• 제목/요약/키워드: nitrogen and hydrogen

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수소연료 생산의 효율향상을 위한 초음파응용에 관한 연구(용액과 농도 중심으로) (A Study on the Ultrasonic Application for the Efficiency Elevation of the Hydrogen Fuel Production (On solution and concentration))

  • 송민근;이상범;손승우;주은선
    • 한국수소및신에너지학회논문집
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    • 제12권2호
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    • pp.129-136
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    • 2001
  • An investigation on the A/V(ampere/volt) gradient according to the concentration and the kind of solution in a electrolyzer is carried out to obtain the basic data on the ultrasonic application for the efficiency elevation of the hydrogen fuel production. KOH is selected as an electrolyte and concentrations are 0%, 10%, 20% and 30%. The solutions are city water, city water with nitrogen. distilled water and distilled water with nitrogen. The Electrochemical analyzer(BAS Co.) is used as a measuring device to observe the A/V gradient. And the limit of volt is from -3000mV to +3000mV. The 28kHz magnetic transducer is selected to give them ultrasonic forcing. In results, it is clarified that ultrasonic influences the A/V gradient in the electrolytic solution.

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Source Identification of Nitrate contamination in Groundwater of an Agricultural Site, Jeungpyeong, Korea

  • 전성천;이강근;배광옥;정형재
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.63-66
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    • 2003
  • This study applied a hydrogeological field survey and isotope investigation to identify source locations and delineate pathways of groundwater contamination by nitrogen compounds. The infiltration and recharge processes were analyzed with groundwater-level fluctuation data and oxygen-hydrogen stable isotope data. The groundwater flow pattern was investigated through groundwater flow modeling and spatial and temporal variation of oxygen isotope data. Based on the flow analysis and nitrogen isotope data, source types of nitrate contamination in groundwater are identified. Groundwater recharge largely occurs in spring and summer due to precipitation or irrigation water in rice fields. Based on oxygen isotope data and cross-correlation between precipitation and groundwater level changes, groundwater recharge was found to be mainly caused by irrigation in spring and by precipitation at other times. The groundwater flow velocity calculated by a time series of spatial correlations, 231 m/yr, is in good accordance with the linear velocity estimated from hydrogeologic data. Nitrate contamination sources are natural and fertilized soils as non-point sources, and septic and animal wastes as point sources. Seasonal loading and spatial distribution of nitrate sources are estimated by using oxygen and nitrogen isotopic data.

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흡기중의 수소첨가가 산업용 디젤기관의 성능에 미치는 영향 (The Effect of Hydrogen Added into In-let Air on Industrial Diesel Engine Performance)

  • 박권하;이진아;이화순
    • Journal of Advanced Marine Engineering and Technology
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    • 제34권8호
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    • pp.1050-1056
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    • 2010
  • 디젤기관은 공기만을 흡입 압축한 후에 연료를 분사하여 연소하기 때문에 높은 압축비가 가능하다. 높은 압축비에 의한 고효율의 장점과 연료의 직접분사에 의한 매연미립자의 배출 및 질소산화물의 배출이 많은 단점을 갖고 있다. 이러한 문제점을 해결하기 위하여 많은 연구들이 진행되었으며 수소를 흡기중에 공급하는 기술도 연구되고 있다. 본 논문에서는 미량의 수소를 연소실에 공급하여 엔진성능에 미치는 영향을 평가하였다. 토크와 엔진속도를 100%, 75%, 50%, 25%, 0%와 700rpm, 1000rpm, 1500rpm, 2000rpm로 구분하여 실험하였다. 실험결과 질소산화물이 약간 증가하였지만 연료소비율, 스모크와 일산화탄소 배출은 감소하였다. 수소의 첨가는 저부하 영역에서는 효과가 거의 없었지만 고부하 영역에서 큰 효과가 있었다.

연료전지 자동차용 질소/응축수 통합배출시스템 및 기술 개발 (Development of the Integrated Exhaust System and Techniques of Nitrogen and Condensate for Fuel Cell Electric Vehicle)

  • 심효섭;김효섭;김재훈;권부길;이현준;김치명;박용선
    • 한국수소및신에너지학회논문집
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    • 제25권5호
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    • pp.516-524
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    • 2014
  • Proper discharge of nitrogen gas and water condensate is required in a conventional fuel cell system for performance, stability and durability of fuel cell stacks. Present study covers the development of integrated unit and its functioning logic for simultaneous nitrogen gas purge and water condensate drainage in a fuel cell vehicle system. Configuration of condensate drainage pipe, purge valve and level sensor is considered and optimized in physical integration. As a key factor, discharge time is considered and optimized based on the test result of constant-current operation with various operating temperature in logic development. Consequently, derived optimal values are applied and verified in actual vehicle drive mode test. Increase of system design flexibility, weight reduction and cost reduction are anticipated with this study. Additional study for physical and logical improvement is currently being implemented.

