• Title/Summary/Keyword: nitrogen ($N_2$)

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Crystal properties of wurtzite GaN grown under various nitrogen plasma conditions (여러 질소 플라즈마 상태에서 성장한 wurtzite GaN의 결정특성)

  • 조성환;김순구;유연봉
    • Journal of the Korean Vacuum Society
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    • v.6 no.4
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    • pp.354-358
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    • 1997
  • Crystal properties of wurtzite GaN films grown on $Al_2O_3$(0001) substrates under various nitrogen pressure and plasma power by electron cyclotron resonance molecular beam epitaxy were investigated by full width at half maximum of X-ray diffraction peak and scanning electron microscope. It was found that the nitrogen pressure has a large effect on the FWHM value of XRD, and the GaN film grown under the optimum nitrogen pressure contains high density of dislocations. These results suggest that the crystal quality is sensitive to the plasma source conditions and that the relaxation of stress depends of V/III ratio. However, substrate-surface nitridation has little effect on the relaxation of misfit stress.

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Development of Bacteria for Removal of the Nitrogen in Wastewater (하ㆍ폐수 고도처리를 위한 다기능의 질소원 분해능 균주의 분리)

  • 이진용;김진수;공성호;심호재;이상섭
    • Korean Journal of Microbiology
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    • v.39 no.1
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    • pp.21-26
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    • 2003
  • Ninety strains of photosynthetic bacteria were isolated from a local stream at Kyonggi-do, Korea and were further screened. Using these isolated strains, experiments were performed under various light and oxygen conditions in order to select strains with high nitrogen $(NH_3-N,\; NO_3^--N)$ removal efficiencies. Results showed that all the strains screened removed $NH_3-N$, the light had no effect on nitrogen removal, and the nitrogen removal rate was higher aerobically than anaerobically. The removal of $NO_3^--N$ was showed up to 35.3% in some specific strains. Results of batch experiments using Rhodocyclus gelatinosus, an isolated strain with a superior removal rate of $NH_3--N$ and $NH_3-N$, under the anaerobic condition, showed that the removal rate of organics and $NH_3-N$ was the highest (98.2 and 89.0%, respectively) at the CODcr (mg/L)/biomass (mg/L) ratio of 0.2, and the $NH_3-N$ concentration did not increase with the decreasing $NH_3-N$ concentration. Experimental results from various C/N ratios confirmed that the effective removal rate (75.8%) of $NH_3-N$ occurred even at the low (5:1) C/N ratio as well as high ratios, and the simulataneous removal of $NO_3^--N$ (96.0%).

Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice;I. Effects of Paper Sludge Application on the Nitrogen Forms and Inorganic Nutrients of Paddy Soil (제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響);Ⅰ. 슬러지시용(施用)이 토양중(土壤中) 질소형태(窒素形態) 및 무기성분변화(無機成分變化)에 미치는 영향(影響))

  • Heo, Jong-Soo;Kim, Kwang-Sik
    • Korean Journal of Environmental Agriculture
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    • v.4 no.2
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    • pp.78-87
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    • 1985
  • To investigate the effects of paper sludge, by-products of paper manufactory, on the chemical properties of paddy soil and growth of paddy rice, paper sludges were applied to the pots at the rates of 300, 600, 900 and 1,200㎏/l0a which were either pread-justed C/N ratio to 30 : 1 or not adjusted. The effects were compared with those of control. Seasonal variations of various forms of soil organic nitrogen, the mineralization of organic nitrogen and the contents of soil minerals were analyzed. The results were summarized as follows: 1) The contents of soil organic nitrogen, especially amino sugar-N and amino acid-N, organic matter, CEC and available $SiO_2$ were increased by application of paper sludge compared with that of control. 2) The mineralizations of organic nitrogen after 6 weeks of incubation at $30^{\circ}C$ were 12. 2, 12.6, 15.1, 9.7 and $15.2^{\circ}C$ in the control, 300㎏/l0a sludge treatment, 300㎏/l0a sludge treatment(C/N ratio adjusted), 600㎏/l0a sludge treatment and 600㎏/l0a sludge treatment(C/N ratio adjusted), respectively. 3) Cu and Pb contents in the soil were in the range of $0{\sim}0.2100$ and $0{\sim}0.0013$ ppm, respectively. Cr and Cu in the soil were not detected at all. There were no differences in the contents of all the heavy metals among all the treatments in the soil.

