• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2002년도 추계학술발표회요약집
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• pp.319.2-319
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• 2002

Synchrotron-based X-ray absorption spectroscopy has been applied to determine the changes in bulk oxidation state of uranium oxides in molten salt. From an analysis of XANES data, one can determine the cahnges in bulk oxidation-state of U compounds in salts(LiCl/KCl). XAFS spectroscpy is a powerful tool for probing the changes in valence state and structure of uranium compounds in colten salt as well as in noncrystalline form and doped in other matrices.

• 한국결정성장학회지
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• 제4권3호
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• pp.315-324
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• 1994

고순도 규사 원료를 열처리하는 경우, 불순물로 포함되어 있는 미량성분이 quartz의 전이과정에 미치는 영향 및 전이 경로에 대하여 조사하였다. 미량성분의 영향을 조사한 결과, 규사 중의 미량성분 함량이 많아지면 cristobalite 생성량은 많아지며, quartz의 소멸온도 및 cristobalite의 생성온도는 낮아졌다. quartz의 전이경로를 조사한 결과 quartz $\rightarrow$ 천이비정질상 $\rightarrow$ melt (T) 및 quartz $\rightarrow$ 천이비정질상 $\rightarrow$ cristobalite $\rightarrow$ melt (C)의 경로가 항상 공존하며, 미량성분이 적은 경우는 T 경로가 우세하지만, 미량성분이 많은 경우는 C 경로가 우세한 것으로 규명되었다. 또한 XRD를 이용한 결정질 함량의 분석 결과로 부터 계산한 밀도와 pycnometer로 측정한 밀도를 비교한 결과 서로 일치하였다. 규사를 용융하여 석영유리를 제조하는 경우,특정온도에서 규사의 팽창 정도를 유추할 수 있을 것이다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 봄 학술발표회 논문집
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• pp.135-139
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• 1998

Poly(vinyl acetate) (PVAc) from which atactic poly(vinyl alcohol) (PVA) is derived, is always noncrystalline. This was attributed to the irregular steric arrangement of the acetyl groups in PVAc. However, the X-ray diffraction patterns of atactic PVA, a derivative of PVAc, were found to show distinct crystallinity, and to give an identity period of 2,52 ${\AA}$ along the fiber axis, despite the expectation of an irregular arrangement of the hydroxyl groups in atactic PVA, in the same manner as that of the acetyl groups in PVAc.(omitted)

• 한국진공학회지
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• 제5권1호
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• pp.1-5
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• 1996

Noncrystalline films of diamond-like carbon (DLC) have been prepared by laser ablation technique at room temperature. A Q-switched Nd-YAG laser beam with wavelength of 1064 nm and pulse duration of 10 ns was focused onto a graphite target with power densities of about $10^9 W/\textrm{cm}^2$. The physical properties of the resulting films were analyzed with density, hardness, and resistivity measurements. The surface and bonding structure were investigated by atomic force microscopy (AFM), Raman spectroscopy, electron energy loss spectroscopy (EELS).

• 한국주조공학회지
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• 제23권5호
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• pp.286-290
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• 2003

본 연구에서는 Ni-Zr-Ti의 3원계 합금을 기본으로 하여, Si 및 Sn 등의 원소를 첨가하여 Ni-rich 영역에서 벌크 비정질 합금을 제조하였다. $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ 조성의 합금에서 injection casting에 의하여 약 58 K의 과냉각액상영역을 가지고 있는 직경 3 mm의 벌크 비정질 시편을 제조하였다. 이러한 우수한 비정질 형성능은 액상온도의 저하로 인해 낮은 온도까지 액상이 쉽게 과냉되기 때문인 것으로 사료된다. $Ni_{59}Zr_{20}Ti_{16}Si_5$ 합금은 두 단계에 걸쳐 결정화가 일어나는 반면, $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ 합금은 단일 단계에 의해 orthorhombic $Ni_{10}{(Zr,Ti)}_7$ 결정상과 cubic NiTi 결정상으로 결정화가 일어난다. 벌크 비정질 $Ni_{59}Zr_{20}Ti_{16}Si_2Sn_3$ 합금의 경우 압충강도는 2.7 GPa, 연신율은 약 2% 정도의 값을 가진다.

