• Title/Summary/Keyword: nitrogen ratio

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An aerobic granular sludge process for treating low carbon/nitrogen ratio sewage

  • Yae, JaeBin;Ryu, JaeHoon;Tuyen, Nguyen Van;Kim, HyunGu;Hong, SeongWan;Ahn, DaeHee
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.238-245
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    • 2019
  • This study investigated the characteristic of aerobic granular sludge (AGS) process to treat the sewage having low carbon/nitrogen ratio (Biochemical oxygen demand ($BOD_5$):Total nitrogen (T-N), 4.5:1) in sequencing batch reactor (SBR). The removal efficiency of $BOD_5$, suspended solid (SS), T-N and phosphorus ($PO_4{^{3-}}$-P) were 92.6%, 64.3% and 90.1%. Concentration and size of AGS were changed in proportion to the organic matters and nitrogen concentration of the influent (Concentration and size of AGS: 1,700-3,000 mg/L, 0.5-1.0 mm). Mixed liquor suspended solid (MLSS) also changed with the concentration of AGS (MLSS: 2,000-3,500 mg/L). When the settling time was shortened from 15 min to 10 min, size and shape of AGS were maintained (Size of AGS: 1.0-1.5 mm). In addition, the concentration of AGS and MLSS increased (Concentration of AGS: 3,500 mg/L, MLSS: 4,000 mg/L). Concentration, size and shape of AGS were affected the settling time of the reactor more than the concentration of organic matter and nitrogen in the influent. In the results of removal efficiency and changes in AGS, we confirmed that the SBR process using AGS can be used to treat the sewage having low carbon/nitrogen ratio by applying short settling time.

Selective nitrification and denitrification in fixed bed biofilm reactors

  • Yun, Ho-Jun;An, Seung-Ho;Kim, Dong-Jin
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.278-281
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    • 2001
  • A fixed bed biofilm reactor filled with ceramic media were used to remove nitrogen by selective nitrification (ammonium to nitrite). The effects of experimental conditions (nitrogen load, dissolved oxygen, nitrite ratio, C/N ratio) on denitrification were investigated. The reactor showed more than 80% average T-N removal efficiencies at T-N loading in the range of $1.1{\sim}3.3$ kg $T-N/m^3{\cdot}d$ C/N at the C/N ratio of 1. T-N removal efficiencies increased as nitrite ratio.

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A Study on the Synthesis of Titanium Carbonitride by SHS(Self-propagating High-temperature Synthesis) Method (자체반응열 고온합성법을 이용한 Titanium Carbonitride의 합성에 관한 연구)

  • Ha, Ho;Hwang, Gyu-Min;Lee, Hee-Cheol
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.637-642
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    • 1994
  • Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

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Nitrogen and Phosphorus Removal in Domestic Wastewater using SBR Process with Flow Changing Continuous Feed and Cyclic Draw (교대연속유입식 SBR 공정을 이용한 하수중의 질소 및 인 제거)

  • Seo, In-seok;Kim, Hong-suck;Kim, Youn-kwon;Kim, Ji-yeon
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.203-208
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    • 2006
  • A continuous feed and cyclic draw SBR process was developed to overcome flow rate fluctuation and to maximize organic matters utilization efficiency for nitrogen and phosphorus removal. The developed SBR process was operated with two parallel reactors. Influent was supplied to one reactor which was not obligately aerated. At the same time, the other reactor was just aerated without supplying influent. In addition this mode was changed periodically. Cycle time was 6hr and aeration time ratio($t_{aer}/t_{total}$) was 0.33, respectively. $COD_{cr}$ and SS removal efficiencies of 95% or higher were achieved. Nitrogen removal was so greatly influenced by influent $COD_{cr}/T-N$ ratio. At influent $COD_{cr}/T-N$ ratio of 5.7, removal efficiencies of ammonia-N, T-N and T-P were 96%, 78% and 55%, respectively. Influent $COD_{cr}/T-N$ of 4 or higher ratio was necessary to achieve 60% or higher nitrogen removal. Organic matters of influent was efficiently utilized in denitrification reaction and consumed COD has a good correlation with removed T-N(about 6.5 mgCOD/mgTN). Continuous feed and cyclic draw SBR process could be one of alternative processes for the removal of nutrients in rural area where $COD_{cr}/T-N$ ratio was low and fluctuation of flow rate was severe.

A Characteristic of Nitrogen and Phosphorus Removal in Anoxic/Oxic Basins combined with Iron Electrolysis (철 전기분해장치와 무산소/호기공정을 결합한 질소, 인제거 특성에 관한 연구)

  • Kim, Young-Gyu
    • Journal of Environmental Health Sciences
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    • v.43 no.6
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    • pp.525-531
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    • 2017
  • Objectives: The purpose of this experiment is to better understand the nitrogen and phosphorus removal ratio according to operating conditions in an iron electrolysis system consisting of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis consists of an iron precipitation reactor composed of iron plates in oxic and anoxic basins. We studied the interrelation coefficient between T-N and T-P removal rates and F/M ratio, and the C/N ratio and BOD removal rate. Results: The F/M ratio and the T-N and T-P removal rate per unit area have interrelation coefficients of 0.362 and 0.603, respectively. The removal rate per MLVSS and the T-N and T-P removal rate per unit area have respective interrelation coefficients of 0.49 and 0.59. Conclusions: The removal rate of T-N and T-P increased with the increasing F/M ratio in the influent, and they also linearly increased in proportion to the C/N ratio of influent and BOD removal rate of the reactor.

