• Title/Summary/Keyword: niobium

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A Study on the Electrochemical Properties of Water-soluble Waste Cutting Oil using Boron-Doped Diamond Electrodes (붕소도핑 다이아몬드 전극을 이용한 수용성 폐절삭유의 전기화학적 특성연구)

  • J.H., Park;T.G., Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.35 no.6
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    • pp.337-342
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    • 2022
  • In metal cutting, water-soluble cutting oil is used for cooling the surface of the workpiece and improving the surface roughness. However, waste cutting oil contains preservatives and surfactants, and if it is discarded as it is, it has an great influence on environmental pollution. For this reason, regulations on the use of cutting oil are being stricter. Hence, the development of eco-friendly treatment technologies is required. In this study, a diamond electrode doped with boron on a niobium substrate was deposited by thermal filament chemical vapor deposition and waste cutting oil was treated using an electrochemical method. Compared to the total amount of organic carbon contained in the waste cutting oil, it was confirmed that the boron-doped diamonds developed from this study showed much better performance than electrodes that has been widely used before.

HIP DIFFUSION BONDING OF INTRICATE SHAPE COMPONENTS MADE OF LIGHT ALLOYS AND STEELS

  • Guelman, A.A.
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.769-775
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    • 2002
  • The results gained as part of the study on weldability of compositions from steels, aluminium, titanium alloys in various combinations including similar and dissimilar metal bonding variants with reference to solution of specific practical problems are presented in this work. It has been shown that in the case of HIP/DB carried out with direct interaction of bonding surfaces of the most dissimilar material combinations under study, formation of high-quality joints is not assured due to various reasons. That is why development of special bonding techniques was required. The bonding techniques developed and used for HIP/DB of dissimilar steels, "Steel-bronze", "Titanium-niobium"; "Titanium-steel" and other compositions under study ensured vacuum-tight microvoid-free joints strength of a which was equal to the milder parent metal, including those obtained at reduced welding pressures. Examples of new products manufactured by HIP/DB using the technologies developed are presented.

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Magnetic Field Distribution Analysis of Superconducting Niobium Foil of Linear Type Magnetic Flux Pump using Simulation (시뮬레이션을 이용한 리니어형 자속 플럭스 펌프에서의 초전도 니오븀 박막의 자장분포 해석)

  • Lee, Eung-Ro;Chung, Yoon-Do;Bae, Duck-Kweon;Yoon, Yong-Soo;Ko, Tae-Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.3
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    • pp.60-64
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    • 2009
  • We investigated an operating characteristic of linear-type magnetic flux pump (LTMFP) as a current compensator under the various conditions. In order to explain the mechanism of the LTMFP, the magnetic behavior of superconducting Nb foil according to pumping actions should be understood. In this paper, the magnetic field analysis of superconducting Nb foil installed in LTMFP has been performed based on the three-dimensional finite element method (3D FEM). Through the simulation analysis, the normal spot region on the superconducting Nb foil is found to be enhanced swiftly over about 20 Hz. The simulated finding agreed with an analytical estimation based on the phenomenon of magnetic diffusion.

Study of the Electrical Conductivity of the $({\alpha}-Nb_2O_5)_{1-x^-}(PbO)_x$ Solid Solution ($({\alpha}-Nb_2O_5)_{1-x^-}(PbO)_x$ 고용체의 전기전도도)

  • Roh, Kwon-Sun;Ryu, Kwang-Sun;Jun, Jong-Ho;Lee, Sung-Ju;Yo, Chul-Hyun
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.625-629
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    • 1991
  • The electrical conductivity of the Niobium Oxide-Lead Oxide systems containing 2.5, 5.0, 7.5, and 10.0 mol% of Lead Oxide has been measured in a temperature range 700${\sim}$$1100^{\circ}C$ under oxygen partial pressure of 2.0 ${\times}$ $10^{-1}$${\sim}$1.0 ${\times}$ $10^{-5}$ atm. The electrical conductivities of the system decreased with increasing PbO mol% and varied from $10^{-5}$ to $10^{-1}$ $ohm^{-1}$ $cm^{-1}$. The activation energy for conductivity was about 1.70 eV. The oxygen pressure dependence of electrical conductivity revealed that the system was a mixed conductor between ionic and electronic conductivities at high oxygen pressures and a n-type electronic conductivity with oxygen pressure dependence of -1/4 order at low oxygen pressures. The defect structure and electrical conduction mechanism of the system have been discussed with the data obtained.

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Effect of Niobium and Tin on Mechanical Properties of Zirconium Alloys (Zr 합금의 기계적 특성에 미치는 Nb와 Sn의 영향)

  • Kim, Gyeong-Ho;Choe, Byeong-Gwon;Baek, Jong-Hyeok;Kim, Seon-Jae;Jeong, Yong-Hwan
    • Korean Journal of Materials Research
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    • v.9 no.2
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    • pp.188-194
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    • 1999
  • To investigate the effect of niobium and tin on the mechanical properties of zirconium alloys, the tensile test and the microstructural analysis were performed on the Zr-based binary(Zr-xNb, Zr-xSn) and ternary(Zr-0.8Sn-xNb, Zr-0.4Nb-xSn) alloys. As the content of Nb or Sn element increased, the strengths of the Zr-based alloys tended to gradually increase. The increase of mechanical strength was remarkable strength was remarkable in the range more than the solubility of Nb and Sn. The strengthening effects were discussed on the basis of the solid solution hardening, the precipitate hardening, the grain size effect, and the texture effect. The mechanical strength is mainly controlled by the solid solution hardening and additionally by the precipitate hardening in the content more than solubility limit of Nb and Sn. The grain refinement also has a slight effect on the strength of the zirconium alloys with the addition of Nb and Sn. However, the texture effect can be excluded due to the same Kearns number regardless of the content of alloying elements.

