• Title/Summary/Keyword: non-segregation

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A Study on Electrochemical Evaluation Method of Toughness Degradation for 12%Cr Steel (II) (12%Cr강 인성열화도의 전기화학적 평가법에 대한 연구(II))

  • Kim, Chang-Hui;Seo, Hyun-Uk;Yoon, Kee-Bong;Park, Ki-Sung;Kim, Seoung-Tae
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.268-273
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    • 2001
  • Fossil power plants operated in high temperature condition are composed of components such as turbine, boiler, and piping system. Among these components, turbine blades made with 12%Cr steel operate at a temperature above $500^{\circ}C$. Due to the long term service, turbine blades experience material degradation manifested by change in mechanical and microstructural properties. The need to make life assessment and to evaluate material degradation of turbine blade is strongly required but in reality, there is a lack of knowledge in defining failure mechanism and fundamental data for this component. Therefore, in making life assessment of turbine blade, evaluation of material degradation must be a priority. For this purpose, evaluation of toughness degradation is very important. The major cause of toughness degradation in 12Cr turbine blade is reported to be critical corrosion pitting induced by segregation of impurity elements(P etc.), coarsening of carbide, and corrosion, but the of materials for in-service application. In this study, the purpose of research is focused on evaluating toughness degradation with respect to operation time for 12%Cr steel turbine blade under high temperature steam environment and quantitatively detecting the degradation properties which is the cause of toughness degradation by means of non-destructive method, electrochemical polarization.

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Influence of Nb Addition and Austenitizing Temperature on the Hardenability of Low-Carbon Boron Steels (저탄소 보론강의 경화능에 미치는 Nb 첨가와 오스테나이트화 온도의 영향)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.25 no.11
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    • pp.577-582
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    • 2015
  • The present study is concerned with the influence of niobium(Nb) addition and austenitizing temperature on the hardenability of low-carbon boron steels. The steel specimens were austenitized at different temperatures and cooled with different cooling rates using dilatometry; their microstructures and hardness were analyzed to estimate the hardenability. The addition of Nb hardly affected the transformation start and finish temperatures at lower austenitizing temperatures, whereas it significantly decreased the transformation finish temperature at higher austenitizing temperatures. This could be explained by the non-equilibrium segregation mechanism of boron atoms. When the Nb-added boron steel specimens were austenitized at higher temperatures, it is possible that Nb and carbon atoms present in the austenite phase retarded the diffusion of carbon towards the austenite grain boundaries during cooling due to the formation of NbC precipitate and Nb-C clusters, thus preventing the precipitation of $M_{23}(C,B)_6$ along the austenite grain boundaries and thereby improving the hardenability of the boron steels. As a result, because it considerably decreases the transformation finish temperature and prohibits the nucleation of proeutectoid ferrite even at the slow cooling rate of $3^{\circ}C/s$, irrespective of the austenitizing temperature, the addition of 0.05 wt.% Nb had nearly the same hardenability-enhancing effect as did the addition of 0.2 wt.% Mo.

Numerical Analysis on Rapid Solidification of Gas-atomized Al-8wt. pct Fe Droplets (가스분무한 Al-8wt.%Fe 합금분말의 급속응고과정에 대한 수치해석)

  • Kim, Seong-Gyoon;Choi, Hoi-Jin;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.13 no.5
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    • pp.462-475
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    • 1993
  • A numerical analysis on the microstructural evolutions of microcellular and cellular ${\alpha}-aluminum$ phase in the gas-atomized Al-8wt. pct droplets was represented. The 2-dimensional non-Newtonian heat transfer and the dendritic growth theory in the undercooled melt were combined under the assumptions of a point nucleation on droplet surface and the macroscopically smooth solid-liquid interface enveloping the cell tips. It reproduced the main characteristic features of the reported microstructures quite well. It predicted a considerable volume fraction of segregation-free region in a droplet smaller than $l0{\mu}m$ if an initial undercooling larger than 100K is given. The volume fractions of the microcellular region($g_A$) and the sum of the microcellular and cellular region($g_a$) were predicted as functions of the heat transfer coefficient, h and initial undercooling, ${\triangle}T$. It was shown that $g_A$ and $g_a$, in the typical gas-atomization processes with $h=0.1-1.0W/cm^2K$, are dominated by ${\triangle}T$ and h, respectively, but for h larger than $4.0W/cm^2K$, a fully microcellular structure can be obtained irrespective of the initial undercooling.