Rhodopseudomonas sp. KCTC 1437에 의한 포도당으로부터의 수소 생성 (Evolution of Molecular Hydrogen from Glucose by Rhodopseudomonas sp. KCTC 1437)

  • Woo, Seung-Jin;Lee, Jeong-Kug;Kwon, Tae-Jong;Kho, Yung-Hee
    • 한국미생물·생명공학회지
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    • 제13권3호
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    • pp.257-263
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    • 1985
  • Rhodopseudomonas sp. KCTC 1437은 글루타민산이 질소원으로 존재할 때, 포도당으로부터 질소고 정효소 (nitrogenase)에 의해 효율적으로 수소를 생성하였다. in vivo에서 질소고정 효소의 활성도를 조사해 본 결과, 암모니아 이온의 제한 농도에서 키운 균체가 다른 질소원에서 키운 균체보다 더 큰 정도로 수소를 글루타민산 존재하에서 포도당으로부터 생성하였다. 이 균주는 또한 수소 생성의 억제물질 및 조건으로 알려져 있는 암모니아 이온의 높은 농도와 암조건에서 높은 정도로 수소를 생성했는데 이것은 수소효소 (hydrogenase)의 일종인 포르믹산 수소분해효소 (formic hydrogenlyase)에 의한 것이라 고려된다.

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한국 연안산 질소고정 단세포 남세균 종주의 최적 성장 및 수소생산 온도 (Optimal Temperature for H2 Production and Population Growth of the N2-fixing Unicellular Cyanobacterial Strains from Korean Coasts)

  • 박종우;김형섭;이원호
    • 한국수소및신에너지학회논문집
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    • 제24권1호
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    • pp.20-28
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    • 2013
  • Photobiological hydrogen production by nitrogen-fixing unicellular cyanobacteria has long been considered to be an environmentally sound and very promising method for the future supply of renewable clean energy. Using six Korean nitrogen-fixing unicellular cyanobacterial strains and the Synechococcus sp. strain Miami BG043511 we performed cultivation experiments to find out the strain-specific optimal temperature for population growth and $H_2$ production. Under $20^{\circ}C$ the population growth of all the tested strains was significantly retarded in contrasts to the faster and higher growth under 25, 30 or $35^{\circ}C$. The highest growth rates in all the 7 strains were measured under $30^{\circ}C$ while the maximal biomass yields were under $30^{\circ}C$ (strains CB-MAL 026, 054, and 055) or $35^{\circ}C$ (strains 002, 031, 058, and Miami BG043511). The difference between the maximal biomass yields at $30^{\circ}C$ and $35^{\circ}C$ was not greater than 10%. The quantity of photobiologically produced $H_2$ was only slight larger under $35^{\circ}C$ than that under $20^{\circ}C$. Our result may suggest a two-step process of $H_2$ production which includes rapid and sizable production of biomass at $30^{\circ}C$ and the following high $H_2$ production at $20^{\circ}C$ by the test strains of marine nitrogen-fixing unicellular cyanobacteria.

고분자 연료전지 스택에서 질소 크로스오버 특성에 관한 연구 (Characterization of Nitrogen Gas Crossover in PEM Fuel Cell Stacks)

  • 백경돈;김민수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2227-2230
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    • 2008
  • Crossover of nitrogen from cathode to anode is inevitable in typical membranes used in PEM fuel cells. This crossovered nitrogen accumulates in anode recirculation system and excessive buildup of nitrogen in the recirculating anode gas lowers the hydrogen concentration and finally affects the performance of fuel cell stacks. In this study, characterization of nitrogen gas crossover was investigated in PEM fuel cell stacks. The mass spectroscopy (MS) has been applied to measure the amount of the crossovered nitrogen at the exit of anode. Results show that anode and cathode stoichiometric number ($SR_c$) have a big effect of nitrogen crossover.

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소염상태 근방에서의 대향류 수소확산화염의 구조 (Near-Extinction Structure of Counterflow Nonpremixed Hydrogen-Air Flames)

  • 김후중;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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    • pp.77-87
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    • 1997
  • The axisymmetric Navier-Stokes model together with detailed chemical kinetics and variable transport properties has been applied to analyze the effects of the multidimensional flow on the flame characteristics in the nitrogen-diluted hydrogen counterflow nonpremixed flame. Computations are performed for two nozzle exit area-averaged velocities. Effects of multidimensional flow and strain rate on the near-extinction structure of the highly diluted hydrogen flames are discussed in detail.

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USB 공법에 의한 $NO_3^--N$ 함유 폐수처리 (Treatment of wastewater containing nitrate using upflow sludge blanket process)

  • 김형석;은종극;박승조
    • 한국환경과학회지
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    • 제4권3호
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    • pp.87-87
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

USB 공법에 의한 $NO_3^--N$ 함유 폐수처리 (Treatment of wastewater containing nitrate using upflow sludge blanket process)

  • 김형석;은종극;박승조
    • 한국환경과학회지
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    • 제4권3호
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    • pp.239-247
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    • 1995
  • This study was investigated with denitrification of wastewater containing nitrate using upflow sludge blanket process. Contents of this study were the nitrogen gas Production, relationship between HRT and COD/$NO_3^--N$ ratio in case of various hydrogen donor addition, relationship between nitrate loading rate and various hydrogen donor addition.

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