• 제목/요약/키워드: nitrate pollution

검색결과 146건 처리시간 0.024초

Evaluation for Impacts of Nitrogen Source to Groundwater Quality in Livestock Farming Area

  • Lee, Gyeong-Mi;Park, Sunhwa;Kim, Ki-In;Jeon, Sang-Ho;Song, Dahee;Kim, Deok-hyun;Kim, Tae-Seung;Yun, Seong-Taek;Chung, Hyen Mi;Kim, Hyun-Koo
    • 한국토양비료학회지
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    • 제50권5호
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    • pp.345-356
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    • 2017
  • We investigated 52 livestock farming complexes in Gyeong-Gi and Incheon provinces based on low, medium, and high livestock density and groundwater quality. The objective of this study was to evaluate a relationship between nitrate N concentration in groundwater and animal factors, such as livestock density and animal species. 2,200 groundwater samples for 3 years from 2012 to 2014 at Gyeong-Gi and Incheon provinces were collected and analyzed for pH, EC, DO, ORP, temperature, major anions and cations, such as $NO_3-N$, ${HCO_3}^-$, ${PO_4}^-$, ${SO_4}^{2-}$, $Cl^-$, $NH_4-N$, $K^+$, $Na^+$, $Ca^{2+}$, $Mg^{2+}$, T-N, and TOC. Average concentration of total N for generated load density was $23,973g\;day^{-1}\;km^{-2}$ for cattle, $51,551g\;day^{-1}\;km^{-2}$ for pig, and $52,100g\;day^{-1}\;km^{-2}$ for poultry. For animal feeding species, average ratio for generated load over discharge load was 16.1% for cattle, 7.8% for pig, and 7.1% for poultry. Therefore, cattle feeding region is highly vulnerable for water pollution compared to pig and poultry feeding areas. The concentrations of chloride, nitrate, and total N in the groundwater samples were higher at high animal farming regions than other regions. The average concentration of nitrate, and chloride in groundwater samples was $5.0mg\;L^{-1}$, $16.6mg\;L^{-1}$ for low livestock density, $6.9mg\;L^{-1}$, $17.7mg\;L^{-1}$ for medium livestock density and $7.6mg\;L^{-1}$, $22.7mg\;L^{-1}$ for high livestock density and total nitrogen (T-N) was $7.7mg\;L^{-1}$ for low livestock density, $9.4mg\;L^{-1}$ for medium livestock density, $10.7mg\;L^{-1}$ for high livestock density. In conclusion, based on this research, for managing groundwater quality near livestock farming regions, $Ca-(Cl+NO_3)$ group from the Piper diagram is more efficient than using 19 factors for water quality standard.

임천광산 광미와 주변 토양 및 지하수의 오염조사 (Analysis of mine tailings, soils, stream sediments and ground water around Imcheon disused mine)

  • 김선태;윤양희;박제안;심의섭;박경수
    • 한국토양환경학회지
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    • 제3권3호
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    • pp.33-44
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    • 1998
  • 임천광산의 광미와 주변 밭과 논의 토양, 하상퇴적물 및 지하수에서의 중금속과 시안의 오염도에 대해 조사하였다. 광미 중의 As, Cd, Cu, Hg, Pb, Zn및 CN ̄의 평균농도는 각각 366, 28.8, 202, 15.2, 1.97$\times$1$10^3$, 3.85$\times$$10^3$, 90.6mg/kg이었고 Kloke가 제안한 허용기준치를 이용한 오염지수는 8~19이었으며 pH는 산성이었다. 토양오염공정시험법에 의한 중금속 농도는 광미와 인접한 일부 토양만을 제외하고는 토양환경보전법의 농경지 우려기준이하였다. 광산 인근 주민들이 식수로 이용하는 일부 지하수에서 보건복지부의 음용수 수질기준을 훨씬 넘는 질산이온이 검출되었다.