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The Experience Study on the Floating Properties of High Flow Concrete on volum of Coarse Aggregate used Admixture (굵은골재 체적에 따른 고유동콘크리트의 유동특성에 관한 실험적 연구)

  • Choi, Sung-Woo;Kim, Ho-So;Baek, Chul-Woo;Ban, Seong-Soo;Ryu, Deuk-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.751-754
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    • 2004
  • There are many factors that affect on the flowing properties of high flowing concrete(HFC), which are fluidity, compactibility, non-segregation ability and fillingability. And because the aggregate which is one of the factors occupies high volume in concrete, it has a much effect on the properties of high flowing concrete according to its size, quality and quantity etc. This is an experimental study to analyze the effect of admixture and volume of coarse aggregate in concrete on the flowing properties of high flowing concrete. For this purpose, the kinds of admixture are fly-ash and blast furnace slag. Also volume of coarse aggregate in concrete are 280, 290, 300, 310, 320 $(\ell/m^3)$. The test of flowablity properties is slump-flow, Air content, V-lot, L-Flow. According to test results, it was found that the compactibility of HFC is more superior to use blast furnace slag than other, and according .to kind of admixture, most compatible volume of coarse are different. Also when used blast furnace slag, the volume of coarse are increased than used fly-ash.

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Microstructural Analysis on Oxide Film of Al2024 Exposed to Atmospheric Conditions (대기 노출된 Al2024 알루미늄 합금 산화막에 대한 미세조직 분석)

  • Kwon, Daeyeop;Choi, Wonjun;Bahn, Chi Bum
    • Journal of the Korean institute of surface engineering
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    • v.54 no.2
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    • pp.62-70
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    • 2021
  • Al2024 aluminum alloy specimens were exposed to atmospheric conditions for maximum 24 months and analyzed by electron microscopes to characterize their corrosion behavior and oxide film characteristics. As the exposure time increased from 12 months to 24 months, the number of pitting sites per 1 mm2 increased from ~100 to ~200. The uniform oxidation (or non-pitting) region of the 12-month exposure specimen showed 30~120 nm thick oxide layer, whereas the 24-month exposure specimen showed 170~200 nm thick oxide with the local oxygen penetration region up to 1 ㎛ deep. There was no local corrosion area observed in the 12-month exposure specimen except pitting. However, in the 24-month exposure specimen, local oxygen penetration region was observed beneath the uniform oxide layer and near the pitting cavity. Al2024 showed two times thicker uniform oxide layer but much shallower local oxygen penetration region than Al1050, which appears to be related to low Si concentration. Further research is needed on the effects of Mg segregation near the tip of the oxygen penetration region.

Development, validation and implementation of multiple radioactive particle tracking technique

  • Mehul S. Vesvikar;Thaar M. Aljuwaya;Mahmoud M. Taha;Muthanna H. Al-Dahhan
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4213-4227
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    • 2023
  • Computer Automated Radioactive Particle Tracking (CARPT) technique has been successfully utilized to measure the velocity profiles and mixing parameters in different multiphase flow systems where a single radioactive tracer is used to track the tagged phase. However, many industrial processes use a wide range of particles with different physical properties where solid particles could vary in size, shape and density. For application in such systems, the capability of current single tracer CARPT can be advanced to track more than one particle simultaneously. Tracking multiple particles will thus enable to track the motion of particles of different size shape and density, determine segregation of particles and probing particle interactions. In this work, a newly developed Multiple Radioactive Particle Tracking technique (M-RPT) used to track two different radioactive tracers is demonstrated. The M-RPT electronics was developed that can differentiate between gamma counts obtained from the different radioactive tracers on the basis of their gamma energy peak. The M-RPT technique was validated by tracking two stationary and moving particles (Sc-46 and Co-60) simultaneously. Finally, M-RPT was successfully implemented to track two phases, solid and liquid, simultaneously in three phase slurry bubble column reactors.

Degradation Damage Evaluation of High Temperature Structural Components by Electrochemical Anodic Polarization Test (전기화학적 양극분극시험에 의한 고온 설비부재의 열화손상 평가)

  • Yu, Ho-Seon;Song, Mun-Sang;Song, Gi-Uk;Ryu, Dae-Yeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.6 s.177
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    • pp.1398-1407
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    • 2000
  • The structural steels of power plant show the decrease of mechanical properties due to degradation such as temper embrittlement, creep damage and softening during long-term operation at high temper ature. The typical causes of material degradation damage are the creation and coarsening of carbides(M23C6, M6C) and the segregation of impurities(P, Sb and Sn) to grain boundary. It is also well known that material degradation induces the cleavage fracture and increases the ductile-brittle transition temperature of steels. So, it is very important to evaluate degradation damage to secure the reliable and efficient service condition and to prevent brittle failure in service. However, it would not be appropriate to sample a large test piece from in-service components. Therefore, it is necessary to develop a couple of new approaches to the non-destructive estimation technique which may be applicable to assessing the material degradation of the components with not to influence their essential strength. The purpose of this study is to propose and establish a new electrochemical technique for non-destructive evaluation of material degradation damage for Cr-Mo steels which is widely used in the high temperature structural components. And the electrochemical anodic polarization test results are compared with those of semi-nondestructive SP test.

