• Title/Summary/Keyword: neutralization efficiency

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High Quality Nano Structured Single Gas Barrier Layer by Neutral Beam Assisted Sputtering (NBAS) Process

  • Jang, Yun-Sung;Lee, You-Jong;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.251-252
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    • 2012
  • Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low Water Vapor Transition Rate (WVTR) of $1{\times}10^{-6}g/m^2$/day. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2$/day) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study, we developed an $Al_2O_3$ nano-crystal structure single gas barrier layer using a Neutral Beam Assisted Sputtering (NBAS) process. The NBAS system is based on the conventional RF magnetron sputtering and neutral beam source. The neutral beam source consists of an electron cyclotron Resonance (ECR) plasma source and metal reflector. The Ar+ ions in the ECR plasma are accelerated in the plasma sheath between the plasma and reflector, which are then neutralized by Auger neutralization. The neutral beam energies were possible to estimate indirectly through previous experiments and binary collision model. The accelerating potential is the sum of the plasma potential and reflector bias. In previous experiments, while adjusting the reflector bias, changes in the plasma density and the plasma potential were not observed. The neutral beam energy is controlled by the metal reflector bias. The NBAS process can continuously change crystalline structures from an amorphous phase to nano-crystal phase of various grain sizes within a single inorganic thin film. These NBAS process effects can lead to the formation of a nano-crystal structure barrier layer which effectively limits gas diffusion through the pathways between grain boundaries. Our results verify the nano-crystal structure of the NBAS processed $Al_2O_3$ single gas barrier layer through dielectric constant measurement, break down field measurement, and TEM analysis. Finally, the WVTR of $Al_2O_3$ nano-crystal structure single gas barrier layer was measured to be under $5{\times}10^{-6}g/m^2$/day therefore we can confirm that NBAS processed $Al_2O_3$ nano-crystal structure single gas barrier layer is suitable for OLED application.

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Evaluation of Purification Efficiency of Passive Treatment Systems for Acid Mine Drainage and Characterization of Precipitates in Ilwal Coal Mine (일월탄광에서 유출되는 산성광산배수 자연정화시설의 정화 효율 평가 및 침전물의 특성연구)

  • Ryu, Chung Seok;Kim, Yeong Hun;Kim, Jeong Jin
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.2
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    • pp.97-105
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    • 2014
  • Artificial precipitation ponds, consisting of three steps of oxidation pond, successive alkalinity producing system (SAPS) and swamp, were constructed for the treatment of the acid mine drainage from the Iwal coal mine. The efficacies of the passive treatment system in terms of neutralization of mine water and removal of dissolved ions were evaluated by the chemical analyses of the water samples. Mine water in the mine adits was acidic, showing the pH value of 2.28-2.42 but the value increased rapidly to 6.17-6.53 in the Oxidation pond. The purification efficiencies for the removal of Al and Fe were 100%, whereas those of $SO_4$, Mg, Ca, and Mn were relatively low of 50%, 40%, 24%, and 59%, respectively. These results indicate a need for application of additional remediation techniques in the passive treatment systems. The precipitates that formed at the bottom of the mine water channels were mainly schwertmannite ($Fe_8O_8(OH)_6SO_4$) and those in the leachate water were 2-line ferrihydrite ($Fe_2O_3{cdot}0.5H_2O$).

Determination of Adequate Method for Protein Extraction from Rice Bran and the Substitution of Dried Skim Milk with Protein Concentrate from Rice Bran in Early Weaned Pigs

