• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.29 no.4
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• pp.18-27
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• 1997

This study was performed to obtained the optimal delignified condition of exploded wood on the acid hydrolysis with sulfuric acid. Wood chips of pine wood(Pinus desiflora), oak wood(Quercus serrata) and birch wood (Betula platyphylla var. japonica) were treated with a high pressure steam (20-30kgf/$\textrm{cm}^2$, 2-6 minutes). The exploded wood was delignified with sodium hydroxide and sodium chlorite, and then hydrolyzed with sulfuric acid. The result can be summerized as follows ; In the exploded wood treated with sodium hydroxide, the optimal concentration of sodium hydroxide was 1% as content of lignin in the exploded wood. Lignin content of exploded wood treated with sodium chlorite was lower then that sodium hydroxide. The maximum reducing sugar yield of exploded wood treated with 1% sodium hydroxide was lower than non-treated exploded wood. In the case of sodium chlorite treated, the maximum reducing sugar yield was hgher than non-treated exploded wood. Sugar composition of acid hydrolysis solution was composed of xylose and glucose residue, and the rate of glucose residue was increased in high pressure condition.

• Nuclear Engineering and Technology
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• v.56 no.2
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• pp.611-623
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• 2024

The ISP-47 TOSQAN experiment was analyzed with containmentFOAM which is an open-source CFD code based on OpenFOAM. The containment phenomena taking place during the experiment are gas mixing, stratification and wall condensation in a mixture composed of steam and non-condensable gas. The k-ω SST turbulence model was adopted with buoyancy turbulence models. The wall condensation model used is based on the diffusion layer approach. We have simulated the full TOSQAN experiment which had a duration 20000 s. Sensitivity studies were conducted for the buoyancy turbulence models with SGDH and GGDH and there were not significant differences. All the main features of the experiments namely pressure history, temperature, velocity and gas species evolution were well predicted by containemntFOAM. The simulation results confirmed the formation of two large flow stream circulations and a mixing zone resulting by the combined effects of the condensation flow and natural convection flow. It was found that the natural convection in lower region of the vessel devotes to maintain two large circulations and to be varied the height of the mixing zone as result of sensitivity analysis of non-condensing wall temperature. The computational results obtained with the 2D mesh grid approach were comparable to the experimental results.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.1066-1080
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• 2024

SMART100 has a containment pressure and radioactivity suppression system (CPRSS) for passive containment cooling system (PCCS). This prevents overheating and over-pressurization of a containment through direct contact condensation in an in-containment refueling water storage tank (IRWST) and wall condensation in a CPRSS heat exchanger (CHX) in an emergency cool-down tank (ECT). The Korea Atomic Energy Research Institute (KAERI) constructed scaled-down test facilities, SISTA1 and SISTA2, for the thermal-hydraulic validation of the SMART100 CPRSS. Three separate effect tests were performed using SISTA1 to confirm the heat removal characteristics of SMART100 CPRSS. When the low mass flux steam with or without non-condensable gas is released into an IRWST, the conditions for mitigation of the chugging phenomenon were identified, and the physical variables were quantified by the 3D reconstruction method. The local behavior of the non-condensable gas was measured after condensation inside heat exchanger using a traverse system. Stratification of non-condensable gas occurred in large tank of the natural circulation loop. SISTA2 was used to simulate a small break loss-of-coolant accident (SBLCOA) transient. Since the test apparatus was a metal tank, compensations of initial heat transfer to the material and effect of heat loss during long-term operation were important for simulating cooling performance of SMART100 CPRSS. The pressure of SMART100 CPRSS was maintained below the design limit for 3 days even under sufficiently conservative conditions of an SBLOCA transient.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.837-842
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• 2012

A pilot scale circulating fluidized boiler (CFB) for refuse derived fuel (RDF) is designed and constructed to demonstrate a performance of CFB technology for waste fuel utilization. The boiler has a design capacity of 6 MWth with $400^{\circ}C$ 38 ata steam generation performance. The maximum steam rate of the boiler was about 8 ton/h. The main component of the fuel was RDF (Refuse Derived Fuel) with high volatile contents and showed fast ignition and easy combustion. The pilot plant showed over 99.5% of combustion efficiency. Stable operation of RDF CFBC depended on the content of non combustion materials other than ash and fast removal of them. Emission level was under legal limit except that of HCl without external flue gas treatment facilities. Also about 60% of fuel chlorine was absorbed to fly ash particles. For HCl emission control flue gas treatment technology is required such as wet and dry scrubber in order to comply with Korean regulation.

• Carbon letters
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• v.19
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• pp.79-88
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• 2016

As a replacement for activated carbon, biochar was synthesized and used for the adsorptive removal of formaldehyde and nitrogen oxide. Biochar was produced from the fast pyrolysis of the red marine macro alga, Pyropia tenera. The P. tenera char was then activated with steam, ammonia and KOH to alter its characteristics. The adsorption of formaldehyde, which is one of the main indoor air pollutants, onto the seaweed char was performed using 1-ppm formaldehyde and the char was activated using a range of methods. The char activated with both the KOH and ammonia treatments showed the highest adsorptive removal efficiency, followed by KOH-treated char, ammonia-treated char, steam-treated char, and non-activated char. The removal of 1000-ppm NO over untreated char, KOH-treated char, and activated carbon was also tested. While the untreated char exhibited little activity, the KOH-treated char removed 80% of the NO at 50℃, which was an even higher NO removal efficiency than that achieved by activated carbon.