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1액형 광촉매를 아스팔트 포장에 적용하기 위한 기초연구 (Fundamental Study on Applying an Integral TiO2 Solution to Asphalt Pavement)

  • 박재영;김영;김혁중;황용경;이재준
    • 한국도로학회논문집
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    • 제19권1호
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    • pp.53-62
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    • 2017
  • PURPOSES : This research was a fundamental study on the application of an integral $TiO_2$ solution to asphalt concrete pavement. The integral $TiO_2$ solution was produced in pilot production equipment; application of the integral $TiO_2$ solution to asphalt pavement was conducted to examine the pollution-reducing capability of photocatalytic compounds such as $TiO_2$. The photocatalytic $TiO_2$ reacted with air pollutants, converting them into small amounts of relatively benign molecules. METHODS : In this study, laboratory experiments were conducted using five various testing methods. Tensile strength ratio (TSR) and British pendulum test (BPT) were conducted in order to evaluate the properties of asphalt pavement subsequent to the integral $TiO_2$ solution coating. In addition, methylene blue testing, a measurement of nitrate on the coated pavement, and nitrogen oxide (NOx) reduction testing were conducted in order to evaluate photocatalytic reaction. Lastly, a UV-A lamp was used as a light source for photocatalytic reactions. RESULTS : Test results indicated no change in the properties of asphalt pavement following the integral $TiO_2$ solution coating. In order to evaluate the performance of asphalt pavement as a function of $TiO_2$, the moisture susceptibility and skid resistance were investigated. The moisture susceptibility and skid resistance satisfied there quirements related to pavement quality and safety specification. Furthermore, the effects of reduction of air pollution were significantly improved as determined via the methylene blue test and NOx reduction test. The $TiO_2$-paved asphalt specimen exhibited approximately 43% reduction of NOx. CONCLUSIONS : This study has suggested that applying $TiO_2$ rarely impacts asphalt pavement performance measures such as moisture susceptibility and skid resistance, and that its application may be a better means of reducing air pollution. Further studies, such as proper $TiO_2$ dosage rates and compatibility with various pavement types, are required to broaden and generalize its application.

광화학 상자모델과 기체/입자 평형모델을 이용한 서울의 계절별 질산염 농도 예측 (Prediction of Ambient Concentration of Nitrate in Seoul Using a Photochemical Box Model and a Gas-Aerosol Equilibrium Model)

  • 이시혜;김영성;김용표;김진영
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 춘계학술대회 논문집
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    • pp.347-348
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    • 2003
  • 대기 중의 질산에 의해 생성되는 질산염은 해염성분이나 토양성분과 만나 조대입자 영역에 머물거나 암모늄과 만나 미세입자로 존재할 수 있다. 미세입자로 존재하는 질산염은 여름철과 같은 광화학 반응이 활발할 때 2차적으로 생성되는 물질로, 반휘발성 특성 때문에 측정하는 과정에서 오차가 발생할 가능성도 크다. Seinfeld (1986)에 의하면 미국의 도심 지역에서 미세입자 중 황산염이나 질산염 등 2차 이온 성분의 비율이 전체 입자의 40∼60 %를 차지한다고 보고되고 있으며, 대표적인 도심 지역인 서울에서도 비슷하다 (강충민 등, 1999). (중략)

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정련폐액에서 실크 세리신의 회수방법 및 회수세리신의 특성 (Collecting method of silk sericin from degumming solution and characteristics of recovered sericin)

  • 김영대;권해용;우순옥
    • 한국잠사곤충학회지
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    • 제43권1호
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    • pp.37-40
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    • 2001
  • This study was carried out to investigate the optimum condition for silk sericin collection from degumming solution using some aluminium salts with various treatment conditions and examine the thermal properties of silk sericin collected from degumming solution. Silk sericin was precipitated by treatment of aluminium metal compound from degumming solution. The best optimum collecting conditions of silk sericin from degumming solution are the concentration of 2 $m\ell$/l of polyaluminium chloride (PAC), pH range of 5~7 and room temperature. The reduction of water pollution was evaluated by decreasing the chemical oxygen demand (COD) and nitrate ion (NO$_3$ ̄). Thermal stability of silk sericin collected from degumming solution was a little lower than that of hot water.

