• Title/Summary/Keyword: nitrogen generation

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Atomic Layer Deposition of Nitrogen Doped ZnO and Application for Highly Sensitive Coreshell Nanowire Photo Detector

  • Jeong, Han-Eol;Gang, Hye-Min;Cheon, Tae-Hun;Kim, Su-Hyeon;Kim, Do-Yeong;Kim, Hyeong-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.26.1-26.1
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    • 2011
  • We investigated the atomic layer deposition (ALD) process for nitrogen doped ZnO and the application for n-ZnO : N/p-Si (NW) coaxial hetero-junction photodetectors. ALD ZnO:N was deposited using diethylzinc (DEZ) and diluted $NH_4OH$ at $150^{\circ}C$ of substrate temperature. About 100~300 nm diameter and 5 um length of Si nanowires array were prepared using electroless etching technique in 0.108 g of $AgNO_3$ melted 20 ml HF liquid at $75^{\circ}C$. TEM images showed ZnO were deposited on densely packed SiNW structure achieving extraordinary conformality. When UV (360 nm) light was illuminated on n-ZnO:N/p-SiNW, I-V curve showed about three times larger photocurrent generation than film structure at 10 V reverse bias. Especially, at 660 nm wave length, the coaxial structure has 90.8% of external quantum efficiency (EQE) and 0.573 A/W of responsivity.

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Cool-down test of cryogenic cooling system for superconducting fault current limiter

  • Hong, Yong-Ju;In, Sehwan;Yeom, Han-Kil;Kim, Heesun;Kim, Hye-Rim
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.3
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    • pp.57-61
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    • 2015
  • A Superconducting Fault Current Limiter is an electric power device which limits the fault current immediately in a power grid. The SFCL must be cooled to below the critical temperature of high temperature superconductor modules. In general, they are submerged in sub-cooled liquid nitrogen for their stable thermal characteristics. To cool and maintain the target temperature and pressure of the sub-cooled liquid nitrogen, the cryogenic cooling system should be designed well with a cryocooler and coolant circulation devices. The pressure of the cryostat for the SFCL should be pressurized to suppress the generation of nitrogen bubbles in quench mode of the SFCL. In this study, we tested the performance of the cooling system for the prototype 154 kV SFCL, which consist of a Stirling cryocooler, a subcooling cryostat, a pressure builder and a main cryostat for the SFCL module, to verify the design of the cooling system and the electric performance of the SFCL. The normal operation condition of the main cryostat is 71 K and 500 kPa. This paper presents tests results of the overall cooling system.

Molecular Orbital Calculations for the Formation of GaN Layers on Ultra-thin AlN/6H-SiC Surface Using Alternating Pulsative Supply of Gaseous Trimethyl Gallium (TMG) and NH$_3$

  • Seong, Si Yeol;Hwang, Jin Su
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.154-158
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    • 2001
  • The steps for the generation of very thin GaN films on ultrathin AlN/6H-SiC surface by alternating a pulsative supply (APS) of trimethyl gallium and NH3 gases have been examined by ASED-MO calculations. We postulate that the gallium cul ster was formed with the evaporation of CH4 gases via the decomposition of trimethyl gallium (TMG), dimethyl gallium (DMG), and monomethyl galluim (MMG). During the injection of NH3 gas into the reactor, the atomic hydrogens were produced from the thermal decomposition of NH3 molecule. These hydrogen gases activated the Ga-C bond cleavage. An energetically stable GaN nucleation site was formed via nitrogen incorporation into the layer of gallium cluster. The nitrogen atoms produced from the thermal degradation of NH3 were expected to incorporate into the edge of the gallium cluster since the galliums bind weakly to each other (0.19 eV). The structure was stabilized by 2.08 eV, as an adsorbed N atom incorporated into a tetrahedral site of the Ga cluster. This suggests that the adhesion of the initial layer can be reinforced by the incorporation of nitrogen atom through the formation of large grain boundary GaN crystals at the early stage of GaN film growth.

A stepwised catalytic combustion of ammonia with $H_2$ and CO on supported Pt, Pd and Rh catalysts (Pt, Pd와 Rh가 담지된 촉매상에서 암모니아와 수소/일산화탄소의 단계별 촉매연소에 관한 연구)

  • Hwang, J.Y.;Ryu, I.S.;Lee, K.C.;Lee, S.J.;Noh, D.S.;Rhee, K.S.;Kang, S.K.
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.20-26
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    • 2006
  • This study investigated on the conversion of nitrogen component in ammonia gas to control fuel-NOx. Control conditions were found to suppress the production of NOx in the catalytic combustion of the gasified fuels. Also, the results would provide the basis of the theoretical study on fuel-NOx generation mechanism.

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Characterization of behaviors using electric pulse for phase switching operation of Ge2Sb2Te5 material

  • Lee, Hyeon-Cheol;Choe, Du-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.322-322
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    • 2016
  • Phase change memory (PCM) has attracted much attention as one of the most promising candidates for next-generation nonvolatile memory. In that regard, the purposes of the study are to propose reference of effective pulse parameter to control phase switching operation and to invest the effect of nitrogen doped in PCM materials for improved cycling stability and economic energy consumption. Switching operation of PCM is affected by electric pulse parameter and as shown in figure.1 are composed to RT(rising time), ST(setting time), FT(falling time) and the effect of these parameter was precisely investigated. Transmission electron microscope (TEM) was used to confirm fine structure and retention cycle test was conducted to confirm reliability. Finally improvement reliability and economic power consumption in quantitatively are obtainable by optimum pulse parameter and nitrogen doping in GST material. these study is related to the engineering background of other semiconductor industries and it have confirmed to possibility further applications.