Genetic Diversity of Fusarium proliferatum Populations from Maize, Onion, Rice and Sugarcane in Iran Based on Vegetative Compatibility Grouping

  • Alizadeh, Alireza;Javan-Nikkhah, Mohammad;Fotouhifar, Khalil-Berdi;Motlagh, Elahe Rabiee;Rahjoo, Vahid
    • The Plant Pathology Journal
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    • v.26 no.3
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    • pp.216-222
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    • 2010
  • Fusarium proliferatum is the causal agent of stalk and root rot disease of maize, foot rot disease of rice, basal and root rot disease of onion and knife cut disease of sugarcane in Iran. In recent years, incidence and severity of these diseases have been increased in Iran. Fifty seven F. proliferatum single-spore isolates collected from diseased maize, rice, onion and sugarcane plants at different areas were used to study genetic diversity by determination of vegetative compatibility groups (VCGs). Chlorate-resistant nitrate non-utilizing (nit) mutants were recovered from selected isolates of F. proliferatum and used in complementation tests. All isolates in which both nit1 and NitM (or nit3) mutants were recovered, demonstrated self-compatibility. Vegetative compatibility tests by pairing nit mutants identified 30 VCGs among 57 isolates. Twenty-three isolates belonged to singlemember VCGs and the remaining 34 isolates, belonged to other seven multimember VCGs. Segregation of F. proliferatum isolates obtained from various area and host plants into different VCGs in Iran is reported for the first time. In this study, none of isolates obtained from rice complemented with any other isolates from onion and sugarcane and, non complementation occurred between onion and sugarcane isolates. Also, only one complementation occurred between one isolate of maize and one isolate of sugarcane and rice. Thus, a correlation between VCGs grouping and host preferences was founded. It is concluded that natural populations of F. proliferatum in Iran are probably genetically divergent and include isolates representing a potential risk for disease development.

Agronomic characteristics of stay-green mutant derived from an early-maturing rice variety 'Pyeongwon'

  • Won, Yong-Jae;Ji, Hyeon-So;Ahn, Eok-Keun;Lee, Jeong-Heui;Jung, Kuk-Hyun;Lee, Sang-Bok;Hong, Ha-Cheol;Hyun, Ung-Jo;Ha, Woon-Goo;Kim, Myeong-Ki;Kim, Byeong-Ju
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.72-72
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    • 2017
  • We found a new stay-green mutant from 'Pyeongwon' which is an early-maturing rice variety in Korea. The mutant showed green leaves after grain ripening period and it maintained higher SPAD value than wild type rice plant and original variety 'Pyeongwon'. The stay-green trait in rice, three genes have been identified up to date. The non-yellow coloring1 (NYC1) gene encodes a chloroplast-localized short-chain dehydrogenase/reductase (SDR) with three transmembrane domains. The non-yellow coloring3 (NYC3) gene encodes a plastid-localizing alpha/beta hydrolase-fold family protein with an esterase/lipase motif. The Sgr gene encodes a novel chloroplast protein and regulates the destabilization of the light-harvesting chlorophyll binding protein (LHCP) complexes of the thylakoid membranes, which is a prerequisite event for the degradation of chlorophylls and LHCPs during senescence. After sequencing the PCR products, we found a single nucleotide variation($A{\rightarrow}T$) in the NYC1 gene, which changes the amino acid lysine to methionine. The NYC1 gene encodes a short-chain dehydrogenase/reductase(SDR) protein. And we confirmed the co-segregation between SNP and stay-green trait from genotyping the progenies of the mutant.

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Diet Partitioning between Co-occurring Amblychaeturichthys hexanema and Amblychaeturichthys sciistius in the Southeastern Korean Waters (동해 남부 연안에 출현하는 도화망둑 (Amblychaeturichthys hexanema)과 수염문절(Amblychaeturichthys sciistius)의 먹이 분할)

  • Huh, Sung-Hoi;Park, Joo Myun;Baeck, Gun Wook
    • Korean Journal of Ichthyology
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    • v.28 no.2
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    • pp.79-86
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    • 2016
  • Stomach contents of Amblychaeturichthys hexanema and A. sciistius (Perciformes: Gobiidae) from southeastern waters off Korea were analyzed to determine dietary habits and the presence of any inter- and intra-specific partitioning of food resources. These two species were bottom-feeding carnivores that consumed mainly benthic crustaceans, and other demersal invertebrates and planktonic organisms were also important in their diets. Non-metric multidimensional scaling (nMDS) ordination and multivariate analyses based on gravimetric contributions of the different prey taxa to stomach contents revealed significant inter-specific dietary differences; i.e. partitioning of food resources between the two species. Size-related changes, however, were not significant for their diets. Differences in the types and range of prey ingested by the two species could often be related to differences in the feeding behaviors. Our results of stomach contents analyses provide clear evidence of niche segregation between co-occurring A. hexanema and A. sciistius in southeastern Korean waters, which would reduce the likelihood of inter-specific competition for food resources.