  • Phipek, W.;Nagasinha, C.;Vallisuth, S.;Nongyao, C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.9
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    • pp.1268-1273
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    • 2011
  • The present study was conducted to determine a feasible method of protein concentrate extraction from rice bran (RBPC) and its effect as a substitution for skim milk in early weaning pig diets. An investigation to extract protein concentrate from full fat rice bran was undertaken to determine the best ratio of water and rice bran, the amount of NaOH and a HCl solvent to use in a simple paddle-type mixer with modified spinning to produce RBPC. The results stated that the best ratio for water mixing in the RBPC extraction process was 1:5 with 20 g NaOH and 30 min in a paddle-type mixer at 300 rpm. A mix of 250 ml 0.2 N HCl was optimum for neutralization and protein precipitation. After the fluid was spun out with a washing machine, the sediment was left for 12-14 hours to complete the filtration. One kilogram of rice bran could produce an average of 324.5 gram RBPC and it contained 3.40% ash, 496.48 kcal of GE/100 gram, 1.94% crude fiber, 28.20% ether extract, 7.64% moisture and 16.66% crude protein, respectively. A total of 45 crossbred piglets, weaned at 3 weeks of age were allotted into control diet (A) and dietary treatments formulated with a four different rates of RBPC substitution for skim milk at a percentage of 25 (B), 50 (C), 77 (D) and 100 (E) respectively, in a randomized complete block (RCB) design. All piglets had free access to feed and water until 8 week of age when the experiment ended. Feed intake, average daily gain, growth rate and feed efficiency were not affected by dietary treatments. Blood test parameters after completion of the growth trial indicated normal health. Even though the mean of cell hemoglobin concentration was significantly different between treatments (p<0.05) it was still within the normal range. The cost difference for BW gain of 100% RBPC substituted for skim milk in the weaning diet was approximately 35% lower than that of the control and the relative cost of production was 96.67, 92.85, 70.75 and 64.48% lower for the replacement of 25, 50, 75 and 100% of skim milk respectively. These results implied that this technology is feasible for use by small scale farmers to improve their self-reliance.

An Ecological Interpretation on Korean Traditional Dwelling Houses and Their Landscape Gardens (전통주택과 조경공간의 생태학적 해석 - 동계(桐溪) 정온(鄭蘊) 가옥과 전주(全州) 최씨(崔氏) 종택을 중심으로 -)

  • So, Hyun-Su
    • Journal of the Korean Institute of Landscape Architecture
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    • v.37 no.1
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    • pp.120-130
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    • 2009
  • This study focuses on the methodology of an ecological interpretation of Korean traditional landscapes through both life-oriented philosophy and traditional Korean philosophy which are similar to ecology. Also, useful tools for discovering an ecological technique of formation based on the ecological thoughts in ancestors' life are shown. Ecological key words as interpretative tools on the traditional landscape replaced ecological concepts in Korean culture and landscape. There are 'Bonsung(本性; the original nature)', 'Chungjeol(中絶; moderation)', 'Hyoyul(效率; efficiency)', 'Sangsaeng(相生; symbiosis)', 'Jasaeng(自生; self-generation)', 'Chunghwa(中和; neutralization)', 'Bangtong(旁通; communication)', and 'Byuntong(變通; variableness)'. For the case study, the concepts of 'spatial structure', 'constructive elements in the traditional gardens', and 'structural elements in the dwelling houses' were extracted from $\ulcorner$Imwonkyeongjeji$\lrcorner$ as an interpretative subject. As a result, Jeongon house, Jongtaek of Choi's family(the first incoming resident) showed us an ecological technique of formation by interpretation on the composing elements. Namely, they are natural dwelling houses in harmony with natural conditions and delicate relational styles. Five kinds of ecological characteristics were exposed. They are: 1. land use method following natural features('本性' '相生' '中和'), 2. physical and spatial elements in a body with nature('中絶' '相生' '中和'), 3. sustainable circulation system by recycling limited resources('效率' '自生' '旁通'), 4. use of natural materials based on the regional climate ('中絶' '效率' '自生') and 5. plane and structural decision by microclimate('效率' '自生' '變通'). Consequently, the dwelling houses and their traditional gardens aimed at the consuming space of the efficient resources by utilizing and circulating natural energy more than different types of the traditional spaces.

The Effects of the Residual Ba and Zr on the Acid Pickling in Case of the Recovering of Zr in Pickling Waste Acid through the BaF2 Precipitation Process (BaF2 침전 공정을 통한 폐산세정액 내 Zr 회수 시 잔존 Ba 및 Zr이 산세정에 미치는 영향)

