• Title/Summary/Keyword: non-thermal treatment

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Preparation and characterization of ITO Thin Film By Various Substrate heating temperature (기판온도에 따른 ITO 박막의 제조 및 특성)

  • Kim, Sung Jin;Pak, Hunkyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.94.2-94.2
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    • 2010
  • Indium tin oxide (ITO) Thin films were grown on Non-alkarai glass Substrates by PVD method and Subsequently Subjected to ($100^{\circ}C-350^{\circ}C$) Thermal Annealing (TA) In Nitr Oxygen ambinent. Most of all, The effect of TA treatment on the structural properties were studied by using X-Ray diffraction and atomic force microscopy, while optical properties were studied by UV-Transmittance measurements. After TA treatment, the XRD spectra have shown an effective relaxation of the residual compressive stress, As a result, XRD peaks increase of the intensity and narrowing of full width at half-maximun (FWHM). In addtion The microstructure, The surface morphology, the optical transmittance changed and improved, and we investigated The effects of temperature, Time and atmosphere during the TA on the structural and electrical properties of the ITO/glass on TA at $300^{\circ}C$. As a results, the films are highly transparent (80%~89%) in visible region. AFM analysis shows that the films are very smooth with root mean square surface roughness 0.58nm -2.75nm thickness film. It is observed that resistivity of the films drcreases T0 $1.05{\times}10^{-4}{\Omega}cmt$ $6.06{\times}10^{-4}{\Omega}cm$, while mobility increases from $152cm^2/vs$ to $275cm^2/vs$.

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Effect of Hydrocarbons on the Promotion of NO-$NO_2$ Conversion in NonThermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에 탄화수소 첨가제가 미치는 영향)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.33-46
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of NO-$NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $NO_2$ etc.) successively produced by hydrocarbon decomposition form the primary path of NO-$NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient NO-$NO_2$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

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Effect of Hydrocarbons on the Promotion of $NO-NO_{2}$ Conversion in NonThermal Plasma DeNOx Treatment (비열 플라즈마에 의한 NO의 산화에 탄화수소 첨가제가 미치는 영향)

  • Shin, Hyun-Ho;Yoon, Woong-Sup
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.178-188
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    • 2000
  • In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_{2}$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_{2}$ etc.) successively produced by hydrocarbon decomposition form the primary path of $NO-NO_{2}$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_{2}$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

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Antibacterial Activity of Dielectric Barrier Discharge Plasma against Main Food-borne Bacteria in Suspensions (유전체장벽방전 플라즈마에 의한 주요식중독세균의 살균 효과)

  • Choi, Man-Seok;Kim, Ji Yoon;Jeon, Eun Bi;Park, Shin Young
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.52 no.6
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    • pp.617-624
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    • 2019
  • Dielectric barrier discharge (DBD) plasma is one of the promising next generation non-thermal technologies for food sterilization. The present study investigated the effects of DBD plasma on the reduction of most common food-borne pathogenic bacteria (Staphylococcus aureus, Bacillus cereus, Vibrio parahaemolyticus, Salmonella enterica) and sanitary indicative bacteria (Escherichia coli) in the suspension (initial inoculum of approx. 9 log CFU/mL). The bacterial counts were significantly (P<0.05) reduced with the increase in the treatment time (1-30 min) of DBD plasma in the suspension. The D-values (time for 90% reduction) of DBD plasma by first-order kinetics for S. aureus, B. cereus, V. parahaemolyticus, S. enterica, and E. coli were 17.76, 19.96, 32.89, 21.55, and 15.24 min, respectively (R2>0.90). These results specifically showed that 30 min of DBD plasma treatment in > 90% reduction of seafood-borne pathogenic and sanitary indicative bacteria. This suspension study may provide the basic data for use in seafood processing and distribution.