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On the origin of the extended horizontal branch and the Sandage period-shift effect in the two metal-poor globular clusters NGC2419 and M15

  • Jang, Sohee;Joo, Seok-Joo;Na, Chongsam;Lee, Young-Wook
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.62.2-62.2
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    • 2013
  • Recent spectroscopic observations have provided evidence for complex chemical evolution by supernovae and/or asymptotic giant branch (AGB) stars in the two metal-poor globular clusters (GCs) NGC2419 and M15. In particular, the horizontal branches (HBs) of these metal-poor GCs are very extended in the Hertzsprung-Russell diagram. The origin of these peculiar features, as well as that for the Sandage period-shift effect observed in these clusters, are yet to be understood. Here we show, by constructing population models including the Nitrogen enhanced subpopulation, that the second generation populations in these clusters would be enhanced not only in Helium, but also in Nitrogen. This working hypothesis can simultaneously explain the observed extended feature on the HB and the period-shift of RR Lyrae variables.

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가축분뇨 슬러지의 악취제거 효율이 높은 미생물 개발과 표면반응법을 이용한 발효조건 최적화

  • Kim, So-Yeong;Lee, Jae-Yong;Son, Seok-Min;Lee, Gi-Yeong;Lee, Geon-Sun;Kim, Hong;Chae, Hui-Jeong
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.171-174
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    • 2003
  • Animal excreta is a useful fertilizer, because it has useful nourishments, microelements and three requistes of fertilizer(nitrogen, phosphorus, potassium). But, it has some problems such as generation of bad smell and excess of nitrogen. In this study, a biological tool using microorganisms was investingated. First, 61 species were isolated from soil sample. The enzyme activities of the strains such as protease, cellulase, amylase and lipase were analysed. And from a deodorization test using the isolated strains and finally three strains were selected(NA 2, NA 12, NA 15). The optimal media composition and incubation pH were statistically determined using surface-response method.

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Malonate Metabolism: Biochemistry, Molecular Biology, Physiology, and Industrial Application

  • Kim, Yu-Sam
    • BMB Reports
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    • v.35 no.5
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    • pp.443-451
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    • 2002
  • Malonate is a three-carbon dicarboxylic acid. It is well known as a competitive inhibitor of succinate dehydrogenase. It occurs naturally in biological systems, such as legumes and developing rat brains, which indicates that it may play an important role in symbiotic nitrogen metabolism and brain development. Recently, enzymes that are related to malonate metabolism were discovered and characterized. The genes that encode the enzymes were isolated, and the regulation of their expression was also studied. The mutant bacteria, in which the malonate-metabolizing gene was deleted, lost its primary function, symbiosis, between Rhizobium leguminosarium bv trifolii and clover. This suggests that malonate metabolism is essential in symbiotic nitrogen metabolism, at least in clover nodules. In addition to these, the genes matB and matC have been successfully used for generation of the industrial strain of Streptomyces for the production of antibiotics.

An Extremely Low Temperature Properties of Austenite Stainless Steels (오스테나이트 스테인리스강의 극저온 특성)

  • Jung, Chan-Hoi;Kim, Soon-Kook;Lee, Jun-Hee;Jeong, Se-Jin;Kim, Ik-Soo
    • Korean Journal of Materials Research
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    • v.17 no.1
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    • pp.37-42
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    • 2007
  • The effects of immersion time in the liquid nitrogen and deformation-induced martensitic transformation on the behavior of austenite stainless steels used for the hydrogen storage tank of auto-mobile at cryogenic temperature were investigated. With increasing of immersion time in the liquid nitrogen, the tensile strength of all austenite stainless steels at cryogenic temperature was increased because the martensite transformation of unstable austenite. The restraint of crack generation ana transmission also increased the tensile strength by the active ${\alpha}'$ transformation. The elongation decreasing of 321 steel is not the mechanical deformation of austenite phase but the stress induced martensite phase during the tensile test.

Optical properties of nitrogen doped ZnO thin films grown by dielectric barrier discharge plasma-assisted pulsed laser deposition (Dielectric barrier discharge 플라즈마 펄스 레이져 증착법을 통해 성장한 nitrogen 도핑 된 산화아연 박막의 광학적 특성)

  • Lee, Deuk-Hee;Kim, Sang-Sig;Lee, Sang-Yeol
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1256_1257
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    • 2009
  • We have grown, for the first time to our knowledge, N-doped ZnO thin films on sapphire substrate by employing novel dielectric barrier discharge in pulsed laser deposition (DBD-PLD). DBD guarantees an effective way for massive in-situ generation of N-plasma under the conventional PLD process condition. Low-temperature photoluminescence spectra of the N-doped ZnO film provided near band-edge emission after thermal annealing process. The emission peak was resolved by Gaussian fitting to find a dominant acceptor-bound exciton peak ($A^0X$) that indicates the successful p-type doping of ZnO with N.

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