  • An, Chang Mo;Choi, Jeong Hun;Han, Seul Ki;Park, Chul Ho;Kahng, Jong Won;Lee, Young Jun;Lee, Jong Hyeon
    • Resources Recycling
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    • v.26 no.5
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    • pp.97-104
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    • 2017
  • Nuclear fuel cladding tubes are manufactured through pilgering and the annealing process. In order to remove the oxidized layer and impurities on the surface of the tube, a pickling process is required. Zirconium (Zr) is dissolved in a HF and $HNO_3$ acid mixture during the process and the pickling waste acid, including the dissolved Zr, is completely discarded after neutralization. This study observes the effects of the residual impurities (Ba) in the pickling solution regenerated from the $BaF_2$ precipitation process on the waste pickling solution. In addition, the concentration of Ba and Zr for the actual nuclear fuel cladding tube process was optimized. The regenerated pickling solution was tested through a pilot plant pickling process device that simulates the commercial pickling process of nuclear fuel cladding tubes, and the pickling efficiency was analyzed through AFM analysis of the roughness of the cladding tube surface.

Protein Quality Evaluation and Effect of Plasma Lipid Contents of Acid Hydrolysates of Cocoon inn Rats Fed by High Cholesterol, High Triglyceride and High Sucrose Diet (누에고치 산 가수분해물의 단백질의 질적 평가와 고콜레스테롤, 고지질, 고당질식이 흰쥐의 혈장지질에 미치는 영향)

  • 황은희;강병기;김복량;이형자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.5
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    • pp.1004-1009
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    • 2001
  • Acid hydrolysates of cocoon was gained by acid hydrolysis of 2 N HCl, 11$0^{\circ}C$, 48 hours, neutralization and desalting from the cocoon. The amino acid compositions of acid hydrolysates of cocoon were glycine 43.25%, alanine 34.39%, serine 10.05% and valine 2.44%. The contents of essential amino acid was 10.05%. Food efficiency ratio of acid hydrolysates of cocoon group was equal to the reference protein, casein. Liver weight, GOT, GPT activity, serum albumin and serum total protein level of rats were not significantly different among the experimental groups. Therefore, the protein acid hydrolysates of cocoon is not of high quality. When the rat fed with high cholesterol, high lipid, and high sucrose diet was administered with 5% acid hydrolysates of cocoon, its plasma lipids concentration of acid hydrolysates of cocoon was favorably affected: its triglyceride was decreased, and the level of phospholipid and HDL cholesterol were increased. There was also an unfavorable effect: the levels of LDL cholesterol and total cholesterol went up. Therefore, the acid hydrolysates of cocoon is not a good protein food source, but is can be used a cosmetic, medical, or packing material. Further research will reveal how it will affect or improve plasma lipid.

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Behavior of Synthetic Layered Double Hydroxides in Soils (인공합성된 Layered Double Hydroxides의 토양중 행동)

  • Choi, Choong-Lyeal;Seo, Yong-Jin;Lee, Dong-Hoon;Kim, Jun-Hyeong;Yeou, Sang-Gak;Choi, Jyung;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.5
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    • pp.412-417
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    • 2007
  • This study was to elucidate the effects of layered double hydroxides(LDHs) application on the chemical properties of the soils along with the fate of the applied LDHs. The effects of LDHs application were compared with those of calcium carbonate widely used for the neutralization of acidic soils. Incorporation of LDHs into the soil resulted in higher pH value and $Mg^{2+}$ content in soil leachate than that of $CaCO_3$ treatment. There was no significant difference in water-soluble P content in both the treatments. However, $Al^{3+}$ and $Si^{4+}$ contents were decreased by LDHs and $CaCO_3$ treatment, even though a large amount of $Al^{3+}$ was released into soil solution with the disintegration of LDHs framework. LDHs structure in soil was gradually disintegrated from the its original layered structure under acidic condition of soil. Therefore, this study suggests that LDHs could be utilized as a carrier of functional substances to enhance the efficiency of various ago-chemicals without any ill effects on the soil environments.