Inhibitory Effects of Ultrasound in Combination with Ascorbic Acid on Browning and Polyphenol Oxidase Activity of Fresh-cut Apples

  • Jang, Ji-Hyun;Kim, Sang-Tae;Moon, Kwang-Deog
    • Food Science and Biotechnology
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    • v.18 no.6
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    • pp.1417-1422
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    • 2009
  • This study was conducted to investigate the effect of ultrasound with ascorbic acid on the quality of fresh-cut apples. Prepared apple cubes were dipped in distilled water (US) or in 1% ascorbic acid solution (AS), both were treated with ultrasound at 40 kHz, while the other sample was just dipped in 1% ascorbic acid solution for 1 min (AA). All samples were stored at $4^{\circ}C$ for 12 days. AS treatment had an effect on apple cube color as indicated by its significantly higher L values and lower ${\Delta}E$ value whereas AA- and US-treated samples showed a considerable browning. Higher inhibition rate on browning and polyphenol oxidase (PPO) activity of 46 and 98%, respectively, were observed after AS treatment. The highest total phenolic content of AS-treated samples was shown during whole storage periods. This investigation revealed that the use of ultrasound in combination with ascorbic acid had a positive effect on quality maintaining of fresh-cut apples.

A Study on the Sulfonation of Persimmon Tannin (감타닌의 술폰화에 관한 연구)

  • Kwon, Seul Gi;Bae, Do Gyu
    • Textile Coloration and Finishing
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    • v.29 no.2
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    • pp.69-76
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    • 2017
  • To get the proper treatment conditions, sulfonation reactions of persimmon tannin with sodium sulfite and sulfuric acid were proceeded in various settings, respectively. Also, the property changes were investigated by carrying out the additional analysis: elementary analysis and instrumental analysis using FT-IR, DSC, and TGA. The degree of $-SO_3Na$ substitutions appeared 0.216 and 0.208 under the treatment time of 3 hours and 6 hours, respectively and the degree of $-SO_3H$ substitutions indicated 0.200 and 0.167 under 9 hours and 18 hours, respectively by elemental analysis. In terms of the FT-IR spectras, there was a peak based on the bonds of pyran ring and ether in relation to non-treated and sulphonated tannin at $1,102cm^{-1}$. No peak was shown in the sulfited tannin. An absorption peak which was due to the $C{\rightarrow}O$ of secondary -OH group became evident in nontreated and sulfited tannin at $1,092cm^{-1}$ and $1,090cm^{-1}$, respectively but the same result was not found in sulphonated tannin. The results of TGA analysis of the sulfonated persimmon tannin showed that the sulfonation of it improved thermal properties.

Decomposition Behavior of Secondary Solidification Phase During Heat Treatment of Squeeze Cast Al-Cu-Si-Mg (용탕단조 Al-Cu-Si-Mg합금의 열처리시 제2응고상의 분해거동)

  • Kim, Yu-Chan;Kim, Do-Hyang;Han, Yo-Sub;Lee, Ho-In
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.560-568
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    • 1997
  • The dissolution behavior of secondary solidification phases in squeeze cast Al-3.9wt%Cu-1.5wt%Si-1.0wt%Mg has been studied using a combination of optical microscope, image analyzer, scanning electron microscope(SEM), energy dispersive spectrometer(EDS), X-ray diffractometer(XRD) and differential thermal analyzer (DTA). Special emphasis was placed on the investigation of the effects of the nonequilibrium heat treatment on the dissolution of the second solidification phases. Ascast microstructure consisted of primary solidification product of ${\alpha}-Al$ and secondary solidification products of $Al_2Cu$, $Mg_2Si$ and $Al_2CuMg$. Equilibrium and non-equilibrium solution treatments were carried out at the temperatures of $495^{\circ}C$, $502^{\circ}C$ and $515^{\circ}C$ for 3 to 5 hours. The amount of the dissolved secondary phases increased with increasing solution treatment temperature, for example, area fractions of $Al_2Cu$, $Mg_2Si$ and $Al_2CuMg$ were approximately 0%, 1.6% and 4.2% after solution treatment at $495^{\circ}C$ for 5hours, and were approximately 0%, 0.36% and 2% after solution treatment at $515^{\circ}C$ for 5hours. The best combination of tensile properties was obtained when the as-cast alloy was solution treated at $515^{\circ}C$ for 3hours followed by aging at $180^{\circ}C$ for 10 hours. Detailed DTA and TEM study showed that the strengthening behavior during aging was due to enhanced precipitation of the platelet type fine ${\theta}'$ phase.

