• Journal of Biosystems Engineering
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• v.35 no.5
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• pp.343-349
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• 2010

Rapid on-site sensing of nitrate-nitrogen and potassium ions in hydroponic solution would increase the efficiency of nutrient use for greenhouse crops cultivated in closed hydroponic systems while reducing the potential for environmental pollution in water and soil. Ion-selective electrodes (ISEs) are a promising approach because of their small size, rapid response, and the ability to directly measure the analyte. The capabilities of the ISEs for sensing nitrate and potassium in hydroponic solution can be affected by the presence of other ions such as calcium, magnesium, sulfate, sodium, and chloride in the solution itself. This study was conducted to investigate the applicability of two ISEs consisting of TDDA-NPOE and valinomycin-DOS PVC membranes for quantitative determinations of $NO_3$-N and K in hydroponic solution. Nine hydroponic solutions were prepared by diluting highly concentrated paprika hydroponic solution to provide a concentration range of 3 to 400 mg/L for $NO_3$-N and K. Two of the calibration curves relating membrane response and nutrient concentration provided coefficients of determination ($R^2$) > 0.98 and standard errors of calibration (SEC) of < 3.79 mV. The use of the direct potentiometry method, in conjunction with an one-point EMF compensation technique, was feasible for measuring $NO_3$-N and K in paprika hydroponic solution due to almost 1:1 relationships and high coefficients of determination ($R^2$ > 0.97) between the levels of $NO_3$-N and K obtained with the ion-selective electrodes and standard instruments. However, even though there were strong linear relationships ($R^2$ > 0.94) between the $NO_3$-N and K concentrations determined by the Gran's plot-based multiple standard addition method and by standard instruments, hydroponic $NO_3$-N concentrations measured with the ISEs, on average, were about 10% higher than those obtained with the automated analyzer whereas the K ISE predicted about 59% lower K than did the ICP spectrometer, probably due to no compensation for a difference between actual and expected concentrations of standard solutions directly prepared.

• Journal of Conservation Science
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• v.31 no.4
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• pp.403-409
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• 2015

Malachite and Azurite are the typical copper system pigments which used the mural paintings since ancient times. The mural painting is at risk for damages of the painting layer by atmosphere gas because it is exposed at external environment. In this study, it did experiment about an effect to Malachite and Azurite by environmental pollution gas($NO_2$, $CO_2$, $SO_2$) then analysis and estimate about test for pieces using mural painting colored that two pigments. As a result, Malachite and Azurite were changed on $NO_2$ but not changed $CO_2$ and $SO_2$. Especially as the concentration of $NO_2$ is increased, exfoliation of the pigment layer weave remarkably formed pores on the pigment particles on SEM, the phenomenon to be pieces were observed together with smaller particles. In the case of Malachite that were exposed to $NO_2$ gas, new compounds(Rouaite : dicopper (nitrate(V) trihydroxide, $Cu_2(NO_3)(OH)_3$)) was appeared by XRD analysis. Therefore, there had been able to verify the fact that the cause exfoliation and discoloration phenomena accompanied by chemical changes for Malachite and Azurite.

• Journal of Korean Society on Water Environment
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• v.28 no.2
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• pp.255-268
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• 2012