• 제어로봇시스템학회:학술대회논문집
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• 1992.10b
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• pp.74-78
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• 1992

This paper describes an intelligent system to automatic evaluation of eddy current(EC) signal for Inspection of steam generator(SG) tubes in nuclear power plant. Some features of the intelligent system design in the proposed system are : (1) separation of representation scheme ,or event capturing knowledge in EC signal and for structural inspection knowledge in SG tubes inspection; (2) each representation scheme is implemented in different methods, one is syntactic pattern grammar and the other is rule based production. This intelligent system also includes an data base system and an user interface system to support integration of the hybrid knowledge processing methods. The intelligent system based on the proposed concept is useful in simplifying the knowledge elicitation process of the rule based production system, and in increasing the performance in real time signal inspection application.

• Bulletin of the Korean Chemical Society
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• v.25 no.5
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• pp.681-686
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• 2004

Ti-ZSM-5 prepared by secondary synthesis, from the reaction of H-ZSM-5 with vapor phase $TiCl_4$, was characterized with several physicochemical techniques including FT-IR and UV/VIS-DRS. It was found that zeolite structure, surface area and pore volume did not change, and the framework aluminum could not be replaced by titanium atom during the secondary synthesis of Ti-ZSM-5. The incorporation of titanium into the framework might be due to reaction of $TiCl_4$with the silanol groups associated with defects or surface sites. The formation of extra-framework titanium could not be avoided, unless the samples were further treated by water vapor at 550 $^{\circ}C$ or higher temperature. High temperature steam treatment of Ti-ZSM-5 prepared by chemical vapor deposition with $TiCl_4$was efficient to prevent the formation of non-framework titanium species. Ti-ZSM-5 zeolites prepared in this work contained only framework titanium species and exhibited improved catalytic property close to TS-1 prepared by hydrothermal synthesis.

• Journal of computational fluids engineering
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• v.20 no.4
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• pp.14-20
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• 2015

Without electirc power to cool down the hot reactor core, passive systems utilizing natural circulation are becoming a big specialty of recent neculear systems after the severe accident in Fukusima. When we consider the natural circulation in a pool, thermal mixing phenomena may start from single phase circulation and can continue to two phase condition. Since the CUPID code, which has been developed for two-phase flow analysis, can deal with the phase transition phenomena, the CUPID would be pertinent to natural convection problems in single- and two-phase conditions. Thus, the CUPID should be validated against single- and two-phase natural circulation phenomena. For the first step of the validation process, this study is focused on the validation of single-phase natural circulation. Moreover, the CUPID code solves the fluid properties by the relationship to pressure and temperature from the steam table considering non-condensable gas effects, so that the effects from variable properties are included. Simple square thermal cavity problems are tested for laminar and turbulent conditions against numerical and experimental data. Throughout the investigation, it is found that the variable properties can affect the flow field in laminar condition, but the effect becomes weak in turbulence condition, and the CUPID code implementing steam table is capable of analyzing single phase natural circualtion phenomena.

• Explosives and Blasting
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• v.25 no.2
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• pp.11-21
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• 2007

The main structure of Gunsan steam power station was demolished by the toppling method using high explosives. Height of a main building is 58m and a total floor area is $292,000m^2$. It is Rahmen(rigid-frame) structure consisted of almost columns and beams and slabs exist only in one part of the building for the electricity generators equipments. To improve the efficiency of blasting work, it is separated into 4 sectors. Blasting floors were 1, 2, 3, & 4 stories from first sector to third sector, while 1, 2, 5, & 7 of fourth sector were blasted because it had not slabs. About 102.675 kg of the MegaMITE were used with 225 electric detonator and 638 non-electric detonators to check detonator connection and confidence of detonation. The blasting noise and vibration were monitored to evaluate the environment effect and the damage of the nearby structures.

• Korean Journal of Pharmacognosy
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• v.1 no.3
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• pp.93-99
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• 1970

There have been reported by several workers for the isolation and determination of the amine derivatives as Metbylephedrine Hydrochloride and Ephedrine Hydrochloride adopting neutralization method, steam distillation method, non-aqous titration method, ion-exchange resin method, titration method after acetylation, colorimetric method, gravimetric method, iodine titration method and gas chromatography. Those methods mentioned in above, can be practically applied for the sample which is not mixed one mith the other amine compounds. Presently, it has not shown on the isolative determination of the mixed sample of amine derivatives. In this paper, it is discussed on the isolative determination of Methylephedrine Hydrochloride as the tertiary amine compound and Ephedrine Hydrochloride as the secondary amine compound. According to the results of the experiment, it could be summarized as follows: 1. There is no time-variation on the color reaction of Methylephedrine Hydrochloride and Ephedrine Hydrochloride with the color reagent, bromcresolgreen. And Methylephedrine Hydrochloride and Ephedrine Hydrochloride, respectively, can be determined spectrophotometrically by means oft his color reaction. 2. For the isolation of Methylephedrine Hydrochloride and Ephedrine Hydrochloride from the mixed sample, Methylephedrine Hydrochloride can be eluted by chloroform, while Ephedrine Hydrochloride by the mixed solvent of chloroform and ethylalcohol (2:1), from the celite column adsorbed at pH6.4 followed by extraction with ether undersodium hydroxide alkali re action. 3. When the sample is mixed with quinine hydrochloride, dihydrocodeine bitartate, and noscapine, these mixed compounds can be eliminated by means of stram distillation. 4. When the sample is mixed with chlorpheniramine maleate, dextromethorphan hydrobromide and diphenhydramine hydrochloride, the mixed compounds can be eliminated by means of steam distillation and celite adsorption column chromatography, In conclusion, the isolative determination method for Methylephedrine Hydrochloride and Ephedrine Hydrochloride studied in this paper, indicates with the excellent reproducibility and accuracy.