Removal Efficiency of Ammonia and Toluene using Mobile Scrubber (이동형 스크러버를 이용한 암모니아 및 톨루엔의 제거 효율)

  • Kim, Jae-Young;Kim, Jang-Yoon;Lee, Yeon Hee;Kim, Min Sun;Kim, Min-Su;Kim, Hyun Ji;Ryu, Tae In;Jeong, Jae Hyeong;Hwang, Seung-Ryul;Kim, Kyun;Lee, Jin Hwan
    • Korean Journal of Environmental Agriculture
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    • v.37 no.1
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    • pp.49-56
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    • 2018
  • BACKGROUND: The mobile vortex wet scrubber was developed to remove the harmful chemicals from accidental releases. However, there was a disadvantage that it was limitedly used for volatile organic compounds (VOCs) such as toluene according to the physicochemical properties. This study compared the removal efficiencies of an improved mobile scrubber on toluene and ammonia by applying diverse adsorption and absorption methods. METHODS AND RESULTS: The removal efficiencies on harmful chemicals were examined using various adsorption and absorption methods of water vortex process (C), phosphoric acid-impregnated activated carbon adsorption (PCA), pH-controlled water (pH 2.5) vortex process absorption with sulfuric acid (SWA) after ammonia exposure, granular activated carbon adsorption (GCA), and activated carbon mat adsorption (CMA) after toluene exposure. As a result, the best removal efficiency was shown in the SWA for ammonia and GCA for toluene. Also, the SWA and GCA methods were compared with different concentration levels. In the case of ammonia exposure (5, 10 and 25%), there was no difference by concentration levels, and the concentration in the outlet gradually increased, with pH change from acid to base. In the case of toluene exposure (50, 75 and 100%), the outlet concentration was higher relative to the exposure concentration in the initial 10 min, but the outlet concentration was remained steady after 10 min. CONCLUSION: The newly improved mobile scrubber was also effective in removing VOCs through adsorption techniques (activated carbon, activated carbon fiber, carbon mat filter etc.), as well as removing acid-base harmful chemicals by neutralization reaction.

Effects of Dietary Supplementation of Lysine Cell Mass as a Fish Meal Replacer in Juvenile Nile Tilapia (치어기 틸라피아에 있어 사료내 어분 대체원으로서 라이신 부산물의 첨가효과)

  • 김강웅;이진영;배승철;이희석
    • Journal of Aquaculture
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    • v.14 no.3
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    • pp.197-203
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    • 2001
  • To replace fish meal (FM) in the diet of Nile tilapia, Oreochromis nloticus, different levels of Iysine cell mass (LCM) were added to diet on protein equivalent base. fish averaging 3.0 g fed one of nine diets containing isonitrogenous and isocaloric basis of 35% crude protein and 15.3kJ available energy/g diet: $LCM_0, 100% FM: LCM_{10}, 90% FM+10% LCM, LCM_{20}, 80% FM+20% LCM; LCM_{30}, 70% FM+30% LCM; LCM_{40}, 60% FM+40% LCM; LCM_{30}l, 70% FM+30% LCM+lysine; LCM_{30}ln, 70% FM +30% LCM + lysine +NaOH; LCM_{40}lan, 60% FM+40% LCM+lysine+arginine; LCM_{40}/lan, 60% FM+40% LCM+lysine+arginine+NaOH.$. After 8 weeks of feeding trial, there were no significant differences in weight gain (WG) and specific growth rate (SGR) among fish fed LCM$_{0}$ (control diet), LCM_{10}, LCM_{30}, LCM_{40}, LCM_{30}l, LCM_{30}ln, LCA_{40}la and LCM_{40}lan diets (P>0.05)$, while fishes fed $LCM_{20} diet were significantly higher than those fed LCM_{0}, LCM_{30}, LCM_{40}, LCM_{40}la and LCM_{40$}lan diets (P<0.05). There were no significant differences in feed efficiency (FE) and protein efficiency ratio (PER) among fish fed control diet, $LCM_{10}, LCM_{20}, LCM_{30}ln, LCM_{ 40}la and LCM_{40}$lan diets (P>0.05), while fishes fed control diet were significantly higher than those fed $LCM_{30}, LCM_{40} and LCM_{40}l diets (P<0.05)$. Positive effects were not shown in WG and SGR with supplementation of amino acids (lysine & arginine) and neutralizatio, while FE and PER from fish fed $LCM_{40}la and LCM_{40}lan diets were significantly higher than those fed LCM_{30}, LCM_{40} and LCM_{30}$l diets (P<0.05). Hence, LCM can replace FM up to 40%, and dietary suppl-ementacon and neutralization of amino acids showed positive effects, when FE and PER were considered in juvenile tilapia diet.

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