• Title/Summary/Keyword: non-polar

Search Result 431, Processing Time 0.028 seconds

Land-Cover Classification of Barton Peninsular around King Sejong station located in the Antarctic using KOMPSAT-2 Satellite Imagery (KOMPSAT-2 위성 영상을 이용한 남극 세종기지 주변 바톤반도의 토지피복분류)

  • Kim, Sang-Il;Kim, Hyun-Cheol;Shin, Jung-Il;Hong, Soon-Gu
    • Korean Journal of Remote Sensing
    • /
    • v.29 no.5
    • /
    • pp.537-544
    • /
    • 2013
  • Baton Peninsula, where Sejong station is located, mainly covered with snow and vegetation. Because this area is sensitive to climate change, monitoring of surface variation is important to understand climate change on the polar region. Due to the inaccessibility, the remote sensing is useful to continuously monitor the area. The objectives of this research are 1) map classification of land-cover types in the Barton Peninsular around King Sejong station and 2) grasp distribution of vegetation species in classified area. A KOMPSAT-2 multispectral satellite image was used to classify land-cover types and vegetation species. We performed classification with hierarchical procedure using KOMPSAT-2 satellite image and ground reference data, and the result is evaluated for accuracy as well. As the results, vegetation and non-vegetation were clearly classified although species shown lower accuracies within vegetation class.

Preparation of Asymmetric Membranes by Addition of Nonsolvent (비용매 첨가제를 이용한 비대칭막의 제조)

  • Kim, Nowon
    • Membrane Journal
    • /
    • v.25 no.1
    • /
    • pp.32-41
    • /
    • 2015
  • High performance polysulfone microfiltration membranes with a high were successfully prepared by vapor induced phase separation (VIPS) coupled with non-solvent induced phase separation (NIPS) process. Asymmetric Membranes were prepared with PSF/DMF/PVP/PEG/DMSO/water mixed solutions and water/IPA coagulant. PSF, DMF, PVP, PEG, DMSO, water was used as a membrane polymer, a solvent, a hydrophilic polymer additive, a polar protic liquid polymer, a polar aprotic nonsolvent, and a polar protic nonsolvent in the casting solution, respectively. The addition of polar aprotic nonsolvents, and polar protic nonsolvents is a convenient and effective method to control membrane structure. In order to control the morphology of polymeric membranes, the spontaneous emulsification induced by drawing water vapor into the exposed casting solution surface has been used. Control of the internal morphology of polymeric membranes by using mixed coagulation solution such as water and IPA is discussed in the present work. The pure water permeability, pore size distribution, surface hydrophilicity and membrane morphology were investigated. Due to the addition of DMSO to casting solution, the mean pore size increased almost $0.2{\mu}m$ and the water flux increased about 1000-1800 LMH.

The Solubility Characteristics of Organic Compounds in Urban Aerosol Samples

  • Kim, Young-Min;Peter Brimblecombe;Tim Jickells;Baek, Sung-Ok
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.14 no.E
    • /
    • pp.27-40
    • /
    • 1998
  • The solubility characteristics of organic compounds were studied in terms of the extraction efficiency as a function of the polarity of the organic solvent, and the acidity of water in urban aerosol samples collected in University of East Anglia (UEA), Norwich, England. The extraction efficiency of organic compounds were evaluated with respect to the organic carbon, -nitrogen and -hydrogen by means of a wide range of solvent which include polar and nonpolar organic solvents as well as acids and alkaline water. In addition, after being dissolved in aqueous solution, the aqueous chemistry of organic compounds were studied in terms of the organic metal complexes in aerosol, which were studied with oxalic acid, copper, and zinc. The results of this study indicate that solubility characteristics of organic compounds depend on the polarity of the solvents and the acidity of the solvents. In particular, some organic compounds are water soluble, even though they are much smaller than acetone soluble fractions. In the comparison between polar organic solvent extraction and non- polar organic solvent extraction, it can be thought that significant fraction of organic compounds analysed in the aerosol samples, are polar organic compounds because of the higher extraction efficiencies of organic compounds in polar organic solvent extraction than in nonpolar organic solvent extraction. Regarding the study of the oxalic -metal complexes, it can be thought that most oxalic acids are present in the form of oxalic -copper complexes in the aerosols collected at UEA.

  • PDF

Rotated Face Detection Using Polar Coordinate Transform and AdaBoost (극좌표계 변환과 AdaBoost를 이용한 회전 얼굴 검출)

  • Jang, Kyung-Shik
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.25 no.7
    • /
    • pp.896-902
    • /
    • 2021
  • Rotated face detection is required in many applications but still remains as a challenging task, due to the large variations of face appearances. In this paper, a polar coordinate transform that is not affected by rotation is proposed. In addition, a method for effectively detecting rotated faces using the transformed image has been proposed. The proposed polar coordinate transform maintains spatial information between facial components such as eyes, mouth, etc., since the positions of facial components are always maintained regardless of rotation angle, thereby eliminating rotation effects. Polar coordinate transformed images are trained using AdaBoost, which is used for frontal face detection, and rotated faces are detected. We validate the detected faces using LBP that trained the non-face images. Experiments on 3600 face images obtained by rotating images in the BioID database show a rotating face detection rate of 96.17%. Furthermore, we accurately detected rotated faces in images with a background containing multiple rotated faces.

