• Title/Summary/Keyword: nematic mixtures

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Chemical Characteristics of Liguid Crystals and Its Applicability (액정의 화학적성질과 응용의 가능성)

  • 김준용
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.10 no.3
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    • pp.10-22
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    • 1973
  • Recently, nematic and nematic-cholesteric mixtures of substances have been discovered which have stimulated progress in electronics research and industry. In the liquid crystalline state, compounds with nematic mesopheses possess the ability to scatter light, depending on the strength of an applied electric field. The rewaking of interest in this fascinating but long-neglected area has occasioned the introduction of the subjects at the situation of the chemists. Since 1888 year, approximately 2000 compounds have been found to possess the unusual properties of what are commonly referred to as liquid crystals. In this paper, a comprehensive review will not be attempthed here. Nevertheless, some general information necessary to familarize the reader with rather exotic field will facilitate an understanding of the new effect and its application.

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The Novel Liquid Crystal Materials for AM-LCDs

  • Yamaguchi, T.;Kibe, S.;Matsui, S.;Yamamoto, H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.924-929
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    • 2002
  • We have developed the novel liquid crystal materials with a difluoromethyleneoxy (CF2O) moiety as a linkage group in order to satisfy the diversified various requirements for AM-LCDs. These novel CF2O LC materials have excellent physical properties that are high dielectric anisotropy, low viscosity and wide nematic temperature ranges. Physical properties measurement results that mixtures containing CF2O LC materials have suitable for characteristics for AM-LCDs. The CF2O LC materials are excellent compound for quick response and low driving voltage application.

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Novel Liquid Crystal Compounds and Its Mixtures for VA-TFT-LCD TV Application

  • Kim, Y.B.;Roh, S.D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.471-474
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    • 2002
  • Three-ring types liquid crystalline compounds having fluoro and isothiocyanate substituent were synthesized and their physical and electro-optical properties were measured to evaluate the applications to active matrix VA liquid crystal displays. The tetrakis(triphenylphosphine)palladium(0) catalyzed cross coupling of aryl boronic acids with aryl halides is used to prepare trans-4'-Alkoxy-2,3-difluoro-3'-isothiocyanato-4-(4-alkylcyclohexyl}-biphenyl series. The synthesized compounds showed the nematic liquid crystalline phase and the negative dielectric anisotropy. The prepared mixtures showed faster response time and lower threshold voltage than their host mixture.

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Synthesis and Physical Properties of Novel Fluorinated Liquid Crystalline Compounds

  • Keum, Hye-Won;Roh, Su-Dong;Do, Yun-Sun;Lee, Jae-Ho;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1142-1146
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    • 2004
  • The synthetic route and physical properties for three-ring derivatives, trans-2,3,2',3'-tetrafluoro-4-alkyl-4'-(4-alkyl-cyclohexyl)-biphenyl and 4-alkyl-cyclohexane carboxylic acid 2,3,2',3',4'-pentafluoro-biphenyl-4-yl ester are presented. They exhibit broad range nematic phases exceeding 30K and low viscosity of nematic liquid crystal mixtures containing these materials. Their viscosity is compared with that of homologues with a lateral isothiocyanate group and show large negative dielectric anisotropies. The threshold voltage $V_{th}$ was low enough to be operated at a driving voltage of 5V. Our novel LC compounds are suitable materials for the improvement of dielectric anisotropy of vertical align liquid crystal displays (VA-LDCs).

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Dielectric and Electro-Optical Properties of Ceramic Nanoparticles Doped Liquid Crystals

  • Porov, Preeti;Chandel, Vishal Singh;Manohar, Rajiv
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.2
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    • pp.69-78
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    • 2016
  • Liquid crystals are important materials because of their applications in display technology and many other scientific applications. Different mixtures of liquid crystals and their doped samples have gained interest because a single liquid crystal compound cannot fulfill all the required parameters for the display application. The doping can be accomplished with dyes, polymers, or composite nanoparticles among other substance. The addition of nanoparticles can modify the physical properties of the host liquid crystal and enhances the performance of electro-optical devices. The present study is focused on investigations of possible changes in dielectric and electro optical properties of liquid crystals caused by doping with ceramic nanoparticles. Including smaller nanoparticles were found to be better candidates for use in suppressing the unwanted ion effects in liquid crystal displays.

