• Title/Summary/Keyword: non-isothermal

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On the Galaxy Formation: Two Theories of Galaxy Formation

  • Hyun, Jong-June
    • Publications of The Korean Astronomical Society
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    • v.2 no.1
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    • pp.21-29
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    • 1985
  • Two theories, the adiabatic and the isothermal, of galaxy formation are surveyed with regard to the current observational constraints, Some advantage of non-baryonic theory compared with the usual baryonic theory is discussed.

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Evaluation of Kinetic Parameters and Thermal Stability of Melt-Quenched BixSe100-x Alloys (x≤7.5 at%) by Non-Isothermal Thermogravimetric Analysis

  • Ahmad, Mais Jamil A.;Abdul-Gader Jafar, Mousa M.;Saleh, Mahmoud H.;Shehadeh, Khawla M.;Telfah, Ahmad;Ziq, Khalil A.;Hergenroder, Roland
    • Applied Microscopy
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    • v.47 no.3
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    • pp.110-120
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    • 2017
  • Non-isothermal thermogravimetry (TG) measurements on melt-quenched $Bi_xSe_{100-x}$ specimens (x=0, 2.5, 7.5 at%) were made at a heating rate ${\beta}=10^{\circ}C/min$ in the range $T=35^{\circ}C{\sim}950^{\circ}C$. The as-measured TG curves confirm that $Bi_xSe_{100-x}$ samples were thermally stable with minor loss at $T{\leq}400^{\circ}C$ and mass loss starts to decrease up to $600^{\circ}C$, beyond which trivial mass loss was observed. These TG curves were used to estimate molar (Se/Bi)-ratios of $Bi_xSe_{100-x}$ samples, which were not in accordance with initial composition. Shaping features of conversion curves ${\alpha}(T)-T$ of $Bi_xSe_{100-x}$ samples combined with a reliable flow chart were used to reduce kinetic mechanisms that would have caused their thermal mass loss to few nth-order reaction models of the form $f[{\alpha}(T)]{\propto}[1-{\alpha}(T)]^n$ (n=1/2, 2/3, and 1). The constructed ${\alpha}(T)-T$ and $(d{\alpha}(T)/dT)-T$ curves were analyzed using Coats-Redfern (CR) and Achar-Brindley-Sharp (ABS) kinetic formulas on basis of these model functions, but the linearity of attained plots were good in a limited ${\alpha}(T)-region$. The applicability of CR and ABS methods, with model function of kinetic reaction mechanism R0 (n=0), was notable as they gave best linear fits over much broader ${\alpha}(T)-range$.

Non-isothermal Crystallization Behavior of Poly(glycolide-co-ε-caprolactone-co-L-lactide) Block Copolymer (생체분해성 Poly(glycolide-co-ε-caprolactone-co-L-lactide) 블록 공중합물의 비등온 결정화 거동에 관한 연구)

  • Choi, Sei-Young;Song, Seung-Ho
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.13-23
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    • 2014
  • In this work, glycolide, L-lactide and ${\varepsilon}$-caprolactone monomers were polymerized into the triblock copolymers by two step polymerization method and their non-isothermal crystallization behaviors were studied by combination of modified Avrami and Ozawa formula for further analysis of their behaviors. The result showed that PGCLA21 gave the highest value for supercooling analysis and super cooling degree increased with L-lactide content. Crystallization velocity constant, however, showed no significant change. The result of cooling function in specific relative crystallization degree showed that the increase of L-lactide content made an effect on the more enhancement of crystallization velocity of the PGCLA than PGCL. The result of big logF(T) value with the L-lactide content above critical point for PGCLA41 and PGCLA21 showed that bigger cooling velocity needed to gain same crystal size compared with PGCL. This means that it gives negative effect in the increase of crystallization velocity.

A computational study on the removal of the non-isothermal concentrated fume from the semi-enclosed space

  • Chang, Hyuksang;Seo, Moonhyeok;Lee, Chanhyun
    • Environmental Engineering Research
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    • v.22 no.2
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    • pp.216-223
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    • 2017
  • For the prediction of the ventilation rate for removing the non-isothermal concentrated fume from the semi-enclosed space, the computational fluid dynamics (CFD) analysis was done. Securing the proper ventilation conditions in emergency state such as in fire is crucial factor for the protection of the resident in the space. In the analysis for the determining the proper ventilation rate, the experimental study had the limitation for simulating the versatile conditions of fume development. The theoretical and computational method had been chosen as the alternate tool for the experimental analysis. In this study, the CFD analysis was done on the defined model which already had been done the experimental analysis by the previous workers. By comparing the prediction on the plume heights and the ventilation rates by the CFD analysis at, and in the parametric model of $1m^3$ with those of the previous experimental works, the feasibility of the computational analysis was evaluated. For the required ventilation rate analyzed by the CFD analysis was over predicted in 7.1% difference with that of the experimental results depending on the different plume height. With the comparison with the analytical Zukoski model at, the CFD analysis on the ventilation was under predicted in 8.3%. By the verification of the feasibility of the CFD analysis, the extended analysis was done for getting the extra information such as the water vapor distribution and $CO^2$ distribution in the semi-enclosed spaces.

