• Title/Summary/Keyword: nitrogen limitation

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A Sensitivity Analysis of the OZIPR Modeling Result for the Seoul Metropolitan Area (OZIPR 모델링 결과의 민감도 분석)

  • Lee, Sun-Hwa;Jin, Lan;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.7 no.3
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    • pp.99-108
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    • 2011
  • To establish area specific control strategies for the reduction of the ozone concentration, the Ozone Isopleth Plotting Package for Research(OZIPR) model has been widely used. However, the model results tend to changed by various input parameters such as the background concentration, emission amount of NOx and volatile organic compounds (VOCs), and meteorological condition. Thus, sensitivity analysis should be required to ensure the reliability of the result. The OZIPR modeling results for five local government districts in the Seoul Metropolitan Area (SMA) in June 2000 were used for the sensitivity analysis. The sensitivity analysis result showed that the modeling result of the SMA being VOC-limited region be still valid for a wide range of input parameters' variation. The estimated ozone concentrations were positively related with the initial VOCs concentrations while were negatively related with the initial NOx concentrations. But, the degree of the variations at each local district was different suggesting area specific characteristics being also important. Among the five local governments, Suwon was chosen to identify other variance through the period from April to September in 2000. The monthly modeling results show different ozone values, but still showing the characteristics of VOCs-limited region. Limitations due to not considering long range transport and transfer from neighbor area, limitation of input data, error between observed data and estimated data are all discussed.

Effects of Nitrogen Fertilization Levels and Some Additives on the Chemical Composition and Silage Quality of Forage Rape (Brassica napus Subsp. oleifera) I. Effects of harvestinh dates and N forage rape (질소시비수준과 첨가제가 사초용 유채의 사료가치 및 사일리지의 품질에 미치는 영향 I. 예취시기 및 질소시비수준이 수량 및 사료가치에 미치는 영향)

  • 조무환;김동암
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.8 no.1
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    • pp.33-39
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    • 1988
  • Insufficient herbage during the fall in the temperate areas of the world has been a serious limitation in animal production, but leafy brassicae are potentially very useful for extending the grazing season when the growth and quality of grass is poor. This study was conducted to determine the effects of cutting stage and N fertilization on dry matter (DM) yield, forage quality and chemical composition of forage rape (Brassica napus Subsp. oleifera). The experiment was conducted in the Experimental Livestock Farm of Seoul Nat'l Univ., at Suweon, during 1985- 1986. The results obtained are summarized as follows: 1. DM percentage and yield significantly increased as the growth period was prolonged and decreased as the N fertilization increased, but in-vitro dry matter digestibility (IVDMD) was unaffected by the treatments. 2. Plant height, DM yield and $NO_3$-N content significantly increased as the rate of N fertilization increased and DM percentage decreased, but the IVDMD was unaffected. 3. The forage rape had high percentage of crude protein and ash. Glutamic acid, pro!ine and aspartic acid were the major amino acids. Concentration of P, Ca and Mg were high.

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Microcystin Production by Microcystis sp. under N or P Limitation

  • Oh Hee-Mock;Kim Jee-Hwan
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2001.11a
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    • pp.113-120
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    • 2001
  • The production of microcystins from Microcystis aeruginosa was investigated in a P-limited continuous culture and a batch culture. The microcystin content of M aeruginosa was higher at a lower $\mu$, whereas the microcystin (MC)-producing rate was linearly proportional to $\mu$. The ratios of the MC-producing rate to the C-fixation rate were higher at a lower $\mu$. Consequently, increases in the microcystin content per dry weight along with the production of the more toxic form, MC-LR, were both observed under more P-limited conditions. The microcystin content of M. aeruginosa exhibited a high correlation with the total N content regardless of N-fixed or P-fixed culture. The microcystin concentration was investigated from spring to autumn in 1999 in the Daechung Reservoir, Korea. The dominant species in the algal blooming season was Microcystis. When the microcystin concentration exceeded about 100 ng $1^{-1}$ the ratio of particulate to dissolved total nitrogen (TN) or total phosphorus (TP) interestingly converged at a value of 0.6. The microcystin concentration was lower than 50 ng $1^{-1}$ at a particulate N:P ratio below 8, whereas the microcystin concentration varied quite substantially from 50 ng $1^{-1}$ to 250 ng $1^{-1}$ at a particulate N:P ratio> 8.

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A Review on the Photochemical Oxidant Modeling as Applied to Air Quality Studies in Complex Terrain

  • Hwa-Woon Lee;Yoo
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.19-33
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    • 1992
  • The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorolog ital processecs . In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification Process through observation is emphasized.

