• 2005

• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.1972-1981
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• 2022

A typical ferritic/martensitic (F/M) steel sheet was subjected to pulsed laser surface remelting (LSR) and corrosion test in lead-bismuth eutectic (LBE) at 550 ℃. There present two modification zones with distinct microstructures in the LSRed specimen: (1) remelted zone (RZ) consisting of both bulk δ-ferrite grains and martensitic plates and (2) heat-affected zone (HAZ) below the RZ, mainly composed of martensitic plates and high-density precipitates. Martensitic transformation occurs in both the RZ and the HAZ with the Kurdjumov-Sachs and Nishiyama-Wassermann orientation relationships followed concurrently, resulting in scattered orientations and specific misorientation characteristics. Hardnesses of the RZ and the HAZ are 364 ± 7 HV and 451 ± 15 HV, respectively, considerably higher than that of the matrix (267 ± 3 HV). In oxygen-saturated and oxygen-depleted LBE, thicknesses of oxide layers developed on both the as-received and the LSRed specimens increase with prolonging corrosion time (oxide layers always thinner under the oxygen-depleted condition). The corrosion resistance of the LSRed F/M steel in oxygen-saturated LBE is improved, which can be attributed to the grain-refinement accelerated formation of dense Fe-Cr spinel. In oxygen-depleted LBE, the growth of oxide layers is very low with both types of specimens showing similar corrosion resistance.

• Corrosion Science and Technology
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• v.15 no.5
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• pp.245-252
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• 2016

The pipelines and equipments are degraded by flow-accelerated corrosion (FAC), and a large-scale test facility was constructed for simulate the FAC phenomena in secondary coolant environment of PWR type nuclear power plants. Using this facility, FAC test was performed on weld pipe (carbon steel and low alloy steel) at the conditions of high velocity flow (> 10 m/s). Wall thickness was measured by high temperature ultrasonic monitoring systems (four-channel buffer rod type and waveguide type) during test period and room temperature manual ultrasonic method before and after test period. This work deals with the complex effects of flow velocity on the wall thinning in weld pipe and the test results showed that the higher flow velocity induced different increasement of wall thinning rate for the carbon steel and low alloy steel pipe.

• Nuclear Engineering and Technology
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• v.49 no.4
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• pp.760-768
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• 2017

The transition temperature shift (TTS) of the reactor pressure vessel materials is an important factor that determines the lifetime of a nuclear power plant. The prediction of the TTS at the end of a plant's lifespan is calculated based on the equation of Regulatory Guide 1.99 revision 2 (RG1.99/2) from the US. The fluence factor in the equation was expressed as a power function, and the exponent value was determined by the early surveillance data in the US. Recently, an advanced approach to estimate the TTS was proposed in various countries for nuclear power plants, and Korea is considering the development of a new TTS model. In this study, the TTS trend of the Korean surveillance test results was analyzed using a nonlinear regression model and a mixed-effect model based on the power function. The nonlinear regression model yielded a similar exponent as the power function in the fluence compared with RG1.99/2. The mixed-effect model had a higher value of the exponent and showed superior goodness of fit compared with the nonlinear regression model. Compared with RG1.99/2 and RG1.99/3, the mixed-effect model provided a more accurate prediction of the TTS.