• 한국안전학회지
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• 제7권2호
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• pp.57-62
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• 1992

In this thesis, the electrification phenomenon was studied by measurement of charging current and discharging current in polymers when the carriers generated by corona discharge were supplied to the surface of polymers. Corona charging current of PVC, polar and noncrystalline polymer, was larger than that of nonpolar and amorphous polymers. Corona charging current on the specimen of naked upper surface (CIM) was larger than charging current on the specimen of electrode made. Carrier injection differed from interfacial phase of polymer surFace. The transfer phenomenon vaned with chemical structure of polymer and then the polar effect of PVC was remarkable because of large electron affinity of Cl. In the characteristics of discharging current of PVC, the abnormal current was observed. It was supposed that this phenomena presented the trap of injected carriers in PVC and that static electricity phenomenon was generated by trap.

• 한국표면공학회지
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• 제22권4호
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• pp.179-184
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• 1989

This study seeks to the morphological changes in the oxide skin of the Al-10wt.%si alloy melts. These changes depend on the oxidation time and the temperature of the molten alloy, as well as the effects of adding Mg, Cu and Ni. Thess affects observed by X-ray diffractometer(XRD) and scanning electron microscope(SEM)' Very litte oxide skins on Al-10wtwt.%Si alloy melts can be detected by XRD because it is less than the measuring capabillity of the XRD, or the formation of noncrystalline oxide skins oxide skins canbe deteced by SEM. The addition of 1%Mg and 1%Cu-1%Mg-2.5%Ni to this base alloy crystallized the structure of the oxide skins and increased the oxidation in proportion to the length of time, but adding 3% had hardiy anyaffect at all on the crystal structure of the oxide skins.

• 한국주조공학회지
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• 제24권1호
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• pp.26-33
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• 2004

The pressure of the mold flux acting on the meniscus shell was investigated through the coupling analysis of heat transfer in the mold and fluid flow in the flux caused by the mold oscillation. Finite element method was employed to solve the conservation equation associated with appropriate boundary conditions. As reported by previous workers, the axial pressure is positive on the negative strip time and negative on the positive strip time. A maximum pressure is predicted toward the top of the meniscus shell which has the thin shell arid a maximum value is in proportion to the relative mold oscillation velocity. The relative mold oscillation velocity was changed by the effect of meniscus level fluctuation. Therefore the pressure of the mold flux acting on the meniscus shell was different each cycle of the mold oscillation due to the irregularity of relative mold oscillation velocity.

• Bulletin of the Korean Chemical Society
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• 제31권5호
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• pp.1165-1171
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• 2010

The lyotropic mesomorphism of lamellar liquid crystalline phase was examined by observing the swelling behavior of Distearoylphosphatidylcholine(DSPC) in glycerin and panthenol without water. The lyotropic mesomorphism was examined by using DSC, XRDs and Cryo-SEM. Increase of two polar solvents under non-hydrous condition showed distinctive differences in the lyotropic mesomorphism from forming different anisotropic structures with DSPC. Glycerin did not affect to the crystalline region of lamellar phase, whereas typical swelling mesomorphism was shown in the noncrystalline region. In contrast, panthenol showed some effect on the crystalline region, but common swelling mesomorphism was found in the non-crystalline region. In this case, the isopropyl and propyl groups in panthenol were the main factor to affect to the lipophilic domain in the crystalline region of lamellar phase. Also, it was found that the formation of well-arranged lamellar structure only by introducing glycerin and panthenol as a solvent without water, was possible. These results were confirmed by examination of the swelling mesomorphism of liquid crystal membrane triggered by introducing the two polar solvents.

• 열처리공학회지
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• 제15권1호
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• pp.9-15
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• 2002

Deformation behavior of nickel-rich Ti-51.5at.%Ni single crystals was investigated over a wide range of temperatures(77 to 440K) and strain levels(up to 9%) in compression. These alloys combined superior strength with wide range of pseudoelasticity temperature interval(~200K). The slip deformation in [001] orientation did not occur due to the prevailing slip system, and consequently, exhibited pseudoelastic deformation at temperatures ranging from 77 to 283K and 273 to 440K for the solutionized and over-aged cases, respectively. The critical transformation stress levels were in the range of 800 to 1800MPa for the solutionized case, and 200 to 1000MPa for the over-aged case depending on the temperature and specimen orientation. These stress levels are considerably higher compared to these class of alloys having lower Ni contents. The maximum transformation strains, measured from incremental straining experiments in compression, were lower compared to the phenomenological theory with Type II twinning. A compound twinning model depending on the successive austenite(B2) to intermediate phase(R) to martensite(B19') transformation predicts lower transformation strains compared to the Type II twinning case.