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$NO_x$Removal by using Double Barrier Discharge (이중베리어방전을 이용한 $NO_x$ 제거)

  • Kim, Dong-Uk;Jeong, Yeong-Sik
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.1
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    • pp.37-43
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    • 2000
  • In this experimental study we proposed the double dielectric barrier discharge (DDBD) reactor to produce as high an electric field as possible. The experiment are conducted for applied voltage from 15 to 20[kV], $1~4[\ell/min]$ of gas flow rate and 120[Hz] and 240[Hz] of pulse rate. Superposition discharge(SPD) generated in DDBD which combined the surface discharge with the silence discharge was the most effective to reduce the $NO_x$. In the decomposition efficiency per watt, the low pulse rate gave better efficiency than the high pulse rate. However in DeNOx rate, the high pulse rate gave better performance than the low pulse rate. $NO_x$ removal rate and efficiency increased with increasing the applied voltage in all reactors.

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Porous Photocatalytic Concrete Filter Manufacturing and Efficiency Evaluation for NOx Reduction (NOx 저감을 위한 다공성 광촉매 콘크리트 필터 제조 및 효율평가)

  • Kim, Jong Kyu
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.223-229
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    • 2022
  • A porous photocatalyst concrete filter was successfully produced to remove NOx, by mixing TiO2 photocatalyst with lightweight aerated concrete. Ultra Fine Bubbles were used to form continuous pores inside the porous photocatalytic concrete filter, which was mixed via a bubble generation experiment. The optimal mixing condition was determined to be with 4 % of the bubble generation agent B. NO removal specimens were prepared for various photocatalytic loading conditions, and the specimen containing 3 % P-25 removed NO at a concentration of 1.03 µmol in 1 h. The NO removal rate of the porous photocatalytic concrete filter prepared in this study was 10.99 %. This photocatalytic filter performance was more than 9 times the amount of NO removed by a general photocatalytic filter. The porous photocatalyst concrete filter for removing NOx developed in this study can be applied to various construction sites and the air quality can be solved by reducing NOx contributing to the formation of fine particles.

Removal of Nitrogen and Phosphorus by Salix gracilistyla Miq. (갯버들(Salix gracilistyla Miq.)의 질소와 인 제거능)

  • 신정이;차영일
    • Korean Journal of Environmental Biology
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    • v.17 no.4
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    • pp.449-457
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    • 1999
  • Removal efficiency and potential of N and P by Salix gracilistyla Miq. are determined in continuous flow tanks as a function of hydraulic retention time (HRT, days) and nutrient concentration (NC). Results show that the removal efficiency was longer HRT and lower nutrient solution. And also removal potential was higher at shorter HRT and higher nutrient concentration, and the regression equations were estimated. Mean above ground biomass of Salix gracilistyla Miq. in the middle reaches of Suip stream was 4880.81 g/$m^2$, and estimated removal by this vegetation from biomass and estimated equation above were 0.49~15.49 NH$_4$-N kg/day, 5.83~405.39 NO$_3$-N kg/day, 7.57~23.22 PO$_4$-P kg/day in Suip stream, respectively when HRT was 0.59~5.21, inflow concentration was 0.05~0.4, mg/L NH$_4$-N, 1.42~11.36 mg/L NO$_3$-N, 0.1~0.27 mg/L PO$_4$-P. According to this study, it is concluded that Salix gracilistyla Miq. are contribute by their high biomass and for water quality improvement of stream through nutrient removal potential.

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Bacterial Community and Biological Nitrate Removal: Comparisons of Autotrophic and Heterotrophic Reactors for Denitrification with Raw Sewage

  • Lee, Han-Woong;Park, Yong-Keun;Choi, Eui-So;Lee, Jin-Woo
    • Journal of Microbiology and Biotechnology
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    • v.18 no.11
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    • pp.1826-1835
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    • 2008
  • An autotrophic denitrification reactor (ADR-l) and a heterotrophic denitrification reactor (HDR-2) were operated to remove nitrate and nitrite in an anoxic environment in raw sewage. The $NO_3$-N removal rate of ADR-l was shown to range from 52.8% to 78.7%, which was higher than the $NO_3$-N removal rate of HDR-2. Specific denitrification rates (SDNR) of ADR-l and HDR-2 were 3.0 to 4.0 and 1.1 to $1.2\;mgNO_3$-N/gVSS/h, respectively. From results of restriction fragment length polymorphism (RFLP) of the 16S rRNA gene, Aquaspirillum metamorphum, Alcaligenes defragrans, and Azoarcus sp. were $\beta$-Proteobacteria that are affiliated with denitritying bacteria in the ADR-l. Specifically, Thiobacillus denitrificans was detected as an autotrophic denitrification bacteria. In HDR-2, the $\beta$-Proteobacteria such as Denitritying-Fe-oxidizing bacteria, Alcaligenes defragrans, Acidovorax sp., Azoarcus denitrificans, and Aquaspirillum metamorphum were the main bacteria related to denitrifying bacteria. The $\beta$-and $\alpha$-Proteobacteria were the important bacterial groups in ADR-l, whereas the $\beta$-Proteobacteria were the main bacterial group in HDR-2 based on results of fluorescent in situ hybridization (FISH). The number of Thiobacillus denitrificans increased in ADR-l during the operation period but not in HRD-2. Overall, the data presented here demonstrate that many heterotrophic denitritying bacteria coexisted with autotrophic denitrifying bacteria such as Thiobacillus denitrificans for nitrate removal in ADR-l. On the other hand, only heterotrophic denitritying bacteria were identified as dominant bacterial groups in HDR-2. Our research may provide a foundation for the complete nitrate removal in raw sewage of low-COD concentration under anoxic condition without any external organic carbon or the requirement of post-treatment.