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Adhesive Bonding Properties between NBR and Polyamide Woven Fabric with Atmospheric Pressure Plasma Treatment (대기압 플라즈마 처리한 폴리아미드 직물과 NBR의 접착특성)

  • Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Composites Research
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    • v.23 no.6
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    • pp.32-38
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    • 2010
  • The effect of the atmospheric pressure plasma(APP) treatments is experimentally investigated to ascertain the optimum condition to yield the best adhesive properties between a polyamide woven fabric and acrylonitrile butadiene rubber(NBR). For the atmospheric pressure flame plasma(APFP) treatment, the optimum number of treatment at given conditions is 2 times. The thermal deformation of the fabric is more serious with increasing the number of APFP treatment. The adhesive strength of the case with APFP treated fabric is increased about 35% when compare to the case with non-APFP treated one for the interface(bonding agent one or two coatings). When the surface is coated twice with the bonding agent, the adhesive energy with APFP treated fabric is increased about 4 times. It was found that the surface modification of polyamide woven fabric by APFP treatment is a fast, economic and applicable method to improve the adhesive properties between woven fabric and rubber when compared to other APP treatments.

Manufacturing of artificial lightweight aggregate from water treatment sludge and application to Non-point treatment filteration (정수슬러지를 재활용한 인공경량골재의 제조 및 비점오염원 여재의 적용)

  • Jung, Sung-Un;Lee, Seoung-Ho;Namgung, Hyun-Min
    • Industry Promotion Research
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    • v.6 no.4
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    • pp.1-9
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    • 2021
  • The purpose of this study is to manufacture lightweight aggregates for recycling water treatment sludge, to identify the physical properties of the aggregates, and present a method of utilizing the manufactured lightweight aggregates. The chemical composition and thermal properties were examined via a raw materials analysis. The aggregate examined here was fired by the rapid sintering method and the single-particle density and water absorption rate were measured. Water treatment sludge has high ignition loss and high fire resistance. When 30wt% of purified sludge was added, the single-particle density of the aggregates was in the range of 0.8~1.2g/cm3 at a temperature of 1,150~1,200℃. At temperatures of 1200℃ or higher, ultra-light aggregates having a single-particle density of 0.8 or less could be produced. When applied to concrete by replacing the general aggregate in the concrete, a specimen having strength values of 200 to 450 kgf/cm2 on 28 days was obtained, and when applied as a filter material, the performance was equal to or higher than that of ordinary sand.

Photoluminescence properties of oxy-fluoride glass-ceramics of La2O3-CaF2-Al2O3-SiO2 system (La2O3-CaF2-Al2O3-SiO2 계 oxy-fluoride 결정화 유리의 광 발광 특성)

  • Ha, Taewan;Kang, Seunggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.2
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    • pp.84-88
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    • 2021
  • The change of the photoluminescence properties of La2O3-CaF2-Al2O3-SiO2 glass-ceramics doped with rare earth material, that is used as laser and optical sensors, was analyzed according to heat treatment temperature. The heat treatment conditions for fabricating glass-ceramics were obtained through non-isothermal thermal analysis, and X-ray diffraction analysis was performed to determine the degree of crystal growth and kinds of crystal phases generated according to the heat treatment temperature. Using Scherrer's equation, it was predicted that crystals with a size of 25~40 nm would be generated inside the glass-ceramics. Photoluminescence (PL) analysis showed that the specimens heat-treated at 660℃ to 670℃ for 1 hour had the highest PL intensity. Also, from the CIE color coordinate analysis, all glass-ceramics specimens emitted red-orange light regardless of the heat treatment condition.