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The Analysis of Water Quality and Suspended Solids Effects against Transparency of Major Artificial Reservoirs in Korea. (우리나라 주요 인공호의 투명도에 대한 수질 및 수중 부유물 영향 분석)

  • Kong, Keon-Hwa;Lee, Jae-Hoon;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.221-231
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    • 2009
  • This study was carried out to comparatively identify characteristics of turbid water influence in Imha Reservoir, Soyang Reservoir, and Daecheong Reservoir in Korea. We used 3 years dataset from 2002 to 2004 and analyzed seasonal water quality characteristics, particular parameters in association with turbidity, and light transparency to figure out the trends. All parameters to be used in the study were total phosphate (TP), total nitrogen (TN), chlorophyll-${\alpha}$ (Chl), suspended solids (SS), Secchi depth (SD), conductivity, and verticallight extinction coefficienct($K_d$), euphotic zone ($Z_{eu}$), and critical depth ($Z_p$). All parameters depend on season and watershed. Suspended solids from Soyang Reservoir were usually caused by TP, mainly related to living wastes and agricultures in upper stream. Daecheong Reservoir was influenced by organic matters related to large phytoplankton biomass in summer and inorganic suspended solids by nutrients in the winter. However, in case of Imha Reservoir, turbid water, consisted in silt and clay through heavy precipitation remained in the waterbody to decrease water transparency along with TP and caused the light limitation in winter. Overall results suggest that it was necessary to establish various management programs because the reasons occurring turbidity were varied according to the reservoir circumstances.

Effects of Water Temperature on The Mass Mortality of Pacific Oyster, Crassostrea gigas in Gamak Bay (가막만 양식 굴, Crassostrea gigas 폐사에 영향을 끼치는 수온의 영향)

  • Kim, Chul Won;Oh, Hyun Ju;Shin, Yun Kyung
    • The Korean Journal of Malacology
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    • v.29 no.3
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    • pp.245-250
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    • 2013
  • We investigated the factors of mass-mortality in terms of water temperature and prey, in order to prevent the mass-mortality of cultured oysters at Gamak Bay in Yeosu City in 2007. The real-time water temperature was recorded as high, 28 to 31C, during late August. Nutrients, Dissolved Inorganic Nitrogen (DIN) and Dissolved Inorganic Phosphate (DIP) were downed in September. The analyzed results of chlorophyll a content were 0.78-1.50 ${\mu}gL^{-1}$ and phytoplankton for food resources was 81 cells $mL^{-1}$, both were low. The finding here indicate that Gamak Bay is in an oligotrophic state. The mass-mortality of cultured oysters occurred 43.6% in Gamak Bay. The mortality rate of oyster were above 67.0%, at Wanpo, however, it was showed 18.3% at Gumchun. Therefore, we believe the mass-mortality of cultured oysters at Gamak Bay comes from the destruction of bio-rhythms due to high water temperature and quantitatively and qualitatively decreasing food resources due to the limitation of nutrients.

Numerical Analysis of Flow Uniformity in Selective Catalytic Reduction (SCR) Process Using Computational Fluid Dynamics (CFD)

  • Shon, Byung-Hyun
    • International Journal of Advanced Culture Technology
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    • v.10 no.3
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    • pp.295-306
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    • 2022
  • The NOx removal performance of the SCR process depends on various factors such as catalytic factors (catalyst composition, shape, space velocity, etc.), temperature and flow rate distribution of the exhaust gas. Among them, the uniformity of the flow flowing into the catalyst bed plays the most important role. In this study, the flow characteristics in the SCR reactor in the design stage were simulated using a three-dimensional numerical analysis technique to confirm the uniformity of the airflow. Due to the limitation of the installation space, the shape of the inlet duct was compared with the two types of inlet duct shape because there were many curved sections of the inlet duct and the duct size margin was not large. The effect of inlet duct shape, guide vane or mixer installation, and venturi shape change on SCR reactor internal flow, airflow uniformity, and space utilization rate of ammonia concentration were studied. It was found that the uniformity of the airflow reaching the catalyst layer was greatly improved when an inlet duct with a shape that could suppress drift was applied and guide vanes were installed in the curved part of the inlet duct to properly distribute the process gas. In addition, the space utilization rate was greatly improved when the duct at the rear of the nozzle was applied as a venturi type rather than a mixer for uniform distribution of ammonia gas.

Short-term Nutrient Enrichment Bioassays (NEBs) by Manipulation of TN:TP Ratios and the Response of Primary Productivity (as Chlorophyll-a) (N:P Ratio 조절에 의한 단기 영양염 첨가 바이오에세이(NEBs) 및 1차 생산력(엽록소-a)의 반응성 테스트)

