• 제목/요약/키워드: nitrous oxide

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하수처리수의 방류를 받는 하천감조부에서의 N2O생성 (Production of Nitrous Oxide in Tatara Estuary Receiving Treated Wastewater)

  • 이승윤
    • 한국수자원학회논문집
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    • 제42권8호
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    • pp.631-641
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    • 2009
  • 본 연구는 부영양화되어 있는 하구감조역에서의 $N_2O$생성과 거동을 파악하는 것을 목적으로 도시역에서의 N2O발생에 착안하여 그 중에서도 인위적 임팩트가 크다고 판단되는 하수처리수 생활폐수 등이 유입되는 도시하천감조역을 대상으로 현지 정점조사를 실시하여 수역의 사계절에 걸친 각 질소성분의 농도변화와 flux를 상세히 파악하고 저질간극수 중의 연직분포를 측정하였다. 그 결과, 완혼합이고 염수쐐기설(楔)가 형성되는 Tatara천(川)에서 하수처리수는 해수의 혼합형태의 영향을 크게 받고 고농도수괴(水塊)로서 표층을 이동하고 있으며, 이 수역의 질소변환기구 및 $N_2O$생성과정에 큰 영향을 미치고 있는 것이 밝혀졌다. 이 수역에서 관측된 $N_2O$농도는 1.8-20.9 $\mu M$로서 대기중의 포화농도와 담수중의 포화농도를 고려하면 항상 포화농도상태이며, 주발생원은 수역저토였다. 저질간극수 중의 각 질소성분의 농도분포는 호소와 인근해역에서의 분포와는 달리 분자확산 이외의 수송경로가 있다는 것이 시사되었다.

Effect of Mixed Treatment of Urea Fertilizer and Zeolite on Nitrous Oxide and Ammonia Emission in Upland Soil

  • Park, Jun-Hong;Park, Sang-Jo;Seo, Young-Jin;Kwon, Oh-Heun;Choi, Seong-Yong;Park, So-Deuk;Kim, Jang-Eok
    • 한국토양비료학회지
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    • 제47권5호
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    • pp.368-373
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    • 2014
  • Ammonia loss from urea significantly hinders efficient use of urea in agriculture. The level of nitrous oxide ($N_2O$) a long-lived greenhouse gas in atmosphere has increased mainly due to anthropogenic source, especially application of nitrogen fertilizers. There are reports in the literature showing that the addition of zeolite to N sources can improve the nitrogen use efficiency. This study was conducted to evaluate nitrous oxide ($N_2O$) and ammonia ($NH_3$) emission by mixed treatment of urea and zeolite in upland crop field. Urea fertilizer and zeolite were applied at different rates to study their effect on $N_2O$ emission during red pepper cultivation in upland soils. The $N_2O$ gas was collected by static closed chamber method and measured by gas chromatography. Ammonia concentration was analyzed by closed-dynamic air flow system method. The total $N_2O$ flux increased in proportion to the level of N application. Emission of $N_2O$ from the field increased from the plots applied with urea-zeolite mixture compared to urea alone. But urea-zeolite mixture treatment reduced about 30% of $NH_3$-N volatilization amounts. These results showed that the application of urea and zeolite mixture had a positive influence on reduction of $NH_3$ volatilization, but led to the increase in $N_2O$ emission in upland soils.

Effect of Intermittent Drainage on Nitrous Oxide Emission and Global Warming Potential in Rice Paddy Soil

  • Kim, Gun-Yeob;Lee, Seul-Bi;Lee, Jong-Sik;Choi, Eun-Jung
    • 한국토양비료학회지
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    • 제45권6호
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    • pp.1187-1193
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    • 2012
  • Water control is mainly one of the key factors that can affect nitrous oxide ($N_2O$) emissions from soils. This study was undertaken to determine the effect of intermittent drainage compared to continuous flooding (conventional water regime) on $N_2O$ emission to global warming potential (GWP) with NPK (standard cultivation practice), NPK+Straw, and PK fertilizations. Nitrous oxide emission rates were collected twice a week using a closed chamber method. With continuous flooding, nitrogen (N) application increased $N_2O$ emission by 106.6% ($0.64kg\;ha^{-1}$ in NPK) with respect to the PK treatment ($0.31kg\;ha^{-1}$), and straw addition to NPK enhanced 148.3% of seasonal $N_2O$ flux ($0.77kg\;ha^{-1}$ in NPK+Straw). Although seasonal $N_2O$ emission slightly increased by 16.1-42.9% with intermittent irrigation, its seasonal $CH_4$ emission drastically reduced at 43.5-52.8% resulting in a lower GWP at 48.9-58.5% with respect to that of continuously flooded treatments ($4.51Mg\;CO_2\;ha^{-1}$, PK; $7.60Mg\;CO_2\;ha^{-1}$, NPK; $14.55Mg\;CO_2\;ha^{-1}$, NPK+Straw). Rice yield, at similar fertilization with the continuously-flooded rice field, was not affected by intermittent irrigation. Conclusively, intermittent irrigation can be very effective and a rational soil management strategy to mitigate GWP with considering rice productivity in a temperate paddy rice field like Korea.

