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Monitoring of Particulate Matter and Analysis of Black Carbon and Some Particle Containing Toxic Trace in the City of Yaoundé, Cameroon

  • Tchuente, Siaka Y.F.;Saidou, Saidou;Yakum, N.Y.;Kenmoe, N.X.;Abdourahimi, Abdourahimi
    • Asian Journal of Atmospheric Environment
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    • v.7 no.2
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    • pp.120-128
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    • 2013
  • The concentration and composition of particulate matter (PM) in the atmosphere can directly reflect the environmental pollution. The atmospheric pollution in some Cameroonian cities is increasing with the industrial development and urbanization. Air pollution is inherently complex, containing PM of varied size and composition. This PM exists as a dynamic cloud interacting with sunlight and is modified by the meteorology. The reflectometer and the EDXRF spectrometry are applied to determine the concentration of some specific elements at four sites in the city of Yaound$\acute{e}$. The particular aim of the present work is to put in place data base on air pollution in urban area and elaborate regulations on the emissions issued to industrial and vehicle activities. This study provides an overview of the concentration of black carbon and some specific elements in the air, which have impacts on human health. The measurement was done by distinguishing the size of particle. So that, the particle with aerodynamic diameter between $2.5-10{\mu}m$ (so-called coarse particle) and aerodynamic diameter < $2.5{\mu}m$ (so-called fine particle) were considered to obtain more information about levels of the inhalable fraction of the location. The results obtained in four locations of the city of Yaound$\acute{e}$ show that the black carbon concentration is very considerable, the element sulfur is a major pollutant and the concentration of fine particle is very greater. The results obtained of fine and coarse filters range from $5-17{\mu}g/m^3$ and $10-18{\mu}g/m^3$ for the black carbon. S, Cu, Zn, Pb, Cd, As, Se and Hg are the specific findings of this work. The pollutants with a greater concentration are S, Pb, and Zn. These later seem to be non-uniformly, non-regular in some location and high compared to other countries. This work allows us to make a potential relation between pollutants and emission sources. In this framework, some suggestions have been proposed to reduce emissions for an improvement of the air quality in the environment and thus, the one of the city of Yaound$\acute{e}$.

A Comparative Study on Improvements of Non - listed Stock Valuation System of Advanced Countries (비상장주식가치평가의 국가별 비교연구)

  • Choi, Dong-choon
    • Journal of Venture Innovation
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    • v.2 no.2
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    • pp.127-140
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    • 2019
  • A stock valuation on the tax law is based on the valuation by market price. But, unlike the listed stocks, the unlisted stocks mostly have the unclear market price. Accordingly, it is necessary to calculate the fair value which corresponds to the market price. The purpose of this paper is to examine the appropriateness of the complementary valuation method in the Inheritance Tax and Gift Tax Act and to provide suggestions for improvement. This study is intended to provide the problems and solutions relating to the valuation of unlisted stocks through analysis of foreign legal systems and actual disputes. When the actual profit/loss data are used to calculate the net profit/loss value on the present regulations, it has the different weight on the latest 3 years' net profits and losses uniformly. Therefore, to extend the range of unlisted stocks valuation and to show the independent and high professionalism of appraisal council not the subsidy appraisal agency of the National Tax Service, it is necessary to change the current rule that the commissioner of the National Tax Service unilaterally appoints the private members into the method of public offering.

The nature of non-specific inhibitor and natural agglutinin for goose erythrocytes in chicken serum (계혈청(鷄血淸)에 들어 있는 뇌염(腦炎)바이러스에 대한 비특이물질 및 거위 혈구(血球)에 대한 응집소의 성상(性狀)에 관한 연구(硏究))