Effectiveness and safety of rotary and reciprocating kinematics for retreatment of curved root canals: a systematic review of in vitro studies

  • Lucas Pinho Simoes;Alexandre Henrique dos Reis-Prado;Carlos Roberto Emerenciano Bueno;Ana Cecília Diniz Viana ;Marco Antonio Hungaro Duarte ;Luciano Tavares Angelo Cintra;Cleidiel Aparecido Araujo Lemos;Francine Benetti
    • Restorative Dentistry and Endodontics
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    • v.47 no.2
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    • pp.22.1-22.18
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    • 2022
  • Objectives: This systematic review (register-osf.io/wg7ba) compared the efficacy and safety of rotary and reciprocating kinematics in the removal of filling material from curved root canals. Materials and Methods: Only in vitro studies evaluating both kinematics during retreatment were included. A systematic search (PubMed/MEDLINE, Scopus, and other databases, until January 2021), data extraction, and risk of bias analysis (Joanna Briggs Institute checklist) were performed. Efficacy in filling removal was the primary outcome. Results: The search resulted in 2,795 studies, of which 15 were included. Efficacy was measured in terms of the remaining filling material and the time required for this. Nine studies evaluated filling material removal, of which 7 found no significant differences between rotary and reciprocating kinematics. Regarding the time for filling removal, 5 studies showed no difference between both kinematics, 2 studies showed faster results with rotary systems, and other 2 showed the opposite. No significant differences were found in apical transportation, centering ability, instrument failure, dentin removed and extruded debris. A low risk of bias was observed. Conclusions: This review suggests that the choice of rotary or reciprocating kinematics does not influence the efficacy of filling removal from curved root canals. Further studies are needed to compare the kinematics safety in curved root canals.

Removal of Nitrate-Nitrogen in Pickling Acid Wastewater from Stainless Steel Industry Using Electrodialysis and Ion Exchange Resin (전기투석과 이온교환수지를 이용한 스테인레스 산업의 산세폐수 내 질산성 질소의 제거)

  • Yun, Young-Ki;Park, Yeon-Jin;Oh, Sang-Hwa;Shin, Won-Sik;Choi, Sang-June;Ryu, Seung-Ki
    • Journal of Environmental Science International
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    • v.18 no.6
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    • pp.645-654
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    • 2009
  • Lab-scale Electrodialysis(ED) system with different membranes combined with before or after pyroma process were carried out to remove nitrate from two pickling acid wastewater containing high concentrations of $NO_3\;^-$(${\approx}$150,000 mg/L) and F($({\approx}$ 160,000 mg/L) and some heavy metals(Fe, Ti, and Cr). The ED system before Pyroma process(Sample A) was not successful in $NO_3\;^-$ removal due to cation membrane fouling by the heavy metals, whereas, in the ED system after Pyroma process(Sample B), about 98% of nitrate was removed because of relatively low $NO_3\;^-$ concentration (about 30,000 mg/L) and no heavy metals. Mono-selective membranes(CIMS/ACS) in ED system have no selectivity for nitrate compared to divalent-selective membranes(CMX/AMX). The operation time for nitrate removal time decreased with increasing the applied voltage from 10V to 15V with no difference in the nitrate removal rate between both voltages. Nitrate adsorption of a strong-base anion exchange resin of $Cl\;^-$ type was also conducted. The Freundlich model($R^2$ > 0.996) was fitted better than Langmuir mode($R^2$ > 0.984) to the adsorption data. The maximum adsorption capacity ($Q^0$) was 492 mg/g for Sample A and 111 mg/g for Sample B due to the difference in initial nitrate concentrations between the two wastewater samples. In the regeneration of ion exchange resins, the nitrate removal rate in the pickling acid wastewater decreased as the adsorption step was repeated because certain amount of adsorbed $NO_3\;^-$ remained in the resins in spite of several desorption steps for regeneration. In conclusion, the optimum system configuration to treat pickling acid wastewater from stainless-steel industry is the multi-processes of the Pyroma-Electrodialysis-Ion exchange.