Effect of Dicyandiamide and Hydroquinone on Ammonia and Nitrous Oxide Emission from Pig Slurry Applied to Timothy (Phleum pretense L.) Sward

  • Park, Sang-Hyun;Lee, Bok-Rye;Kim, Tae-Hwan
    • 한국초지조사료학회지
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    • 제36권3호
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    • pp.199-204
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    • 2016
  • The objective of this study was to determine the effect of nitrification inhibitor dicyandiamide (DCD) and urease inhibitor hydroquinone (HQ) on ammonia ($NH_3$) and nitrous oxide ($N_2O$) emission from pig slurry applied to Timothy (Phleum pretense L.) sward. The daily emission of ammonia ($NH_3$) and nitrous oxide ($N_2O$) was monitored for 9 days in three different treatments; 1) control (only pig slurry application), 2) DCD treatment (pig slurry + DCD), and 3) HQ treatment (pig slurry + HQ). Most $NH_3$ emission occurred after 4~5 days in three treatments. Total $NH_3$ emission, expressed as a cumulative amount throughout the measurement time, was $1.33kg\;N\;ha^{-1}$ in the control. The DCD and HQ treatment decreased total $NH_3$ emission by 16.3% and 25.1%, respectively, compared to the control. Total $N_2O$ emission in the control was $47.1g\;N\;ha^{-1}$. The DCD and HQ treatment resulted in a reduction of 67.9% and 41.8% in total $N_2O$ emission, respectively, compared to the control. The present study clearly indicated that nitrification and urease inhibitor exhibited positive roles in reducing N losses through $NH_3$ and $N_2O$ emission.

추진제 응용을 위한 아산화질소의 촉매 분해 특성 연구 (Study on the Characteristics of Nitrous Oxide Catalytic Decomposition for Propellant Applications)

  • 김태규;용승주;박대일
    • 한국항공우주학회지
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    • 제38권4호
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    • pp.369-375
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    • 2010
  • 추진제로써 아산화질소를 활용하기 위해 아산화질소의 촉매 분해 특성에 대한 연구를 수행하였다. 아산화질소 분해 반응을 위한 고성능 촉매를 선정하기 위해 Pt, Ir, Ru 촉매를 합성하였다. 촉매 합성을 위해 각각의 촉매 전구체를 함침법을 이용하여 $Al_2O_3$ 지지체에 담지하였다. 제조된 촉매는 관형 반응기를 사용하여 공간속도와 반응온도에 따른 $N_2O$ 전환율을 가스 분석을 통해 측정하였다. 또한 촉매 내구성을 판단하기 위해 $800^{\circ}C$에서 2시간 동안 반응한 후 촉매 유실량을 측정하였다. $N_2O$ 전환율은 공간속도가 낮을수록 반응온도가 높을수록 높았고, Ru/$Al_2O_3$ 촉매가 낮은 온도에서 가장 높은 $N_2O$ 전환율을 보였고 내구성도 가장 우수하였다.

선박용 디젤엔진에서 아산화질소의 배출특성에 대한 연구 (Investigation on emission characteristics of nitrous oxide from marine diesel engine)

  • 유동훈
    • Journal of Advanced Marine Engineering and Technology
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    • 제38권9호
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    • pp.1051-1056
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    • 2014
  • 아산화질소($N_2O$, Nitrous Oxide)는 박테리아의 물질대사와 같은 생물학적인 활동에 의하여 자연적으로 발생한다. 하지만, 최근의 대기 중 $N_2O$는 산업의 성장과 같은 인간의 활동에 의하여 증가되어져 왔다. 이 중에 대기 중의 $N_2O$농도를 증가시키는 요인들 중에 하나는 선박용 연료 연소로부터 발생하는 $N_2O$이다. 현재 해상 운송은 국제 물류의 99퍼센트 이상을 담당하고 있고, 선박척수는 물동량의 증가와 함께 증가하고 있다. 따라서, 본 연구에서는 4-행정 선박용 디젤엔진을 사용하여 다른 성분 농도들을 포함하는 연료의 연소가 $N_2O$ 배출률에 미치는 영향에 대하여 실험적인 조사를 실시하였다. 또한, 연소실 내의 연료 연소 패턴이 $N_2O$ 배출률에 미치는 영향에 대하여 평가하였다.

리도카인을 이용한 경막외 마취시 Nitrous Oxide가 감각차단에 미친 영향 (Nitrous Oxide Enhances the Level of Sensory Block by Epidural Lidocaine)

  • 구영권;우수영;조강희
    • The Korean Journal of Pain
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    • 제12권1호
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    • pp.43-47
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    • 1999
  • Backgroud: Systemic administration of opioid can prolong the duration of epidural anesthesia. The authors examined the effect of nitrous oxide ($N_2O$) on the level of sensory block induced by epidural lidocaine. Methods: Twenty minutes after epidural injection of 2% lidocaine (below 70 years : 20 ml, 70 years and above : 15 ml), the level of sensory block was assessed (2nd stage). Patients were randomly assigned to receive either medical air (control group, n=15) or 50% $N_2O$ in oxygen ($N_2O$ group, n=15) for 10 minutes, the level of block was reassessed (3rd stage). Pateints were given room air (control group) or 100% oxygen for 5 minutes and room air for 5 minutes ($N_2O$ group), and the level of block was reassessed (4th stage). Results: At the 3rd stage, $N_2O$ group showed 4.3 cm cephalad increase in the level of sensory block (p=0.005), but control group revealed 1.43 cm regression. After discontinuation of gas, the level of block regressed in both group (p=0.000). At the 4th stage, $N_2O$ group revealed 3.5 cm cephalad increase (p=0.048) and control group 1.97 cm regression (p=0.001) as compared with the 2nd stage. Conclusions: The level of sensory block induced by epidural lidocaine was significantly increased cephalad by concommitant use of 50% $N_2O$ for 10 minutes.

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