  • CHUNG, Y.S.
    • Korean Journal of Veterinary Research
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    • v.11 no.2
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    • pp.123-136
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    • 1971
  • (1) The non-specific inhibitors (NSI) in normal chicken sera were active against all the tested group A and group B arboviruses, but the group B arbovirus were more sensitive than group A arboviruses. (2) The titres of the NSI were distributed nearly uniformly among chickens from seven different age groups to group A arboviruses. In contrast, the NSI titres to group A arboviruses were found to increase with age. (3) No significant difference could be demonstrated between acetone-ether extraction and kaolin adsorption for removal of the NSI in normal chicken sera. (4) After heating, the NSI titres in chicken sera were increased for both group A and group B arboviruses. (5) After heating the sera at $80^{\circ}C$ and $100^{\circ}C$, kaolin adsorption was less efficient for removing the NSI than it, was in unheated serum. Acetone-ether extraction of the NSI was unimpaired after heating at $80^{\circ}C$ but was less efficient after heating at $100^{\circ}C$. (6) The NSI activity was found mainly in the first peak (IgM) and diffused to a part of second peak (IgG) by fractionation of chicken serum by gel filtration through Sephadex G200. After zonal centrifugation of chicken serum in a linear ten to 40 percent sucrose gradient all of the NSI activities were found on the top of the centrifugal tubes. These properties of large molecular size and low density indicated that the NSI in chicken serum were probably lipoproteins. (7) The natural agglutinins for goose erythrocytes in chicken sera were partially destroyed by acetone-ether extraction but not by kaolin adsorption, and were efficiently adsorbed with ten percent goose erythrocytes. No difference of the NA titre was demonstrated with diluents of different pH. (8) The NA in chicken serum was found to possess the properties of IgM by gel filtration through Sephadex G200 and zonal centrifugation in linear ten to 40 percent sucrose gradient.

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On Optimal Antenna Tilting Angles for Cooperative Transmissions Between Sectors in Cellular Systems (셀룰러 시스템의 섹터 간 협력 전송 시 최적의 안테나 틸팅 각도 결정 방식)

  • Ko, Jin-Seok;Kim, Jae-Won;Park, Jong-Hyun;Sung, Won-Jin
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.47 no.7
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    • pp.29-35
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    • 2010
  • The cooperative transmission between sectors in next generation communications standards, e.g., 3GPP LTE-Advanced and IEEE 802.16m, has become an important research issue. Hence methods to decide the optimal antenna tilting angle in cooperative transmission between sectors are needed. This paper proposes methods to decide the optimal antenna tilting angle in cases of non-cooperative and cooperative transmissions between sectors. The proposed methods use an objective function that maximizes the cell average log rate or the cell average rate for users distributed uniformly within the radius of the sector. Also, the objective function which maximizes the cell average rate determined by adaptive modulation and coding (AMC) used in actual cellular systems is considered. When the cell average rate becomes the objective function, the system rate efficiency increases significantly for both cooperative and non-cooperative transmission. When the cell average log rate and the AMC rate become the objective functions, an optimal antenna tilting decision method which effectively increases the efficiency of cell boundary users is discussed.

Development of an Automatic Sprayer Arm Control System for Unmanned Pest Control of Pear Trees (배나무 무인 방제를 위한 약대 자동 제어시스템 개발)

  • Hwa, Ji-Ho;Lee, Bong-Ki;Lee, Min-Young;Choi, Dong-Sung;Hong, Jun-Taek;Lee, Dae-Weon
    • Journal of Bio-Environment Control
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    • v.23 no.1
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    • pp.26-30
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    • 2014
  • Purpose of this study was a development of a sprayer arm auto control system that could be operated according to distance from pear trees for automation of pest control. Auto control system included two parts, hardware and software. First, controller was made with an MCU and relay switches. Two types of ultra-sonic sensors were installed to measure distance from pear trees: one on/off type that detect up to 3 m, and the other continuous type providing 0~5 V output corresponding to distance of 0~3 m. Second, an auto control algorithm was developed to control. Each spraying arm was controlled according to the sensor-based distance from the pear trees. And it could dodge obstacles to protect itself. Max and min signal values were eliminated, when five sensor signals was collected, and then signals were averaged to reduce sensor's noises. According to results of field experiment, auto control test result was better than non auto control test result. Spraying rates were 69.25% (left line) and 98.09% (right line) under non auto control mode, because pear trees were not planted uniformly. But, auto control test's results were 92.66% (left line) and 94.64% (right line). Spraying rate was increased by maintaining distance from tree.