Effects of Dissolved Organic Nitrogen on the Growth of Dominant Phytoplankton in the Southwestern Part of East Sea in Late Summer (늦여름 동해 남서해역에서 용존 유기 질소가 우점 식물플랑크톤의 생장에 미치는 영향)

  • Kwon, Hyeong-Kyu;Jeon, Seul-Gi;Oh, Seok-Jin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.1
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    • pp.42-51
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    • 2016
  • We investigated the distribution of dissolved nutrients, phytoplankton community structure and utilization of nitrogen compounds by dominant species in the southwestern part of East Sea in September, 2014. Dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorus (DIP) were lower in the surface layer, and concentrations were increased with depth. Dissolved organic nitrogen (DON) and dissolved organic phosphorus were the opposite of dissolved inorganic nutrients. Although DIN DIP ratio in all of the water masses was higher than Redfield ratio (16), DIN : DIP ratio in mixed layer was about 2, indicating that inorganic nitrogen is the limiting factor for the growth of phytoplankton. In particular, DON proportion in dissolved total nitrogen was about 88 % in the mixed layer where inorganic nitrogen is limiting factor. The dominant species Chaeotceros debilis and Prorocentrum minimum were able to grow using DIN as well as DON such as urea and amino acids. Therefore, DON utilization of phytoplankton may play a role as a survival strategy in the DIN-limited conditions of East Sea.

Advanced wastewater treatment capacity and growth of Chlorella vulgaris by nitrogen and phosphorus concentrations (N, P 농도에 따른 Chlorella vulgaris의 성장 및 하수고도처리능 평가)

  • Han, Su-Hyun;Lee, Yunhee;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.77-82
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    • 2013
  • The growth and removal capacity of nitrogen and phosphorus of Chlorella vulgaris were evaluated in artificial wastewater with different nitrogen and phosphorus concentrations as element growing components for microalgae growth. The nitrogen concentration was varied in 9, 15, 30 and 60 mg-N/L with fixed phosphorus concentration of 3 mg-P/L. The growth and phosphorus removal capacity of C. vulgaris were high at initial nitrogen concentration of 15 and 30 mg-N/L, and the corresponding N/P ratios calculated were 5 and 10. In the case of varying in 1.5, 3, 6 and 10 mg-P/L of phosphorus concentration with fixed nitrogen concentration of 30 mg-N/L, the growth and removal capacity of nitrogen and phosphorus were excellent with phosphorus concentration of 3 and 6 mg-P/L. The corresponding N/P ratios were shown as 10 and 5. Therefore, the appropriate N/P ratio was concluded between 5 and 10 for wastewater treatment using C. vulgaris.

Influence of carbon type and carbon to nitrogen ratio on the biochemical methane potential, pH, and ammonia nitrogen in anaerobic digestion

  • Choi, Yongjun;Ryu, Jeongwon;Lee, Sang Rak
    • Journal of Animal Science and Technology
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    • v.62 no.1
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    • pp.74-83
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    • 2020
  • Organic waste used as a feedstock in the anaerobic digestion (AD), it includes carbon and nitrogen. Carbon and nitrogen have an effect on the various digestive characteristics during AD, however, the study is rare about those of the interaction. This study investigates the influence of carbon type and carbon to nitrogens (C/N ratios) on the AD characteristics of organic waste. Experimental treatments involved a combination of three carbon types with three C/N ratios. The AD tests were carried out using a 125-mL serum bottle at a constant temperature of 37℃ and moisture 95% for 18 days. Degradation pattern shows the difference among three-carbon treatments, the starch group was faster than other groups. Maximum methane production date was similar between starch (9.96 ± 0.05 day) and xylan group (10.0 ± 0.52 day), those of the cellulose group (14.6 ± 1.80 day) was slower than other groups (p < 0.05). The lag phase was only affected by the carbon type (p < 0.05). Ammonia nitrogen was mainly affected by nitrogen concentration regardless of carbon type (p < 0.05). This study showed that xylan is useful as feedstock in order to decrease the lag phase, and it showed that ammonia was independently affected by the nitrogen concentration.

Disintegration of Cryogenic Jet in Super-critical Environment (초임계 환경으로 분사되는 극저온 제트의 분열)

  • Lee, Keonwoong;Kim, Dohun;Koo, Jaye
    • Journal of ILASS-Korea
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    • v.18 no.3
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    • pp.140-145
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    • 2013
  • Sub/supercritical spray experiments were conducted, and cryogenic nitrogen and gaseous argon were selected for simulants. liquid nitrogen and gaseous argon were injected in subcritical case, and supercritical nitrogen and near-critical gaseous argon were injected in near-critical/supercritical cases. shadowgraph method was used to visualize spray, and analyzed about the breakup length. The breakup length was measured from numbers of Instantaneous shadowgraph Images from each case, and they were compared with momentum flux ratios and density ratios. It was observed that the relation between breakup length and momentum flux ratio was fitted into former experiment results. and the reasonable constant was suggested about the relation between breakup length and density ratio.

Plasma Characterization of Facing Target Sputter System for Carbon Nitride Film Deposition

  • Lee, Ji-Gong;Lee, Sung-Pil
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.3
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    • pp.98-103
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    • 2004
  • The plasma properties in the facing target sputtering system during carbon nitride film deposition have been investigated. The ionized nitrogen species of the deposited films increased with increasing discharge current and were independent of the nitrogen pressure. The nitrogen content in the films did not vary significantly with the variation of nitrogen gas. The electron temperature was high close to that in the inter-cathode region, reduced as the electrons moved away from the most intense region of magnetic confinement and increased again outside this region. Calculations based on the film composition showed that the ion to carbon atom ratio at the substrate was about 50 and that the ratio between the ionized and neutral nitrogen molecules was about 0.25.