• 제목/요약/키워드: non-chemical

검색결과 3,850건 처리시간 0.03초

Controlling the pore size of macroporous membranes by adding non-solvent

  • Shin, Se-Jong;Im, Se-Jun;Park, Seung-Ryul;Lee, Seung-Yun;Min, Byoung-Ryul
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
    • /
    • pp.107-114
    • /
    • 2003
  • This study investigated the effect of 2-methoxy ethanol (2-Me) non-solvent as additive included in casting solution. Macroporous polymer membranes were prepared by using polyethersufone (PES)/N-methyl-2-pyrrolidone (NMP)/2-Me casting solution and water coagulant. The phase separation co-process of the vapor-induced phase separation (VIPS) and liquid-induced phase separation (LIPS) were used by means of membrane preparation method. The pore size and pore size distribution were controlled with additive (non-solvent), and measured with Automated Perm Porometer. By increasing additive (non-solvent) in the casting solution, the membranes produced changed from finger structure to sponge structure. That is due to the different diffusion rates. At slow diffusion process, sponge-like structure was formed and at fast diffusion process, finger-like structure was formed. Also relative humidity, evaporation time, temperature of casting solution and coagulation bath etc. had effects on the pore size distribution and the porosity of the membrane.

  • PDF

Improvement in the Quality of Kimchi by Fermentation with Leuconostoc mesenteroides ATCC 8293 as Starter Culture

  • Li, Ling;Yan, Yu;Ding, Weiqi;Gong, Jinyan;Xiao, Gongnian
    • 한국미생물·생명공학회지
    • /
    • 제48권4호
    • /
    • pp.533-538
    • /
    • 2020
  • To investigate the effect of the predominant microorganisms in kimchi on quality, Leuconostoc mesenteroides ATCC 8293 was used as starter culture during kimchi fermentation. A higher number of lactic acid bacteria and lower initial pH were observed in starter kimchi than in non-starter kimchi in the early stage of fermentation. The concentrations of the main metabolite, lactic acid, were 69.88 mM and 83.85 mM for the non-starter and starter fermented kimchi, respectively. The free sugar concentrations of starter kimchi decreased earlier than those of non-starter kimchi, and the levels of free sugars in both kimchi samples decreased during fermentation. At the end of fermentation, non-starter kimchi had a softer texture than starter kimchi, suggesting that L. mesenteroides is useful in extending shelf life. Sensory evaluation showed that starter kimchi had higher sourness and lower bitterness and astringency values, resulting in high sensory quality. These results suggest that the L. mesenteroides ATCC 8293 strain could be a potential starter culture in kimchi.

화장품 제조업 근로자의 화학물질 인식도 비교 (Comparison of Recognition of Chemical Substances of Cosmetics Manufacturing Workers)

  • 이상민;박근섭;어원석
    • 한국안전학회지
    • /
    • 제35권2호
    • /
    • pp.17-27
    • /
    • 2020
  • To identify the relationship between types of employment(regular and non-regular group) and departments classification (administration, product and research group) and the levels of recognition of chemical substances, a total of 117 workers in cosmetics workplaces. Mainly, regular group and research group showed higher recognition of chemical substances (PPE, ventilation, chemical management, hazards in handling chemicals, skin contact) than non-regular group and administration, product group, but In some cases, production and administrative groups were high. Descriptive statistics(SAS ver9.2)was performed. the results of recognition of chemical substances were analyzed the mean and standard deviation by t-test, and anova, (P=0.05). These results cosmetics manufacturing workplaces have normal level of the perception of chemical substances. In most of the employment types, the regular workers showed high recognition, and the working departments showed high recognition in the research and production groups. Therefore, OEM and ODM cosmetics manufacturers regularly identify characteristics and needs of workplaces and workers, and suggest the development of experience and practiced education programs and risk assessment tools that can raise worker awareness.