  • Jeong, Da-Bin;An, Kwang-Guk
    • Korean Journal of Environmental Biology
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    • v.31 no.4
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    • pp.383-392
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    • 2013
  • The objective of this study was to determine the effects of N:P ratio on primary productivity measured as chlorophyll-a (CHL) using the approach of In Situ Nutrient Enrichment Bioassays (NEBs) in Daechung Reservoir. The effects of NEBs on the N:P mass ratios were compared with the field data obtained from monthly-chemical monitoring during 2009~2012. The short-term NEBs showed that the response of primary productivity in the phosphorus spiked treatments (5, 15, 20 and 30 N:P ratios) were greater than the responses in the control (C) and nitrogen spiked treatment (N:P ratio=150, $T_{VI}$). The response in the nitrogen treatment (N:P ratio=150, $T_{VI}$) was less compared to control and all five treatments ($T_I{\sim}T_{VI}$). The outcomes of the NEBs suggest that phosphorus limited the phytoplankton growth and nitrogen addition inhibited the algal growth. In the analysis of nutrients and CHL from the ambient epilimnetic water in Daechung Reservoir, minimum N:P ratios resulted in maximum concentrations of CHL. Overall, our results suggest that the N:P ratio was the key factor in regulating the phytoplankton growth in NEB experiments.

Evaluation of Water Quality Variation and Sediment of a Shallow Artificial Lake (Lake llgam) in Located the Metropolitan Area (도심의 얕은 인공호인 일감호의 수질변화특성과 퇴적환경의 평가)

  • Kim, Ho-Sub;Ko, Jae-Man;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.36 no.2 s.103
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    • pp.161-171
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    • 2003
  • The present study evaluated water quality variation, limiting nutrient, and sediment of a shallow eutrophic lake (Lake Ilgam) in the metropolitan area from 2000 to 2002. According to annual mean chl.a ($77.2{\pm}36.6\;{\mu}g/l) and TP ($66.6{\pm}20.5\;{\mu}g/l) concentration and trophic state index (>60), Lake llgam was in very eutrophic status. Both inorganic nitrogen ($NH_3-N$ and $NH_3-N$) and phosphorus (SRP) concentrations in the water column increased during winter and spring, but decreased during summer followed by the phytoplankton development. Evidence for phosphorus and nitrogen as being the potential limiting nutrients for phytoplankton growth was supported by the ratio of DIN/DIP (by mass) (${\sim}$835.8), TSI derivations analysis, and algal growth potential bioassay. Based on the results of TSI derivations, strong nutrient limitation by both N and P occurred from September to November when P content in sediment (114.6 mg P/kg) was relatively low compared with the summer. Sediment contained a large amount of nitrogen (TKN: 4,452${\pm}$283.0mg N/kg dry sediment). Phosphorus content in sediment (TP: 313${\pm}$155 mg P/kg) was relatively low with temporal change. P release rate (0.29${\pm}$0.02 mg $m^{-2}$ $day^{-1}$) was high under the aerobic condition at pH 9. These results indicate that the sediment could play an important role as a source of a limiting nutrient, and temporal change of P content in the sediment is closely related with water quality, especially algal biomass change in Lake llgam.

Limitation of Nitrogen ion Implantation and Ionplating Techniques Applied for Improvement of Wear Resistance of Metallic Implant Materials (금속 임플란트 소재의 내마모성 향상을 위하여 적용되는 질소 이온주입 및 이온도금법의 한계)

  • 김철생
    • Journal of Biomedical Engineering Research
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    • v.25 no.2
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    • pp.157-163
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    • 2004
  • Nitrogen ion implantation and ion plating techniques were applied for improvement of the wear resistance of metallic implant materials. In this work, the wear dissolution behaviour of a nitrogen ion implanted super stainless steel (S.S.S, 22Cr-20Ni-6Mo-0.25N) was compared with those of S.S.S, 316L SS and TiN coated 316L SS. The amounts of Cr and Ni ions worn-out from the specimens were Investigated using an electrothermal atomic absorption spectrometry. Furthermore, the Ti(Grade 2) disks were coated with TiN, ZrN and TiCN by use of low temperature arc vapor deposition and the wear resistance of the coating layers was compared with that of titanium. The chemical compositions of the nitrogen ion implanted and nitride coated layers were examined with a scanting auger electron spectroscopy. It wat observed that the metal ions released from the nitrogen ion implanted S.S.S surface were significantly reduced. From the results obtained, it was shown that the nitrogen ion implanted zone obtained with 100 KeV ion energy was easily removed within 200,000 revolutions from a wear dissolution testing under a similar load condition when applied to artificial hip joint. The remarkable improvement in wear resistance weir confirmed by the nitrides coated Ti materials and the wear properties differ greatly according to the chemical composition of the coating layers. for specimens with the same coating thickness of about 3$\mu\textrm{m}$, TiCN coated Ti showed the highest wear resistance. However, after removing the coating layers, the wear rates of all nitrides coated Ti reverted to their normal rates of below 10,000 revolutions from Ti-disk-on-disk wear testing under the same load condition. From the results obtained, it is suggested that the insufficient depth of the 100 Kel N$\^$+/ ion implanted zone and of the nitrides coated layers of 3$\mu\textrm{m}$ are subject to restriction when used as frictional parts of load bearing implants.