Study on the Non-isothermal Crystallization Kinetics of Branched Polypropylene (분지형 폴리프로필렌의 비등온결정화 거동 연구)

  • Yoon, Kyung-Hwa;Shin, Dong-Yup;Kim, Youn-Cheol
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.245-250
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    • 2012
  • Branched polypropylenes (PP) with long chain branch were prepared by solid state reaction with three different branching agent of 0.3 wt% content. The chemical structures, non-isothermal crystallization behavior and complex viscosity of the branched PP were investigated by FTIR, DSC, optical microscope, and dynamic rheological measurement. The chemical structure of the branched PP was confirmed by the existence of =C-H stretching peak of the branching agent at 3100 $cm^{-1}$. There was no distinct change in melting temperature in case of PP-D-0-3 and PP-F-0-3, but PP-H-0-3 indicated a decrease in melting temperature. The decrease in melting temperature was interpreted by the fact that the degradation reaction of PP was more dominant than branched reaction, and confirmed by a decrease in complex viscosity. The non-isothermal crystallization behavior of the branched PP was analyzed using by Avrami equation. The Avrami exponent of PP was 3, and the values of the branched PP with DVB and FS were below 3. The activation energy of PP calculated by Kissinger method was 25 kJ/mol, and there were no big difference in activation energies of the branched PPs compared to PP.

Development of Finite Element Program for Analyzing Springback Phenomena of Non-Isothermal Forming Processes for Aluminum Alloy Sheets (Part2 : Theory & Analysis) (알루미늄 합금박판 비등온 성형공정 스프링백 해석용 유한요소 프로그램 개발 (2부 : 이론 및 해석))

  • ;;R.H. Wagoner
    • Transactions of Materials Processing
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    • v.12 no.8
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    • pp.710-717
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    • 2003
  • The implicit, finite element analysis program for analyzing the springback in the warm forming process of aluminum alloy sheets was developed. For the description of planar anisotropy in warm forming temperatures, Barlat's yield function is employed, and the power law type constitutive equation is used in terms of working temperatures for the depiction of work hardening in high temperatures. Also, Jetture's 4-node shell elements are introduced for reflecting the mechanical behavior of aluminum alloy sheet and the non-steady heat balance equations are solved for considering heat gain and loss during the forming process. For the springback evaluation, Newton-Raphson iteration method is introduced for overcoming the geometric nonlinearlity problem. In order to verify the validity of the FEM program developed, the stretching bending and springback processes are simulated. Though springback analysis results are slightly bigger than experimental ones, they have the same trend of the decreasing springback as the forming temperature increases.

Development of Finite Element Program for Analyzing Springback Phenomena of Non-isothermal Forming Processes for Aluminum Alloy Sheets (Part II : Theory & Analysis) (알루미늄 합금박판 비등온 성형공정 스프링백 해석용 유한요소 프로그램 개발 (2부 : 이론 및 해석))

  • Keum Y. T.;Han B. Y.;Wagoner R.H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.08a
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    • pp.13-20
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    • 2003
  • The implicit, finite element analysis program for analyzing the springback in the warm forming process of aluminum alloy sheets was developed. For the description of planar anisotropy in warm forming temperatures, Barlat's yield function is employed, and the power law type constitutive equation is used in terms of working temperatures fur the depiction of work hardening in high temperatures. Also, Jetture's 4-node shell elements are introduced for reflecting the mechanical behavior of aluminum alloy sheet and the non-steady heat balance equations are solved for considering heat gain and loss during the forming process. For the springback evaluation, Newton-Raphson iteration method is introduced for overcoming the geometric nonlinearlity problem. In order to verify the validity of the FEM program developed, the stretching bending and springback processes are simulated. Though springback analysis results are slightly bigger than experimental ones, they have the same trend of the decreasing springback as the forming temperature increases.

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The study on the Two-Phase Swirl Flow Characteristics in Cylindrical Pipe (원관내의 이상선회유동 특성에 관한 연구)

  • 차경옥;김재근
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.1
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    • pp.187-197
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    • 1996
  • Many investigations have been made to determine the pressure drop and heat transfer characteristics for single phase flow in tape generated swirl flow. But few studies have been carried out to investigate the heat transfer in two component, two phase swirl flow with non-boiling. An experimental study has been conducted to determine the effects of tape twist ratios on two phase convective heat transfer coefficients, pressure drop, and void fraction distribution in a non-boiling, air-water, two phase flow. The flow conditions were both swirl and non swirl flows. The internal diameter of the test section is 42.5mm. The tape twist ratios of pitch to diameter ratio varied from 4.0 to 10.6. The heating conditions were isothermal and nonisothermal. The flow patterns identified with experiments were bubbly, bubbly-slug, slug, and slug-annular flow in up-flow. This study has concluded that no significant difference in void fraction distribution were observed both isothermal and nonisothermal conditions, the pressure drop for two phase flow with twisted tape swirler increase as the tape twist ratio decrease, and that values of two phase heat transfer coefficient increase when the tape twist ratio decreases.

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Optimal Process Design in Non-Steady Metal Forming by the Design Sensitivity (설계민감도를 이용한 비정상상태 소성가공공정 최적 설계)

  • 정석환;황상무
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.03a
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    • pp.113-118
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    • 1997
  • A new approach to process optimal design in non-isothermal, non-steady state metal forming is presented. In this approach, the optimal design problem is formulated on the basis of the integrated thermo-mechanical finite element process model so as to cover a wide range of the objective functions and design variables, and the derivative based approach is adopted for conducting optimization by design iteration. The process model, the formulation for process optimal design, and the procedures for the evaluation of the design sensitivity and for design iteration for optimization are described.

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