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Relation of Organic Matter Content and Nitrogen Mineralization of Soils Collected from Pepper Cultivated Land (고추 재배 밭에서 채취한 토양의 유기물 함량과 질소 무기화 량의 관계)

  • Lee, Yejin;Lee, Seulbi;Kim, Yangmin;Song, Yosung;Lee, Deogbae
    • Korean Journal of Environmental Agriculture
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    • v.38 no.3
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    • pp.119-123
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    • 2019
  • BACKGROUND: Estimation of soil nitrogen supply is essential to manage nitrogen fertilization in arable land. In Korea, nitrogen fertilization is recommended based on the soil organic matter content because it is difficult to assess nitrogen (N) mineralization of upland soils directly. In this study, the relationship between soil organic matter (SOM) content and N mineralization was investigated to explore the limitation of using SOM in predicting soil N mineralization. METHODS AND RESULTS: Soil samples from the 0 to 10 cm depth were collected from 18 individual pepper cultivated fields in Tae-an and Chung-yang provinces before fertilization. N mineralization in the soils was quantified using incubation for 70 days at $30^{\circ}C$. The mineralizable soil N (MSN) was positively correlated with SOM, and the relation equation between MSN and SOM was '$MSN(kg\;10a^{-1})=0.2933{\ast}SOM(g\;kg^{-1})+0.0897$ ($r^2=0.6224$, p<0.001)'. However, the differences of N mineralization among the soils with the similar concentrations of soil organic matter were about 3 to 4.6 times, suggesting that the other soil factors such as total N concentration or EC should affect N mineralization. CONCLUSION: We concluded that SOM alone could not reflect the capacity of soil to supply N that is used for recommendation of N fertilization rate. Therefore, other soil properties should be considered to improve N fertilization management in arable land for sustainable agriculture.

Effect of Nitrogen Application Rates on Nitrous Oxide Emission during Crop Cultivations in Upland Soil

  • Lee, Jong-Eun;Yun, Yeo-Uk;Choi, Moon-Tae;Jung, Suck-Kee;Nam, Yun-Gyu;Pramanik, Prabhat;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.31 no.3
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    • pp.205-211
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    • 2012
  • BACKGROUND: Generally, nitrogen (N) fertilization higher than the recommended dose is applied during vegetable cultivation to increase productivity. But higher N fertilization also increases the concentrations of nitrate ions and nitrous oxide in soil. In this experiment, the impact of N fertilization was studied on nitrous oxide ($N_2O$) emission to standardize the optimum fertilization level for minimizing $N_2O$ emission as well as increasing crop productivity. Herein, we developed $N_2O$ emission inventory for upland soil region during red pepper and Chinese milk vetch cultivation. METHODS AND RESULTS: Nitrogen fertilizers were applied at different rates to study their effect on $N_2O$ emission during red pepper and Chinese milk vetch cultivation. The gas samples were collected by static closed chamber method and $N_2O$ concentration was measured by gas chromatography. The total $N_2O$ flux was steadily increased due to increasing N fertilization level, though the overall pattern of $N_2O$ emission dynamics was same. Application of N fertilization higher than the recommended dose increased the values of both seasonal $N_2O$ flux (94.5% for Chinese cabbage and 30.7% for red pepper) and $N_2O$ emission per unit crop yield (77.9% for Chinese cabbage and 23.2% for red pepper). Nitrous oxide inventory revealed that the $N_2O$ emission due to unit amount of N application from short-duration vegetable field in fall (autumn) season (6.36 kg/ha) was almost 70% higher than that during summer season. CONCLUSION: Application of excess N-fertilizers increased seasonal $N_2O$ flux especially the $N_2O$ flux per unit yield during both Chinese cabbage and red pepper cultivation. This suggested that the higher N fertilization than the recommended dose actually facilitates $N_2O$ emission than boosting plant productivity. The $N_2O$ inventory for upland farming in temperate region like Korea revealed that $N_2O$ flux due to unit amount of N-fertilizer application for Chinese cabbage in fall (autumn) season was comparatively higher than that of summer vegetables like red pepper. Therefore, the judicious N fertilization following recommended dose is required to suppress $N_2O$ emission with high vegetable productivity in upland soils.

THE EFFECT OF NITROGEN ON THE MICROSTRUCTURE AND THE CORROSION RESISTANCE OF Fe-Hf-C-N THIN FILMS

  • Choi, J.O.;Han, S.H.;Kim, H.J.;Kang, I.K.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.641-644
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    • 1995
  • We have studied the effect of the nitrogen on the microstructure, thermomagnetic properties and corrosion resistance of Fe-Hf-C-N nanocrystalline thin films with high permeability and high saturation magnetization. These films were fabricated by reactive sputtering in $Ar+N_{2}$ plasma using an rf magnetron sputtering apparatus. As $P_{N2}$ increases, the microstructure changes from amorphous to crystalline $\alpha$-Fe phase and again returns to amorphous one. Spin wave stiffness constant increases with $P_{N2}$ until 5% $P_{N2}$, and then decreases with the further increase. This trend corresponds well with that of the microstructure with increasing $P_{N2}$. The Fe-Hf-C-N films with over 3% $P_{N2}$ show higher corrosion resistance than the N-free Fe-Hf-C films. The Fe-Hf-C-N films are considered to have high potentials for the head core materials suitable for high density recording systems, owing to their excellent soft magnetic properties and corrosion resistance.