Operation of CROM System and its Effects of on the Removal of Seston in a Eutrophic Reservoir Using a Native Freshwater Bivalve (Anodonta woodiana) in Korea. (담수산 이매패 펄조개를 이용한 흐름형 유기물 제어(CROM) 운영 - 퇴적물의 영향)

  • Kim, Baik-Ho;Baik, Soon-Ki;Hwang, Su-Ok;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.161-171
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    • 2009
  • A 'continuous removal of organic matters (CROM) system' using a native freshwater bivalve in Korea Anodonta woordiana, was developed to determine its potential of controlling various sestons in eutrophic lake system, and to evaluate its effect on water quality improvement under consideration of sediment addition as habitat. We designed CROM experiments with four treatments: no mussels and no sediment (W, negative control), no mussels and sediment (WS, positive control), mussels and no sediment (WM), and mussels and sediment (WMS). The experiments were performed at the condition of 18${\sim}$25 L $h^{-1}$ of inflow, mussel density of 486.1 indiv. $m^{-2}$, and temperatures between 15 and $22^{\circ}C$ for 13 consecutive days. Physicochemical and biological parameters were measured at daily (10:00 am) intervals after the mussel addition. Results indicated that mussel stockings without addition of sediment effectively removed sestons (suspended solids and chlorophyll-a) at nearly same level over 80 percentage of the control during the study, while there were no differences in removal activities of sestons between with and without sediment (P>0.5). Therefore, it clearly suggests that CROM system using A. woordiana has a strong potential to control the seston in surface water of eutrophic lake.

Correlation Research between Simultaneous Removal Reaction for NOx, Soot and Physico-chemical Properties of Pt/TiO2's Supports (Pt/TiO2 촉매의 담체 물성과 NOx, Soot 동시 반응특성과의 상관관계 연구)

  • Kim, Sung Su;Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.178-182
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    • 2010
  • Simultaneous removal reaction for NOx, soot over Pt catalysts using various $TiO_2$ as support was studied. The catalytic tests ware carried out injectin NO, soot, NO and soot simultaneously on each catalysts. As results, it showed different NOx removal efficiency and soot oxidation rate according to various kinds of $TiO_2$. Onset temperature of soot oxidation has a correlation to $NO_2$ generated for the independently performed NOx. It was investigated that NO to $NO_2$ oxidation was intimately related to crystallite size and surface area, and it has a tremendous impact on Pt aggregation on the catalyst surface and catalyst' reducibility. Therefore, we concluded that major index of the reaction was physico-chemical properties of catalyst' supports.

Effect of pH and Initial Phosphorus Concentration on Phosphorus Removal by Aluminum Salts (알루미늄염에 의한 인 제거 시 pH와 초기 인 농도의 영향)

  • Park, Jeongwon;Kwak, Hyoeun;Min, Sojin;Chung, Hyung-Keun;Park, Pyung-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.2
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    • pp.123-130
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    • 2016
  • Phosphorus (P) removal by aluminum sulfate solution was investigated with varying pH and initial P concentrations. P removal was the highest at around pH 6. The pH range where P removal occurred was slightly wider at higher initial P concentrations. Compared to theoretical calculations, it was confirmed that $AlPO_4$ precipitation was the main reason for P removal at low pH. At high pH, where there should be no $AlPO_4$ precipitates, the P removal by adsorption of amorphous $Al(OH)_3$ precipitates was experimentally observed. The P removal by adding amorphous $Al(OH)_3$ precipitates prepared before the adsorption experiments, however, was lower than that by injecting aluminum sulfate solution because the prepared precipitates became larger, leading to less specific surface area available for adsorption. Ions other than sulfate had little influence on P removal.

Removal characteristics of surfactant by ozone and biological activated carbon (오존과 생물활성탄에 의한 합성세제 제거 특성 연구)

  • Ku, Suk Hyen;Kwon, Jin Hyoung;Lee, Jae In;Lim, Jin Kyung;Kim, Dong Youn
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.1
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    • pp.99-107
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    • 2000
  • In this article, the removal of surfactant by ozone and BAC was studied. Batch and pilot tests were carried out for these studies. In batch tests, efficiency of ozone oxidation process was evaluated for LAS(Linear Alkylbenzen Sulfonate) and SLS(Sodium Lauryl Sulfate) removal. Under oxidant conditions, the removal of LAS was more effective than that of SLS. The removal of surfactant was more enhanced with increasing pH in oxidant systems. Pilot tests are carried out with BAC single process and ozone oxidation/BAC combined process. The removal of LAS was more effective in ozone oxidation/BAC combined process than BAC single process about 10-20%. In the case of SLS, the efficiency of BAC single process was similar to that of ozone oxidation BAC combined process. According to temperature, the removal efficiency of SLS changed from 70% to 95% and initial concentration of surfactant had no effects on removal efficiency of SLC under applied temperature above $15^{\circ}C$.

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