Nonpoint source pollution has become a concern for water quality in the Han River system, especially during the high runoff events during the monsoon season. The patterns in nonpoint source runoff the relationships with land use, rainfall intensity, and stream nutrients concentrations were surveyed in 19 streams in the Han River watershed. The results show that the magnitude of NPS inputs of nutrients and sediment in the Han River watershed are of a serious concern. In the South Han River watershed, event mean concentrations (EMC) for biochemical oxygen demand (BOD), suspended sediment (SS), dissolved organic carbon (DOC), dissolved total phosphorus (DTP), total nitrogen (TN) Nitrate ($NO_3$-N) and total phosphorus (TP) were $1.94mg{\cdot}L^{-1},\;251mg{\cdot}L^{-1},\;2.75mg{\cdot}L^{-1},\;0.076mg{\cdot}L^{-1},\;2.82mg{\cdot}L^{-1},\;2.40mg{\cdot}L^{-1}$ and $0.232mg{\cdot}L^{-1}$, respectively. In the North Han River watershed, EMCs for BOD, SS, DOC, DTP, TN, $NO_3$-N and TP were $1.34mg{\cdot}L^{-1},\;172mg{\cdot}L^{-1},\;2.63mg{\cdot}L^{-1},\;0.032mg{\cdot}L^{-1},\;1.97mg{\cdot}L^{-1},\;1.55mg{\cdot}L^{-1}$ and $0.148mg{\cdot}L^{-1}$, respectively. The specific export coefficients of nutrient and sediments were much higher than those of other reports. Our study also found that the proportion of agricultural field area was significantly correlated with the EMCs for nutrients. Therefore, efforts to reduce NPS loading must focus on agricultural practices in the watershed. The relationships between land use and nutrient and sediment export found in this study can be used to derive estimates of runoff coefficients for agricultural field and as input data for modeling works and to develop total maximum daily load and best management practices in the Han River watershed.

• Korean Journal of Environmental Biology
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• v.17 no.3
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• pp.337-344
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• 1999

This study was carried out to investigate the influence of spa sewage on water quality and chemical contents in the paddy soil along stream from 1997 to 1998. Concentration of $PO_4, SO_4, Cl, NH_{4}, Ca, Na$ and COD in the spa sewage were lower than standard for agricultural usage, and were lowered as the sewage flew to the into stream. The concentration of $SO_4$in spa sewage was over the criteria for agricultural usage in the inlet, but was lower than criteria for agricultural usage by inlet of non polluted stream water. Concentration of pollutants in the sediment of water channel were the highest in the inlet site. There were no pollutants accumulation in the paddy soil where spa sewage was irrigated. It may be resulted from nutrients uptake of rice plant and self purification of paddy soil. On the while, considering electric conductivity and nitrate in spa sewage, this results suggest that long-term irrigation of the spa sewage may be required general management with some decreasing fertilization.

• Journal of Environmental Health Sciences
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• v.44 no.3
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• pp.259-266
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• 2018

Objectives: Considered the "national fish" in Korea, the walleye pollock (Gadus chalcogrammus) has disappeared in the East Sea (Sea of Japan), a main habitat and fishing ground for the species. The reason for the disappearance is still a matter of controversy. This study was performed to investigate the long-term relationship between the walleye pollock catch and various meteorological and oceanographic factors in these waters. Methods: Fishery data on walleye pollock and data on meteorological and marine environmental factors over the 30 years (1981-2010) were obtained from the official national database. Time series analysis and correlation and regression analyses were performed to study the relationships. Results: Both air temperature and sea surface temperature in the East Sea rose over these 30 years, and the latter became more prominent. Salinity and dissolved oxygen showed a tendency to decrease while concentrations of nutrients such as nitrite nitrogen and nitrate nitrogen showed an increasing tendency. Sea surface temperature, air temperature, atmospheric pressure, and wind grade were negatively correlated with the catch size of walleye pollock (p<0.05), but salinity was positively correlated (p<0.001). Conclusion: The results of this study indicate that climate change, especially ocean warming, affected the habitat of walleye pollock. The results also indicate that lower sea surface and air temperatures, milder wind grade, and higher salinity were preferred for the survival of the fish species. It is necessary to pay attention to changes of the ocean ecosystem in terms of environmental pollution as well as seawater temperature.