Physiological Response of Potato Variety to Soil Salinity (토양염농도에 따른 감자 품종들의 생장특성)

  • Kim, Sun;Yang, Chang-Hyu;Jeong, Jae-Hyeok;Choi, Weon-Young;Lee, Kyu-Seong;Kim, Si-Ju
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.2
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    • pp.85-90
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    • 2013
  • This study was conducted to examine the basis for the information to select the suitable potato varieties grown in new reclaimed land. The potatoes of five varieties were planted in the port with 4 different electrical conductivities of saturated extracts of soil taken the Saemangeum reclamation area, which was made of non-treatment salt and three concentrations of salt treatment, 1.6 dS $m^{-1}$, 3.2 dS $m^{-1}$, 4.8 dS $m^{-1}$, respectively. All of the potato varieties were uniformly emerged without missing plant in all treatment groups, even 4.8 dS $m^{-1}$ treatment group. According to the salt concentration of soil, required date to the emergence of the potato comparing to non-treatment salt was delayed 3-4 days in 1.6 dS $m^{-1}$, 6-10 days in 3.2 dS $m^{-1}$, 7-13 days in 4.8 dS $m^{-1}$, respectively, and the number of its branch decreased by 14-58% comparing to non-treatment salt depending on varieties. Since the increase of the salt concentration of the soil was more serious the decrease of the number of its branch, but plant height tended to increase when branch number per plant was small, which was depending on more number of its branch than salt concentration. Fresh tuber yield of potato comparing to non-treatment salt were decrease 33.7% in 1.6 dS $m^{-1}$, 59.5% in 3.2 dS $m^{-1}$, 79.3% 7-13 days in 4.8 dS $m^{-1}$, respectively. The threshold EC starting the growth inhibition of fresh weight decreased was 1.2 dS $m^{-1}$ for Chudong, 1.8 $m^{-1}$ for Chubeak, 1.9 $m^{-1}$ for Chugang and Chuyeong, and 2.0 $m^{-1}$ for Sumi, and EC which decreased 50% of dry weight index was 2.4 dS $m^{-1}$ for Chubaek, 2.45 dS $m^{-1}$ for Chudong, 2.81 dS $m^{-1}$ for Chugang, 3.03 dS $m^{-1}$ for Chuyeong, and 3.29 dS $m^{-1}$ for Sumi. The present results suggest that Sumi is considered to the suitable potato variety grown on saline soils.

Highly Doped Nano-crystal Embedded Polymorphous Silicon Thin Film Deposited by Using Neutral Beam Assisted CVD at Room Temperature

  • Jang, Jin-Nyeong;Lee, Dong-Hyeok;So, Hyeon-Uk;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.154-155
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    • 2012
  • The promise of nano-crystalites (nc) as a technological material, for applications including display backplane, and solar cells, may ultimately depend on tailoring their behavior through doping and crystallinity. Impurities can strongly modify electronic and optical properties of bulk and nc semiconductors. Highly doped dopant also effect structural properties (both grain size, crystal fraction) of nc-Si thin film. As discussed in several literatures, P atoms or radicals have the tendency to reside on the surface of nc. The P-radical segregation on the nano-grain surfaces that called self-purification may reduce the possibility of new nucleation because of the five-coordination of P. In addition, the P doping levels of ${\sim}2{\times}10^{21}\;at/cm^3$ is the solubility limitation of P in Si; the solubility of nc thin film should be smaller. Therefore, the non-activated P tends to segregate on the grain boundaries and the surface of nc. These mechanisms could prevent new nucleation on the existing grain surface. Therefore, most researches shown that highly doped nc-thin film by using conventional PECVD deposition system tended to have low crystallinity, where the formation energy of nucleation should be higher than the nc surface in the intrinsic materials. If the deposition technology that can make highly doped and simultaneously highly crystallized nc at low temperature, it can lead processes of next generation flexible devices. Recently, we are developing a novel CVD technology with a neutral particle beam (NPB) source, named as neutral beam assisted CVD (NBaCVD), which controls the energy of incident neutral particles in the range of 1~300eV in order to enhance the atomic activation and crystalline of thin films at low temperatures. During the formation of the nc-/pm-Si thin films by the NBaCVD with various process conditions, NPB energy directly controlled by the reflector bias and effectively increased crystal fraction (~80%) by uniformly distributed nc grains with 3~10 nm size. In the case of phosphorous doped Si thin films, the doping efficiency also increased as increasing the reflector bias (i.e. increasing NPB energy). At 330V of reflector bias, activation energy of the doped nc-Si thin film reduced as low as 0.001 eV. This means dopants are fully occupied as substitutional site, even though the Si thin film has nano-sized grain structure. And activated dopant concentration is recorded as high as up to 1020 #/$cm^3$ at very low process temperature (< $80^{\circ}C$) process without any post annealing. Theoretical solubility for the higher dopant concentration in Si thin film for order of 1020 #/$cm^3$ can be done only high temperature process or post annealing over $650^{\circ}C$. In general, as decreasing the grain size, the dopant binding energy increases as ratio of 1 of diameter of grain and the dopant hardly be activated. The highly doped nc-Si thin film by low-temperature NBaCVD process had smaller average grain size under 10 nm (measured by GIWAXS, GISAXS and TEM analysis), but achieved very higher activation of phosphorous dopant; NB energy sufficiently transports its energy to doping and crystallization even though without supplying additional thermal energy. TEM image shows that incubation layer does not formed between nc-Si film and SiO2 under later and highly crystallized nc-Si film is constructed with uniformly distributed nano-grains in polymorphous tissues. The nucleation should be start at the first layer on the SiO2 later, but it hardly growth to be cone-shaped micro-size grains. The nc-grain evenly embedded pm-Si thin film can be formatted by competition of the nucleation and the crystal growing, which depend on the NPB energies. In the evaluation of the light soaking degradation of photoconductivity, while conventional intrinsic and n-type doped a-Si thin films appeared typical degradation of photoconductivity, all of the nc-Si thin films processed by the NBaCVD show only a few % of degradation of it. From FTIR and RAMAN spectra, the energetic hydrogen NB atoms passivate nano-grain boundaries during the NBaCVD process because of the high diffusivity and chemical potential of hydrogen atoms.