Low Power Consumption in Twisted Nematic Mode Using Novel Liquid Crystal Mixture

  • Jeon, Sang-Youn;Song, In-Bum;Hong, Sung-Ho;Lee, Dong-Jin;Choi, Hyun-Chul;Park, Man-Hyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.337-339
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    • 2008
  • Recently, Note PCs have being widely used due to their features such as good mobility and low power consumption. In order to ensure the current market position, further improvement is required. Especially, the lower operating voltage is essential for the long operating time of Note PCs. For the achievement of lower operating voltage, possible contributions from LC materials side are to lower the viscosity and to increase the dielectric constant without sacrificing the reliability. In order to achieve lower driving voltage, new LC mixtures have been developed, optimizing theirs physical properties.

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Materials Aspects for fast switchable NLC/FLC Devices

  • Haase, Wolfgang;Bezborodov, Vladimir;Lapanik, Valery;Podgornov, Fedor
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.986-989
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    • 2007
  • In this review, several aspects for improving the quality of materials parameters of Nematic Liquid Crystals (NLCs) and Ferroelectric Liquid Crystals (FLCs) will be discussed. In particular the decrease of the response time is a need. It will be demonstrated that the materials parameters of NLCs and FLCs can be improved among other ways due to optimization of chemical structures of the NLCs and /or FLCs mixtures, due to doping them with nanomaterials and by using fast elastic relaxation processes.

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Electro-optical Properties of Polymer Dispersed Liquid Crysta Displays (고분자 분상형 액정표시소자의 전기광학적 특성 연구)

  • 박우상;고영부;박세근
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.10
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    • pp.885-890
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    • 1998
  • The electro-optical properties of polymer dispersed liquid crystals (PDLCs) depend on dispersion structures and nematic alignment which can be controlled by taking proper liquid crystal/polymer mixtures and process conditions. To achieve excellent electro-optical properties such as low driving voltage, good contrast ratio and negligible hysteresis, we have developed optimization procedure. Under the optimized conditions, PDLC of low threshold voltage less than 3.1 V, high contrast ratio more than 150 and negligible hysteresis were obtained.

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Ionic Conductivities of the LiCF$_3$SO$_3$Complexes with Liquid Crystalline Aromatic Polyesters Having Oligo(oxyethylene) Pendants

  • Lee, Jun-Woo;Joo, Sung-Hoon;Jin, Jung-Il
    • Macromolecular Research
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    • v.12 no.2
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    • pp.195-205
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    • 2004
  • We have synthesized new aromatic polyesters (DiPEG-HQ and DiPEG-BP) by condensation polymerization of a terephthalic acid derivative bearing a pendant oligo(oxyethylene) (DP = 7, MW = 350), which has a methoxy terminal group, and two different aromatic diols, hydroquinone and 4,4'-biphenoI. The synthesized polymers were characterized by differential scanning calorimetry (DSC), polarizing microscopy, and X-ray diffractometry for their liquid crystallinity (LC), thermal transitions, and structural morphologies in mesophases. The morphology of the LC phases depends strongly on the length of the rigid backbone repeating unit. The DiPEG-BP polymer having a longer repeating unit exhibits both layered and nematic structures before isotropization, whereas the DiPEG-HQ polymer having a shorter repeating unit shows only the layered structure in the mesophase. We found that the layer spacing for DiPEG-HQ is larger than that for DiPEG-BP. Both polymers easily form complexes with LiCF$_3$SO$_3$; we studied this complex formation by FT-IR spectroscopy. The layer spacing of the polymer-electrolyte composites increases upon increasing the amount of the lithium salt. The polymer/salt electrolyte mixtures we investigated at molar ratios of EO:salt in the range of 5-20 exhibit electrical conductivity values at 40$^{\circ}C$ of 2.4${\times}$10$\^$5/ and 1.1${\times}$10$\^$-5/ S/cm for DiPEG-HQ/LiCF$_3$SO$_3$ and DiPEG-BP/LiCF$_3$SO$_3$, respectively. At 80 $^{\circ}C$, these values are higher: 4.6${\times}$10$\^$-3/ and 1.1${\times}$10$\^$-4/ S/cm, respectively. The activation energy of conductivity depends strongly on the salt concentration.