Facile preparation of superhydrophobic thin films using non-aligned carbon nanotubes

  • Goh, Yee-Miin;Han, Kok Deng;Tan, Lling-Lling;Chai, Siang-Piao
    • Advances in nano research
    • /
    • 제2권4호
    • /
    • pp.219-225
    • /
    • 2014
  • A simple preparation method on creating superhydrophobic surface using non-aligned carbon nanotubes (CNTs) was demonstrated. Superhydrophobic CNT thin films were prepared by doping a sonicated mixture of CNTs and chloroform onto a glass slide. Water contact angles of the CNT thin films were measured using a contact angle goniometer. The thin films were characterized using laser microscope and scanning electron microscope. Experimental results revealed that the highest average contact angle of $162{\pm}2^{\circ}$ was achieved when the films' thickness was $1.628{\mu}m$. The superhydrophobic surface was stable as the contact angle only receded from $162{\pm}2$ to $157{\pm}2^{\circ}$ after 10 min under normal atmospheric condition.

The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

  • Kim, Kyoung-Ho;Kim, Min-Soo;Yeu, Tae-Whan
    • Bulletin of the Korean Chemical Society
    • /
    • 제31권11호
    • /
    • pp.3183-3189
    • /
    • 2010
  • In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials. The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides. The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects; the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium ($Li^+$) ions. The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrode.

Hydrophobic Membrans of Tetrafluoroethylene and 2,2,4, Trifluoro 5 Trifluorometoxy 1,3 Dioxole

  • Gordano, A.;Clarizia, G.;Tocci, E.;Drioli, E.
    • Korean Membrane Journal
    • /
    • 제1권1호
    • /
    • pp.50-58
    • /
    • 1999
  • Symmetric asymmetric and composite perfluoropolymer membranes made with HYFLON AD have been prepared and evaluated. Porous and non porous symmetric membranes have been prepared by solvent evaporation with various processing conditions. Non-contact atomic force microscopy (AFM) was used to investigate the membrane morphology in air. Analysis of the images gave quantitative imformation on the surface pore strcture in particular on the pore size distributin. Possible useful uses of porous membranes are envisaged in the field of gas-liquid separations such as membrane contactors (MSc) Molecular Dynamics(MD) simulations structure of HYFLON AD 60X copolymer supporting these results are also reported. Amorphous perfluoropolymer membranes appears to be ideal other than in MCs when separation processes have to be performed in hostile environments i.e. high temperatures and aggressive non-aqueous media such as chemicals and solvents. In these cases HYFLON AD mem-branes can exploit the outstanding resistance of perfluoropolymers.

  • PDF

Non-negative matrix factorization 을 이용한 마이크로어레이 데이터의 클러스터링 (Clustering gene expression data using Non -Negative matrix factorization)

  • Lee, Min-Young;Cho, Ji-Hoon;Lee, In-Beum
    • 한국생물정보학회:학술대회논문집
    • /
    • 한국생물정보시스템생물학회 2004년도 The 3rd Annual Conference for The Korean Society for Bioinformatics Association of Asian Societies for Bioinformatics 2004 Symposium
    • /
    • pp.117-123
    • /
    • 2004
  • 마이크로어레이 (microarray) 기술이 개발된 후로 연관된 유전자 클러스터 (cluster)를 찾는 문제는 깊이 연구되어왔다. 이 문제는 핵심적인 과제 중 하나는 생물학적으로 타당한 클러스터의 수를 결정하는 데 있다. 본 논문은 최적의 클러스터 수를 결정하는 기준을 제시하고, non-negative factorization (NMF)를 이용해 클러스터 centroid의 패턴을 찾는 방법을 제안한다. NMF에 의해 발견된 각각의 패턴은 생물학적 프로세스의 특정 부분으로 해석될 수 있다. NMF는 factor matrix의 entity를 non-negative로 제약 (constraint)하고, 이 제약은 오직 additive combination만 허용하기 때문에 이러한 부분적인 패턴을 찾아낼 수 있다. NMF의 유용성은 이미지 분석과 텍스트 분석에서 이미 입증되어 있다. 본 논문에서 제안한 방법에 의해 위의패턴과 유사한 발현 패턴을 갖는 유전자를 모을 수 있었다. 제안된 방법은 human fibroblast데이터와 yeast cell cycle 데이터에 적용해 성능을 입증하였다.