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Morphological Study on the Epithelial Cells in the Gall Blader of Vertebrates (각급 척추동물의 담낭 상피세포에 대한 형태학적 연구)

  • 노용태
    • The Korean Journal of Zoology
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    • v.17 no.2
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    • pp.57-68
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    • 1974
  • These experiments were performed in order to study histologically and histochemically on the epithelial cells of gall bladder in Carassius carassius, Bufo bufo gargarizans, Natrix tigrina lateralis, Urloncha striata var. domesticus and Bos taurus var. domesticus. The results of the observation were as follows: 1. There were different cell types in the epithelium of gall bladder in each animal and it could not be supported histochemically that the epithelia cells of gall bladder were divided into two cell types of the rod-shaped and barrel-shaped ones. 2. The epithelium of gall bladder in Carassius carassius, Bufo bufo gargarizans, Natrix tigrina lateralis, Urloncha striata var. domesticus and Bos taurus var. domesticus was simple columnar epithelium. 3. The eosinophilities of cytoplasm in the epithelial cells of gall bladder were in uniform stronger in the upper portion of nucleus in Carassius carassius, Bufo bufo gargarizans and Natrix tigrina lateralis than its other portions, and in Urloncha striata var. domesticus and Lepus cuniculus var. domesticus existed uniformly in all portions, but there were many non-eosinophilic cells in Bufo bufo gargarizans and many cells that weakly eosinophilic around nucleus in Bos taurus var. domesticus. 4. The periodic acid Schiff's reactivities in the epithelial cells of gall bladder were different in each other and the epithelial cells in PAS reaction were divided into two cell types of the dark and light ones. There presented the light cells of 6.4%, 4.3% and 3.7% of epithelial cell of gall bladder in Carassius carassius, Bufo bufo gargarizans and Urloncha striata var. domesticus for each other, but were not presented in Natrix tigrina lateralis and Bos taurus var. domesticus. 5. The ninhydrin-Schiff-active proteins were much in the epithelial cells of gall bladder in Bos taurus var. domesticus, Carassius carassius, Urloncha striata var. domesticus and Natrix tigrina lateralis in order and were much in epithelial cells in the upper portion of mucosal folds in Carassius carassius, Urloncha striata var. domesticus and Natrix tigrina lateralis, and the ninhydrin-Schiff-active protein of the epithelium of gall bladder in Bufo bufo gargarizans was uniformly distributed. 6. The epithelial cells of gall bladder in Carassius carassius, Natrix tigrina lateralis, Urloncha striata var. domesticus and Bos taurus var. domesticus had no stain reactivity or weak stain reactivity to neutral fat and all epithelial cells in Bufo bufo gargarizans had strong stain reactivity, though they were different in quantity of epithelial cell portion. 7. The stain reactivities to RNA and DNA were stronger in the epithelial cells of the upper portion of mucosal fold than in those of other portions.