• Asian Journal of Atmospheric Environment
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• v.9 no.1
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• pp.78-85
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• 2015

In the past several decades, biofuels have emerged as candidates to help mitigate the issues of global warming, fossil fuel depletion and, in some cases, atmospheric pollution. To date, the only biofuels that have achieved any significant penetration in the global transportation sector are ethanol and biodiesel. The global consumption of biodiesel was rapidly increased from 2005. The goal of this study was to examine the chemical composition on particulate pollutant emissions from a diesel engine operating on several different biodiesels. Tests were performed on non-road diesel engine. Experiments were performed on 5 different fuel blends at 2 different engine loading conditions (50% and 75%). 5 different fuel blends were ultra-low sulfur diesel (ULSD, 100%), soy biodiesel (Blend 20% and Blend 100%) and canola biodiesel (Blend 20% and Blend 100%). The chemical properties of particulate pollutants were characterized using an Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS). Organic matter and nitrate were generally the most abundant aerosol components and exhibited maximum concentration of $1207{\mu}g/m^3$ and $30{\mu}g/m^3$, respectively. On average, the oxidized fragment families ($C_xH_yO_1{^+}$, and $C_xH_yO_z{^+}$) account for ~13% of the three family sum, while ~87% comes from the $C_xH_y{^+}$ family. The two peaks of $C_2H_3O_2$ (m/z 59.01) and $C_3H_7O$ (m/z 59.04) located at approximately m/z 59 could be used to identify atmospheric particulate matter directly to biodiesel exhaust, as distinguished from that created by petroleum diesel in the AMS data.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.2
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• pp.133-145
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• 2001

The receptor modeling is one of the statistical methods to achieve reasonable air pollution strategies. The pur-pose of this study was to survey the concentration variability oi inorganic elements and ionic species in the PM-10 particles, to qualitatively characterize emission sources by an advanced algorithm called positive matrix factoriza-tion(PMF) as a receptor model that can strictly provide results in every loading matrix. A total of 254 samples was collected by a PM-10 high volume air sampler from Mar. 1997 to Feb. 1998 in Kyung Hee University at Suwon Campus. Fourteen chemical species(Zn, Cu, Fe, Pb, Al, Mn, $Na^{+}$, NH$_4$+, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, $SO_4^{2-}$, $NO_{3}^{-}$, and $Cl^{-}$) were determined by AAS and IC methods. The study results showed that the average monthly concentration of PM-10 particles were 86.3$\mu\textrm{g}$/$\textrm{m}^3$ in March (maximum) and 28.5$\mu\textrm{g}$/$\textrm{m}^3$ in August(minimum), respectively. The concentrations of Na+, NH$_4$+, $K^{+}$ and $Cl^{-}$ in winter, $Mg^{2+}$, $Ca^{2+}$ and $NO_{3}^{-}$, in spring, and $SO_4^{2-}$ in summer showed the largest peak concentration for the respective season. Through and app-lication of a PMF program of Pm-10 concentration data of Suwon, 9 sources were qualitatively identified , such as incineration source, oil burning source, soil related source, open burning source automobile source, coal burning sources, secondary sulfate related source, and secondary nitrate related source.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.35-37
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• 2001

This study has investigated the chemical characteristics and the contamination of groundwater in relation to land use in Daejeon Metropolitan City. An attempt was made to distinguish anthrophogenic inputs from the influence of natural chemical weathering on the chemical composition of groundwater at Taejon. Groundwater samples collected at 170 locations in the Taejon area show very variable chemical composition of groundwater, e.9. electrical conductance ranges from 65 to 1,290 S/cm. Most groundwater is weakly acidic and the groundwater chemistry is more influenced by land use and urbanization than by aquifer rock type. Most of groundwater from green areas and new town residential districts has low electrical conductance, and is of Ca-HC $O_3$ type, whereas the chemical composition of groundwater from the old downtown and industrial district is shifted towards a Ca-Cl (N $O_3$+S $O_4$) type with high electrical conductance. A number of groundwater samples in the urbanized area are contaminated by high nitrate and chlorine, and exhibit high hardness. The Ep$CO_2$, that is the $CO_2$ content of a water sample relative to pure water, was computed to obtain more insight into the origin of $CO_2$ and bicarbonate in the groundwater. Factor analysis of the chemical data shows that the HC $O_3$ and N $O_3$ concentrations have the highest factor loadings on factor 1 and factor 2, respectively. Factors 1 and 2 represent major contributions from natural processes and human activities, respectively. The results of the factor analysis indicate that the levels of $Ca^{2+}$, $Mg^{2+}$, N $a^{+}$, Cl and SO4$^2$ derive from both pollution sources and natural weathering reactions.ons.