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도시 대기중에서 $NH_4NO_{3(s)} -HNO_{3(g)} -NH_{3(g)}$의 평형에 관한 연구 (A Study on Equilibrium of $NH_4NO_{3(s)} -HNO_{3(g)} -NH_{3(g)}$ in Urban Atmosphere)

  • 천만영;강병욱;김희강
    • 한국대기환경학회지
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    • 제8권3호
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    • pp.198-203
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    • 1992
  • Theoretical predictions of the atmospheric equilibrium involving $HNO_3, NH_3 and NH_4NO_3$ were compared with atmospheric measurements of particulate nitrate$(NO_3^-)$, $HNO_3$ and $NH_3$ concentration by triple filter pack sampler and Andersen air sampler in Seoul from 8th to 11th Oct 1991. The measured $HNO_3-NH_3$ concentration product K was higher than equilibrium costant Kc calculated from thermodynamic data of $HN_4NO_{3(s)} -HNO_{3(g)} -NH_{3(g)}$. The cause of K is greater than Kc was the result of air pollution, partcicularly anthropogenic $NH_3$.

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황해상 덕적도 PM2.5오염원의 확인 (Source Identification of PM2.5 at the Tokchok Island on the Yellow Sea)

  • 윤용석;배귀남;김동술;황인조;이승복;문길주
    • 한국대기환경학회지
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    • 제18권4호
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    • pp.317-325
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    • 2002
  • An air pollution monitoring station has been operated at Tokchok Island since April 1999 to characterize the background atmosphere in the vicinity of the Yellow Sea. In this study, eight chemical species in PM$_{2.5}$ and three gaseous species were analyzed. A total of 53 samples were collected for the analysis of PM$_{2.5}$ and gaseous species from April, 1999 to April, 2001. The overall mean mass concentration of PM$_{2.5}$ was 20.8 $\mu\textrm{g}$/㎥ and the eight soluble ionic species accounted for about 46.8% of PM$_{2.5}$ mass. Approximately 80% of samples appeared to experience the chloride loss effect. Air pollutant sources of PM$_{2.5}$ measured at Tokchok Island were qualitatively identified by the principal component analysis. It was found that five principal components are secondary aerosol, soil, incineration, phase change of nitrate, and ocean.and ocean.

미세입자($PM_{2.5}$) 측정시 유발되는 질산염 휘발 (Nitrate Volatilization Associated with Fine Particles($PM_{2.5}$) Measurement)

  • 강병욱;이학성
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2000년도 추계학술대회 논문집
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    • pp.81-82
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    • 2000
  • 미국 EPA에서 $PM_{2.5}$를 새로운 대기환경기준으로 설정함에 따라 $PM_{2.5}$를 측정하기 위한 새로운 Reference method가 설정되었다. 새로운 $PM_{2.5}$측정방법(Reference method)은 2.5$\mu\textrm{m}$ cut-diameter를 가진 cyclone을 통하여 16.7 L/min 유량으로 24시간동안 테프론 필터에 시료를 채집하는 것으로 규정하고 있다. 최근에 국내외에서 $PM_{2.5}$에 대한 활발한 연구가 수행되고 있으며 이들 연구의 대부분이 현재 미국 EPA의 $PM_{10}$ Reference method인 Dichotomous 샘플러를 이용하여 테프론 필터에 시료를 채취하고 있다 (중략)

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TiO$_2$ 광촉매를 이용한 기상 TCE의 분해에 관한 연구 (A Study on degradation of gas-phase TCE using TiO$_2$ photocatalyst)

  • 김상범;박태성;조영민;홍성창
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2002년도 춘계학술대회 논문집
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    • pp.307-308
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    • 2002
  • 최근 들어 지구환경의 보전 필요성이 그 어느 때보다도 강하게 제기되면서 대류권 내에서 진행되는 광화학적 대기오염 현상과 그에 따른 오존농도의 증가에 대해 많은 관심이 집중되고 있다 광화학적 대기오염현상이란 대기중의 휘발성 유기화합물(Volatile Organic Compounds VOCs)과 질소산화물(NOx)이 햇빛 내의 자외선에 의해 반응하면 오존, 알데히드, peroxyacetyl nitrate 등과 같은 2차 오염물질인 광화학 산화물을 생성하는 것을 의미하는데 이 광화학 산화물은 생물체에 악영향을 주고 아울러 성층권의 오존층을 파괴하여 궁극적으로는 지구 온난화 현상의 원인이 되고 있다. (중략)

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