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Uptake and Content of Ions on Several Organs of Mulberry Tree(Morus alba L.) in Relation to Different Nitrogen Sources in Water Culture (수경액중(水耕液中)의 공급질소형태(供給窒素形態)에 따른 상수(桑樹)의 이온 흡수와 기관별(器官別) 분포(分布)에 관한 연구)

  • Lee, Won-Chu;Ryu, Keun-Sup
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.4
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    • pp.270-276
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    • 1982
  • Water culture experiment with mulberry (Morus alba L.)was carried out to investigate the ionic composition in the exudate and the ionic content in the organs (leaves, petioles, stem cortex, and roots) of mulberry tree with three different nitrogen sources ($NO_3-N$, $NH_4-N$, and $NH_4NO_3$). 1. Amount of exudate was much lower for $NH_4-N$ than for $NO_3-N$. 2. Total nitrogen content in the exudate was the highest in the NH4-N, the order of 2.2 times than in the $NO_3-N$. However, total nitrogen amount absorbed by tree per hour was proportional with the exudate amount. As the result, total nitrogen amount was higher 1.6 times in $NO_3-N$ ($289.6\;me\;plant^{-1}\;hr^{-1}$ than in $NH_4-N$. 3. Ammonium nitrogen depressed $Ca^{2+}$ uptake critically and even all of the anions, whereas $Mg^{2+}$, $K^+$ and $Na^+$ affected little. 4. Reduction of $NO_3$ may occured both in root and in leaves. 5. Content of cations and anions was highest in petioles, except $Ca^{2+}$ which was highest in leaves. As the result, petioles may be the storage organ of nutrients. 6. By increasing $NH_4-N$, ionic balance (C-A) decreased proportionally. 7. Nutrients amount in the exudate were approximatelly proportional with the amount in the roots. This suggested that roots may be the part diagnosed for nutrients. Being the sum of anions (${\Sigma}A$) higher than that of cations (${\Sigma}C$) in the roots, the ionic balance showed negative value.

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Estimating the Nitrogen and Phosphorus Loads of Wintering Waterfowl Feces in Lake Paldang (팔당호에서 겨울철새 분변에 의한 질소와 인 오염부하량 산정)

  • Lee, Jangho;Park, Hae-Kyung
    • Journal of Korean Society on Water Environment
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    • v.26 no.2
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    • pp.311-316
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    • 2010
  • We estimated the nitrogen and phosphorus loads of wintering waterfowl feces in Lake Paldang. The average number of individual birds that belonged to Anatidae species was 2,852.5 from 2005 to 2008 in Lake Paldang. The number of Anatidae reached 97.4% of the total number of individual birds. For evaluating the loading amounts of N and P by waterfowl to Lake Paldang, the feces dry weight (g/day) of each Anatidae species was estimated by multiplying the body weight of the each bird by 2.25% and assumed that N and P in feces contain 1.46% and 0.33%, respectively. We assigned probability 1/3 to the nutrient decomposition of the bird feces in water. The nitrogen loading by wintering waterfowl feces was 0.06 ton/year and the phosphorus loading was 0.001 ton/year. These amounts were 0.0002% of all N loadings and 0.0001% of all P loadings. Therefore the wintering waterfowl might have little impact on the water quality in terms of eutrophication in Lake Paldang.

Changes of Physicochemical Parameters During the Aerobic Composting Process of Swine Manure (돈부의 호기성 퇴비화 단계별 물리.화학적 성상 변화)

  • 김태일;정광화;최기춘;류병희;곽정훈;전병수;박치호;김형호;한정대
    • Journal of Animal Environmental Science
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    • v.3 no.1
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    • pp.13-18
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    • 1997
  • This study was conducted to investigate the physicochemical changes during the aerobic composting of swine manure mixed with bulking agent, sawdust(v/v, 1:1), in a full-scale composting plant using rectangular escalator-aginated bed composting system. Physical and chemical properties were analyzed on the samples which were collected at 5, 15, and 25 day of composting, curing and final step. The results of this study were summarized as follows; 1. Moisture and K2O content, and pH of final step were higher than those of 5th day of composting (p<0.05). 2. Ammonium nitrogen, total organic corbon and organic matter content, and electrical conductivity(EC) were significantly decreased (p<0.05) but nitrate nitrogen, ash and P2O5 content increased(p<0.05) throughout the aerobic composting process. 3. Total organic carbon per total nitrogen(C/N) and total organic matter per total nitrogen(OM/N) ratio were significantly decreased throughout the aerobic composting process(p<0.05). 4. Physical and chemical properties of swine manure were varied by aerobic fermentation using rectangular escalor-aginated bed composting system.

Effect of Inoculation of Rhizobic on Sesbania nitrogen fixation (Sesbania 에 대(對)한 근류균접종(根瘤菌接種) 효과(效果)와 질소고정(窒素固定)에 관(關)한 연구(硏究))

  • Ahn, Sang Bae;Yoneyama, J.;Gamo, H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.4
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    • pp.455-461
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    • 1988
  • The pattern of nitrogen fixation by water culture of Sesbania, known as an effective legume plant for nitrogen fixation, in the growth cabinet by Leonard-Jar methods and nitrogen fixation pattern to sesbania are as follows: 1. Dry weight per pot after inoculation of rhizobia to sesbania was by the order for root + stem > root > control and nitrogen contents of plant parts also showed the same tendency as dry weight except leaf. 2. $^{15}N$ value based on natural abundance was by the order of root + stem > root > control, $^{15}N$ value of root nodule and stem nodule among total nitrogen content exhibited positive value but it showed negative value from root, stem and leaf.

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