• Journal of Soil and Groundwater Environment
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• v.16 no.2
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• pp.61-76
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• 2011

This study was objected to provide suggestions for best management practices to restore the cultural and historical values of the wells in Palaces as well as their water qualities. Water resources in the five Palaces in Seoul Metropolitan, including Gyeongbokgung, Changdeokgung, Changgyeonggung, Jongmyo Shrine, and Deoksugung, were surveyed for their physical flows and chemical compositions from April to July in 2010. Ground waters in most wells were found at depths within 5 m from the ground surface, showing typical water-table aquifer systems. Hydraulic gradients indicate water resources in Gyeongbokgung, Changdeokgung, and Changgyeonggung flowing toward south, and toward east in Deoksugung area. Especially, water-level fluctuation data at S-10 in Deoksugung implied the influence of groundwater discharge facility. In Jongmyo Shrine, water was not detected in wells, indicating the water level was lower than the well depth. Based on the water chemistry and stable isotope analyses, water resources and their qualities appeared to be formed by the water-rock interaction along the groundwater paths. S-10 (Deoksugung) and S-14 (Changgyeonggung) samples were contaminated with nitrate ($NO_3$) in levels of higher than Korean drinking water standard, 10 mg/L as $NO_3$-N, but once in four sampling campaigns. In the situation that water resources in Palaces still maintain natural characteristics, the materials that will be used for the restoration and improvement of the Palace water supplies should be carefully selected not to disturb the natural integrity. In addition, because the wells are located in the center of metropolitan area, a systematic monitoring should be applied to detect and to manage the potential impacts of underground construction and various pollution sources.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.519-519
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• 2003

We performed a hydrochemical study on a total of 89 bedrock groundwaters collected from preexisting wells (30 to 300 m deep) in the Boeun area. Hydrochemical data showed significant variations in the area, due to varying degrees of anthropogenic pollution. The waters were mostly enriched in Ca and HCO$_3$ but locally contained significant concentrations of anthropogenic constituents in the general order of Cl >NO$_3$>SO$_4$. In particular, about 11% of the examined wells exceeded the drinking water standard with respect to nitrate. We consider that aquifers in the area are locally highly susceptible to the contamination related to agricultural activities. Diagrams showing the relationships between the summation of cations (∑cations) and the concentration of several anions with different origin (natural versus anthropogenic) were used to estimate the relative role of anthropogenic contamination. A good correlation was observed for the relationship between ∑cations and bicarbonate, indicating that water-rock interaction (namely, hydrolysis of silicate minerals) is most important to control the water quality. Thus, we made an assumption that the equivalent of dissolved cations for a water should be equal to the alkalinity, if the chemistry were controlled solely by a set of natural weathering reactions. If we excluded the equivalent quantities of cations and bicarbonate (natural origin) from the acquired data for each sample, the remainder therefore could be considered to reflect the degree of anthropogenic contamination. Finally, we performed a multiple regression approach for hydrochemical data using the ∑cations as a dependent variable and the concentration data of each anion (natural or anthropogenic) as an independent variable. Using this approach, we could estimate the relative roles of anthropogenic and natural processes. Rather than the conventional evaluation scheme based on water quality criteria, this approach will be more useful and reasonable for the evaluation of groundwater quality in a specific region and also can be used for planning appropriate protection and remedial actions.