  • PDF

The Effect of Mechanical Properties of Polishing Pads on Oxide CMP(Chemical Mechanical Planarization)

  • Hong, Yi-Koan;Eom, Dae-Hong;Kang, Young-Jae;Park, Jin-Goo;Kim, Jae-Seok;Kim, Geon;Lee, Ju-Yeol;Park, In-Ha
    • KSTLE International Journal
    • /
    • 제5권1호
    • /
    • pp.32-35
    • /
    • 2004
  • The purpose of this study is to investigate the effects of the structure and mechanical properties of laser-processed pads on their polishing behavior such as their removal rate and WIWNU (within wafer non-uniformity) during the chemical mechanical planarization (CMP) process. The holes on the pad acted as the reservoir of slurry particles and enhanced the removal rate. Without grooves, no effective removal of wafers was possible. When the length of the circular-type grooves was increased, higher removal rates and lower wafer non-uniformity were measured. The removal rate and non-uniformity linearly increased as the elastic modulus of the top pad increased. Higher removal rates and lower non-uniformity were measured as the hardness of the pad increased.

Synthesis and Non-Isothermal Crystallization Behaviors of Maleic Anhydride onto High Density Polyethylene

  • Ahn, Youngjun;Jeon, Jong Hyuk;Baek, Chul Seoung;Yu, Young Hwan;Thenepalli, Thriveni;Ahn, Ji Whan;Han, Choon
    • 한국세라믹학회지
    • /
    • 제53권1호
    • /
    • pp.24-33
    • /
    • 2016
  • The grafting reaction for maleic anhydride (MA) onto high density polyethylene (HDPE) was investigated from solution process with initiators. The chemical modification of neat HDPE was carried out with various contents of MA (3-21 wt.%) and initiator (0.2-1 wt.%) at different temperature ($80-130^{\circ}C$). The grafting degree was obtained from the titration and the highest grafting degree was 3.1%. The grafting degree increased as the content of MA and initiator increased, however, the highest grafting degree was demonstrated for a particular content of MA and initiator. In the non-isothermal crystallization kinetics, the Ozawa model was unsuitable method to investigate the crystallization behavior of MA onto HDPE, whereas the Avrami and Liu models found effective. The crystallization rate was accelerated as the cooling rate increased, but postponed by combination of MA onto neat HDPE backbone.

New Separators Based on Non-Polyolefin Polymers for Secondary Lithium Batteries

  • Seol, Wan-Ho;Lee, Yong-Min;Lee, Jun-Young;Han, Young-Dal;Ryu, Myung-Hyun;Park, Jung-Ki
    • 전기화학회지
    • /
    • 제10권2호
    • /
    • pp.82-87
    • /
    • 2007
  • New porous separators based on non-polyolefin materials including the blend of poly (vinyl chloride) (PVC)/poly (vinylidene fluoride-co-hexafluoropropylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA), and the porous separator based on poly (vinylidene fluoride) (PVdF) were prepared by phase inversion method. The porosity and morphology were controlled with phase inversion rate, which is governed by the relative content of non-solvent and solvent in coagulation bath. To enhance tensile strength, the solvent pre-evaporation and uni-axial stretching processes were applied. The ionic conductivity was increased with increasing stretching ratio, and tensile strength was increased with increasing solvent pre-evaporation time and stretching ratio. The 200% stretched PVdF separator showed 56 MPa of tensile strength, and the ionic conductivity of the stretched PVdF separator was $8.6{\times}10^{-4}\;S\;cm^{-1}\;at\;25^{\circ}C$.