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Experimental Study on the Determination of Slope and Height of Curbs Considering the VRUs (교통약자를 고려한 보도의 경사도와 높이 결정을 위한 실험연구)

  • Kim, Hyunjin;Lim, Joonbeom;Choe, Byongho;Oh, Cheol;Kang, Inhyeng
    • International Journal of Highway Engineering
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    • v.20 no.1
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    • pp.107-115
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    • 2018
  • PURPOSES : As the population of the mobility handicapped, who are classified as the disabled, the elderly, pregnant women, children, etc., has increased, the voices for guaranteeing their rights have been increasing as well. Thus, the design manuals for roads and sidewalks for the mobility handicapped were developed by the local government, such as the Ministry of Land, Transport, and Tourism, in Seoul City. However, according to the 2013 survey results of the Seoul Metropolitan City, the mobility handicapped still feel uncomfortable with the sidewalks, and particularly request for the improvement of the step and slope of the sidewalk curb. Therefore, in this study, we conducted an empirical experimental study to determine the slope of the sidewalk curb and height of the steps considering the mobility handicapped and analyzed whether there is a statistically significant difference. METHODS : The methodology of this study is an empirical experimental one. In the study, five non-disabled people, 10 wheelchair users, and 10 eye patch and stick users walked about 2-3 min on the sidewalk plates of the sloped type (0%, 5%, 6.3%, 8.3%) and stepped type (0 cm, 1 cm, 3 cm, 6 cm), and their human physiological responses, such as the skin temperature, volume of perspiration on forehead and chest, and heart rate, were measured and recorded. After combining the data, we conducted a nonparametric test, ANOVA, or t-test to determine whether there was a statistically significant difference according to each slope and step type. RESULTS : It was found that for the non-disabled, there was no significant difference in human physiological responses according to the slope and steps of the sidewalk. It can be said that the non-disabled do not feel much physiological discomfort while walking. In the case of the sloped sidewalk plate, the heart rate of the wheel chair users increased when the slope was 6.3%. In the case of the eye patch and stick users, the volume of perspiration on the chest increased at a slope of 5.0%. In general, it is judged that a sidewalk with a slope that is less than 5% does not cause a change in the physiological response. In the case of a stepped sidewalk plate, when 0 cm, 1 cm, and 3 cm were compared for wheelchair users, the amount of forehead perspiration increased from 1 cm. Meanwhile, in the case of the eye patch and stick users, when 0 cm and 6 cm were compared, the amount of perspiration on the forehead and chest as well as the heart rate all increased at 6 cm. Taken together, in the case of wheelchair users, a difference was shown when the height of the step of the sidewalk plate was 1 cm, suggesting that installing it at 0 cm does not cause any physiological discomfort. Moreover, in the case of the eye patch and stick users, when comparing only 0 cm and 6 cm, 0 cm was considered to be suitable, as there was a difference in physiological response at 6 cm. CONCLUSIONS : In this study, we set the human physiological responses such as chest skin temperature, amount of perspiration, and heart rate as evaluation items, and our study was considered to be a meaningful experiment that targeted wheelchair users as well as eye patch and stick users. The validity of the evaluation items was confirmed, as the results of human physiological responses were significant. As for the sidewalk design, according to the experiment result, it is considered that differential application should be implemented according to the type of mobility handicap, rather than uniformly applying a sidewalk step of 2 cm and sidewalk slope of 1/25, which are the current legal standards.

Resistive Switching Characteristic of Direct-patternable Amorphous TiOx Film by Photochemical Metal-organic Deposition (광화학증착법에 의한 직접패턴 비정질 TiOx 박막의 제조 및 저항변화 특성)

  • Hwang, Yun-Kyeong;Lee, Woo-Young;Lee, Se-Jin;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.1
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    • pp.25-29
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    • 2020
  • This study demonstrates direct-patternable amorphous TiOx resistive switching (RS) device and the fabrication method using photochemical metal-organic deposition (PMOD). For making photosensitive stock solutions, Ti(IV) 2-ethylhexanoate was used as starting precursor. Photochemical reaction by UV exposure was observed and analyzed by Fourier transform infrared spectroscopy and the reaction was completed within 10 minutes. Uniformly formed 20 nm thick amorphous TiOx film was confirmed by atomic force microscopy. Amorphous TiOx RS device, formed as 6 × 6 ㎛ square on 4 ㎛ width electrode, showed forming-less RS behavior in ±4 V and on/off ratio ≈ 20 at 0.1 V. This result shows PMOD process could be applied for low temperature processed ReRAM device and/or low cost, flexible memory device.