Synthesis and Application of Sorbic Acid Grafted Hydrogenated Dicyclopentadiene Hydrocarbon Resin (소르빅산 변성 수소첨가 DCPD계 석유수지의 합성 및 응용)

  • Kong, Won Suk;Park, Jun Hyo;Yoon, Ho Gyu;Lee, Jae Wook
    • Journal of Adhesion and Interface
    • /
    • v.16 no.1
    • /
    • pp.29-34
    • /
    • 2015
  • Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.

Phenanthrene Derivatives, 3,5-Dimethoxyphenanthrene-2,7-diol and Batatasin-I, as Non-Polar Standard Marker Compounds for Dioscorea Rhizoma

  • Yoon, Kee-Dong;Yang, Min-Hye;Nam, Sang-Il;Park, Ju-Hyun;Kim, Young-Choong;Kim, Jin-Woong
    • Natural Product Sciences
    • /
    • v.13 no.4
    • /
    • pp.378-383
    • /
    • 2007
  • Phenathrene derivatives, such as batatasins, are well-known constituents in Dioscorea Rhizoma. Although phenanthrenes have been reported as representative compounds in this plant, standard markers for quality control have been focused on the polar constituents (saponins and purine derivatives). Herein, simple, rapid and reliable HPLC method was developed to determine 3,5-dimethoxyphenanthrene-2,7-diol (DMP) and batatasin-I (BA-I) as non-polar standard maker compounds of Dioscorea Rhizoma. DMP and BA-I were analyzed under optimized HPLC conditions [column: Columbus $5{\mu}$ C18 100A ($30{\times}4.6mm$ i.d., $5{\mu}m$; mobile phase: $H_2O$ with 0.025% $CH_3COOH$ (v/v) for solvent A and $CH_3CN$ with 0.025% $CH_3COOH$ (v/v) for solvent B, gradient elution; flow rate: 2 mL/min; detection: 260 nm), and each experiment was finished within 13 min. Good linearity was achieved in the range from 0.5 to $10.0{\mu}g/mL$ for each compound, and intra- and inter-day precision were in the acceptable levels. The recovery test were performed with three different Dioscorea Rhizoma samples (D. opposita, D. batatas and D. japonica), and showed its accuracy values in the range of 97.2 - 102.8% for three different concentrations of DMP and BA-I. The content levels of DMP and BA-I were ranged under 0.0020%. These results demonstrated that amounts of DMP and BA-I are easily determined with conventional HPLC-UV-DAD method although the content levels were lower than those of saponins and allantoin in Dioscorea Rhizoma. This HPLC method could be used for quality control of various Dioscorea preparations.

Change in the non-extractable bound residue of TCAB as a function of aging period in soil (Aging 기간에 따른 TCAB의 추출불가 잔류물의 토양중 변화)

  • Lee, Jae-Koo;Kyung, Kee-Sung
    • Korean Journal of Environmental Agriculture
    • /
    • v.10 no.2
    • /
    • pp.149-157
    • /
    • 1991
  • In order to elucidate the possible change in the non-extractable bound residue of TCAB(3,3' 4,4' - tetrachloroazobenzene) in soil as a function of aging period, uniformly ring-labelled $^{14}C-TCAB$ was treated to soil(organic matter : 1.8%), and aged for 3, 6, 9, 12 and 15 months at $21{\pm}1^{\circ}C$, respectively. $^{14}CO_2$ evolution and volatilization loss during the aging were negligible. The amounts of non-extractable bound residue of TCAB increased gradually from 7.55% in 3-month aging to 19.32% in 15-month aging. Partition data suggested no formation of polar groups in the chemical structure of TCAB. Most of $^{14}C-radioactivity$ of bound residues was present in humin in the range of 50.52 to 58.93%. The fact that the number of microorganisms in soil decreased relative to the control suggested no chance of their involvement in the formation of non-extractable bound residues. Accordingly, the increase in the non-extractable bound residue of TCAB in soil with aging period is believed to be due to the transformation of the trans isomer to the cis one which is more polar and more adsorptive than the former.

  • PDF

Monte Carlo Simulation Study of Solvent Effect on Selectivity of 18-Crown-6 to between La3+ and Nd3+ Ion

  • Kim, Hag-Sung
    • Bulletin of the Korean Chemical Society
    • /
    • v.24 no.6
    • /
    • pp.751-756
    • /
    • 2003
  • We have investigated the solvent effects on Δlog $K_s$ (the difference of stability constant of binding) and the relative free energies of binding of $La^{3+} and Nd^{3+}$ ions to 18-crown-6 by a Monte Carlo simulation of statistical perturbation theory (SPT) in diverse solvents. We compared relative binding Gibbs free energies and the differences in stability constant (Δlog $K_s$) of binding of $La^{3+} and Nd^{3+}$ ions to 18-crown-6 in $CH_3OH$ in this study with the experimental. There is a good agreement between our study and the experimental. We noted that Borns function of the solvents, the electron pair donor properties of the solvent, the radii of host and guest and the differences in solvation dominate the differences in the stability constant (Δlog $K_s$) as well as the relative free energies of binding of TEX>$La^{3+} to Nd^{3+}$ ions to 18-crown-6. The results of this study appear promising for providing the association properties of crown ethers with alkaline earth metals among polar solvents and the less polar or non-polar solvents.