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Oxidation Behavior of Simudated Metallic U-Nb Alloys in Air (모의 금속전환체 U-Nb 합금의 공기중 산화거동)

  • Lee Eun-Pyo;Ju June-Sik;You Gil-Sung;Cho il-Je;Kook Dong-Hak;Kim Ho-Dong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.239-244
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    • 2004
  • In order to enhance an oxidation resistance of the pure uranium metal under air condition, a small quantity of niobium(Nb) which is known to mitigate metal oxidation is added into uranium metal as an alloying element. A simulated metallic uranium alloy, U-Nb has been fabricated and then oxidized in the range of 200 to $300^{\circ}C$ under the environment of the pure oxygen gas. The oxidized quantity in terms of the weight gain(wt%) has been measured with the help of a thermogravimetric analyzer. The results show that the oxidation resistance of the U-Nb alloy is considerably enhanced in comparison with that of the pure uranium metal. It is revealed that the oxidation resistance of the former with the niobium content of 1, 2, 3, and 4 wt% is : 1) 1.61, 7.78, 11.76 and 20.14 times at the temperature of $200^{\circ}C$ ; 2) 1.45, 5.98, 10.08 and 11.15 times at $250^{\circ}C$ ; and 3) 1.33, 4.82, 8.87 and 6.84 times at $300^{\circ}C$ higher than that of the latter, respectively. Besides, it is shown that the activation energy attributable to the oxidation is 17.13~21.92 kcal/mol.

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Nanostructured Bulk Ceramics (Part I)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.225-228
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    • 2009
  • The processing and characterization of ceramic nanocomposites, which produce bulk nanostructures with attractive mechanical properties, have been emphasized and introduced at Prof. Mukherjee's Lab at UC Davis. The following subjects will be introduced in detail in Part II, III, and IV. In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. The next part will show that an alumina-carbon nanotube-niobium nanocomposite produced fracture toughness values that are three times higher than that of pure nanocrystalline alumina. It was possible to take advantage of both fiber-toughening and ductile-metal toughening in this investigation. In the fourth section, discussed will be a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of $1400^{\circ}C$. This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method. This allowed the sintering to be completed at significantly lower temperatures and during much shorter times. These improvements in mechanical properties will be discussed in the context of the results from the microstructural investigations.

Study on the Purification and Single Crystal Growth of Niobium Metal by Electron Beam Floating Zone Melting (Electron Beam Floating Zone Melting에 의한 니오븀의 정련 및 단결정 성장에 관한 연구)

  • 최용삼;확준섭
    • Korean Journal of Crystallography
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    • v.3 no.2
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    • pp.72-84
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    • 1992
  • The investigation has been carried out for purification, single crystal growth mechanism and convective phenomena in EBFZM of Nb metal. It is found that the EBFZM refined effectively oxygen and nitrogen, the interstitial impurities in Nb, but carbon was increased slightly by backstream of diffusion pump oil. The mechanism of single crystal growth associated with the second recrystallieation in Nb was suggested from the relationship between texture of starting materials and the crystal growth in EBFZM. It was observed from the investigation of convection phenomena in molten zone that the Marangoni convection was dominant in molten zone, which caused the striation in Nb and increased the purification effect of oxygen and nitrogen.

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Comparisons and analysis on the prototype EU-DEMO TF CICC with Nb3Sn cable

  • Kwon, Soun Pil
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.4
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    • pp.31-39
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    • 2017
  • European R&D on designing their version of a DEMO fusion tokamak has recently resulted in the testing of a prototype $Nb_3Sn$ Cable-in-Conduit Conductor (CICC) for the DEMO TF coil. The characteristics and reported results of low temperature performance tests with the prototype CICC sample are compared with those from CICC samples incorporating other recent $Nb_3Sn$ cable designs. The EU-DEMO TF CICC prototype shows performance characteristics similar to that of the ITER CS CICC with short twist pitch. This is a first for a CICC sample that does not have a circular cross section. Assessment of its internal magnetostatic self-field suggests that a reduction in the internal self-field due to the rectangular geometry of the EU-DEMO TF CICC prototype compared to one with a circular geometry may have contributed to the performance characteristics showing current sharing temperature ($T_{cs}$) initially increase then stabilize with repeated electromagnetic loading, similarly to ITER CS CICC results. However, constraints on the internal self-field are not a sufficient condition for this $T_{cs}$ characteristic to occur.

Fatigue Characteristics and FEM Analysis of 18Ni(200) Maraging Steel (18Ni 마르에이징강의 피로특성 및 유한요소해석)

  • 장경천;국중민;최병희;정재강;최병기
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.04a
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    • pp.136-142
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    • 2004
  • Effects of Nb(Niobium) contents and solution annealing on the strength and fatigue lift of 18%Ni maraging steel commonly using in aircraft, space field, nuclear energy, and vehicle etc. were investigated. Also the fatigue life stress intensity factor were compared experiment result and FEA(finite element analysis) result. The more Nb content, the higher or the lower fatigue lift on base metal specimens or solution annealed specimens showing that the fatigue life was almost the same. The maximum stresses of X, Y, and Z axis direction showed about 2.12${\times}$10$^2$MPa, 4.40${\times}$10$^2$MPa and 1.32${\times}$10$^2$MPa respectively. The Y direction stress showed the highest because of the same direction as the loading direction. The fatigue lives showed about 7% lower FEA result than experiment result showing almost invariable error every analyzed cycle. Stress intensity factor of the FEA result was lower about 3.5∼10% than that of the experiment result showing that the longer fatigue crack length, the higher error. It considered that the cause for the difference was the modeled crack tip having always the same shape and condition regardless of the crack growth.

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